Sediment record of short-lived ice-contact lakes, Burroughs Glacier, Alaska

Sediments deposited in two small ice-contact lakes with low rates of sediment input have been studied in subaerial exposures. Sediment characteristics are a function of the water source (glacial meltwater versus non-meltwater), proximity to the glacier margin and lake shore, amount of supraglacial debris, and lake duration. Calving Lake expanded (and later partially drained) as a calving ice margin retreated. Nearshore deltas contain 1 × 10⁵ m³ stratified sand and gravel deposited at rates up to 1 m/yr during a 9-yr interval. Deltaic sediment contains types A and B ripple-drift cross-lamination, draped lamination, and scour surfaces caused by variations in water-flow velocity and the amount of sediment settling from suspension. Most water inflow came from non-subglacial meltwater sources and was sediment-poor, so overflow and interflow sedimentation processes dominated the offshore environment. Offshore sediment generally contains massive silt or silt interbedded with fine-grained sand deposited at rates of 1.3-1.5 cm/yr. Iceberg gravity craters observed on the lake plain were formed when icebergs impacted the lake floor during calving events. In Bruce Hills Lake, proximity to glacier ice and the presence of supraglacial sediment formed coarsening-upward successions when debris fell directly from an ice ledge onto silty lacustrine sediment.     

Dynamic sea-level change during the last deglaciation of northern Iceland

Rundgren, M., Ingólfsson, Ó., Björck, S., Jiang, H. & Haflioason, H. 1997 (September): Dynamic sea-level change during the last deglaciation of northern Iceland. Boreas , Vol. 26, pp. 201–215. Oslo. ISSN 0300–9483.
A detailed reconstruction of deglacial relative sea-level changes at the northern coast of Iceland, based on the litho- and biostratigraphy of lake basins, indicates an overall fall in relative sea level of about 45 m between 11300 and 9100 BP, corresponding to an isostatic rebound of 77 m. The overall regression was interrupted by two minor transgressions during the late Younger Dryas and in early Preboreal, and these were probably caused by a combination of expansions of local ice caps and readvances of the Icelandic inland ice-sheet margin. Maximum absolute uplift rates are recorded during the regressional phase between the two transgressions (10000–9850 BP), with a mean value of c . 15 cm ¹⁴C yr^-1 or 11–12 cm cal. yr^-1. Mean absolute uplift during the regressional phase following the second transgression (9700–9100 BP) was around 6 cm ¹⁴C yr^-1, corresponding to c . 3 cm cal. yr^-1, and relative sea level dropped below present-day sea level at 9000 BP.     

A Late Weichselian find of polar bear (Ursus maritimus Phipps) from Denmark and reflections on the paleoenvironment

The mandible of a polar bear (Ursus maritimus Phipps) found in about 1920 at Kjul Å, North Jutland, and described by Nordmann & Degerbol in 1930. has been ^l4C dated to 11.100 ± 160 B.P. It is so far the only find of polar bear in Denmark. Comparison with recent ¹⁴C datings of Swedish and Norwegian polar bears shows that the Danish specimen was a member of a southern Scandinavian Late Weichselian population. The contemporaneous Zirphaeu sea deposits can be regarded as the boreal-arctic shallow water equivalent of the arctic Upper Saxicava sand deposits from northern Jutland. The polar bear mandible, however, was deposited on land, as was the metacarpal bone of a brown bear ( Ursus arctos ) from the nearby Nr. Lyngby locality of Allerød age. The overall picture of the Late Weichselian mammal fauna in Denmark shows a mixed composition of different ecotypes. Their sympatric occurrence points at a unique environment not comparable to any now existing, and probably related to the very low latitude of the Weichselian ice sheet.     

Chronology and paleoenvironments during the late Weichselian deglaciation of the southwest Iceland shelf

Foraminifera, sedimentology, and tephra geochemistry in core 93030-006 LCF from the southwestern Iceland shelf were used to reconstruct paleoenvironments between 12.7 and 9.4 ¹⁴C ka BP. Seismic-reflection profiles place the core in glacial-marine and marine sediments within one meter of the underlying glacial till. Foraminifers in the earliest glacial-marine sediments provide a record of ice-distal conditions and immigration of slope species onto the shelf in association with warm Atlantic water. Meltwater increased during the Allerød under a weakened Atlantic water influence. Arctic conditions began by 11.14 ₁₄C ka BP with an abrupt increase in meltwater and near exclusion of boreal fauna from the shelf. Meltwater diminished in the early Younger Dryas, coinciding with sea-surface cooling between 11.14 and 10.5 ¹⁴C ka BP. A slight warming recorded in the uppermost glacial-marine sediments was interrupted by an inferred jökulhlaup event emanating from glacier ice on the Western Volcanic Zone. Retreat of the ice margin from the sea sometime between c. 10.3 and 9.94 ¹⁴C ka BP coincided with this event. The onset of postglacial marine sedimentation occurred along with increasing evidence of Atlantic water c. 9.94 ¹⁴C ka BP and was interrupted by a short-lived Pre-boreal cooling of the Irminger Current c. 9.91 ¹⁴C ka BP. Conditions similar to those today were established by 9.7 ¹⁴C ka BP.     

Apatite fission track analysis in the Argentera massif: evidence of contrasting denudation rates in the External Crystalline Massifs of the Western Alps

Apatite fission track dating from a central transect in the Argentera massif (southernmost External Crystalline Massif = ECM) yielded ages between 8.05 ± 0.6 and 2.4 ± 0.2 Myr, with a positive age/altitude correlation above 3 Ma, 1200 m. Recognising a thermal peak at c . 250°C, 33 Ma, based on stratigraphic, metamorphic and ³⁹Ar/⁴⁰Ar data, the present results suggest a slow cooling rate (8–5°C) for the Argentera massif during the Oligocene–early Pliocene. This rate compares with that from the Pelvoux massif, but contrasts with those observed in the northern ECM (Mont-Blanc and Aar: up to 14°C Myr⁻¹) for the same time interval. This can be related to the different location of the ECM within the collided European margin. At about 3–4 Ma, the denudation rate would have increased up to c . 1 mm yr⁻¹ in the Argentera massif, reaching the same value as in the Belledonne and northern ECM, likely a consequence of Penninic thrust inversion.     

The flow of surface-derived fluids through Alice Springs age middle-crustal ductile shear zones, Reynolds Range, central Australia

The south-east Reynolds Range, central Australia, is cut by steep north-west-trending Alice Springs age ( c. 334  Ma) shear zones that are up to hundreds of metres wide and several kilometres long with reverse senses of movement. Amphibolite facies (550–600  °C, 500–600  MPa) shear zones cut metapelites, while greenschist facies shear zones (420–535  °C, 400–650  MPa) cut metagranites. The sheared rocks commonly underwent metasomatism implying that the shear zones were the pathways of significant fluid flow. Altered granites within greenschist facies shear zones have gained Si and K but lost Ca and Na relative to their unsheared counterparts, suggesting that the fluid flowed down-temperature (and hence probably upward) through the shear zones. Time-integrated fluid fluxes calculated from silica addition are up to 2.1×10¹⁰ mol  m⁻² ( c. 4.2×10⁵  m³  m⁻²). Similar time-integrated fluid fluxes are also estimated from changes in K and Na. The sheared granitic rocks locally have δ¹⁸O values as low as 0 which is much lower than the δ¹⁸O values of the adjacent unsheared granites (7 to 9), implying that the fluid which flowed through these shear zones was derived from the surface. For the estimated time-integrated fluid fluxes, the fluids would be able to retain their isotopic signature for many tens to hundreds of kilometres. The flow of surface-derived fluids into the ductile middle crust, with subsequent expulsion upwards through the shear zones, may have been driven by seismic activity accompanying the Alice Springs deformation.     

Optimizing sampling strategy for radiocarbon dating of Holocene fluvial systems in a vertically aggrading setting

In this paper we address the question of how to determine the period of activity (sedimentation) of fossil (Holocene) fluvial systems in vertically aggrading environments. Our data base consists of almost 100 ¹⁴C ages (partly AMS) from the Rhine–Meuse delta in the central Netherlands. Radiocarbon samples from the tops of lithostratigraphically correlative organic beds underneath overbank deposits (sample type 1) yield consistent ages, indicating a synchronous onset of overbank deposition over distances of at least up to 20 km along channel belts. Similarly, ¹⁴C ages from the base of organic residual channel fills (sample type 3) generally indicate a clear termination of within-channel sedimentation. In contrast, ¹⁴C ages from the base of organic beds overlying overbank deposits (sample type 2), commonly assumed to represent the end of fluvial sedimentation, show a large scatter reaching up to 1000 ¹⁴C years. This setting usually produces ¹⁴C ages significantly younger than residual channels of the same fluvial system, indicating the presence of non-depositional unconformities. These usually occur on top of slightly elevated sediment bodies (especially natural levee deposits), which often contain palaeosols. Such hiatuses appear to be much more abundant than hitherto supposed. We conclude that a combination of sample types 1 and 3 generally yields a satisfactory delimitation of the period of activity of a fossil fluvial system. The problems associated with ¹⁴C samples of type 2 may also be present in coastal areas with an alternation of tidal deposits and organic beds.     

Natural Cadmium Isotopic Variations in Eight Geological Reference Materials (NIST SRM 2711, BCR 176, GSS-1, GXR-1, GXR-2, GSD-12, Nod-P-1, Nod-A-1) and Anthropogenic Samples, Measured by MC-ICP-MS

In this study, the Cd isotopic composition of various geological reference materials and anthropogenic samples was investigated. The measurements were made by multicollector ICP-MS and instrumental mass fractionation was controlled using a "sample-standard bracketing" technique. Cadmium isotopic data are reported relative to an internal Cd solution (Cd Spex) and expressed as the ¹¹⁴ Cd/¹¹⁰Cd delta value. Two other Cd solutions (Prolabo and JMC) were analysed and yielded the same 0% delta value. A fractionated Cd metal sample (Münster Cd) was used as a secondary reference material for Cd isotopic measurements and we obtained a ¹¹⁴ Cd/¹¹⁰ Cd delta value of 4.48% relative to Cd Spex solution. As opposed to multi-stage Cd purification previously published in the literature, a new one step anionic exchange purification using dilute HCl for the analysis of Cd isotopes in geological samples was developed. This method enabled a high recovery (> 95%) and effective separation of the sample matrix to be achieved. The long-term external reproducibility was evaluated at 0.12% (2 standard deviations) for the ¹¹⁴ Cd/¹¹⁰Cd ratio, based on reference solutions and replicated measurements of samples over one year. The variation of Cd isotopic composition of natural terrestrial samples is restricted to a small range of 0.4%, which is similar to previously reported results. In contrast, large variations of Cd isotopic composition were found for anthropogenic samples with values as low as −0.64% for a dust sample issued from a lead smelter and values as high as +0.50% for NIST SRM 2711 (metal-rich soil). These variations are 10 times larger than the reproducibility and suggest that Cd isotopes can be useful as tracers of anthropogenic sources of Cd in the environment.     

Dating bedrock gorge incision in the French Western Alps (Ecrins-Pelvoux massif) using cosmogenic 10Be

We report in-situ produced ¹⁰Be data from the Gorge du Diable (French Western Alps) to date and quantify bedrock gorge incision into a glacial hanging valley. We sampled gorge sidewalls and the active channel bed to derive both long-term and present-day incision rates. ¹⁰Be ages of sidewall profiles reveal rapid incision through the late Holocene (ca 5 ka) at rates ranging from 6.5 to 13 mm yr⁻¹. Present-day incision rates are significantly lower and vary from 0.5 to 3 mm yr⁻¹ within the gorge. Our data imply either delayed initiation of gorge incision after final ice retreat from internal Alpine valleys at ca 12 ka, or post-glacial surface reburial of the gorge. Our results suggest that fluvial incision rates >1 cm yr⁻¹ into crystalline bedrock may be encountered in transient landscape features induced by glacial-interglacial transitions.     

AMS 14C measurements and macrofossil analyses of a varved sequence near Pudozh, eastern Karelia, NW Russia

The laminated sediments at Pudozh in eastern Karelia are generally assumed to have been deposited between 13 000 and 16 000 ¹⁴C yr BP and have been used to date the recession of the active ice margin. However, 17 AMS ¹⁴C measurements performed on terrestrial plant macrofossils contained in these sediments show that deposition began during the late Allerφd, when the ice margin had already receded to the northern part of Lake Onega. Based on an age model, we assume that the 1933-year-long varved sequence covers the time period between c. 12 900 and 11 000 calendar years BP. During this period, which comprises the later part of the Late Weichselian and the early Holocene, the local vegetation consisted of open, tree-less dwarf shrub heaths. Increased soil erosion may have occurred before 12 550 calendar years BP.     

40Ar/39Ar Constraints on the tectonic history and architecture of the ultrahigh-pressure Sulu orogen

New ⁴⁰Ar/³⁹Ar ages are presented from the giant Sulu ultrahigh-pressure (UHP) terrane and surrounding areas. Combined with U-Pb ages, Sm-Nd ages, Rb-Sr ages, inclusion relationships, and geological relationships, they help define the orogenic events before, during and after the Triassic collision between the Sino–Korean and Yangtze Cratons. In the Qinling microcontinent, tectonism occurred between 2.0 and 1.4 Ga. The UHP metamorphism occurred in the Yangtze Craton between 240 and 222 Ma; its thermal effect on the Qinling microcontinent was limited to partial resetting of K-feldspar ⁴⁰Ar/³⁹Ar ages. Subsequent unroofing at rates of 5–25 km Myr⁻¹ brought the UHP terrane to crustal levels where it underwent a relatively short amphibolite facies metamorphism. The end of that metamorphism is marked by ⁴⁰Ar/³⁹Ar ages in the 219–210 Ma range, implying cooling at crustal depths at rates of 50–200 °C Myr⁻¹. Ages in the 210–170 Ma range may reflect protracted cooling or partial resetting by Jurassic or Cretaceous magmatism. Jurassic 166–149 Ma plutonism was followed by cooling at rates of c. 15 °C Myr⁻¹, suggesting relatively deep crustal conditions, whereas Cretaceous 129–118 Ma plutonism was succeeded by cooling at rates of c. 50 C Myr⁻¹, suggesting relatively shallow crustal depths.     

Timing of the last deglaciation in Lithuania

Boulders from the Grūda Moraine, which is associated with the maximum extent of the Scandinavian Ice Sheet (SIS) during the last glaciation, and the Baltija (also referred to as the South Lithuanian), the Middle and North Lithuanian moraines, which are associated with recessional stages of the SIS, were sampled for surface exposure dating using ¹⁰Be. By combining these data with existing radiocarbon ages, we developed a chronology for the retreat of the SIS margin in Lithuania. Our new ¹⁰Be ages suggest that the SIS margin began to retreat from its maximum extent at 18.3 ± 0.8 ¹⁰Be kyr. Based on a probable correlation of the Baltija Moraine with the Pomeranian Moraine in Poland, we infer that the Baltija Moraine was formed following a re-advance of the SIS margin. The ice margin retreated from the Baltija position at 14.0 ± 0.4 ¹⁰Be kyr. The SIS-margin retreat paused at least two more times to form the Middle Lithuanian Moraine at 13.5 ± 0.6 ¹⁰Be kyr and the North Lithuanian Moraine (tentatively correlated to the Pajūris Moraine) at 13.3 ± 0.7 ¹⁰Be kyr. Subsequent ice-margin retreat from the North Lithuanian Moraine represented the final deglaciation of Lithuania. Direct dating of these moraines better constrains the relation of ice-margin positions in Lithuania to those in adjacent countries as well as the SIS response to climate change.     

Isotope geochemistry, petrology and depositional environments of the diatomite-dominated Tripoli Formation (Lower Messinian), Sicily

ABSTRACT The Tripoli Formation (Lower Messinian) in Sicily includes diatomites irregularly alternating with marl and carbonate beds and lies, stratigraphically, between the Tortonian pelagic marls and the evaporitic Calcare di base. The relationships between mineralogy, textural features and oxygen-carbon isotopic compositions of carbonate components point to a wide variability of depositional conditions and suggest that Tripoli sedimentation occurred in small basins characterized by periodic and marked restriction from the open sea.
The isotopic values of calcite and dolomite in the diatomites suggest an evolution from normal marine towards more restricted environments. Evaporating conditions are also indicated by the occurrence of anhydrite, length-slow chalcedonic quartz and moulds of gypsum. In a more advanced stage, the precipitation of heavy δ¹⁸0 dolomite in the interstitial pores of fossil-poor diatomites denotes an environment with highly evaporated water. Mixing of meteoric and marine waters, on the other hand, might have favoured the precipitation of a dolomite characterized by relatively low δ¹⁸0 and δ¹³C values.
The deposition of marl and carbonate beds alternating with or overlying the diatomites took place in an environment with highly evaporated marine waters on the basis of δl¹⁸O values of dolomite (up to + 9.10‰) and aragonite (up to + 5.83‰), occurrence of evaporitic minerals and lack of fossils. The presence at these levels of calcite with extremely negative δ¹³C values (down to - 38.40‰), filling gypsum moulds, suggests activity of sulphate-reducing bacteria. Some aragonitic marls, however, bear evidence of deposition in relatively normal marine conditions.     

Climate variability in the SE Alps of Italy over the past 17 000 years reconstructed from a stalagmite record

Stalagmite SV1 from Grotta Savi, located at the SE margin of the European Alps (Italy), is the first Alpine speleothem that continuously spans the past c . 17kyr. Extension rate and δ¹⁸O_c record for the Lateglacial probably reflect a combination of temperature and rainfall, with rainfall exerting the dominant effect. Low speleothem calcite δ¹⁸ O_c values were recorded from c . 14.5 and 12.35 kyr, during GI-1 (Bølling— Allerød) interstadial, which in our interpretation, was warm and wet. The GS-1 (Younger Dryas) was characterized by a shift to heavier δ¹⁸ O_c, coinciding with δ¹³C_c enrichment and extremely low extension rate (<8 μm/year). These characteristics indicate that GS-1 climate was cool and dry in the SE Alps. Calibration using historical data revealed that there is a positive δ¹⁸O_c/dT relationship. A 1°C rise in mean annual temperature should correspond to c . 2.85% increase of SV-1 δc¹⁸O_c. We reconstructed a slow and steady temperature rise of c . 0.5°C since 10 kyr BP, in broad agreement with reconstructions from pollen data for SE Europe. Stalagmite SV1 indicates that climate variability in the SE Alps has been influenced by the Mediterranean Sea for the past c . 17 kyr.     

Horizontal Strain Rate in Relation to Vein Formation of the Hishikari Gold Deposits, Southern Kyushu, Japan

Abstract: The Hishikari deposits comprise the Honko (Main), Yamada, and Sanjin deposits. The horizontal strain in the direction (approx. N40°W normal to the general NE-SW strike of the Hishikari vein system was calculated, based on the measured total vein widths to the distance along three crosscuts. Veins were assumed to accompany no significant fault displacement in the calculation. Veins in the eastern and the middle parts of the Honko-Sanjin deposits spatially occupy 3. 2% and 1. 3%, respectively, and veins in the Yamada deposit occupy 6. 7%. Significant local variation of strain is observed in some areas. Reported K-Ar ages on adularia-quartz veins indicate the duration of vein opening to be 2. 6 × 10⁵ yr in the Honko-Sanjin deposits and 5. 9 × 10⁵ yr in the Yamada deposit. Horizontal strain rates were calculated to be 5. 0–12 × 10^-8 yr^-1through the Hishikari deposits. The calculated strain rates at the Hishikari deposits are roughly comparable to the regional horizontal strain rate in the Recent. Widespread extensional movement in southern Kyushu seems to have been able to provide sufficient strain for the formation of the Hishikari deposits, rather than contribution of local movements.     

Holocene lateral expansion, peat growth and carbon accumulation on Haukkasuo, a raised bog in southeastern Finland

Paludification intensity and peat deposition on Haukkasuo bog in southeastern Finland were studied with peat stratigraphic investigations by taking 79 samples for ¹⁴C carbon dating and 164 volumetric samples. Peat formation of Haukkasuo, a concentric raised bog, began about 10 400 cal. BP. Lateral expansion has been largely controlled by the flat clayey floor, which has favoured rapid growth of the bog. During the first 400 years of its existence the bog covered one-fifth, and in the following 2000 years one-half, of its present extent. The long-term carbon accumulation rate averages 22.3 g C/m²/yr in the central part of Haukkasuo and 16.7 g C/m²/yr in its margins. The highest rates of carbon accumulation over 500-year periods were recorded in the central part of the bog in 6500–5500, 3500–2500 and 1500–0 cal. BP. The rate of vertical peat increment was higher than average in these periods, and the peat was mainly slightly humified and, when close to the surface, un compacted. The rate of carbon accumulation was lowest in 5500–3500 and 2500–2000 cal. BP, when the rate of vertical growth was lower than average and the peat was more humified than average. The formation of peat, the rate of vertical peat increment and the succession of peat types in Haukkasuo have mainly been controlled by hydrological changes caused by local factors, although climatic factors might also be important. In particular, the formation of slightly humified peat in 3300–2700 cal. BP and during the last 1300 years can be related to humid climate.     

Lateglacial and Holocene terrestrial and marine proxies reflecting climate changes in the Malangen fjord area, Norway, northeast North Atlantic

A high-resolution Younger Dryas–late Holocene record of climate and environment from the Malangen fjord has been established on the basis of two marine sediment cores. Five pollen-spore assemblage zones have been defined covering the period c . 11 500 cal. yr BP (10 200 ¹⁴C yr BP) to c . 1600 cal. yr BP (1600 ¹⁴C yr BP) with a hiatus of c . 2000 cal. years between c . 10 200 and 8100 cal. yr BP (9000 and 7300 ¹⁴C yr BP). The Holocene vegetation development from pioneer vegetation to forest development, identified in the marine pollen record, correlates well with pollen records from terrestrial sections of northern Norway. The marine pollen record was also correlated directly with marine proxy records of the bottom water temperature investigated in the same sediment cores. Correlation between the marine and terrestrial proxies suggests that changes in the influx of warm Atlantic Water to the fjord led to an instant change in the vegetation of the surrounding land area. The results thus support a strong link between marine and atmospheric mean climatic states in the North Atlantic region throughout the Holocene.     

Refinements in BaSO4 to CO2 Preparation and δ18 O Calibration of the Sulfate Reference Materials NBS-127, IAEA SO-5 and IAEA SO-6

Refinements have been made to achieve over 99% yield in the conversion of CO to CO₂ in order to improve the reproducibility and accuracy of δ¹⁸ O measurements in sulfates. BaSO₄ (10-15 mg) was mixed with an identical amount of spectrographic-grade graphite and loaded into a Pt boat. The mixture was gradually heated to 1100 °C to reduce sulfate to CO and CO₂; the former gas was simultaneously converted to CO₂ by a glow discharge between Pt electrodes immersed in a magnetic field (produced by a pair of external neodymium magnets). A small memory effect was noticed during the analysis (less than 0.3‰ per 10‰ difference in δ¹⁸ O between two subsequently analysed samples). The memory effect, however, was suppressed by repetitive preparation of the same specimen. CO₂ produced in this way from sulfate reference samples was analysed on a dual inlet and triple collector mass spectrometer along with CO₂ equilibrated with VSMOW, GISP and SLAP water reference samples. To avoid large departures of measured isotope ratios from ¹⁸O/¹⁶O of the working calibrator we used CO₂ gas prepared from ocean water sulfate for this purpose. The calibrated δ¹⁸ O values (in ‰) obtained in this way for NBS-127, IAEA SO-5 and IAEA SO-6 reference materials were 8.73 ± 0.05, 12.20 ± 0.07 and -10.43 ± 0.12, respectively.     

Diffusion-controlled corona reaction and overstepping of equilibrium in a garnet granulite, Yenisey Ridge, Siberia

Diffusion modelling is applied to layered garnet–pyroxene–quartz coronas, formed by a pressure-induced reaction between plagioclase and primary pyroxene in a metabasic granulite. The reconstructed reaction involves some change in composition of reactant minerals. The distribution of minerals between layers is satisfactorily explained by diffusion-controlled reaction with local equilibrium, in which the diffusion coefficient for Al was smaller than those for Fe, Mg and Ca by a factor of approximately four. Diffusion of Mg towards plagioclase implies a chemical-potential gradient for MgO component in a direction opposite to the changing Mg content of garnet; this is explained by the influence of Al₂O₃ on the chemical potential of the pyrope end-member. Grain-boundary diffusion is suggested to have operated, possibly with composition gradients different from those in the bulk minerals. Chemical-potential differences across the corona are estimated from the variation in garnet composition, enabling affinity (the free energy change driving the reaction) to be estimated as 6.9±1.8  kJ per 24-oxygen mole of garnet produced. This implies that the pressure for equilibrium among the minerals was overstepped by 1.4±0.4  kbar. The probable P–T conditions of reaction were in the range 650–790  °C, 8–10  kbar. Assuming a timescale of reaction between 10⁶ and 10⁸ years, estimated diffusion coefficients for Fe, Mg and Ca are in the range 9×10⁻²³ to 5×10⁻²⁰ m² s⁻¹. These are consistent with experimental values in the literature for solid-state diffusion, including grain-boundary diffusion.     

Carbon sources in arc volcanism, with implications for the carbon cycle

New CO₂/³ He data from the East Sunda Arc (Indonesia) confirm earlier observations that arc volcanic gases have higher CO₂/³ He ratios than MOR environments.On average, > 80% of arc volcanic CO₂ is recycled, exogene carbon. Addition of a few percent of carbonate-bearing sediments to the mantle wedge explains much of the carbon abundance andcarbon isotopic data of arc gases, but can not explain the He isotope observations. The CO₂/³He in arc volcanoes is not strongly dependent on the composition of modem trough sediments (e.g. deep sea clays vs carbonate-rich sequences), and calcite veins in the hydrothermally altered subducted slab may provide a contribution to the recycled carbon flux of, arcs. The sum of globally deep-subducted sediment and slab carbon exceeds the estimated arc CO₂ flux, and approximately 3.5 teramole of carbon may return annually to the mantle in convergent zones. The modem combined processes of MOR volcanism, slab alteration, and subduction volcanism do not produce a substantial carbon flux into the exosphere, and rate-changes in ocean floor spreading are unlikely to cause major changes in atmospheric CO₂ as a result of changes in the volcanic CO₂ fluxes. Intense pulses of flood basalt volcanism, however, may alter the CO₂ contents of the atmosphere over the course of a millenium or so, and influence global climate.