深圳市电镀废水微生物处理初步研究

利用一株絮凝效果好的胶质芽胞杆菌所产的微生物絮凝剂进行了深圳市较具代表性电镀废水絮凝性实验。结果表明,微生物絮凝剂有较强的吸附作用,能降低电镀废水中重金属离子的浓度,对废水pH值有一定的调节作用。实验确定了处理综合电镀废水中重金属的条件,初步提出电镀废水的处理和回用工艺。     

天然铁的硫化物净化含铬污水的新方法

天然铁的硫化物净化含铬污水的新方法鲁安怀（中国地质大学材料系,北京,１０００８３）在为确保环境质量而开展的重金属污染物防治活动中,人们特别注重含铬废水的治理,并已成为国内外环保界优先控制的项目。而含铬废水主要来源于电镀企业中镀铬漂洗水、各种铬钝化漂洗...     

电镀废水改进的CAFE处理工艺设计及案例

电镀园区废水处理过程中,由于园区企业难以做到彻底的分质分流,导致废水处理出现破络不彻底,次亚磷酸盐、氰化物等出现再络合与难降解等问题,同时,深度处理后,浓水需要进行深度处理,重金属离子浓度、总磷、总氮处理都存在难以达标的情况。本文根据企业电镀废水的典型水质和水量特征,研究设计了改进的CAFE处理工艺,详细论证了各工艺的处理过程、主要设备及相关设计参数,并将该工艺在南通某电镀园区电镀废水处理中进行了实际应用。运行的实践表明,该套设计方案污水处理运行稳定,最终出水的COD_Cr（化学需氧量）、NH₄-N、总铬、六价铬、总镍指标的平均质量浓度分别为34.00、5.41、0.29、0.03、0.05 mg/L,均远远小于电镀废水的排放标准,达到了电镀废水的深度处理要求。     

矿山铁的硫化物矿物处理皮革厂含铬废水的研究

为了全面提升内蒙古大型硫铁矿的综合利用价值,尝试将其主要成分磁黄铁矿和黄铁矿分别用于处理含铬废水,找到了天然硫铁矿和改性硫铁矿处理Cr(Ⅵ)的最佳实验条件。与已有的研究相比,本研究所使用的矿样粒径减少到80~100目,用量减少了70%,所处理的含铬废水浓度增大到50 mg/m L。将处理含铬废水后的硫铁矿经XPS扫描分析后发现,天然黄铁矿在pH值分别为1.84、4.15和10.87的反应体系中处理Cr(Ⅵ)后,大部分的Cr(Ⅲ)以Cr2S3的物相出现,分别占总铬物相的77.99%、86.53和100%。天然磁黄铁矿在pH值为6.5,加热500℃改性后的黄铁矿在pH值为4.15时,也有相当量的三价铬以Cr2S3的物相出现。用已经获得的处理含铬Cr(Ⅵ)的最佳条件,直接用于处理某皮革厂高浓度的含Cr(Ⅲ)实际废水,去除率达73%。本研究为综合处理含铬废水提供了思路,成为矿山资源化的途径之一。     

累托石层孔材料处理含铬废水的研究

以累托石层孔材料为吸附剂、以FO2为添加剂对含铬电镀废水进行处理，并对其吸附性能做了初步的探讨，实验结果表明，在不改变原水pH值的条件下，吸附剂用量为2.5g/L，还原剂用量为0.5g/L，处理后水中残留铬浓度为0.2mg/L，远低于国标GB8978-1996一级排放标准，累托石吸附铬的反应符合Freundlich吸附经验式：lgQ=-1.9102 0.3545lgC。     

陕西某汞锑矿含铬废水治理前后全铬及六价铬的测定

根据陕西某汞锑选矿厂含铬废水成因及治理工艺特点，在GB7466－87标准方法的基础上，拟订了该矿区含铬废水中全铬及六价铬的测定方法。加标回收实验的回收率为99.9%－100.2%，对ρ（TCr)为216.5mg/L的样液测定10次，其RSD％为1.3，广泛适应该矿区实验室的分析测定。     

颗粒炭动态吸附含Cu－EDTA电镀废水的研究

本文采用颗粒状活性炭，动态吸附处理含Ｃｕ－ＥＤＴＡ电镀废水，对动态法的工艺条件进行了系统研究．最佳工艺条件为：炭粒颗粒度８０～１００目，ｑＨ＝５．５，吸附等温方程式为ｑ＝１９．０Ｃ０．２５９，吸附容量（１５０～２００ｍｌ废水）／ｇ活性炭，过滤速率为１２ｍｌ／ｍｉｎ．结果表明，该方法具有处理效果好，易于扩大应用的优点．     

氢氧化镁处理含铬废水的研究

用硫酸亚铁将废水中Ｃｒ（Ⅵ）还原成Ｃｒ（Ⅲ）,再用氢氧化镁乳液和废水中的酸,使铬离子,铁离子氢氧化物沉淀,澄清分离,这样含铬废水经处理后,铬的含量及ｐＨ值有达到排放标准,该方法操作简便,效果显著。     

颗粒炭动态吸附含Cu—EDTA电镀废水的研究

本文采用颗粒状活性炭，动态吸附处理含Ｃｕ－ＥＤＴＡ电镀废水，对动态法的工艺条件进行了系统研究。最佳工艺条件为：炭粒颗粒度８０－１００目，ＰＨ＝５．５，吸附等温方程为ｑ＝１９．０Ｃ＾０．２５０，吸附容量（１５０－２００ｍｌ废水）／ｇ活性炭，过滤速度为１２ｍｌ／ｍｉｎ，结果表明，该方法具有处理效果好，易于扩大应用的优点。     

AMA吸附剂吸附铬(Ⅵ)的性能研究及应用

用凹凸棒石粘土改性制备了AMA吸附剂，对其吸附铬(Ⅵ)的性能进行了较系统地研究。选择了吸附铬(Ⅵ)的最佳条件，用来处理含铬(Ⅵ)废水，铬(Ⅵ)的去除率在96％以上，铬(Ⅵ)的残余浓度小于0．5mg/L，符合国家的排放标准。可以在废水治理中推广应用。     

Statistical considerations for grain-size analyses of tills

Relative percentages of sand, silt, and clay from samples of the same till unit are not identical because of different lithologies in the source areas, sorting in transport, random variation, and experimental error. Random variation and experimental error can be isolated from the other two as follows. For each particle-size class of each till unit, a standard population is determined by using a normally distributed, representative group of data. New measurements are compared with the standard population and, if they compare satisfactorily, the experimental error is not significant and random variation is within the expected range for the population. The outcome of the comparison depends on numerical criteria derived from a graphical method rather than on a more commonly used one-way analysis of variance with two treatments. If the number of samples and the standard deviation of the standard population are substituted in at-test equation, a family of hyperbolas is generated, each of which corresponds to a specific number of subsamples taken from each new sample. The axes of the graphs of the hyperbolas are the standard deviation of new measurements (horizontal axis) and the difference between the means of the new measurements and the standard population (vertical axis). The area between the two branches of each hyperbola corresponds to a satisfactory comparison between the new measurements and the standard population. Measurements from a new sample can be tested by plotting their standard deviation vs. difference in means on axes containing a hyperbola corresponding to the specific number of subsamples used. If the point lies between the branches of the hyperbola, the measurements are considered reliable. But if the point lies outside this region, the measurements are repeated. Because the critical segment of the hyperbola is approximately a straight line parallel to the horizontal axis, the test is simplified to a comparison between the means of the standard population and the means of the subsample. The minimum number of subsamples required to prove significant variation between samples caused by different lithologies in the source areas and sorting in transport can be determined directly from the graphical method. The minimum number of subsamples required is the maximum number to be run for economy of effort.     

Stress-strain analysis of geogrid-supported liners over subsurface cavities

Summary Finite element analyses were conducted to investigate the magnitude of tensile strains imposed on landfill liners due to the formation of subsurface cavities. The study incorporated the significance of using geogrids to reduce the magnitude of strains and possibly the potential for collapse of landfill liners. Variations of key parameters included depth of overburden (D) and diameter of the cavity (B). Estimated stress distributions were compared to theoretical values obtained from a model reported in the literature. Results indicated that, contrary to conventional wisdom, the critical area based on the mechanics of arching was above the edge of the cavity where stress concentration occurred. Incorporation of geogrid reinforcement reduced the magnitude of tensile strains. The tensile force in the geogrid was dependent upon the size of the cavity, the depth of the overburden, and the applied pressure.     

Evolution of the European Cenozoic Rift System: interaction of the Alpine and Pyrenean orogens with their foreland lithosphere

The evolution of the European Cenozoic Rift System (ECRIS) and the Alpine orogen is discussed on the base of a set of palaeotectonic maps and two retro-deformed lithospheric transects which extend across the Western and Central Alps and the Massif Central and the Rhenish Massif, respectively.During the Paleocene, compressional stresses exerted on continental Europe by the evolving Alps and Pyrenees caused lithospheric buckling and basin inversion up to 1700 km to the north of the Alpine and Pyrenean deformation fronts. This deformation was accompanied by the injection of melilite dykes, reflecting a plume-related increase in the temperature of the asthenosphere beneath the European foreland. At the Paleocene–Eocene transition, compressional stresses relaxed in the Alpine foreland, whereas collisional interaction of the Pyrenees with their foreland persisted. In the Alps, major Eocene north-directed lithospheric shortening was followed by mid-Eocene slab- and thrust-loaded subsidence of the Dauphinois and Helvetic shelves. During the late Eocene, north-directed compressional intraplate stresses originating in the Alpine and Pyrenean collision zones built up and activated ECRIS.At the Eocene–Oligocene transition, the subducted Central Alpine slab was detached, whereas the West-Alpine slab remained attached to the lithosphere. Subsequently, the Alpine orogenic wedge converged northwestward with its foreland. The Oligocene main rifting phase of ECRIS was controlled by north-directed compressional stresses originating in the Pyrenean and Alpine collision zones.Following early Miocene termination of crustal shortening in the Pyrenees and opening of the oceanic Provençal Basin, the evolution of ECRIS was exclusively controlled by west- and northwest-directed compressional stresses emanating from the Alps during imbrication of their external massifs. Whereas the grabens of the Massif Central and the Rhône Valley became inactive during the early Miocene, the Rhine Rift System remained active until the present. Lithospheric folding controlled mid-Miocene and Pliocene uplift of the Vosges-Black Forest Arch. Progressive uplift of the Rhenish Massif and Massif Central is mainly attributed to plume-related thermal thinning of the mantle-lithosphere.ECRIS evolved by passive rifting in response to the build-up of Pyrenean and Alpine collision-related compressional intraplate stresses. Mantle-plume-type upwelling of the asthenosphere caused thermal weakening of the foreland lithosphere, rendering it prone to deformation.     

Tectonics of the western part of the Polish Outer Carpathians

The western part of the Polish Outer Carpathians is built up from the thrust, imbricated Upper Jurassic-Neogene flysch deposits. The following Outer Carpathian nappes have been distinguished: Magura Nappe, Fore-Magura group of nappes, Silesian, Subsilesian and Skole nappes. Interpretation of seismic and magnetotelluric survey from the region South of Wadowice, allows observation of relationship between basement and flysch nappes in the Outer Carpathians. It also allows identification of dislocation cutting both flysch nappes and their basement. All the Outer Carpathian nappes are thrust over the southern part of the North European Platform. The platform basement is composed of older Precambrian metamorphic rocks belonging to the Bruno-Vistulicum terrane. Sedimentary cover consists of Paleozoic, Mesozoic and Neogene sequences. The characteristic features of this boundary are horsts and troughs of general direction NW-SE, turning W-E. Faults cutting only the consolidated basement and the Paleozoic cover were formed during the Hercynian Orogeny in the Carboniferous and the Early Permian. Most of the older normal faults were covered by allochtonous flysch nappes forming thus the blind faults. During the last stage of the geodynamic development the Carpathians thrust sheets moved towards their present position. Displacement of the Carpathians northwards is related to development of dextral strike-slip faults of N—S direction. The orientation of this strike-slip fault zones zone more or less coincides with the surface position of the major faults perpendicular to the strike of the Outer Carpathian thrustsheets. The huge fault cuts formations from the Paleozoic basement through the flysch allochton between the boreholes in Sucha Beskidzka area. The displacement of nappes of the Carpathian overthrust and diapiric extrusion of plastic formations of the lower flysch units occurred along this fault.     

Lower Carboniferous (Dinantian) stratigraphy and structure of the Walterstown-Kentstown area,Co. Meath,Ireland

Stratigraphic units are defined and described for the Lower Carboniferous succession in the Walterstown-Kentstown area of Co. Meath, Ireland. A complete (unexposed) Courceyan succession from the terrestrial red bed facies of the Baronstown Formation to the Moathill Formation of the Navan Group has been penetrated in several boreholes. Although the lower part of the sequence is comparable with the Courceyan succession at Navan and Slane, the middle part of the sequence differs markedly in the Walterstown-Kentstown area and two new members, the Proudstown and Walterstown Members, are defined in the upper part of the Meath Formation. Syndepositional faulting was initiated during the Courceyan, probably in latest Pseudopolygnathus multistriatus or early Polygnathus mehli latus time. Movement on the ENE trending St. Patrick's Well Fault influenced the deposition of the Walterstown Member and the overlying Moathill Formation and was probably associated with the development of the East Midlands depocentre to the south of the area. A second episode of tectonism in the latest Courceyan or early Chadian resulted in uplift and erosion and the development of ‘block and basin’ sedimentation. Subsequent transgression of the uplifted block led to the establishment of the Kentstown Platform, bounded to the north, west and south by rocks of basinal facies. The Milverton Group (Chadian-Asbian), confined to this platform, unconformably overlies Courceyan or Lower Palaeozoic strata and is subdivided into three formations: Crufty Formation (late Chadian), Holmpatrick Formation (late Chadian-Arundian) and Mullaghfin Formation (late Arundian-Asbian). The Walterstown Fault controlled the western margin of the Kentstown Platform at this time. Contemporaneous basinal sediments of the Fingal Group (Lucan and Naul Formations) accumulated to the west of the Walterstown Fault and are much thicker than age-equivalent platform facies. Platform sedimentation ceased in latest Asbian to early Brigantian time with tectonically induced collapse and drowning of the platform; platform carbonates of the Mullaghfin Formation are onlapped northwards by coarse proximal basinal facies of the Loughshinny Formation. A distinct gravity anomaly in the Kentstown area suggests the presence of a granitoid body within the basement. The Kentstown Platform is therefore considered to have formed on a buoyant, granite-cored, footwall high analogous to the Askrigg and Alston Blocks of northern England.     

Controls on the evolution and demise of Lower Carboniferous carbonate platforms,northern margin of the Dublin Basin,Ireland

Shallow water platform limestones of the Chadian–Asbian Milverton Group are restricted to the north-eastern part of the Lower Carboniferous (Dinantian) Dublin Basin. Here, they are confined to two granite-cored fault blocks, the Kentstown and Balbriggan Blocks, known to have been active during the late Dinantian. Three areas of platform sedimentation are delimited (the Kentstown, Drogheda and Milverton areas), although in reality they probably formed part of a single carbonate platform. Resedimented submarine breccias and calciturbidites (Fingal Group) composed of shallow water allochems and intraclasts sourced from the platform accumulated, along with terrigenous muds, in the surrounding basinal areas. Sedimentological evidence suggests that the Kentstown and Balbriggan Blocks possessed tilt-block geometries and developed during an episode of basin-wide extensional faulting in late Chadian time. Rotation of the blocks during extension resulted in the erosion of previously deposited sequences in footwall areas and concomitant drowning of distal hangingwall sequences. Antithetic faults on the northern part of the Balbriggan Block aided the preferential subsidence of the Drogheda area and accounts for the anomously thick sequence of late Chadian platform sediments present there. Continued subsidence and/or sea-level rise in the late Chadian–early Arundian resulted in transgression of the Kentstown and Balbriggan Blocks; carbonate ramps developed on the hangingwall dip slopes and transgressed southward with time. Subsequent progradation and aggradation of shallow water sediments throughout the Arundian to Asbian led to the development of carbonate shelves. Several coarse conglomeratic intervals within the contemporaneous basinal sequences of the Fingal Group attest to periodic increases of sediment influx associated with the development of the shelves. Sedimentological processes controlled the development of the carbonate platforms on the hangingwall dip slopes of the Kentstown and Balbriggan Blocks, though periodic increases of sediment flux into the basinal areas may have been triggered by eustatic falls in sea level. In contrast, differential subsidence along the bounding faults of these blocks exerted a strong control on the margins of the late Dinantian shelves, maintaining relatively steep slopes and inhibiting the progradation of the shelves into the adjacent basins. Tectonically induced collapse and retreat of the platform margins occurred in the late Asbian–early Brigantian. Platform sediments are overlain by coarse-grained proximal basinal facies which fine upwards before passing into a thick shale sequence, indicating that by the late Brigantian carbonate production had almost stopped as the platforms were drowned.     

Viscous effects on penetrating shafts in clays

The penetration of rigid objects such as piles and penetrometers into soils creates a zone of soil disturbance around them. The extent of this disturbed zone influences the resistance of the moving rigid body. This paper presents a theoretical framework to analyze the resistance in the disturbed zone created by a shaft penetrating a clay soil. The soil is modeled as a viscous material after it reaches failure [critical state (CS)]. The results of this analysis show that the viscous drag stress component on the shaft surface is influenced by the size of disturbed zone that has reached CS around the shaft, the shear viscosity of the soil and the velocity profile (or strain rate) in the CS zone around the shaft. The size of CS zone, the velocity profile and the viscosity of soil are interdependent. Large variation in viscous drag occurs when the size of the CS soil zone is less than four times the shaft’s radius. Limiting drag occurs when the size of the CS soil zone exceeds six times the shaft’s radius. The theoretical velocity distribution of the movement of soil in the CS zone shows that the soil is dragged along with shaft in the near field (close to the shaft surface) and moves upwards in the far field.     

具彩色斑纹颅形贝在广西桂林下石炭统黄金组中的发现:兼论颅形贝属的地质地理分布

文中描述了产自广西桂林地区下石炭统黄金组下部的颅形贝属一新种,桂林颅形贝(Cranaena guilinensis)。新种以平直的前结合缘和背壳上发育中槽为特征。在4枚标本上发现保存有放射状的彩色条带,表明该种当时生活在温暖海域的浅水环境。对该属70个种的地质地理分布和生物多样性变化的初步分析表明,该属可能起源于早泥盆世欧美大陆西北缘的老世界区,之后的地理分布和生物多样性发展以北美地区为中心,经历了中泥盆世—晚泥盆世早期和早石炭世2次比较明显的辐射演化、迁移扩散高峰和晚泥盆世晚期的1次严重衰退。第1次高峰是中泥盆世—晚泥盆世早期,该属的生物多样性达到巅峰,生物地理分布范围扩大到欧美大陆之外的西伯利亚板块、哈萨克斯坦板块和华南板块等;第2次高峰是早石炭世,该属的生物多样性虽不及前一次,但获得了最广泛的地理分布,不仅在北方大陆有分布,而且已进入到冈瓦纳大陆边缘。晚泥盆世晚期该属的1次严重衰退显然与F/F灭绝事件有关。早石炭世之后,该属进入衰退阶段,最终在二叠纪初灭绝。     

Nouvelle interprétation tectonique de la montagne Sainte-Victoire (Provence,France)

The explanation normally given for the tectonics of Sainte-Victoire Mountain, a dozen kilometres east of Aix-en-Provence, to the north of the limestone Provence, is incorrect. To the east, the morphology of the Sainte-Victoire is subdued, whereas to the west, before the mountain breaks savagely, the morphology is that of a young mountain as appears in Alpine landscapes. This unusual aspect in the region and the large subvertical faults with vertically striated surfaces that mark the massif to the south and to the west, induce the idea of strong vertical uplifts and caste doubt on the tectonic interpretation given in 1962 by Corroy et al. According to those authors, the Sainte-Victoire is a unit of Jurassic and Cretaceous formations overthrusting 1800 m to the south conglomerates of the Late Cretaceous or Palaeocene. New observations about the conglomerate transgression over the Jurassic and Cretaceous beds, and about the faults around and on the massif do not give evidence of an overthrusting but, on the contrary, induce the idea of a uplift, perhaps still active, in the form of a ‘piano key’ inclined to the northeast. To cite this article: J. Ricour et al., C. R. Geoscience 337 (2005).     

中国中新元古代重要沉积地质事件及其意义

地球曾经历了3次超大陆演化过程,其中2次超大陆(哥伦比亚(Columbia)和罗迪尼亚(Rodinia))旋回涉及中新元古代,并与一系列区域性事件相联系,形成了多成因的超大陆演化模型。华北中东部新元古代沉积事件、扬子和塔里木新元古代裂谷事件、雪球事件等都被视为Rodinia超大陆的裂解响应,它们对定时三大陆块相互关系及定位其在全球超大陆的位置具有至关重要的作用,也反映了重要沉积地质事件在超大陆研究中不可或缺的作用和意义。此外,在中新元古代的Columbia和Rodinia超大陆演化过程中,还伴随发育具有广泛区域性甚至全球意义的巨厚白云岩与碳酸盐岩微生物(岩)、红层与黑色页岩、全球性臼齿亮晶碳酸盐岩和埃迪卡拉纪盖帽碳酸盐岩等沉积事件群及元素(同位素)漂移等地球化学异常事件,也包括特殊且重要的磷块岩、锰、铁矿等沉积成矿事件。由于不断显示出来在全球古大陆重建和古地理恢复方面的重要作用,它们越来越得到学术界的广泛关注和研究。文中通过系统分析中国中新元古代超大陆旋回演化中发育的部分重要或关键地质事件(群)时空发育与分布特征,并结合作者团队的实际资料和测试数据,以期揭示超大陆演化过程与重要沉积地质事件的内在联系,为超大陆聚散旋回演化和时空定位及原型沉积盆地的发育和评价提供科学证据。