The interstellar chemistry of protostellar disks

A study has been undertaken of the gas-grain chemistry of protostellar disks which are sufficiently cool that in the outer regions, where the gas density is less than 10¹³ cm^–3 and the ionization rate highest, a bimolecular chemistry resembling that of dark clouds can occur. Since the gas-grain collision rate is so high, outgassing mantle molecules effectively determine the gas phase composition at any position in the disk. In contrast to previous work, a detailed gas phase chemistry is considered along with the accretion and desorption of mantle species which is controlled locally by the dust temperature.     

Very high resolution profiles of four diffuse interstellar bands

Ultra-high-resolution  ( R ∼ 300 000)  profiles of four diffuse interstellar bands (DIBs) are presented. The λλ 5797-, 5850-, 6196- and 6379- Å DIBs were observed towards the reddened supergiant HD 24398, a line of sight free of Doppler splitting; thus the observed profiles can be considered as intrinsic to the DIB carriers. Three of the profiles show substructure which supports the hypothesis of a molecular origin for these DIBs.     

Deuterium enrichment of the interstellar medium

Despite the low elemental abundance of atomic deuterium in the interstellar medium (ISM), observational evidence suggests that several species, both in the gas phase and in ices, could be heavily fractionated. We explore various aspects of deuterium enrichment by constructing a chemical evolution model in both gaseous and granular phases. Depending on various physical parameters, gases and grains are allowed to interact with each other through the exchange of their chemical species. It is known that HCO⁺ and N₂H⁺ are two abundant gas phase ions in the ISM and, their deuterium fractionation is generally used to predict the degree of ionization in the various regions of a molecular cloud. For a more accurate estimation, we consider the density profile of a collapsing cloud. The radial distributions of important interstellar molecules, along with their deuterated isotopomers, are presented. Quantum chemical simulations are computed to study the effects of isotopic substitution on the spectral properties of these interstellar species. We calculate the vibrational (harmonic) frequencies of the most important deuterated species (neutral and ions). The rotational and distortional constants of these molecules are also computed in order to predict the rotational transitions of these species. We compare vibrational (harmonic) and rotational transitions as computed by us with existing experimental and theoretical results. It is hope that our results will assist observers in detecting several hitherto unobserved deuterated species.     

Blueshifted diffuse interstellar bands in the spectrum of HD 34078

In this paper, we report the very first observation of diffuse interstellar bands (DIBs) that, in the spectrum of HD 34078 (AE Aur), are blueshifted with respect to the normal position that they have in other objects, where the rest-wavelength velocity frame is determined using very sharp interstellar atomic lines or molecular features. Only reasonably narrow DIBs seemingly show this effect, which is absent in broader ones. The result is confirmed independently using three different spectrographs attached to two different telescopes.     

The chemistry of transient dense cores

We investigate the chemistry of a transient density fluctuation, with properties similar to those of a dense core within a molecular cloud. We run a multipoint chemical code through a core's condensation from a diffuse medium to its eventual dispersion, over a period of ∼1 Myr. We find a significant enhancement of the chemical composition of the core material on its return to diffuse conditions, whilst the expansion of the core as it disperses moves this material out to large distances from the core centre. This process transports molecular species formed in the high-density regions out into the diffuse medium. Chemical enrichment of the cloud as a whole also occurs, as other cores of various sizes, life-spans and separations evolve throughout. Enrichment is strongly affected by freeze-out on to dust grains, which takes place in high-density, high visual extinction regions. As the core disperses after reaching its peak density and the visual extinction drops below a critical value, grain mantles are evaporated back into the gas phase, initiating more chemistry. The influence of the sizes, masses and cycle periods of cores will be large both for the level of chemical enrichment of a dark cloud and ultimately for the low-mass star formation rate. We also consider the case of a self-gravitating core, by holding its peak density conditions for a further 0.4 Myr. We find that the differences are generally small, and the resultant column densities do not provide definitive criteria for detection of this condition. However, increases in fractional abundances due to reinjection of mantle-borne species may provide a criterion for a negative detection.     

Far-ultraviolet extinction and diffuse interstellar bands

We relate the equivalent widths of the major diffuse interstellar bands (DIBs) near 5797 and 5780 Å with different colour excesses, normalized by E ( B − V ) , which characterize the growth of interstellar extinction in different wavelength ranges. It is demonstrated that the two DIBs correlate best with different parts of the extinction curve, and the ratio of these diffuse bands is best correlated with the far-ultraviolet (UV) rise. A number of peculiar lines of sight are also found, indicating that the carriers of some DIBs and the far-UV extinction can be separated in certain environments, e.g. towards the Per OB2 association.     

On the detection of the linear C5 molecule in the interstellar medium

An upper limit of the column density of the C₅ linear molecule in translucent interstellar clouds is estimated from high-resolution ( R =80 000) and very high signal-to-noise ratio (∼1000) echelle spectra. It is 10¹² cm⁻² per E ( B − V )=1 (two orders of magnitude lower than that of C₂).     

Correlation patterns between 11 diffuse interstellar bands and ultraviolet extinction

We relate the equivalent widths of 11 diffuse interstellar bands, measured in the spectra of 49 stars, to different colour excesses in the ultraviolet. We find that most of the observed bands correlate positively with the extinction in the neighbourhood of the 2175-Å  bump. Correlation with colour excesses in other parts of the extinction curve is more variable from one diffuse interstellar band to another; we find that some diffuse bands (5797, 5850 and 6376 Å) correlate positively with the overall slope of the extinction curve, while others (5780 and 6284 Å) exhibit negative correlation. We discuss the implications of these results on the links between the diffuse interstellar band carriers and the properties of the interstellar grains.     

New approaches to the modelling of surface chemistry on interstellar grains

In recent years, the need to replace rate equations for studying grain-surface chemistry in the modelling of interstellar clouds has become apparent. In this article, we discuss the three new replacement methods that have been suggested to date, and contrast their relative strengths and weaknesses. This revised version was published online in July 2006 with corrections to the Cover Date.     

The small-scale structure in interstellar H i: a resolvable puzzle

During the past decade or so, measurements of Galactic H  i absorption using VLBI against extragalactic sources, as well as multi-epoch observations in pulsar directions, have detected small-scale transverse variations corresponding to tens of au at the distance of the absorbing matter. Hitherto these measurements have been interpreted as small-scale structure in the H  i distribution with densities n _{H  i} ∼10⁴–10⁵ cm⁻³, orders of magnitude greater than those of the pc-scale structure. Naturally, it is difficult to imagine how such structures could exist in equilibrium with other components of the ISM.
In this paper we show that structure on all scales contributes to the differences on neighbouring lines of sight, and that the observed differences can be accounted for by a natural extension of the distribution of irregularities in the distribution of H  i opacities at larger scales, using a single power law. This, in our opinion, should put an end to the decades-long puzzle of the so-called small-scale structure in H  i and other species in the Galaxy.     

Thermal desorption of water ice in the interstellar medium

Water (H₂O) ice is an important solid constituent of many astrophysical environments. To comprehend the role of such ices in the chemistry and evolution of dense molecular clouds and comets, it is necessary to understand the freeze-out, potential surface reactivity and desorption mechanisms of such molecular systems. Consequently, there is a real need from within the astronomical modelling community for accurate empirical molecular data pertaining to these processes. Here we give the first results of a laboratory programme to provide such data. Measurements of the thermal desorption of H₂O ice, under interstellar conditions, are presented. For ice deposited under conditions that realistically mimic those in a dense molecular cloud, the thermal desorption of thin films (≪50 molecular layers) is found to occur with zeroth-order kinetics characterized by a surface binding energy, E _des, of 5773 ± 60 K, and a pre-exponential factor, A , of 10^30 ± 2 molecules cm⁻² s⁻¹. These results imply that, in the dense interstellar medium, thermal desorption of H₂O ice will occur at significantly higher temperatures than has previously been assumed.     

The diffuse interstellar bands: a dipolebound state hypothesis

It is proposed that some, possibly many, of the unidentified diffuse interstellar absorption bands arise from rovibronic transitions between the ground states of negatively charged molecules and/or small grains, and shallow dipolebound electronic states which lie close to the electron detachment threshold. Under this hypothesis the attributes for the neutral 'molecular' frameworks are electron affinities between 1 and 3 eV and permanent electric dipole moments of 2 debye or greater. Boundbound spectra involving the lowest rotational levels have not been detected in the laboratory, but these proposed carriers appear to be capable of satisfying the main observational astronomical constraints: transitions that lie in the range from the near-ultraviolet to the near-infrared; a wide range of widths; band wavelengths that are invariant; and a large number of related but distinct carriers. The wavelengths of the lowest rotational lines of the band of the transition between the ground and a dipolebound electronic state of the CH₂CN molecule appear to be consistent with a diffuse band near 8037 Å.     

H3+ in diffuse interstellar gas

A model is constructed of the material in front of the star Cygnus OB2 no. 12 in which dense cores are embedded in diffuse clumps of gas. The model reproduces the measured abundances of C₂ and CO, and predicts a column density of 910¹⁰ cm² for HCO⁺.     

The effect of grain size distribution on H2 formation rate in the interstellar medium

The formation of molecular hydrogen  (H₂)  in the interstellar medium takes place on the surfaces of dust grains. Hydrogen molecules play a role in gas-phase reactions that produce other molecules, some of which serve as coolants during gravitational collapse and star formation. Thus, the evaluation of the production rate of hydrogen molecules and its dependence on the physical conditions in the cloud are of great importance. Interstellar dust grains exhibit a broad size distribution in which the small grains capture most of the surface area. Recent studies have shown that the production efficiency strongly depends on the grain composition and temperature as well as on its size. In this paper, we present a formula that provides the total production rate of  H₂  per unit volume in the cloud, taking into account the grain composition and temperature as well as the grain size distribution. The formula agrees very well with the master equation results. It shows that for a physically relevant range of grain temperatures, the production rate of  H₂  is significantly enhanced due to their broad size distribution.     

The interstellar medium in the Upper Cepheus-Cassiopeia region

We have studied the kinematics and spatial distribution of the interstellar gas in the sky region  110°≤ l ≤ 135°, 10°≤ b ≤ 20°  , using the extensive Leiden–Dwingeloo Survey of H  i emission and the Columbia Survey of CO emission. The spectra show two main velocity components, namely feature A that has a mean local standard of rest (LSR) velocity of  ∼0  km s⁻¹  and is due to the Lindblad ring of the Gould belt, and feature C that has a mean LSR velocity of  ∼−11  km s⁻¹  and is associated to the local arm or Orion arm. The H  i and CO distributions of feature A in the region trace a large complex of gas and dust known as the Cepheus Flare, which lies at a distance of 300 pc. The spectral line profiles of feature A, which are rather broad and often double-peaked, reveal that the Cepheus Flare forms part of a big expanding shell of interstellar matter that encloses an old supernova remnant associated with a void inside the Cepheus Flare. On the other hand, by analysing the distribution and velocity structure of feature C, we have detected a second large expanding shell in the region, located at a distance of 800 pc in the local arm. This shell surrounds the stellar association Cepheus OB4 and was probably generated by stellar winds and supernovae of Cepheus OB4. The radii, expansion velocities and H  i masses of the two shells are approximately 50 pc, 4  km s⁻¹ and  1.3 × 10⁴ M_⊙  for the Cepheus Flare shell and 100 pc, 4 km s⁻¹ and  9.9 × 10⁴ M_⊙  for the Cepheus OB4 shell. Both shells have similar ages of the order of a few 10⁶ yr.     

The possibility of nitrogen isotopic fractionation in interstellar clouds

The possibility of nitrogen isotopic fractionation owing to ion–molecule exchange reactions involving the most abundant N-containing species in dense interstellar clouds has been explored. We find that exchange reactions between N atoms and N-containing ions have most influence on the fractionation, although the extent of fractionation is too small to be readily detectable.