Evolution of clay mineral assemblages and organic matter in the late glacial-Holocene sedimentary infill of Lake Annecy, (northwestern Alps): paleoenvironmental implications

The basin fill of Lake Annecy was investigated from a 44 m core which reached down to glacial sediments of the last glaciation (called Würm in the alpine areas). We analyzed three main parameters: sediment texture (optical microscopy and laser microgranulometry), clay mineral assemblages (CMA by XRD), and organic matter (OM by Rock-Eval pyrolysis). Settling of suspended load, under variable hydrodynamic conditions is the main depositional process. Both CMA and OM provenances can be recognized for the different sedimentary and igneous-metamorphic formations (Carboniferous to Quaternary, and older crystalline basement) and corresponding areas, in the surrounding region of Lake Annecy. Oligocene-Miocene molasses, Early Cretaceous marls, and Early-Middle Jurassic marls and shales are the main sedimentary sources. Two distinct processes were operating: destruction of glacial sediments (till sensu largo) and reworking, or direct erosion and run-off from ice-free catchment areas. Clay minerals related to pedogenesis, and non-reworked terrestrial and lacustrine OM, were progessively added to these primary sources during the Late Würmian/Holocene transition to warmer climatic conditions. Rapid modifications of CMA and OM sources during the earlier phase of sedimentary infilling (Unit 2) suggest that valley glaciers connected to the lake basin almost completely disappeared within a few centuries.     

The lacustrine depression at Annecy (France), geological setting and Quaternary evolution

The Annecy lacustrine depression lies in a tectonic transverse valley of structural origin, linking the present day towns of Annecy and Ugine and bounded by the Bauges and Bornes massifs. Only the last two major glacial periods are represented in the stratigraphic and geomorphic evidence from the area, but its successive glaciations that have been largely responsible for the form of the valley within which the present day lake lies. Of particular importance were the lobes of the Arve glacier, one shaping the depression from the south-east; the other from the north. The retreat of the glaciers left behind a more extensive precursor of the present day Lac d'Annecy, which latter constitutes the residual body of open water after lake level lowering, partial infilling and drainage diversions within the catchment. The drainage basin of the extended lake formed shortly after the last glacial maximum (LGM) in the region. Its extent can be determined from field sampling and coring and its elevation can be established at 460 m above present day sea level. The present day lake is more isolated, since the Fier river, to the north, no longer drains into it. To the southeast, the course of the Chaise river has also been diverted, leaving the lake's drainage basin reduced to half its post-LGM size. The major paleogeographical events in the Late-Quaternary evolution of the basin are described in chronological sequence.     

Palyno- and chronostratigraphy of a long sequence from Lac d'Annecy (northern outer Alps, France)

Pollen analysis (absolute and relative frequencies) of a 44 m sedimentary sequence from Lac d'Annecy provides a record of vegetation history since deglaciation in the northern part of the French alpine foreland. Sixteen pollen zones are described and compared with those obtained from sites in adjacent areas, and 17 AMS radiocarbon dates provide a chronology which enables a minimum age for the termination of the last glaciation to be inferred. The pollen assemblages reflect the influence of a number of depositional processes, including selective sorting and sediment reworking, and thus illustrate some of the limitations inherent in the AMS radiocarbon dating of macroscopic plant remains. For instance, the basal Picea pollen assemblage zone corresponds to a lithological unit that contains reworked material, attributed to deposits older than St Germain II, which makes the ¹⁴C AMS radiocarbon date of 25 Ka BP obtained for this zone rather questionable. The existence of two climatic events prior to the Younger Dryas is confirmed. An influx of pollen from the nearby river inlet may explain why these events are well expressed in the pollen stratigraphy.     

The sedimentation history of Lake Huron and Georgian Bay: results from analysis of seismic reflection profiles

An extensive seismic reflection profile survey conducted concurrently with a sediment coring program in northern Lake Huron, Georgian Bay, and the North Channel revealed a detailed Holocene lake level history. Seven acoustic sequences were identified in the seismic stratigraphy, and these sequences show great variation in both the character and the spatial distribution of sediment deposition through time. The depths to the acoustically-defined sequence boundaries were digitized from the analog seismic records and merged with Loran-C navigation records from the cruise, yielding a three-dimensional record of the location of each sequence boundary. Thicknesses of the sequences were calculated from these depths, and a minimum-curvature spline surface was fit to the thickness data. These surfaces were used to construct isopach maps which show the trends in thickness of sediment accumulation throughout the lake basins for each of the sequences. ¹⁴C-AMS dates of materials from the cores fixed the dates of the sediment sequence boundaries, allowing sediment accumulation rates to be calculated. The distribution of sedimentation in the basins as shown on the isopach maps allowed assessment of sediment transport and water flow through the basins over time, which when combined with the work of Lewis & Anderson (1989), provides a detailed record of the transport and drainage of water through these basins as the Wisconsinan ice sheet retreated and isostatic rebound opened and closed outlets. Reversals of flow direction through the Straits of Mackinac and through the channels connecting Lake Huron and Georgian Bay and the North Channel are indicated by changes in sediment thickness distributions.     

Seismic stratigraphy of Lago Puyehue (Chilean Lake District): new views on its deglacial and Holocene evolution

Prior to the collection of a series of sediment cores, a high- and very-high-resolution reflection seismic survey was carried out on Lago Puyehue, Lake District, South-Central Chile. The data reveal a complex bathymetry and basin structure, with three sub-basins separated by bathymetric ridges, bedrock islands and interconnected channels. The sedimentary infill reaches a thickness of >200 m. It can be sub-divided into five seismic-stratigraphic units, which are interpreted as: moraine, ice-contact or outwash deposits (Unit I), glacio-lacustrine sediments rapidly deposited in a proglacial or subglacial lake at the onset of deglaciation (Unit II), lacustrine fan deposits fed by sediment-laden meltwater streams in a proglacial lake (Unit III), distal deposits of fluvially derived sediment in an open, post-glacial lake (Unit IV) and authigenic lacustrine sediments, predominantly of biogenic origin, that accumulated in an open, post-glacial lake (Unit V). This facies succession is very similar to that observed in other glacial lakes, and minor differences are attributed to an overall higher depositional energy and higher terrigenous input caused by the strong seismic and volcanic activity in the region combined with heavy precipitation. A long sediment core (PU-II core) penetrates part of Unit V and its base is dated as 17,915 cal. yr. BP. Extrapolation of average sedimentation rates yields an age of ca. 24,750 cal. yr. BP for the base of Unit V, and of ca. 28,000 cal. yr. BP for the base of Unit IV or for the onset of open-water conditions. This is in contrast with previous glacial-history reconstructions based on terrestrial records, which date the complete deglaciation of the basin as ca. 14,600 cal. yr. BP. This discrepancy cannot be easily explained and highlights the need for more lacustrine records from this region. This is the second in a series of eight papers published in this special issue dedicated to the 17,900 year multi-proxy lacustrine record of Lago Puyehue, Chilean Lake District. The papers in this special issue were collected by M. De Batist, N. Fagel, M.-F. Loutre and E. Chapron.     

U- and Th-series disequilibria in coastal infill sediments from Praia da Rocha (Algarve Region, Portugal): a contribution to the study of late Quaternary weathering and erosion

U- and Th-series disequilibria observed in a sequence of infill sediments from Praia da Rocha, southern Portugal, were used in combination with geochemical and particle size data to investigate sediment provenance with a view to resolving the late Quaternary weathering and erosion history of the Algarve region, and the stratigraphy of coastal karstic exposures of the Faro/Quarteira (FQ) formation. The red infill units can be distinguished from the brown and buff units on the basis of their lower residual U- and Th-concentrations, their differing post-depositional histories (as revealed by U- and Th-series disequilibria in sequentially extracted sediment phases), and their greater degree of sediment processing. Hence, the buff and brown infill units appear to be derived locally from weathering of the Miocene limestone whilst the red infill may be linked to large-scale mass movement of the FQ formation from further inland, but south of Silves, during the Late Pleistocene. This sequence of events confirms a close association between the formation of karst topography and infilling by gravitational slumping, debris flow and fluvial activity, and, hence, accounts for the complex (three-stage) sediment provenance of the infill material.     

The environmental history of a mountain lake (Lago Paione Superiore, Central Alps, Italy) for the last c. 100 years: a multidisciplinary, palaeolimnological study

A palaeoecological study of an oligotrophic alpine lake, Paione Superiore (Italy), provided a record of historical changes in water quality. Historical trends in lake acidification were reconstructed by means of calibration and regression equations from diatoms, chrysophycean scales and pigment ratios. The historical pH was inferred by using two different diatom calibration data sets, one specific to the alpine region. These pH trends, together with the record of sedimentary carbonaceous particles and chironomid remains, indicate a recent acidification of this low alkalinity lake.Concentration of total organic matter, organic carbon, nitrogen, biogenic silica (BSiO₂), chlorophyll derivatives (CD), fucoxanthin, diatom cell concentration and number of chironomid head capsules increased during the last 2–3 decades. When expressed as accumulation rates, most of these parameters tended to decrease from the past century to c. 1950, then all except P increased to the present day. A marked increase in sedimentary nitrogen may be related to atmospheric pollution and to the general increases in output of N in Europe. High C/N ratios indicate a prevailing allochthonous source of organic matter.Finally, the increase in measured air temperature from the mid-1800's appeared to be related to lake water pH before industrialization: cold periods generally led to lower pH and vice-versa. The more recent phenomenon of anthropogenic acidification has apparently decoupled this climatic-water chemistry relationship.     

Holocene diatom flora and stratigraphy from sediment cores of two Antarctic lakes (King George Island)

The diatom stratigraphy of Holocene sediment cores from two Antarctic lakes (Mondsee, Tiefersee; 62° 10 S/58° 50 W) of King George Island was investigated. The diatom assemblages were dominated by cosmopolitan species. The flora was composed of three main components: 1) taxa of submersed bryophytic habitats, which also occur in the bryophilic diatom flora of southern South America; 2) species of various terrestrial habitats, including some specific subantarctic taxa; 3) species distributed in coastal inland waters influenced by sea-spray.Changes in sediment pattern and diatom species composition seemed to reflect climatic changes. At least three different core sections were distinguished in both lakes: Two sections rich in mosses occur between approx. 7000–4700 B.P. and from 3200 B.P. to present, in general resembling present day conditions. In between is a section of high allochthonous content with generally low diatom concentrations and rising percentages of aerophilic, halophilic and alkaliphilic diatoms. An increase of melt water discharge, possible sea-spray influence, and lake- level fluctuations are discussed.Three new taxa are described: Achnanthes metakryophila nov. spec., Achnanthes renei nov. spec., Navicula australomediocris nov. spec. The taxonomy of selected taxa is discussed.     

The long-term succession of high-altitude cladoceran assemblages: a 9000-year record from Sägistalsee (Swiss Alps)

Cladoceran remains were analysed in a 1344 cm long sediment core from Sägistalsee (Swiss Alps, 1935 m asl) which covered the last 9000 years. Planktonic Cladocera were almost exclusively represented by Daphnia species, which occurred throughout the core. The chydorid fauna consisted of four species: Alona quadrangularis, Alona affinis, Acroperus harpae and Chydorus sphaericus of which the former was by far the most frequent species. The chydorid succession was characterised by disappearance and re-appearance of Acroperus harpae and Chydorus sphaericus at about 8400 and 3340 cal. BP, respectively. As a result, there was a long period of about 5000 years in which only two chydorid species were present with strong predominance (88.9%) of Alona quadrangularis. There was also a long-term trend of an increase of Alona affinis at the expense of Alona quadrangularis throughout the core.     

Multipathing and spectral modulation of the downgoing wavefield in a complex crust: an example from the KTB (Germany) borehole

VSP data collected in the KTB (Germany) borehole to a depth of 8.5 km in 1999 show a surprising spectral modulation of the downgoing wavefield. After filtering the data with the singular value decomposition technique it was found that below about 6.2 km there are two depth intervals where the modulation can be explained in terms of a basic wavelet plus two weighted and delayed copies of that wavelet, with the delay for each wavelet remaining almost constant in each interval. The boundary between the two intervals is at about 7.25 km depth and above and below this depth the delay for the second wavelet is almost the same, while the delay for the third wavelet is significantly different. Neither the modulation nor its depth variation are source related and cannot be explained in terms of multiple reflections in a subhorizontal low-velocity layer. On the other hand, finite difference synthetic data show that subvertical layering (which is prevalent in the borehole area) provides a mechanism that can explain the observations. This mechanism has analogies with the generation of the standard refracted (i.e. head) waves. When a plane wave front propagates perpendicular to the boundaries of a vertical low-velocity layer surrounded by two vertical high-velocity layers, refracted wave fronts are generated in the low-velocity layer, which in turn generate secondary wave fronts in the high-velocity layers. These wave fronts trail the primary wave fronts by a constant delay whose magnitude has a simple dependence on the thickness of the low-velocity layer and the velocities involved. This process creates multipath arrivals that in geological settings with steeply inclined and faulted layers may appear and disappear rather abruptly, which may contribute to a scattered appearance of the wavefield.     

The PIRLA project (Paleoecological Investigation of Recent Lake Acidification): an introduction to the synthesis of the project

Collected sets of papers synthesizing data derived from the PIRLA project (Paleoecological Investigation of Recent Lake Acidification) will appear in coming issues of the Journal of Paleolimnology. This paper is designed to highlight these forthcoming papers, review the development and objectives of PIRLA, and acknowledge the many who have supported PIRLA in so many crucial ways.This is the first of a series of papers to be published by this journal which is a contribution of the Paleoecological Investigation of Recent Lake Acidification (PIRLA) project. Drs. D.F. Charles and D.R. Whitehead are guest editors for this series.     

The late Pleistocene ostracod record of the crater lake sediments from Lago di Albano (Central Italy): changes in trophic status, water level and climate

Four cores (ranging between ca. 9 and ca. 14 m in length) from Lago di Albano in Central Italy were studied for their ostracod content, as well as algal and bacterial pigments, CaCO3 and concentration of organic matter. Cores PALB 94 1E and PALB 94 1C from Site 1, located at the bottom of a steep slope at 70 m water depth, where oxygen concentration is below 6 mg l-1, spans the Holocene and the late Pleistocene until 28 kyr B.P. (calibrated age). The other cores, PALB 94 6A and PALB 94 6B taken at a depth of 30 m, where oxygen is 7--11 mg l-1, represent mainly Pleistocene deposits.Ostracod valves were found in the lowermost ca. 3 m of the sequence at Site 1, dated to ca. 28--24 kyr B.P., and throughout the sequence from Site 6 which represents the interval 23--17 kyr B.P.Candona neglecta is the dominant species in most of the levels at Site 1, whereas both C. neglecta and Cyclocypris sp. dominate during different biostratigraphic zones at Site 6. The influx of springs entering the lake at Site 1 was inferred on the basis of species of the genus Potamocypris and Ilyocypris bradyi present in the record. Wide fluctuations in species abundance and assemblages in both coring sites indicate lake-water level oscillations between 28 to 17 kyr B.P. In particular, a strong rise in water level of the order of 40 m occurred between 24 and 23 kyr B.P. Fluctuations in productivity, oxygen availability and water temperature at both sites were also reconstructed on the basis of the ostracod assemblages and the algal and bacterial pigment concentrations. The environmental reconstruction reached using ostracod remains and pigments was verified with other proxy records published elsewhere such as invertebrate remains, diatoms, magnetic properties, etc. A synthesis of climatic reconstructions for Central and Southern Italy for the late Full Glacial is attempted on the basis of previous studies on hydrology, lithostratigraphy and palynology. Sharp fluctuations in lake palaeoproductivity/palaeoclimate recorded by invertebrate and pigment remains at both sites from Lago di Albano might be related to similar events reported in North Atlantic Full-Glacial records from marine and ice cores.