Bispectra of spike-array type time series and their application to the analysis of oceanic microstructures

Bispectral analysis is applied to records of the vertical profile of the vertical temperature gradient in the oceanic thermocline in the San Diego Trough. The bispectra exhibit three notable features; (1) bispectral peaks at the points (0.2 m^–1, 0.2 m^–1) and (0.2 m^–1, 0.1 m^–1), (2) bispectral ridges along the lines ( ₁= ₀, ₂= ₀ and ₁+ ₂= ₀ corresponding to peak wavenumbers ₀ in power spectra, and (3) array of bispectral peaks of interval of 0.2 m^–1 The results are compared with the bispectra of several modeled time series of spike-array type. The periodicity of 5 m found in the records seems to have two meanings: spacing of predominant spikes and wavelength of predominant sinusoidal wave. If this indicates the existence of internal waves having a vertical wavelength the same as the scale of homogeneous layers, it would suggest the possible importance of internal waves in the formation and maintenance mechanisms of oceanic microstructure.     

Climatic ‘norms’ of the main properties of the world's oceans

The important values in the ocean's climatology — the norms of the main parameters of seawater such as temperature, salinity, density and dissolved oxygen — have been studied. The results of computation of the multi-annual average values of these parameters were analysed for the entire world's oceans and their separate regions. General regularities adherent in the global structure of the main hydrophysical and hydrochemical fields are revealed. A series of fundamental conclusions was derived that indicate the exclusive stability of the ocean's climate.Translated by Mikhail M. Trufanov.     

The thermal effects of cooling system of a thermal power plant on photosynthesis of marine phytoplankton

The activity of photosynthesis and the contents of chlorophylla and pheo-pigments were compared in the samples of the intake and effluent seawater of Owase-Mita Thermal Power Plant and in the seawater samples in the Yoshimi Bay before and after heat treatment. At Owase-Mita Thermal Power Plant, after passage of sea water through the cooling system chlorophylla content reduced to about a half and pheo-pigment content doubled in August with high temperature (25–27C), but the contents of chlorophylla and pheo-pigments changed little in January with low temperature (16C); whereas the depression of photosynthetic activity after passing through the cooling system was 71–77 % in August and 31–46 % in January. In the laboratory experiments, the heat treatment at 34–43C for 7–8 sec., which resulted in temperature rise of 7–8C, gave the decrease of chlorophylla and an increase of pheo-pigments in August temperature (26.5C), but a slight decrease of chlorophylla and a slight increase of pheo-pigments in November at the initial temperature of 19.2C, while in January and December the samples with low initial temperature (11.6 and 10.8C) showed almost no change in the content of pigments; the decrease in photosynthetic activity was 32 % in August sample,ca. 11 % in November sample,ca. 15% in January and almost no change in December. It is concluded that the photosynthetic carbon assimilation of marine phytoplankton is suppressed by passing through the cooling system of a thermal power plant even at lower water temperature in winter, while the content of chlorophylla is affected very little at a temperature below 20C.     

Mineralogical study of the core samples from the Indian Ocean,with special reference to the vertical distribution of clay minerals

The clay minerals in the 18 core samples collected from the northern, equatorial and southeastern Indian Ocean are illite, chlorite, montmorillonite and kaolinite. In the fraction finer than 2 in the surface layer (top to 5 cm deep) of each core, the relative abundance of clay minerals varies widely from area to area. Kaolinite possesses the maximum proportion of the clay mineral composition and chlorite has the minimum proportion.Kaolinite is particularly dominant in sediments near off the northwestern coast of Australia. In the factions finer and coarser than 2 of the surface layer, montmorillonite and kaolinite tend to be abundant in the fraction finer than 2, and chlorite and illite tend to be abundant in the fraction coarser than 2. In some cores, kaolinite-rich layers in sediments which are considered to have been transported by turbidity currents from the Bay of Bengal are found. Turbidity currents appear partly a role in transport of sediments to the equatorial Indian Ocean.As to the relation between the vertical change of clay mineral composition and geochronological data, montmorillonite and kaolinite tend to be more abundant in interglacial ages than in glacial ages, while illite and chlorite tend to exhibit opposite trend.Muscovite and biotite highly concentrated in the cores Ka-9 and Ka-15 collected from the equatorial Indian Ocean seem to originate from granite or gneiss of Ceylon and/or India.     

Calcium-alkalinity relationship in the North Pacific

The dissolution of calcium carbonate in deep ocean water causes variation in calcium concentration (Ca) and alkalinity (TA) in the ratio of one to two. The decomposition of organic matter generates nitric acid, phosphoric acid and sulfuric acid. A proton flux which is derived from this process also changes alkalinity. Using the variation in nitrate concentration (NO₃) as an index of the proton flux, the relationship betweenCa,TA andNO₃ is expressed asCa=0.5TA+0.63NO₃ The values of Ca obtained from direct measurements in the North Pacific are in good agreement with the values estimated from this equation.     

Thermolability of dehydrogenases from a psychrophilic marine bacterium

The heat lability of succinic dehydrogenase, malic dehydrogenase and lactate dehydrogenase in cell-free extracts ofVibrio marinus MP-1 grown at 15C was compared for the tris buffer suspended enzymes and the NaCl suspended enzymes. The tris buffer suspended enzymes lost 50 percent activity at low thermal exposure between 5C and 27C. No activity was evident on thermal exposure between 32C and 39C. The enzyme extracts suspended in NaCl at 36 % were more heat stable, losing 50 percent activity after exposure between 16C and 40C. The enzymes lost all activity on thermal exposure between 33C and 42C in the presence of NaCl.     

Regeneration of silicate in the ocean

Regeneration of silicate in the Japan Sea, an example of semi-closed sea, was studied. In the Japan Sea Proper Water the apparent regenerative ratio of the nutrients was determined to be:O C N P Si=–289 (116)14.3181.It was assumed that the dissolved silicate present in sea water is grouped into three fractions; 1)preformed silicate of conservative nature, 2)oxidative silicate which dissolves in oxidation process of organisms with consumption of oxygen, and 3)non-oxidative silicate which dissolves without oxygen consumption. The dissolution rate ofnon-oxidative silicate in the Japan Sea Proper Water was estimated to be 0.07g-at. Si/l/yr from the data ofAOU values and assumed rates of oxygen consumption. This dissolution rate ofnon-oxidative silicate agreed with that obtained in the deep Pacific by the vertical advection diffusion model byKido andNishimura (1972).     

Petrography and stable isotope aspects of cold-vent activity imprinted on Miocene-age “calcari aLucina” from Tuscan and Romagna Apennines,Italy

Over 20 occurrences of discontinuous limestone blocks, locally called calcari aLucina, were mapped in the Tuscan—Romagna region of the northern Italian Apennines. The limestones, consisting of a variable mixture of authigenic carbonates (calcite, dolomite, and aragonite), sulfides (primarily pyrite), and allogenic silicates, occur in association with turbidite and hemipelagite units that were deposited in foredeep basins during early to late Miocene times. The limestone blocks are interpreted to represent relicts of carbonate buildups formed around methane-rich fluid vents on the basis of their (1) striking petrographic similarities to carbonates from cold vents in the modern oceans; (2) unique chemosynthetic-like fauna, and (3) anomalously negative ¹³C values ( ¹³C = – 16 to – 58 PDB). The contemporaneous tectonism of the Apennine orogeny is likely to be the primary cause for the expulsion of the methane-rich fluids to the seabed in a manner analogous to the fluid-flow processes occurring at modern accretionary prisms.     

On nonlinear sea waves and the induced mean flow

The nonlinear modulation of water wave groups is investigated and the interaction equations with induced flows are obtained. The analysis is performed up to the third order of the wave steepness a by treating it as a small parameter in the singular perturbation technique by means of the Krylov-Bogoliubov-Mitropolski method. The equation which governs the development of the wave envelope is found by a modification of the ordinary nonlinear Schroedinger equation for the case of uniform depth. The equations governing the behavior of the induced mean flow are examined by deriving the second order flow when the form of the modulated wave train is prescribed. The present theory can describe the mean flow caused by the radiation stress. Some applications containing the monochromatic wave instability are given to confirm the theoretical results.An outline of this paper was presented at The Ocean Surface Symposium (Sendai, 1984).     

Intrusive Stratification of the Gulf-Stream Frontal Zone According to the Results of Investigations Performed during Cruise 43 of the R/V Akademik Vernadskii

We analyze the data of investigation of the intrusive structure of the Gulf-Stream frontal zone obtained in making frequent drift sections with the help of an MGI-8102 probing complex, study the regularities of variation of temperature, salinity, and density along separate intrusions, and present a series of results connected with the specific features of initiation and development of intrusions and the types of exchange processes determining their transformations. It is shown that the T-diagrams of all intrusions are well separated into segments with different slopes. Moreover, by comparing the slopes and locations of these segments with each other and with the T-diagrams of the Gulf Stream and slope waters, we can fairly reliably attribute the corresponding segments of intrusions to one of the following four types: initial dynamic folds of the frontal zone, layers of domestic water separating the intrusive segments of foreign water from each other, intrusive segments characterized by the penetration of ambient water, and segments not intrusive initially but getting the required slope as a result of interaction with upper and lower intrusive segments. For segments of the last two types, it is possible to specify the predominant type of exchange.     

A field study of physico-chemical states of artificial radionuclides in seawater

The physico-chemical states of artificial radionuclides,⁹⁰Sr,¹³⁷Cs and¹⁴⁴Ce in seawater were investigated by radiochemical analysis of filtered and unfiltered seawater. The difference of radionuclide concentrations between unfiltered and filtered seawaters was defined as the particulate form radioisotope and its particle ratio was discussed.Practically no particulate⁹⁰Sr, greater than 0.22 in size, was observed in both coastal and open seawaters, but some of¹³⁷Cs seemed to be insoluble in some circumstances, especially in coastal waters. A considerable amount of¹⁴⁴Ce was found to be particulate.An estimation of the radionuclides in particulate form was made for Kashima-nada seawaters collected in 1970 to 1972, and it was shown that the possible occurrence of particulate radionuclides, greater than 0.22 in size, were 1% or less for⁹⁰Sr and 6% for¹³⁷Cs. In the coastal water, 80 % of¹⁴⁴Ce were seemed to be in particulate form, but in the open seawater only a few%. The influences of suspended materials to¹³⁷Cs and¹⁴⁴Ce concentration levels in seawater were not negligible and further investigations are desirable.     

Mean Vertical Distribution of the Dissipation Rate of Turbulent Energy in the Black Sea. Comparison with the Existing Models

We compare the results obtained by using theoretical and semiempirical models developed for the evaluation of the dissipation rate of turbulent energy in a stratified ocean with independent distribution of this quantity established by the authors for the active layer of the Black Sea (50–300 m) by using a one-dimensional model taking into account the balance of heat, salt, and fluid inside the layer. It is shown that, in a layer with gradual variation of the Väisälä–Brunt frequency N as a function of depth, the predominant sink of the energy of motion into dissipation N ² is ensured by the flow of energy through the spectrum of internal waves toward low frequencies and small vertical scales. On the contrary, in layers with abrupt drops of density as a function of depth (layers with jumps of density), an important role is played by the interface-type waves and the dependence of on N transforms into N .     

Microbial Diversity in Nankai Trough Sediments at a Depth of 3,843 m

Dense populations of bivalves, primarily Calyptogena sp., were observed at cold seeps of the Nankai Trough. Bacterial input to the sediment was estimated through determination of phospholipid ester-linked fatty acid (PLFA) and DNA profiles. Results indicated a bacterial biomass of 10⁹ cells (g dry wt)^-1 while individual fatty acid profiles revealed a predominance of monounsaturated fatty acids, mainly 18:1 isomers. The presence of these fatty acids can be interpreted to reflect a response to low temperature and a predominance of psychrophilic bacteria. DNA fragments encoding bacterial ribosomal RNA small-subunit sequences (16S rDNA) were amplified by the polymerase chain reaction method using DNA extracted directly from the sediment samples. From the sequencing results, at least 19 kinds of bacterial 16S rDNAs related to mostly the Proteobacteria and a few gram-positive bacteria were identified. These results suggest that the bacterial community in the Nankai Trough sediments consists of mainly bacteria belonging to the Proteobacteria , , and subdivisions. Bacteria belonging to the and subdivisions, which are known to include epibiont and sulfate reducing bacteria, respectively, were mostly detected in the sediment obtained from inside the area of the Calyptogena community, and the -Proteobacteria may function to supply reduced sulfur to bacterial endosymbionts of Calyptogena.     

Vertical distribution of heavy metals and its seasonal variations in Beppu Bay

From July to November, the thermocline which has strong temperature gradient (0.7C m^–1) is formed in the bottom water of Beppu Bay, and it prevents the downward mixing of surface water. This has caused the bottom water of the basin to become depleted in oxygen, and in November the bottom water below about 60 m depth becomes anoxic. Accordingly manganese and iron are reduced and more soluble under the anoxic condition, those concentrations are high relative to surface water, and the maximums are 1,240g l^–1 and 80g l^–1. Under the anoxic condition, the flux of dissolved manganese from the sediment is about 10g cm^–2 day^–1.     

Classification of “siome”, streaks and fronts

Siome, which was firstly defined by Uda (1938); is a line of convergence on the sea surface. There are many kinds of siome in the sea. I propose in this paper that siome should be classified into streak and front. Streak is defined as the convergence within the same water mass and front the convergence between two different water masses. Streaks and fronts are classified into more details on the basis of their mechanisms of generation. The proposed classification will be useful for understanding the dynamics of siome and should help to promote interdisciplinary studies around siome regions.     

Encystment ofChattonella antiqua in laboratory cultures

Cysts ofChattonella antiqua (Raphidophyceae) were obtained in laboratory cultures for the first time. They were formed on the surface of glass coverslips added to both P- and N- depleted mediums. The yield was 50–250 cysts cm^–2. Crossing experiments showed the highest cyst production in mixed cultures, although cysts were observed in clonal cultures as well. Cysts had approximately double the DNA content of synchronously growing vegetative cells (G₁ phase). The encystment process was also monitored: Under P-depleted conditions, small cells were formed that fused to become a triangle-shaped cell which in turn changed into a cyst.These results strongly suggest that cysts are the products of fusion and are diploid. Small cells, triangle-shaped cells, and cysts are considered to be gametes, planozygotes, and hypnozygotes, respectively. Significant mortality was observed in laboratory cysts stored in the cold and dark for five months, although those remaining were capable of germination to reestablish a motile, vegetative population.     

Variation of water system distribution in the Sanriku Coastal Area

We analyzed hydrographic data obtained monthly by the Iwate Prefectural Fisheries Laboratory during 1977–1981. Our attention was focussed on the classification of waters based on the Temperature-Salinity (T-S) scatter diagram analyses, and on the extraction of the mean state of their distribution for each season. The water system was defined as all waters occupying some specific region on the T-S plane, and the mean state for each season was expressed by the distribution of the mode water systems (i.e., the most commonly occuring water system).Because of the coexistence of the Tsugaru Warm Current, the Oyashio and the Kuroshio, and their large seasonal variability, the sea waters had a wide variety of T-S combinations. The detailed T-S scatter diagram analyses allowed us to classify the waters into six water systems. A time-longitude diagram of water systems and the distribution of mode water systems are presented. The latter showed clear seasonal variations of the Tsugaru Warm Current and the Oyashio.Though the water system analysis was successfully able to present the distribution of the various waters in the Sanriku Coastal Area and to clearly extract the mean state of sea conditions, it was found that the classification of water systems on the T-S plane was not complete in all cases for this area.     

Effects of ligand speciation on determinations of the complexing abilities of strong ligands in natural waters

The presence of organic ligands (L) whose conditional stability constants (K_ML) are strong enough to allow them to form complexes with copper has been reported in oceanic waters. However, there is no general agreement on the distributional characteristics of such strong ligands in the water column. We present that these inconsistencies are derived from not only different analytical methods employed for their detection but also different oceanographic conditions. In particular, the nature and quantities of detectable natural ligands are affected by what kind of form the ligands are presentin situ in different marine environments, that is, chemical speciation of natural ligands (ligand speciation), which depends strongly on the variations in concentrations of coexisting trace metals. Using published data from observations in the laboratory and the field, we provide limits to the ranges of conditional stability constants of organic ligands for copper, zinc and cadmium that are detectable by the extensively used direct metal-titration method. For example, our model indicates that organic ligands for copper with log K_CuL(Cu)>12.4 in surface water and with log K_CuL(Cu)>9.9 in deep water might not have been detected because stronger ligands had formed complexes with ambient metalsin situ at a station in the North Pacific. The estimation suggests that there is a basinscale difference in speciation of natural organic ligands and, moreover, that this difference influences metal speciation. It is postulated that comparisons of the occurrence and levels of organic ligands might not be possible among spatially and temporally different observations without reconciliation of the effects of speciation of the ligands, even if an identical method is used in every case.     

Formation of the vertical salinity profile in the Black Sea

The vertical distribution of salts brought by the Bosphorus undercurrent is numerically evaluated. By multiplying the average vertical salinity gradient by the diffusion coefficient,K _z , and the cross-section of the sea at the appropriate depth, we can determine the total vertical salt flux,Q(z). The derivative ofQ with respect toz depicts the salt source intensity distribution over depth. The highest intensity, Q/z, matches the 200 m depth level, i.e. the shelf edge. Below 1500 m, Q/z equals merely 0.1% of the value observed at a depth of 200 m. Above 37 m, salts are noted to sink, which corresponds to their outflow with the Bosphorus current. The distribution of Q/z and the respective values of mineral phosphorus and hydrogen sulphide are matched up.Translated by Vladimir A. Puchkin.     

The content and the oxidation state of arsenic and antimony in coastal water of Japan

The content and the oxidation state of arsenic and antimony in coastal seawater were determined coupled with chemical separation and neutron activation method. The contents of arsenic and antimony in coastal seawater were estimated to be 1.56–2.73g As/l, 0.25–0.57g Sb/l. Most parts of these elements exist as soluble ionic species, passing through 0.45 pore-size membrane filter, and at surface, 80–97% of arsenic occurs as arsenate and 70–94 % of antimony may occurs as antimonate. The vertical distribution of arsenite and arsenate is almost constant from the surface to 1,200 m depth. However the distribution of Sb(III) and Sb(V) is much more complicated with depth.