Comparative analysis of the methods used for the determination of the optical parameters of waters in the black sea according to the data of satellite measurements

We demonstrate the possibility of determination of the spectral characteristics of absorption and backward scattering of light in the Black Sea according to the data of a SeaWiFS satellite device. We use specially selected data of observations obtained under favorable atmospheric conditions. It is shown that the results of calculations performed by using different methods are almost identical and weakly depend on the model parameters of the spectral course of the coefficients of absorption of light by yellow substance and its scattering by suspended particles.     

Climatic intrannual variability of the geostrophic circulation of the main Black Sea current

A quasi-periodic (wave) spatial-temporal structure of the intrannual variability of the climatic fields of the seawater geostrophic motion within the constant halocline in the Black Sea (75–300m) has been revealed on the basis of generalized archival data on hydrological observations in the main Black Sea current (MBSC) near the Crimea and Caucasus. The variability with annual and semi-annual periods has the character of standing quasi-geostrophic waves at 2- to 4-month periods which become progressive as the direction of their propagation changes during the year. The energy characteristics for the forms of variability revealed are discussed and interpreted from the viewpoint of gradient-eddy waves and the hydrodynamic instability of the MBSC.Translated by Mikhail M. Trufanov.     

A numerical experiment on modelling synoptic eddies in the Black Sea during the summer season

An energetically-balanced model has been used to perform an eddy-resolving experiment on the calculation of the baroclinic circulation in the Black Sea. As the initial and boundary conditions, historical data on the density and tangential wind stress for the summer season have been used. Following the integration of a set of model equations, an array of anticyclonic eddies formed on days 50–60 on the margins of the Black Sea rim current. Off the Caucasus, Crimean, and Bulgarian coast, anticyclonic eddies are shown to be quasi-stationary. The north-western Black Sea and Anatolia coastal zone are areas of Black Sea rim current instability, where synoptic eddies — both cyclonic and anticyclonic — are generated.Translated by Vladimir A. Puchkin.     

Radioactive isotopes of caesium in the waters and near-water atmospheric layer of the Black Sea

The concentrations of¹³⁷Cs and¹³⁴Cs were measured using the sorption method in the waters of the Black Sea during 1986–1987. An inhomogeneous character of the contamination of the surface waters in the Black Sea due to the Chernobyl disaster is shown. The subsequent migration and redistribution of caesium radionuclides in the various seasons of the year were studied. The amount of¹³⁷Cs and¹³⁴Cs in the upper 50 m layer was estimated. The results of measuring the concentration of caesium radionuclides in the near-water atmospheric layer over the Black Sea and Mediterranean Sea in 1986–1987 are also reported.Translated by Mikhail M. Trufanov.     

Characteristics of Underwater Irradiation in the Black Sea in Spring (1993 and 1995)

We present the data on the values of the coefficients of vertical attenuation and diffusive reflection of light in the Black Sea in spring 1993 and 1995, compute the depths of one-percent quantum irradiation and the parameter Μ specifying the fraction of attenuation of directed light as a result of scattering: Μ = σ/ɛ, and compare the characteristics of underwater irradiation in the sea in different seasons for 1989–1995. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 3, pp. 44–48, May–June, 2005.     

Experience of remote monitoring in the Black Sea and the Mediterranean Sea in the optical spectrum band

The methodology of regional remote monitoring of the ocean on the basis of complex largescale studies carried out by the Marine Hydrophysical Institute of the Ukrainian SSR Academy of Sciences in the Black Sea and the Mediterranean Sea in 1987–1988 is considered. The collection of controlled parameters, ground facilities, methods of collecting and processing of satellite and subsatellite data, and features in the compilation of composition maps of the sea surface radiation temperature are discussed.Translated by Mikahil M. Trufanov.     

Analysis of the Variability of the Optical Properties of Water in the Black Sea in Summer 1998 According to the Data of a SeaWiFS Satellite Instrument

We study examples of surveys of the Black Sea performed with the help of a SeaWiFS satellite instrument. It is shown that the results of measurements carried out in spectral channels of 510 and 555nm give information on the basic specific features of the space and time variability of the characteristics of absorption and scattering of light in seawater. The use of a spectral channel of 412nm is inefficient due to the low reliability of the results of the procedure of atmospheric correction performed according to standard algorithms. The results of model calculations demonstrate that the predominant contribution to the absorption of light in the Black Sea in summer is made by the yellow substance.     

A sulfur budget for the Black Sea anoxic zone

A budget for the sulfur cycle in the Black Sea is proposed which incorporates specific biogeochemical process rates. The average sulfide production in the water column is estimated to be 30–50 Tg yr⁻¹, occurring essentially in the layer between 500 and 2000 m. About 3.2–5.2 Tg sulfide yr⁻¹ form during sulfate reduction in surface sediments of the anoxic zone. Total sulfur burial in anoxic sediments of 1 Tg yr⁻¹ consists of 10–70% (ca. 40–50% is the average) water column formed (syngenetic) component, the rest being diagenetic pyrite. As a maximum, between 3 and 5 Tg yr⁻¹ contribute sulfide to the bottom water or diffuse downward in the sediment. About 20–50 Tg yr⁻¹ sulfide is oxidized mostly at the chemocline and about 10–20% of this amount (4.4–9.2 Tg yr⁻¹) below the chemocline by the oxygen of the Lower Bosphorus Current. A model simulating the vertical distribution of sulfide in the Black Sea water column shows net consumption in the upper layers down to ca. 500 m, essentially due to oxidation at the chemocline, and net production down to the bottom. On the basis of the calculated budget anoxic conditions in the Black Sea are sustained by the balance between sulfide production in the anoxic water column and oxidation at the chemocline. On average the residence time of sulfide in the anoxic zone is about 90–150 yr, comparable to the water exchange time between oxic and anoxic zones. Hydrophysical control on the sulfur cycle appears to be the main factor regulating the extent of anoxic conditions in the Black Sea water column, rather than rates of biogeochemical processes.     

Late Quaternary chronology of the southern Black Sea basin

During New Euxinian time when sea level dropped below the sill connecting the Black and Marmara seas, the Black Sea became isolated and freshwater sediments were deposited. Now it is a semieuxinic basin with the oxic/anoxic boundary at 100–150 m. The seasonal changes in sedimentation are preserved in the form of laminated sequences. The counting of varves in southeastern Black Sea cores show the chronology of the O₂/H₂S interface. The age of the Holocene sapropel along the eastern margin ranges from 4000 to 1000 yr BP in deep water and 2500—1000 yr BP in shallower water. Sapropel formation started at 3650 yr BP at a water depth of 2200 m.     

Ventilation of the Black Sea pycnocline. Parameterization of convection, numerical simulations and validations against observed chlorofluorocarbon data

Data from field observations and numerical model simulations are used to understand and quantify the pathways by which passive tracers penetrate into the Black Sea intermediate and deep layers. Chlorofluorocarbon (CFC) concentrations measured during the1988 R.V. Knorr cruise show strong decrease with increasing density in the Black Sea and illustrate the very slow rate of ventilation of deep water in this basin. We develop a 3D numerical model based on the Modular Ocean Model (MOM), and calibrate it in a way to produce consistent simulations of observed temperature, salinity and CFCs. One important feature is the implementation of a special parameterization for convection, which is an alternative of the convective adjustment in MOM and handles the penetration of the Bosporus plume into the halocline. The model forcing includes interannually variable wind, heat and water fluxes constructed from Comprehensive Ocean–Atmosphere Data Set and ECMWF atmospheric analysis data and river runoff data. The analysis of observations and simulated data are focused on correlations between thermohaline and tracer fields, dynamic control of ventilation, and the relative contributions of sources at the sea surface and outflow from the Bosporus Strait in the formation of intermediate and deep waters. A simple theory is developed which incorporates the outflow from the strait along with the vertical circulation (vertical turbulent mixing and Ekman upwelling) and reveals their mutual adjustment. The analyses of simulated and observed CFCs demonstrate that most of the CFC penetrating the deep layers has its source at the sea surface within the Black Sea rather than from the Marmara Sea via the Bosporus undercurrent. Under present-day conditions, the surface CFC signals have reached only the upper halocline. Intrusions below 600 m are not simulated. The major pathways of penetration of CFCs are associated with cold-water mass formation sites, Bosporus effluent, as well as with the diapycnal mixing in the area of Rim Current. Future CFC sampling strategies coherent with the unique conditions in the Black Sea are discussed.     

The European coastal zone: characterization and first assessment of ecosystem metabolism

The geomorphic, oceanographic, terrestrial and anthropogenic attributes of the European coastal zone are described and published data on ecosystem function (primary production and respiration) are reviewed. Four regions are considered: the Baltic Sea, Mediterranean Sea, Black Sea and the European Atlantic coast including the North Sea. The metabolic database (194 papers) suffers from a non-homogeneous geographical coverage with no usable data for the Black Sea which was therefore excluded from this part of our study. Pelagic gross primary production in European open shelves is, by far, the most documented parameter with an estimated mean of 41 mmol C m⁻² d⁻¹, the lowest value is reported in the Mediterranean Sea (21 mmol C m⁻² d⁻¹) and the highest one in the Atlantic/North Sea area (51 mmol C m⁻² d⁻¹). Microphytobenthic primary production, mostly measured in shallow areas, is extrapolated to the entire 0–200 m depth range. Its contribution to total primary production is low in all regions (mean: 1.5 mmol C m⁻² d⁻¹). Although macrophyte beds are very productive, a regional production estimate is not provided in this study because their geographical distribution along the European coastline remains unknown. Measurements of pelagic community respiration are clearly too sparse, especially below the euphotic zone, to yield an accurate picture of the fate of organic matter produced in the water column. With a mean value of 17 mmol C m⁻² d⁻¹, benthic community respiration consumes approximately 40% of the pelagic organic matter production. Estuaries generally exhibit high metabolic rates and a large range of variation in all parameters, except microphytobenthic primary production. Finally, the problem of eutrophication in Europe is discussed and the metabolic data obtained in the framework of the Land–Ocean Interactions in the Coastal Zone (LOICZ) project are compared with available direct measurements of net ecosystem production.     

Water masses and decadal variability in the East Sea (Sea of Japan)

Water masses in the East Sea are newly defined based upon vertical structure and analysis of CTD data collected in 1993–1999 during Circulation Research of the East Asian Marginal Seas (CREAMS). A distinct salinity minimum layer was found at 1500 m for the first time in the East Sea, which divides the East Sea Central Water (ESCW) above the minimum layer and the East Sea Deep Water (ESDW) below the minimum layer. ESCW is characterized by a tight temperature–salinity relationship in the temperature range of 0.6–0.12 °C, occupying 400–1500 m. It is also high in dissolved oxygen, which has been increasing since 1969, unlike the decrease in the ESDW and East Sea Bottom Water (ESBW). In the eastern Japan Basin a new water with high salinity in the temperature range of 1–5 °C was found in the upper layer and named the High Salinity Intermediate Water (HSIW). The origin of the East Sea Intermediate Water (ESIW), whose characteristics were found near the Korea Strait in the southwestern part of the East Sea in 1981 [Kim, K., & Chung, J. Y. (1984) On the salinity-minimum and dissolved oxygen-maximum layer in the East Sea (Sea of Japan), In T. Ichiye (Ed.), Ocean Hydrodynamics of the Japan and East China Seas (pp. 55–65). Amsterdam: Elsevier Science Publishers], is traced by its low salinity and high dissolved oxygen in the western Japan Basin. CTD data collected in winters of 1995–1999 confirmed that the HSIW and ESIW are formed locally in the Eastern and Western Japan Basin. CREAMS CTD data reveal that overall structure and characteristics of water masses in the East Sea are as complicated as those of the open oceans, where minute variations of salinity in deep waters are carefully magnified to the limit of CTD resolution. Since the 1960s water mass characteristics in the East Sea have changed, as bottom water formation has stopped or slowed down and production of the ESCW has increased recently.     

Statistical Modeling of Monthly Anomalies of Atmospheric Precipitations for the Region of the Ukraine and Black Sea

The data array accumulated for the period 1946–1995 is used to select the most significant predictor of monthly anomalies of precipitation in the region of the Ukraine and Black Sea, namely, a large-scale circulation in a sector covering the North Atlantic and Europe. Three large-scale predictors (geopotential at a level of 500GPa, sea-level pressure, and the difference between the geopotentials at levels of 500 and 1000GPa) give almost identical results: their correlation with anomalies of precipitation is equal to 0.7–0.8 in winter and 0.4–0.5 in summer. The predominant mechanism of the influence of circulation on precipitations at low frequencies is the response of the trajectories of European cyclones to changes in the upper-tropospheric jet currents in the Atlantic-European sector described as the superposition of the North-Atlantic oscillation and the Eurasian mode. The decomposition of the fields of precipitations and circulation in the eigenmodes of the canonical correlation analysis opens a possibility of direct computation of the monthly average fields of precipitations for the entire territory of the Ukraine and Black Sea region according to the large-scale geopotential fields.     

Current field in the north-western Black Sea and its role in the distribution of hydrological characteristics

The data derived from the observation of current profiles and hydrophysical features, carried out in the north-western Black Sea in August 1992, are considered. The main features of the currents' structure have been identified; they are consistent with the distribution of the basic characteristics computed from the distributions of the hydrological elements (dynamic heights, cold content, density of the accessible potential energy). A relationship between the thickness of the cold intermediate layer (CIL) and the Richardson numbers near the layer core distinctly manifested itself in the convergence zone over the shelf edge. The average correlation coefficient between these quantities was equal to 0.877, and the range of sampling variability with a probability of 0.95 varied from 0.9 to –0.79.Translated by Vladimir A. Puchkin.     

Spectral contributions of the components of seawater to the beam attenuation coefficient in surface waters of the Mediterranean Sea

We compute model spectra of the beam attenuation coefficient in surface waters of the Mediterranean Sea. These spectra are used to determine the contribution of the components of seawater (suspended matter, yellow substance, pigments of phytoplankton, and pure water) to the beam attenuation coefficient in different types of seawater. For the surface waters, we establish the relationship between the light scattering coefficient and the attenuation coefficient at a wavelength of 547 nm and determine the background (limiting minimum) value of the coefficient of absorption by the yellow substance in waters of the Mediterranean Sea. It is compared with the values of the same parameter for some other basins (Black Sea, Lake Baikal, Baltic Sea, and oceanic waters).     

Influence of Atmospheric Processes on the Long-Period Variations of the Biomass of Anchovy

We study the influence of large-scale atmospheric processes on the cyclic variations of the biomass of anchovy in the Black Sea and analyze the mechanism of action of various ecological factors on its productivity. A conclusion is made that the 4–6-yr periodicity of variations of the biomass of anchovy is caused by the cyclicity of the weather conditions and environmental processes in the Black-Sea basin connected with the North-Atlantic oscillation.__________Translated from Morskoi Gidrofizicheskii Zhurnal, No. 1, pp. 55–62, January–February, 2005.     

Horizontal and Vertical Structure of Geostrophic Currents in the Black Sea According to the Data of the Summer Survey Performed as a Part of the ComSBlack-92 Program

We describe the methodology and software developed for the numerical analysis of the characteristics of the horizontal and vertical structure of geostrophic currents. We present the results of computation of these characteristics according to the data of the summer survey of the Black Sea carried out as a part of the ComSBlack-92 program. The distinctive features of the space structure of geostrophic currents discovered as a result and the established parameters of their variability may supplement the existing data on the current field in the Black Sea.     

Effects of fine grain size on distribution of Mn in shallow and deep water Black Sea sediments: A comparison between oxic and anoxic depositional environments

The uppermost 5–6 cm of the sediments (between 8 and 2248 m water depths) were studied to understand the effects of varying redox conditions on the Mn distribution in the recent sediments of the Black Sea. It was found that most Mn concentrations are consistent with the average abundance in crustal and/or sedimentary rocks. There exist no important differences between Mn concentrations in oxic (shallower water; <70 m) and anoxic (deeper water; 120 m) sediments. Previously reported Mn-enrichment above the Black Sea oxic/anoxic interface, due to the peculiar redox cycling, shows no significant contribution of Mn to the bottom sediments. A marked relationship between total Mn concentrations and clay/mud contents at shelf depth along the southern Black Sea margin indicates increased accumulation of Mn in association with the fine-grained particles and eastward water circulation.     

Vertical mesostructure of deep waters in the Black Sea

Studies of mesoscaleT, S characteristics of deep waters in the Black Sea carried out during 1978–1988 are generalized. Transformed lower Bosphorus waters are spread in the layer from 400 m to the bottom following density isosurfaces corresponding to this water. This is the way that interlayers ofT, S inversions are formed; their vertical thickness reaches 100–200 m in the Anatolian flow. The streamwise decrease of theT, S maxima and the location of isotherms in the cross-sections of these tongues permit the estimation of the order of the values of the coefficients of the vertical and horizontal turbulent diffusion.Translated by Mikhail M. Trufanov.     

Application of the Genetic Algorithm to the Problem of Reconstruction of Missing Data

We study the problem of reconstruction (interpolation and extrapolation) of the vertical profiles of hydrochemical and hydrobiological elements according to incomplete sets of data with simultaneous filtration of short-period components based on expansions in empirical orthogonal functions. The genetic algorithm is used to compute the coefficients of expansion of profiles with missing data. We present the results of processing the data arrays on oxygen, chlorophyll A, and biogenic elements collected in the Black Sea in 1982–1993. The mean error of reconstruction of the profiles enables us to conclude that the proposed method has considerable advantages over the conventional approaches.