The origin and geochemical evolution of the Woodlark Rift of Papua New Guinea

Geochemical, isotopic, and geochronologic data for exhumed rocks in the Woodlark Rift of Papua New Guinea (PNG) allow a tectonic link to be established with the Late Cretaceous Whitsunday Volcanic Province (WVP) of northeastern Australia. Most of the metamorphic rocks in the Woodlark Rift have Nd isotopic compositions (ε_Nd = + 1.7 to + 6.2) similar to the Nd isotopic compositions of rocks in the WVP (ε_Nd = + 1.3 to + 6.6; Ewart et al., 1992), and contain inherited zircons with 90 to 100 Ma U–Pb ages that overlap the timing of magmatism in the WVP. None of the metamorphic rocks in the Woodlark Rift have the highly evolved Hf and Nd isotopic compositions expected of ancient continental crust. Magmas were erupted in the WVP during the middle Cretaceous as eastern Gondwana was rifted apart. The protoliths of felsic and intermediate metamorphic rocks in the Woodlark Rift are interpreted to be related to the magmatic products produced during this Cretaceous rifting event. Some mafic metamorphic rocks exposed in the western Woodlark Rift (eclogites and amphibolites) are not related to the WVP and instead could have originated as basaltic lavas crystallized from mantle melts at (U)HP depths in the Late Cenozoic, or as fragments of Mesozoic aged oceanic lithosphere.Isotopic and elemental comparisons between basement gneisses and Quaternary felsic volcanic rocks demonstrate that felsic lavas in the D'Entrecasteaux Islands did not form solely from partial melting of metamorphic rocks during exhumation. Instead, the isotopic compositions and geochemistry of Quaternary felsic volcanic rocks indicate a significant contribution from the partial melting of the mantle in this region. When combined with geophysical data for the western Woodlark Rift, this suggests that future seafloor spreading will commence south of Fergusson Island, and west of the present-day active seafloor spreading rift tip.     

Late Triassic E-MORB-like basalts associated with porphyry Cu-deposits in the southern Yidun continental arc,eastern Tibet: Evidence of slab-tear during subduction?

It is generally believed that andesite–dacite–rhyolite suites and contemporary porphyry Cu deposits are related to subduction in active continental margin settings. However, it is still unclear which tectonic events result in the generation of porphyry Cu deposits and whether asthenospheric mantle material is involved in this process. Widespread andesitic–dacitic felsic intrusions associated with porphyry Cu deposits and rarer basalts have been identified in the Late Triassic southern Yidun arc (SYA) of eastern Tibet. However, few geochronological and geochemical data are available for these basalts, thereby hampering the development of geodynamic models for this magmatic event and the formation of related porphyry Cu deposits in the region. Here we present the first geochemical and SIMS (secondary ion mass spectrometry) zircon U–Pb data of Xiaxiaoliu basalts in the SYA. The age of the Late Triassic Xiaxiaoliu basalts (216.1 ± 2.8 Ma) is consistent with the timing of emplacement of voluminous porphyritic intrusions and the formation of Cu deposits within the SYA (peaking at 215–217 Ma). The Xiaxiaoliu basalts have E-MORB-like trace element patterns that are free of negative Nb–Ta anomalies, and have high ¹⁴³Nd/¹⁴⁴Nd_(t) values, suggesting they were sourced from asthenospheric mantle without any arc-type influence. These observations, combined with the fact that some Late Triassic mineralized porphyritic intrusions within the SYA have adakitic affinities, suggest that the basalts and other igneous rocks and associated porphyry Cu deposits within the SYA were produced by tearing of a westward-dipping slab, triggering the upwelling of asthenospheric mantle material during subduction of the Garze–Litang Ocean crust.     

Geochemistry and petrogenesis of Permian ultramafic-mafic complexes of the Jinping–Song Da rift (southeastern Asia)

The Jinping–Song Da rift structure in the Emeishan Large Igneous Province is composed of Permian high- and low-Ti volcanic and volcanoplutonic ultramafic-mafic associations of different compositions and genesis. High-Ti picrites, picrobasalts, basalts, and dolerites are enriched in LREE and depleted in HREE and show low Al₂O₃/TiO₂ ratios (~4), commensurate ε_Nd(T) values (+0.5 to +1.1), and low (Th/Nb)_PM ratios similar to those of OIB-enriched mantle source. The established geochemical characteristics evidence that the parental melts of these rocks were generated from garnet lherzolite at the depths of garnet stability (~200 to 400 km). Later, high-Mg low-Ti volcanics (komatiites, komatiitic basalts, and basalts) and associating small peridotite-gabbro massifs and komatiite-basalt dikes were produced as a result of ~20% partial melting of depleted water-poor (≤0.03 wt.% H₂O) peridotite substratum from the hottest upper part of mantle plume at relatively shallow depths (100–120 km). The LREE-depleted komatiites and komatiitic basalts are characterized by low (Ce/Yb)_CH values, ¹⁸⁷Re/¹⁸⁸Os = 0.05–1.2, ⁸⁷Sr/⁸⁶Sr = 0.704–0.706, positive ε_Nd(T) values (+3 to +8), γ_Os = –0.5 to +0.9, and strong negative anomalies of Ba, K, and Sr on the spidergrams. The scarcer LREE-enriched komatiites, komatiitic basalts, and basalts vary greatly in chemical composition and values of ε_Nd(t) (+6.4 to –10.2), ⁸⁷Sr/⁸⁶Sr (0.706–0.712), and γ_Os (+14.8 to +56), which is due to the different degrees of crustal contamination of parental magmas. The Rb-Sr isotopic age of basaltic komatiite is 257 ± 24 Ma. The Re-Os age determined by analysis of 12 komatiite samples is 270 ± 21 Ma. These data agree with the age of flood basalts of the Emeishan Large Igneous Province. The komatiite-basalt complex of the Song Da rift is still the only Phanerozoic PGE-Cu-Ni-complex of this composition. The geochemistry of accompanying Cu-Ni-PGE-ores confirms their relationship with komatiite-basaltic magmatism.     

U–Pb zircon geochronology and geochemistry from NE Vietnam: A ‘tectonically disputed’ territory between the Indochina and South China blocks

Volcanoplutonic complexes in NE Vietnam have recently been interpreted as intraplate products of the Emeishan plume. Alternatively, mafic–ultramafic rocks have been considered as dismembered Palaeotethyan ophiolites juxtaposed along a tectonic mélange zone. New U–Pb zircon geochronological and geochemical datasets presented here suggest a complex geological history that records collision between the Indochina–South China blocks. Mafic–ultramafic rocks exposed within a tectonic mélange (Song Hien Tectonic Zone) include sub-alkaline pillow basalts that define two geochemically distinct ophiolitic suites (SH-1: N-MORB-like, SH-2: transitional E-MORB-like). Both suites have geochemical signatures suggestive of crustal contamination, compatible with a volcanic passive margin/rift setting. We suggest that SH-1 basalts may correlate with the Devonian–Carboniferous Jinshajiang–Ailaoshan–Song Ma branch of the Palaeotethys and form part of the associated Dian–Qiong belt, whereas SH-2 basalts are co-magmatic with Middle–Late Permian mafic–ultramafic intrusive rocks (dolerites, gabbros, peridotites) that developed in a rift basin, most likely on the margin of the down-going South China plate during west-vergent subduction beneath Indochina. During continental orogenesis and thrust stacking, these ophiolitic rocks were juxtaposed with other lithotectonic blocks within the Song Hien Tectonic Zone. Post-collisional relaxation led to the development of a rift basin (Song Hien rift) comprising Late Permian–Triassic volcano-sedimentary strata including < 270–265 Ma terrigenous sandstones, < 252 Ma mudstones, and c. 254–248 Ma felsic effusives. Granites and granodiorites were emplaced across NE Vietnam between c. 252 and 245 Ma in a syn- to post-collisional setting. The Late Permian–Early Triassic felsic magmatic rocks best correlate with coeval rocks in SW Guangxi and the Central and Western Ailaoshan fold belts (China) and the Truong Son fold belt (Vietnam); together they signal the final to post-collisional stages of Indochina–South China collision. We demonstrate that the analysed magmatic rocks in the Lo-Gam–Song Hien domains of NE Vietnam are not genetically linked to the Emeishan Large Igneous Province in the Yangtze block of South China, as has been previously widely proposed.     

Petrogenesis of Carboniferous adakites and Nb-enriched arc basalts in the Alataw area,northern Tianshan Range (western China): Implications for Phanerozoic crustal growth in the Central Asia orogenic belt

Carboniferous volcanic rocks in the Alataw area, Northern Tianshan Range (Xinjiang), consist of early Carboniferous (ca. 320 Ma) adakites and Nb-enriched arc basalts and basaltic andesites (NEBs), and late Carboniferous (ca. 306–310 Ma) mainly high-K calc-alkaline andesites, dacites and rhyolites. The adakites are calc-alkaline, and characterized by high Na₂O/K₂O (1.52–3.32) ratios, negligible to positive Eu anomalies, strong depletion of heavy rare earth elements (e.g., Yb = 0.74–1.47 ppm) and Y (6.7–14.9 ppm), positive Sr and Ba but negative Nb and Ti anomalies, and relatively constant ε_Nd(T) values (+ 3.4–+ 6.6) and (⁸⁷Sr/⁸⁶Sr)_i ratios (0.7035–0.7042). Some andesitic and dacitic adakite samples exhibit high MgO contents similar to magnesian andesites. The NEBs are sodium-rich (Na₂O/K₂O = 2.03–8.06), and differ from the vast majority of arc basalts in their higher Nb, Zr, TiO₂ and P₂O₅ contents and Nb/Th, Nb/La and Nb/U ratios, and minor negative to positive anomalies in Ba, Nb, Sr, Zr and Ti. They have the highest ε_Nd(T) values (+ 6.4–+ 11.6) but varying (⁸⁷Sr/⁸⁶Sr)_i ratios (0.7007–0.7063). The high-K calc-alkaline suite is similar to typical ‘normal’ arc volcanic rocks in terms of moderately fractionated rare earth abundance and distinctly negative Eu, Nb, Sr and Ti anomalies. They have ε_Nd(T) values (+ 1.2–+ 6.4) and (⁸⁷Sr/⁸⁶Sr)_i ratios (0.7018–0.7059). Geochemically, they are similar to coeval I-type granitoids in the Alataw area. Given the presence of early Carboniferous ophiolites in the Northern Tianshan Range, and the isotopically inappropriate compositions of Proterozoic metamorphic basement in the Alataw area, we argue that the Alataw adakites were most probably related to the melting of young subducted crust of the Northern Tianshan Ocean. The NEBs likely originated from mantle wedge peridotites metasomatized by adakites and minor slab-derived fluids. The later high-K calc alkaline suite was generated by AFC processes that acted on melts derived from a mantle wedge metasomatized by hydrous fluids. The larger range of isotopic compositions exhibited by both the NEB and high-K suite, relative to the adakites, suggests that the mantle wedge was heterogeneous prior to slab- or fluid-mediated metasomatism.Continental crustal growth of the Central Asian orogenic belt was dominated by contributions of the juvenile materials from the depleted mantle prior to 270 Ma and possibly afterwards. The results of this study suggest that other Carboniferous Nb-enriched basalts in the Tianshan Range were generated by subduction processes rather than by intraplate tectonics as previously proposed.     

Sources and petrogenesis of Jurassic granitoids in the Yusufeli area,Northeastern Turkey: Implications for pre- and post-collisional lithospheric thinning of the eastern Pontides

Small granitoids emplaced into the early Jurassic volcani-clastic succession in the Yusufeli area, northeastern Turkey, can be temporally and geochemically classified into two groups: early Jurassic low-K and late Jurassic high-K. ⁴⁰Ar–³⁹Ar hornblende analyses yielded 188.0 ± 4.3 Ma for the Dutlup?nar intrusion, dating the subduction related rifting in the region. It comprises metaluminous to weakly peraluminous (ASI = 0.94–1.11) granodiorite and, to a lesser extent, tonalite whose K₂O-poor (< 2.04 wt.%) nature and weak negative Eu anomalies (Eu/Eu? = 0.9–0.7) preclude derivation by fractional crystallization from a K-rich melt. Sr, Nd and Pb isotopic data reveal derivation by partial melting from an already cooled tholeiitic basic rocks which had mantle-like isotope signature. The Sumbated intrusion formed in the late Jurassic (153.0 ± 3.4 Ma) and consists chiefly of metaluminous (ASI = 0.84–0.99) quartz monzodiorite. Medium to high-K₂O, relatively high MgO and Sr contents, flat HREE patterns without prominent Eu anomalies, slightly positive ε_Nd(t) values (+ 1.5 to + 2.5) and low I_Sr ratios (0.7046–0.7056) are consistent with an origin by dehydration melting of a juvenile source, above the garnet stability field, dominated by likely K-amphibole bearing calc-alkaline mafic rocks. Geochemical data show that fractional crystallization from a Sumbated-like quartz monzodioritic magma is the fundamental process responsible for the evolved compositional range of the Keçikaya intrusion. The geochemical and geochronological data presented here indicate that the late Jurassic magmatism occurred in a post-collisional setting. Slab-breakoff, which was followed by shortly after collision, seems to be the most plausible mechanism for the generation of medium to high-K calc-alkaline rocks of the Sumbated and the Keçikaya intrusions, indicating a switch in the geodynamic setting, e.g., from pre-collision to post-collision in the middle Jurassic in the eastern Pontides.     

Characterisation of Triassic rifting in Peru and implications for the early disassembly of western Pangaea

Triassic igneous and sedimentary rocks exposed within the basement of the Andes were deposited in a series of rifts, and may record the early disassembly of western Pangaea. These rocks are sporadically exposed along almost the entire length of western South America, although reliable geochronological and isotopic data are sparse. We combine new geochronological (zircon U–Pb), isotopic (Hf, Nd) and geochemical data with stratigraphic observations to constrain the age and tectonic setting of the Mitu Rift of southern Peru. The Peruvian Mitu Rift is compared with other Triassic rifts in Colombia and Ecuador (Palanda Rift; 240–225 Ma), Bolivia (Mitu Rift; Triassic), Bolivia, Chile and Argentina (e.g. Cuyo Basin; 246–230 Ma), and conclusions are reached regarding the relationship between Triassic extension along the western margin of Pangaea, and the eventual formation of the Proto-Caribbean and Central Atlantic oceans. The Mitu Rift (Peru) was active during ~ 245–240 to ~ 220 Ma and was synchronous with rifting along the Pacific margin of Colombia and Ecuador, along the Chilean margin and western Argentina, and probably rifting within Bolivia. Rifting north of the Huancabamba Deflection was accompanied by subduction and led to seafloor spreading, whereas rifting along the Peruvian and Chilean margins mainly occurred in the absence of subduction and terminated prior to the formation of extensive transitional crust. Extension within Peru and Chile probably occurred via a combination of transtension, steepening and detachment of an arrested slab. We propose that plate tectonic forces initiated the early break-up of Pangaea by attenuating its margins and enhancing mantle upwelling. Prolonged extension may have propagated along pre-existing weak zones that extended into the continental interior, captured melts derived from the upwelled mantle forming a LIP (e.g. Central Atlantic Magmatic Province), became hot and weak and eventually lead to the formation of a juvenile ocean (e.g. Central Atlantic).     

Tectono-sequence stratigraphy and U–Pb zircon ages of the Rincón Blanco Depocenter,northern Cuyo Rift,Argentina

Extensional processes that followed the Gondwanan Orogeny rise to the development of a series of rift basins along the continental margin over older accreted Eopaleozoic terranes. Stratigraphic, structural, paleontological, and isotopic studies are presented in this work in order to constrain the ages of the sedimentary infilling and to analyze the tectosedimentary evolution of one of the Cuyo basin depocenters, known as Rincón Blanco. This asymmetrical half-graben was filled by continental sediments under a strong tectonic control. The infilling was strongly controlled by tectonics which in term produced distinctive features along the whole sedimentary sequence. Using a combination of lithological and structural data the infilling was subdivided into packages of genetically linked units bounded by regional extended surfaces. Several tuffs and acid volcanic rocks have been collected across the whole section of the Rincon Blanco sub-basin for SHRIMP and LA-MC-ICPMS U–Pb zircon dating. The ages obtained range from 246.4 ± 1.1 Ma to 230.3 ± 1.5 Ma which is the time elapsed for the deposition of three tectono-sequence units separated by regional unconformities and mainly constrained to the Middle Triassic. They are interpreted as a result of a reactivation of the extensional system that has evolved along strike as segments of faults that linked together and/or as laterally propagating faults. Regional correlation with coeval rift basins permits to establish north-south propagation in the extensional regime along the western margin of SW Gondwana. This trending started in the lowermost Triassic and extended until the latest Triassic. Two of them were precisely correlated with Cerro Puntudo and Cacheuta half-graben systems. The new data indicate that the three sequences were mostly deposited during the Middle Triassic (246 to 230 Ma), with no evidence of sedimentation during Norian and Rhaetian, which is in conflict with some previous biostratigraphic studies.     

Changing compositions in the Iceland plume; Isotopic and elemental constraints from the Paleogene Faroe flood basalts

Elemental and Sr, Nd, Hf and high precision Pb isotopic data are presented from 59 low-Ti and high-Ti lavas from the syn-break up part of the Faroe Flood Basalt Province. The depleted MORB-like low-Ti lavas erupted in the rift zone between the Faroe Islands and central East Greenland around the time of break up of the North Atlantic have isotopic end-member compositions different from the depleted Iceland lavas. We suggest that the main low-Ti mantle component is NAEM (North Atlantic End-Member (Ellam and Stuart, 2000, J. Petrol. 41, 919) and that the ²⁰⁷Pb/²⁰⁴Pb value of the component should be 15.35 and ε_Hf = + 16.5. NAEM is the main depleted component in the early Iceland plume. This is supported by high mantle potential temperatures (up to 1550 °C) calculated for the source of the low-Ti basalts. The unique mantle isotopic composition of NAEM with low ²⁰⁶Pb/²⁰⁴Pb (17.5) and Δ7/4Pb (? 3.8) precludes a derivation from recycled MORB lithosphere. Instead we suggest that NAEM represents a plume component of recycled depleted Archean lithospheric mantle that was further depleted ~ 500 Ma ago, possibly in connection with the recycling process. Two other isotopic end-members are required to explain the variation of the Faroe low-Ti basalts: (1) The Faroe depleted component (FDC), with ⁸⁷Sr/⁸⁶Sr = 0.7025, ε_Nd = + 11, ε_Hf = + 19.5, ²⁰⁶Pb/²⁰⁴Pb = 18.2, ²⁰⁷Pb/²⁰⁴Pb = 15.454 and ²⁰⁸Pb/²⁰⁴Pb = 37.75, which is similar in composition to some Atlantic MORB and is regarded as a local upper mantle source. (2) An enriched EM-type component similar in geochemistry to the Icelandic Öræfajökull lavas. This component is believed to be recycled pelagic sediments in the plume but it can alternatively be a local crustal or lithospheric mantle component. The enriched Faroe high-Ti lavas erupted inland from the rift have isotopic compositions very similar to the enriched Icelandic neo-volcanics and these lava suites apparently share the two enriched plume end-members IE1 and IE2 (Geochim. Cosmochim. Acta 68, 2, 2004). The lack of mixing between high and low-Ti melts at the time of break up, is explained by a zoned plume where only low-Ti sources were present beneath the rift zone surrounded by high-Ti sources on both sides of the rift. The enriched plume components in the high-Ti lava sequences on the Faroe Islands and central East Greenland changed rapidly on a ka-scale which implies, from geophysical modelling, that this area was positioned above the center of the plume, and that the Iceland plume was centered under the Atlantic ridge already from the Paleocene.     

Magmatism-dominated intracontinental rifting in the Mesoproterozoic: The Ngaanyatjarra Rift,central Australia

The Late Mesoproterozoic (1085–1040 Ma) Ngaanyatjarra Rift, previously referred to as the Giles Event, is the dominant component of the Warakurna Large Igneous Province (LIP) that affected much of central and western Australia. This rift is well preserved and provides excellent examples of rift structure at a variety of crustal levels and times in the rift's evolution. Geological knowledge is integrated with geophysical interpretations and models to understand the crustal structure and evolution of this rift. Two phases are identified: an early rift stage (1085–1074 Ma) that is characterised by voluminous magmatism within the upper crust and relatively little tectonic deformation; and a late rift stage that is characterised by tectonic deformation, synchronous with the deposition of a thick pile of volcanic and sedimentary rocks (1074–1040 Ma). Compared to modern rift examples, this rift is unusual in that the crust was thickened by ~ 15 km and overall extension was very limited. However, its structure and evolution are very similar to the near-contemporaneous Midcontinent Rift, which shows the addition of a similar quantity of magmatic material as well as crustal thickening and limited extension. For these Mesoproterozoic rifts, we suggest that magmatism was the dominant process, and that the extension observed was a response to magmatism-induced crustal thickening and the gravitational collapse of the crustal column. Other Proterozoic rifts show similar characteristics (e.g. Transvaal Rift), whereas most Phanerozoic rifts are dissimilar, showing instead a dominance of extension, with magmatism largely a result of this extension. This change in the style of rifting from the Precambrian to the Phanerozoic may relate to the influence of a typically cooler and stronger lithosphere, which has caused stronger strain localisation and a greater role for extension as the controlling factor in rift evolution.     

Petrology of Karoo volcanic rocks in the southern Lebombo monocline,Mozambique

The Karoo volcanic sequence in the southern Lebombo monocline in Mozambique contains different silicic units in the form of pyroclastic rocks, and two different basalt types. The silicic units in the lower part of the Lebombo sequence are formed by a lower unit of dacites and rhyolites (67–80 wt.% SiO₂) with high Ba (990–2500 ppm), Zr (800–1100 ppm) and Y (130–240 ppm), which are part of the Jozini–Mbuluzi Formation, followed by a second unit, interlayered with the Movene basalts, of high-SiO₂ rhyolites (76–78 wt.%; the Sica Beds Formation), with low Sr (19–54 ppm), Zr (340–480 ppm) and Ba (330–850 ppm) plus rare quartz-trachytes (64–66 wt.% SiO₂), with high Nb and Rb contents (240–250 and 370–381 ppm, respectively), and relatively low Zr (450–460 ppm). The mafic rocks found at the top of the sequence are basalts and ferrobasalts belonging to the Movene Formation. The basalts have roughly flat mantle-normalized incompatible element patterns, with abundances of the most incompatible elements not higher than 25 times primitive mantle. The ferrobasalt has TiO₂ ∼ 4.7 wt.%, Fe₂O_3t = 16 wt.%, and high Y (100 ppm), Zr (420 ppm) and Ba (1000 ppm). The Movene basalts have initial (at 180 Ma) ⁸⁷Sr/⁸⁶Sr = 0.7052–0.7054 and ¹⁴³Nd/¹⁴⁴Nd = 0.51232, and the Movene ferrobasalt has even lower ⁸⁷Sr/⁸⁶Sr (0.70377) and higher ¹⁴³Nd/¹⁴⁴Nd (0.51259). The silicic rocks show a modest range of initial Sr-(⁸⁷Sr/⁸⁶Sr = 0.70470–0.70648) and Nd-(¹⁴³Nd/¹⁴⁴Nd = 0.51223–0.51243) isotope ratios. The less evolved dacites could have been formed after crystal fractionation of oxide-rich gabbroic cumulates from mafic parental magmas, whereas the most silica-rich rhyolites could have been formed after fractional crystallization of feldspars, pyroxenes, oxides, zircon and apatite from a parental dacite magma. The composition of the Movene basalts imply different feeding systems from those of the underlying Sabie River basalts.     

Geology,geochronology and geochemistry of granitic intrusions and the related ores at the Hongshan Cu-polymetallic deposit: Insights into the Late Cretaceous post-collisional porphyry-related mineralization systems in the southern Yidun arc,SW China

The Hongshan Cu-polymetallic deposit is located in the southern Yidun arc in southwestern China, where both subduction-related (Late Triassic) and post-collisional (Late Cretaceous) porphyry–skarn–epithermal mineralization systems have been previously recognized. In this study, two distinct magmatic events, represented by diorite porphyry and quartz monzonite porphyry, have been revealed in the Hongshan deposit, with zircon SHRIMP U–Pb ages of 214 ± 2 Ma and 73.4 ± 0.7 Ma, respectively. The 73 Ma age is comparable to the Re–Os ages of 77 to 80 Ma of ore minerals from the Hongshan deposit, indicating that the mineralization is related to the Late Cretaceous quartz monzonite porphyries rather than Late Triassic diorite porphyries. The Late Triassic diorite porphyries belong to the high-K calc-alkaline series and show arc magmatic geochemical characteristics such as enrichment in Rb, Ba, Th and U and depletion in HFSEs, indicating that they were formed during the westward subduction of the Garzê–Litang Ocean. In contrast, the Late Cretaceous quartz monzonite porphyries show shoshonitic I-type geochemical characteristics, with high SiO₂, K₂O, LILE, low HREE, Y and Yb contents, and high LREE/HREE and La/Yb ratios. These geochemical characteristics, together with the Sr–Nd–Pb isotopic compositions (average (⁸⁷Sr/⁸⁶Sr)_i = 0.7085; ε_Nd(t) = − 6.0; ²⁰⁶Pb/²⁰⁴Pb = 19.064, ²⁰⁷Pb/²⁰⁴Pb = 15.738, ²⁰⁸Pb/²⁰⁴Pb = 39.733) suggest that the quartz monzonite porphyries originated from the partial melting of the ancient lower crust in response to underplating of mafic magma from subduction metasomatized mantle lithosphere, possibly triggered by regional extension in the post-collisional tectonic stage. The S isotopic compositions (δ³⁴S_V-CDT = 3.81‰ to 5.80‰) and Pb isotopic compositions (²⁰⁶Pb/²⁰⁴Pb = 18.014 to 18.809, ²⁰⁷Pb/²⁰⁴Pb = 15.550 to 15.785, and ²⁰⁸Pb/²⁰⁴Pb = 38.057 to 39.468) of ore sulfides indicate that the sulfur and metals were derived from mixed mantle and crustal sources. It is proposed that although the Late Triassic magmatic event is not directly related to mineralization, it contributed to the Late Cretaceous mineralization system through the storage of large amounts of sulfur and metals as well as water in the cumulate zone in the mantle lithosphere through subduction metasomatism. Re-melting of the mantle lithosphere including the hydrous cumulate zone and ancient lower crust during the post-collisional stage produced fertile magmas, which ascended to shallow depths to form quartz monzonite porphyries. Hydrothermal fluids released from the intrusions resulted in porphyry-type Mo–Cu ores in and near the intrusions, skarn-type Cu–Mo ores in the country rocks above the intrusions, and hydrothermal Pb–Zn ores in the periphery.     

A LREE-depleted component in the Afar plume: Further evidence from Quaternary Djibouti basalts

Major, trace element and isotopic (Sr, Nd, Pb) data and unspiked K–Ar ages are presented for Quaternary (0.90–0.95 Ma old) basalts from the Hayyabley volcano, Djibouti. These basalts are LREE-depleted (La_n/Sm_n = 0.76–0.83), with ⁸⁷Sr/⁸⁶Sr ratios ranging from 0.70369 to 0.70376, and rather homogeneous ¹⁴³Nd/¹⁴⁴Nd (ε_Nd = + 5.9–+ 7.3) and Pb isotopic compositions (²⁰⁶Pb/²⁰⁴Pb = 18.47–18.55, ²⁰⁷Pb/²⁰⁴Pb = 15.52–15.57, ²⁰⁸Pb/²⁰⁴Pb = 38.62–38.77). They are very different from the underlying enriched Tadjoura Gulf basalts, and from the N-MORB erupted from the nascent oceanic ridges of the Red Sea and Gulf of Aden. Their compositions closely resemble those of (1) depleted Quaternary Manda Hararo basalts from the Afar depression in Ethiopia and (2) one Oligocene basalt from the Ethiopian Plateau trap series. Their trace element and Sr, Nd, Pb isotope systematics suggest the involvement of a discrete but minor LREE-depleted component, which is probably an intrinsic part of the Afar plume.     

Geochronology and geochemistry of submarine volcanic rocks in the Yamansu iron deposit,Eastern Tianshan Mountains,NW China: Constraints on the metallogenesis

The Yamansu skarn iron deposit is hosted in Early Carboniferous submarine lava flow and volcaniclastic rocks of the Yamansu Formation in Eastern Tianshan Mountains, NW China. The lava flows are predominantly basaltic, with minor andesites. Laser ablation inductively coupled plasma mass spectrometry (LAICP-MS) U–Pb zircon dating of the basalts and skarns yields almost coeval ages of 324.4 ± 0.94 and 323.47 ± 0.95 Ma, respectively. The basalts contain clinopyroxene and plagioclase phenocrysts with a considerable amount of Fe–Ti oxide minerals in the groundmass as interstitial phases, probably suggesting that olivine–, clinopyroxene- and plagioclase fractionated within the magma chamber. Geochemically, the basalts are characterized by slight variations in SiO₂ (42.90–46.61 wt.%), P₂O₅ (0.08–0.12 wt.%), MnO (0.35–0.97 wt.%) and TiO₂ (0.74–0.82 wt.%), and relatively large variations in CaO (6.93–15.13 wt.%), Al₂O₃ (14.71–19.93 wt.%), total Fe₂O₃ (8.14–12.66 wt.%) and MgO (4.96–8.52 wt.%). They possess flat to light rare earth element (REE)-depleted patterns and display variable degrees of depletions in high field-strength elements (HFSE), suggesting a transitional feature between MORB and arc volcanic rocks, and indicating a back-arc tectonic setting. Furthermore, the geochemical signature also suggests that the volcanic rocks of Yamansu Formation were produced by partial melting of the spinel-facies, asthenospheric mantle peridotite which had been metasomatized by slab-derived fluids. The broadly overlapping ages of the basalts and skarn mineralization suggests that the skarn formation in the Yamansu deposit is related to subaqueous volcanism. In combination with the available information including fluid inclusions and stable isotope data, we infer that the hydrothermal fluids that generated the skarns could be a mixture of evolved magma-derived fluids and convecting sea water driven by the heat from the shallow active magma chamber. The Yamansu basalts provided the source of iron for the skarn mineralization. We envisage the submarine volcanism, skarn alteration and iron mineralization in the Yamansu iron deposit as a continuous process, different from either conventional intrusion-related skarn type or submarine volcanic exhalation sedimentation type.     

Origin and tectonic setting of the giant Duolong Cu–Au deposit,South Qiangtang Terrane,Tibet: Evidence from geochronology and geochemistry of Early Cretaceous intrusive rocks

We constrain the origin and tectonic setting of the giant Duolong porphyry–epithermal Cu–Au deposit in the South Qiangtang Terrane of northern Tibet, based on new zircon U–Pb ages and Hf isotopic data, as well as whole-rock major and trace element data from poorly studied ore-associated intrusions in the Duolong area. The LA–ICP–MS zircon U–Pb dating indicates that the ore-associated rocks formed between 121 and 126 Ma. These ore-associated rocks are geochemically similar to low-K tholeiitic M-type granitoids and to mid- to high-K, calc-alkaline I-type granitoids. They have variable and predominantly positive zircon ε_Hf(t) values (− 1.4 to + 15.6) and variable crustal model ages (T^C_DM(Hf); 176–1122 Ma). Taking into account previous data and the regional geology of the study area, we propose that the ore-associated rocks originated from fractional crystallization of mantle-derived mafic melts and magma mixing of mantle-derived mafic and hybrid lower crust-derived felsic melts, and the hybrid lower crust included a mix of juvenile and older continental material. The Duolong porphyry–epithermal Cu–Au deposit formed within an ‘ensialic forearc’ of an active continental margin as a result of the northwards subduction of the Bangong–Nujiang Ocean crust beneath the South Qiangtang Terrane.     

Origin of Archean tonalite–trondhjemite–granodiorite (TTG) suites and granites in the Fiskenæsset region,southern West Greenland: Implications for continental growth

Mesoarchean to Neoarchean orthogneisses (2.95–2.79 Ga) in the Fiskenæsset region, southern West Greenland, are composed of an older suite of metamorphosed tonalites, trondhjemites, and granodiorites (TTGs), and a younger suite of high-K granites. The TTGs are characterized by high Al₂O₃ (14.2–18.6 wt.%), Na₂O (3.4–5.13 wt.%), and Sr (205–777 ppm), and low Y (0.7–17.4 ppm) contents. On chondrite- and N-MORB-normalized trace element diagrams, the TTGs have the following geochemical characteristics: (1) highly fractionated REE patterns (La/Yb_cn = 14–664; La/Sm_cn = 4.3–11.0; Gd/Yb_cn = 1.5–19.7); (2) strong positive anomalies of Sr (Sr/Sr* = 1.0–15.9) and Pb (Pb/Pb* = 1.4–34.9); and (3) large negative anomalies of Nb (Nb/Nb* = 0.01–0.34) and Ti (Ti/Ti* = 0.1–0.6). The geochemical characteristics of the TTGs and trace element modeling suggest that they were generated by partial melting of hydrous basalts (amphibolites) at the base of a thickened magmatic arc, leaving a rutile-bearing eclogite residue. Field observations suggest that spatially and temporarily associated tholeiitic basalts (now amphibolites) in the Fiskenæsset region might have been the sources of TTG melts. The high-K granites have steep REE patterns (La/Yb_cn = 3.8–506; La/Sm_cn = 2.7–18.9; Gd/Yb_cn = 0.92–12.1) and display variably negative Eu anomalies (Eu/Eu* = 0.37–0.96) and moderate Sr (84–539 ppm) contents. Four outlier granite samples have variably positive Eu (Eu/Eu* = 1.0–12) anomalies. Given that the granodiorites have higher K₂O/Na₂O than the tonalites and trondhjemites, it is suggested that the granites were derived from partial melting of the granodiorites. It is speculated that the dense eclogitic residues, left after TTG melt extraction, were foundered into the sub-arc mantle, leading to basaltic underplating beneath the lower rust. Melting of the granodiorites in response to the basaltic underplating resulted in the production of high-K granitic melts. Formation of the Fiskenæsset TTGs, the foundering of the eclogitic residues into the mantle, and the emplacement of the high-K granites led to the growth of Archean continental crust in the Fiskenæsset region.     

Crustal and lithospheric thinning beneath the seismogenic Kachchh rift zone,Gujarat (India): Its implications toward the generation of the 2001 Bhuj earthquake sequence

A high-resolution passive seismic experiment in the Kachchh rift zone of the western India has produced an excellent dataset of several thousands teleseismic events. From this network, 500 good teleseismic events recorded at 14 mobile broadband sites are used to estimate receiver functions (for the 30–310° back-azimuth ranges), which show a positive phase at 4.5–6.1 s delay time and a strong negative phase at 8.0–11.0 s. These phases have been modeled by a velocity increase at Moho (i.e. 34–43 km) and a velocity decrease at 62–92 km depth. The estimation of crustal and lithospheric thicknesses using the inversion of stacked radial receiver functions led to the delineation of a marked thinning of 3–7 km in crustal thickness and 6–14 km in lithospheric thickness beneath the central rift zone relative to the surrounding un-rifted parts of the Kachchh rift zone. On an average, the Kachchh region is characterized by a thin lithosphere of 75.9 ± 5.9 km. The marked velocity decrease associated with the lithosphere–asthenoshere boundary (LAB), observed over an area of 120 km × 80 km, and the isotropic study of xenoliths from Kachchh provides evidence for local asthenospheric updoming with pockets of partial melts of CO₂ rich lherzolite beneath the Kachchh seismic zone that might have caused by rifting episode (at 88 Ma) and the associated Deccan thermal-plume interaction (at 65 Ma) episodes. Thus, the coincidence of the area of the major aftershock activity and the Moho as well as asthenospheric upwarping beneath the central Kachchh rift zone suggests that these pockets of CO₂-rich lherzolite partial melts could perhaps provide a high input of volatiles containing CO₂ into the lower crust, which might contribute significantly in the seismo-genesis of continued aftershock activity in the region. It is also inferred that large stresses in the denser and stronger lower crust (at 14–34 km depths) induced by ongoing Banni upliftment, crustal intrusive, marked lateral variation in crustal thickness and related sub-crustal thermal anomaly play a key role in nucleating the lower crustal earthquakes beneath the Kachchh seismic zone.     

Influence of pre-existing fabrics on fault kinematics and rift geometry of interacting segments: Analogue models based on the Albertine Rift (Uganda), Western Branch-East African Rift System

This study aims at showing how far pre-existing crustal weaknesses left behind by Proterozoic mobile belts, that pass around cratonic Archean shields (Tanzania Craton to the southeast and Congo Craton to the northwest), control the geometry of the Albertine Rift. Focus is laid on the development of the Lake Albert and Lake Edward/George sub-segments and between them the greatly uplifted Rwenzori Mountains, a horst block located within the rift and whose highest peak rises to >5000 m above mean sea level. In particular we study how the southward propagating Lake Albert sub-segment to the north interacts with the northward propagating Lake Edward/George sub-segment south of it, and how this interaction produces the structures and geometry observed in this section of the western branch of the East African Rift, especially within and around the Rwenzori horst. We simulate behaviour of the upper crust by conducting sandbox analogue experiments in which pre-cut rubber strips of varying overstep/overlap connected to a basal sheet and oriented oblique and/or orthogonal to the extension vector, are placed below the sand-pack. The points of connection present velocity discontinuities to localise deformation, while the rubber strips represent ductile domain affected by older mobile belts. From fault geometry of developing rift segments in plan view and section cuts, we study kinematics resulting from a given set of boundary conditions, and results are compared with the natural scenario. Three different basal model-configurations are used to simulate two parallel rifts that propagate towards each other and interact. Wider overstep (model SbR3) produces an oblique transfer zone with deep grabens (max. 7.0 km) in the adjoining segments. Smaller overlap (model SbR4) ends in offset rift segments without oblique transfer faults to join the two, and produces moderately deep grabens (max. 4.6 km). When overlap doubles the overstep (model SbR5), rifts propagate sub-orthogonal to the extension direction and form shallow valleys (max. 2.9 km). Relative ratios of overlap/overstep between rift segments dictate the kind of transition zone that develops and whether or not a block (like the Rwenzoris) is captured and rotates; hence determining the end-member geometry. Rotation direction is controlled by pre-existing fabrics. Fault orientation, fault kinematics, and block rotation (once in play) reinforce each other; and depending on the local kinematics, different parts of a captured block may rotate with variable velocities but in the same general direction. Mechanical strength anisotropy of pre-structured crust only initially centres fault nucleation and propagation parallel to the grain of weakness of the basement, but at later stages of a protracted period of crustal extension, such boundaries are locally defied.     

Late Paleozoic subduction system in the southern Central Asian Orogenic Belt: Evidences from geochronology and geochemistry of the Xiaohuangshan ophiolite in the Beishan orogenic belt

The Xiaohuangshan ophiolite of the Beishan (Inner Mongolia) is located in the southern margin of the Central Asian Orogenic Belt. It consists of several blocks composed dominantly of serpentinized ultramafic rocks, cumulative gabbros and basalts. The geochemical data of gabbros and basalts obtained from the Xiaohuangshan ophiolite are similar to tholeiitic rocks. They all have low TiO₂ and high Al₂O₃ contents. Their light rare earth elements are slightly enriched, (La/Yb)_N = 3.62–6.80, similar to the typical enriched mid-ocean ridge basalts. The mafic rocks display enrichments in large ion lithophile elements and depletions in high field strength elements, as well as significant Nb–Ta–Ti negative anomalies, similar to subduction-derived rocks. All these geochemical characteritics indicate that the Xiaohuangshan ophiolite would form in a subduction zone from a slightly enriched mantle source. Ion microprobes (SHRIMP) U–Pb dating were conducted on zircons from the basalt and gabbro. The weighted mean ages are 336.4 ± 4.1 Ma and 345 ± 14 Ma, which are considered as the crystallization ages of the basalt and gabbro, respectively. Together with other two units, the Dongqiyishan arc belt and the Yueyashan–Xichangjing ophiolite, the Xiaohuangshan ophiolite forms a Late Paleozoic arc-basin system, indicating that the Paleo-Asian Ocean did not close in the early Carboniferous. Based on the geochemical characteristics of adjacent geological bodies and their settings, the Xiaohuangshan ophiolite is considered as an indicator of a suture zone between the different epicontinental belts in the Beishan region.     

Remnants of late Permian–Middle Triassic ocean islands in northern Tibet: Implications for the late-stage evolution of the Paleo-Tethys Ocean

In this paper we present new data for the Tianquan (TQ) and Dabure (DB) ocean islands in the western segment of the Longmuco–Shuanghu–Lancangjiang suture zone, northern Tibet, including the results of major and trace element analyses, zircon U–Pb dating, and Hf isotope analyses. Our aim was to assess the genesis of these ocean islands and to consider the implications for the tectonic evolution of the region as a whole. Both TQ and DB retain an ocean-island-type double-layered structure comprising a volcanic basement (basalt and andesite) and an oceanic sedimentary cover sequence (conglomerate, limestone, and chert). The basalts and andesites in the TQ and DB are enriched in light rare earth elements and high field strength elements (Nb, Ta, Zr, Hf, and Ti), yielding chondrite-normalized REE patterns and primitive-mantle-normalized trace element patterns that are similar to those of ocean island basalts. Given the small and generally positive ε_Hf(t) values of the TQ andesites (+ 4.25 to + 6.22) and DB andesites (− 0.59 to + 1.97, mostly > 0), we conclude that the basalts were derived from the partial melting of garnet peridotite in the mantle and that the andesites were formed by fractional crystallization of the mafic parent magma derived from the garnet peridotite mantle. The ascending magmas underwent varying degrees of fractional crystallization but were not contaminated by crustal material. These features indicate that both TQ and DB are typical ocean islands that formed in an ocean basin. Geochemical analyses of cherts from TQ and DB show that they contain terrigenous material, indicating the proximity of a continental margin. The andesites of TQ contain zircons that yield two U–Pb ages of 251 Ma. Given that ages of 246, 247, and 254 Ma had been reported previously, we conclude that TQ formed during the late Permian–Early Triassic. The andesites of DB contain zircons that yield U–Pb ages of 242 and 246 Ma. Taking into account the youngest age of 244 Ma from the DB basalt, we conclude that DB formed during the Middle Triassic. These data, combined with the geological history of the region, indicate that the development of the Longmuco–Shuanghu–Lancangjiang Paleo-Tethys Ocean continued after the early Permian and that the closure of this ocean was diachronous from east to west. The eastern segment of the ocean closed during the Early Triassic; however, the western segment remained at least partially open until the Middle Triassic, although the ocean was relatively small at this time. The ocean finally closed in the Late Triassic.