The structure of the Precambrian and Lower Paleozoic basement of the Central Andes between 22° and 32°S. Lat.

Three major diastrophic cycles, defined by their structural style and their spatial distribution are recognized in the Andean Basement of this region. The oldest structures are related to the Panamerican Orogeny (500 to 700 m. a.) which produced in the Central Craton multiply deformed complexes of schists, gneisses and granites, that are covered discordantly by unmetamorphosed Cambrian and Ordovician beds. West of the Central Craton Ordovician sedimentary beds are folded with a simple structural style and intruded by granites. Both the sedimentry beds and the granites are covered discordantly by undeformed Devonian sequences. The folding of the Ordovician is attributed to the ocloyic phase of the Caledonian movements. West of the ocloyic belt is another foldbelt consisting of strongly folded Devonian beds attributed to the chanic phase (hercynian). The chanic belt is intruded by carboniferous and permian granites and covered discordantly by Carboniferous and Permian sequences.The features observed in the eastern slope of the Andes suggest that the Paleozoic foldbelts are intracratonic. Whether there are accreted terrains in the Pacific Coastal Cordillera is matter of controversy.

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Zusammenfassung Im Andenbasement dieser Region lassen sich drei diastrophische Hauptzyklen, die durch ihren strukturellen Baustil und ihre geographische Verbreitung definiert sind, unterscheiden. Die ältesten Strukturen sind verknüpft mit den Bewegungen der Panamerikanischen Orogenese (500–700 m. a.), welche im Zentralkraton einen polydeformierten Komplex von Schiefern, Gneissen und Graniten erzeugte. Diesem lagern diskordant kambrische und ordovizische Sequenzen ohne Metamorphose und präandiner Deformation auf. Nach Westen zu gibt es einen Gürtel stark deformierter ordovizischer Sedimente, die einen einfacheren Baustil als das präkambrische Basement aufweisen, und diskordant von undeformierten devonischen Abfolgen bedeckt sind. Die Faltung des Ordoviziums wird der Ocloyischen Phase der Kaledonischen Bewegung zugerechnet.Weiter westwärts tritt ein jüngerer Faltengürtel aus devonischen Sedimenten auf, die während der Chanischen Phase der Herzynischen Bewegung intensiv deformiert wurden, und von karbonischen und permischen Sequenzen diskordant überlagert sind.Der Ocloyische Gürtel ist von postordovizischen Graniten die von devonischen Schichten überlagert sind, und der Chanische Gürtel von karbonischen und permischen Graniten intrudiert. Im präkambrischen Basement des Zentralkratons treten einerseits präkambrische Granite auf, denen diskordant kambrische Schichten auflagern. Andererseits findet man Granite mit paläozoischen Isotopenaltern, letztere aber in Gebieten, wo wegen des Fehlens von Deckschichten eine stratigraphische Kontrolle unmöglich ist.Die gemachten Beobachtungen scheinen darauf hinzudeuten, daß die paläozoischen Faltengürtel intrakratonisch sind. Ob es allochtone »terrains« in der pazifischen Küstenkordillere gibt, ist Gegenstand der Kontroverse.

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Resumen En el basamento de los Andes de esta región se distinguen tres ciclos diastróficos mayores definidos por sus estilos estructurales y su distributión espacial. Las estructuras mas antiguas responden a movimientos que culminaron con la Orogénesis Panamericana (500–700 m. a.) que produjo en el Cratógeno Central un complejo de esquistos, gneises y granitos polideformados, al que se le superponen discordantemente secuencias cámbricas y ordovicicas sin metamorfismo ni déformatión preandina. Hacia el oeste hay un cinturón de sedimentos ordovícicos intensamente deformados con un estilo de plegamiento mas simple que el del basamento precámbrico y cubierto discordantemente por secuencias marinas devónicas sin deformatión. Los movimientos responsables de este plegamiento se atribuyen a la fase oclóyica de los movimientos caledónicos. Más hacia el oeste se manifiesta una franja de deformatión mas jóven atribuída a la Fase chánica de los movimientos hercínicos, en ella se encuentran sedimentitas devónicas intensamente plegadas cubiertas discordantemente por secuencias carbónicas y pérmicas.El cinturón oclóyico esta acompanãdo por granitos postordovícicos cubiertos por Devónico. Asimismo, el cinturón chánico (hercínico) esta intruido por granitos probablemente carbónicos. Con respecta a los granitos intruidos en el zócalo antiguo, hay algunos indudablemente precámbricos por estar cubiertos discordantemente por secuencias cámbricas sin metamorfismo, además hay granitos de edad dudosa que han dado valores isotópicos paleozoicos pero en lugares donde el control estratigráfico no es posible por ausencia de la cobertura paleozoica. De acuerdo a los hechos observados en la ladera oriental de los Andes surge la idea de que los cinturones de plegamiento paleozoicos son intracratónicos, aun es materia de controversia si en la Cordillera de la Costa junto al Pacifico hay terrenos alóctonos acrecionados.

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Evolution of the Neogene Andean foreland basins of the Southern Pampas and Northern Patagonia (34°–41°S), Argentina

The Pampas plain (30°–41°S) has historically been considered as a sector that evolved independently from the adjacent Andean ranges. Nevertheless, the study of the Pampas showed that it is reasonable to expect an important influence from the Andes into the extraandean area. The Pampas plain can be divided into two sectors: the northern portion, adjacent to the Pampean Ranges, has been studied by Davila (2005, 2007, 2010). The southern sector (34°–41°S) is the objective of the present work. The study of this area allowed to characterize two separate foreland basins: the Southern Pampa basin and the Northern Patagonian basin. The infill is composed of Late Miocene and Pliocene units, interpreted as distal synorogenic sequences associated with the late Cenozoic Andean uplift at this latitudinal range. These foreland basins have been defined based on facies changes, distinct depositional styles, along with the analysis of sedimentary and isopach maps. The basins geometries are proposed following De Celles and Gilles (1996) taking into account the infill geometry, distribution and grain size. In both cases, these depocenters are located remarkably far away from the Andean tectonics loads. Therefore they cannot be explained with short-wave subsidence patterns. Elastic models explain the tectonic subsidence in the proximal depocenters but fail to replicate the complete distal basins. These characteristics show that dynamic subsidence is controlling the subsidence in the Southern Pampas and Northern Patagonian basins.     

Morphology and geology of the continental shelf and upper slope of southern Central Chile (33°S–43°S)

The continental shelf and slope of southern Central Chile have been subject to a number of international as well as Chilean research campaigns over the last 30 years. This work summarizes the geologic setting of the southern Central Chilean Continental shelf (33°S–43°S) using recently published geophysical, seismological, sedimentological and bio-geochemical data. Additionally, unpublished data such as reflection seismic profiles, swath bathymetry and observations on biota that allow further insights into the evolution of this continental platform are integrated. The outcome is an overview of the current knowledge about the geology of the southern Central Chilean shelf and upper slope. We observe both patches of reduced as well as high recent sedimentation on the shelf and upper slope, due to local redistribution of fluvial input, mainly governed by bottom currents and submarine canyons and highly productive upwelling zones. Shelf basins show highly variable thickness of Oligocene-Quaternary sedimentary units that are dissected by the marine continuations of upper plate faults known from land. Seismic velocity studies indicate that a paleo-accretionary complex that is sandwiched between the present, relatively small active accretionary prism and the continental crust forms the bulk of the continental margin of southern Central Chile.     

Composition and inner structure of the third layer in the oceanic crust in the subequatorial segment of the Mid-Atlantic Ridge (5°–7° N)

The paper presents data on the major-component, trace-element, and mineralogical composition of plutonic rocks, and the composition of their minerals, from the Sierra Leone region in the crest zone of the Mid-Atlantic Ridge between the Strakhov and Bogdanov fracture zones. According to their relations with seafloor structures, the rock associations are subdivided into those of rift valleys and nontransform offset zones. The troctolites and olivine gabbro composing the rift association were produced early in the fractionation course of oceanic tholeiite melt in unstationary and relatively small magmatic chambers. Most rocks beneath the nontransform offset zones crystallized during the long-lasting fractionation of the melt in large chambers hosted in serpentinized peridotites. This part consists of various cumulates, ranging from troctolites to gabbroids. Where deep tectonic detachments entered partly consolidated portions of the chambers, the melt interacted with the wall rocks. Fluid that was generated via the dehydration of serpentine and concentrated hydrophile elements, locally modified the composition of the melt and resulted in amphibole-bearing rocks. Under stress, the intercumulus melts were squeezed into tectonically weakened zones, mixed there, and also interacted with the wall rocks. These mix melts produced (with the participation of fractional crystallization) mineralized Fe-Ti gabbroids. Residual portions of the melts generated most of the diorites and plagiogranites. The high-Na diorites likely crystallized from acid melts that were derived via the partial melting of older gabbroids where aqueous fluids circulated; these fluids were generated by the deserpenitization of the host rocks in tectonized zones cutting through the chambers.     

Hydrothermal alteration and mineralisation of basalts from the spreading zone of the East Pacific Rise (7°S–23°S)

At the southern part of the East Pacific Rise (EPR), between 6°S and 30°S a survey on volcanic and hydrothermal activity was performed and samples were obtained by means of TV-controlled grab.This paper deals with altered and mineralized basalt sampled between 7°S and 23°S from five sites in a hydrothermal field.These basalts of tholeitic composition are vitreous to holocrystaline. They have suffered pervasive alteration during which rock-forming minerals (pyroxene, plagioclase) have been replaced by kaolinite, chlorite and smectite. As a consequence, strong depletion of Ca, Cr, Ni, Mg, Sr and Al took place, accompanied by an enrichment of Fe, Cu, Co, Mo, Zn, and Pb. The ore mineral assemblage is rather uniform and consists of pyrite, marcasite, wurtzite, sphalerite, chalcopyrite, covellite and goethite.The igneous and hydrothermal activities can be subdivided into different stages: lithification, high-temperature alteration (<400 C), medium to low temperature alteration and two substages of ore formation (250°C – 150°C and <150°C, respectively).This active present-day ore deposition is interpreted in terms of a peripheral zone of a volcanic-hosted ore mineralisation. It may be compared with fossil ophiolite-hosted massive sulfides that formed throughout the Alpine (e.g. Arabia, Cyprus) as well as Caledonian orogeny (e.g. Scandinavia).

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Zusammenfassung Im Südteil des East Pacific Rise (EPR) zwischen 6°S und 30°S wurde eine Übersichtsbeprobung in einem Gebiet starker vulkanischer und hydrothermaler Aktivität durchgeführt. Diese Studie befaßt sich mit alterierten und mineralisierten Basalten die in einem Hyrothermalfeld, an 5 Positionen zwischen 7°S und 23°S genommen wurden. Die tholeiitischen Basalte sind z.T. hyalin. z.T. holokristallin strukturiert. Im Verlauf der sehr starken Alteration wurden die Minerale Pyroxen und Plagioklas in Kaolinit, Chlorit und Smektit ungewandelt. Dieser Verdrängungsprozeß wurde von einer starken Abreicherung an Ca, Cr, Ni, Mg, Sr, Al und einer Anreicherung an Fe, Cu, Co, Mo, Zn und Pb begleitet. Die Vererzung zeigt eine einfache Mineralvergesellschaftung mit Pyrit, Markasit, Wurtzit, Sphalerit, Chalkopyrit, Covellin und Geothit.Die magmatische und hydrothermale Aktivität läßt sich in verschiedene Stadien untergliedern: Basaltentstehung, Hochtemperturalteration (< 400°), Mittelbis Tieftemperaturalteration und Vererzung mit 2 Substadien (250°C–150°C, < 150°C).Diese rezenten Vererzungen lassen sich interpretieren als die Randzone einer vulkanitgebundenen Erzmineralisation. Sie läßt sich mit fossilen Vertretern ophiolit-gebundener massiver Sulfiderze, wie sie im Verlauf den alpidischen (z.B. Arab.-Halbinsel, Zypern) und kaledonischen Orogenese (z.B. Norwegen) entstanden sind, vergleichen.

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Résumé Une étude des activités volcanique et hydrothermale a été effectuée dans la partie sud de l'East Pacific Rise, entre 6° et 30° de latitude sud. Des échantillons y ont été prélevés au moyen d'un engin dirigé par TV.La présente note se rapporte aux basaltes altérés et minéralisés récoltés en cinq points d'un champ hydrothermal, entre 7°S et 23°S.Ces basaltes, de composition tholéiitique sont tantôt vitreux, tantôt holocristallins. Ils ont été le siège d'une forte altération hydrothermale au cours de laquelle les minéraux de la roche (pyroxène, plagioclase) ont été remplacés par de la kaolinite, de la chlorite et de la smectite. Il en est résulté un appauvrissement marqué en Ca, Cr, Ni, Mg, Sr et Al, accompagné d'un enrichissement en Fe, Cu, Co, Mo, Zn et Pb. La minéralisation présente une association simple à pyrite, marcassite, wurtzite, sphalérite, covelline et goethite.On peut distinguer plusieurs stades d'activité magmatique et hydrothermale: formation du basalte, altération de haute température (<400°C), altération de moyenne à basse température avec deux stades de minéralisation (250-150°C; <150°C). Ces dépôts de la nature actuelle peuvent s'interpréter comme la zone périphérique d'une aire de minéralisation volcanogène. On peut les comparer à des gisements fossiles de sulfures massifs liés à des ophiolites, comme il s'en est formé au cours des orogenèses alpine (p. ex.: péninsule arabique, Chypre) et calédonienne (p. ex.: Norvège).

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Endmember analysis of metalliferous sediments from the Galapagos Rift and East Pacific Rise between 2°N and 42°S

594 sediment samples from the Galapagos Rift System (GRS) and the crest of the East Pacific Rise (EPR) were chemically analyzed for 12 elements. Carbonate-free compositional datasets associated with each of 3 regions, the GRS, the EPR 2°N–4°S and the EPR 10°S–42°S, were separately subjected to endmember analysis. The compositions of endmember estimates were constructed for each dataset. These composition largely confirmed theidentities of endmembers that had previously been inferred from the varimax rotated loadings of a conventional factor analysis (of the correlation matrices) of the same 3 datasets.In view of the widely-reported unreliability of the correlation structure of compositional data, the confirmation by endmember analysis of the results of a factor analysis is itself quite remarkable. However, the particular advantage of endmember analysis is that the chemical compositions of extreme sources are estimated, and may readily be interpreted. The samples in the dataset can then be expressed as mixtures of these extreme sources. By contrast, the varimax rotated loadings of a factor analysis indicate only those elements that are associated together on a single factor which may or may not be an endmember, the composition of which nevertheless remains unknown.     

Paleoseismicity and seismic hazard in southern Patagonia (Argentina-Chile; 50°–55°S) and the role of the Magallanes-Fagnano transform fault

Patagonia, including the island of Tierra del Fuego, lies in southernmost South America at the junction of the South American, Antarctic, and Scotia tectonic plates. Historical and instrumental records have documented several local earthquakes of damaging magnitude, posing a threat to the rapidly growing population of 300,000 and the expanding industrial and service infrastructure. Short and inaccurate instrumental records of local seismic events and a diffuse epicenter distribution not clearly related to the recognized seismogenic structures have hindered an adequate evaluation of the seismic hazard for this region. To improve this situation, a paleoseismological study was carried out on two gravelly strandplains on the Atlantic coast of Patagonia. Surveying combined ground-probing radar, vertical electric sounding, and seismic refraction. Coseismic normal faults buried beneath the strandplain bodies were revealed and related to the morphology of the strandplains. The faults have probable ages between 0.9 and 6.4 kyr BP and a recurrence rate of about 1 kyr. The more likely source for these structures is the Magallanes-Fagnano fault, a continental transform fault that crosses Tierra del Fuego. The distance of more than 300 km from the buried coseismic structures to the trace of the Magallanes-Fagnano fault argues for high-magnitude earthquake activity on this fault throughout the Holocene. Urban development on soft glacial and alluvial substrates increases the hazard.     

Geochemical nature and age of the plagiogranite-gabbronorite association of the oceanic core complex of the Mid-Atlantic ridge at 5°10′S

Our newly obtained data on the geochemistry and age of plagiogranite-gabbronorite association in the oceanic core complex of the Mid-Atlantic Ridge (MAR) at 5°10′S suggest close genetic relations between these rocks in this segment of the ridge. The U/Pb zircon age of an oceanic plagiogranite (OPG) sample is 1.059 ± 0.055 Ma and is in good agreement with the zircon age of plutonic rocks in the oceanic core complex of northern MAR. A distinctive geochemical feature of the rocks is their unusually depleted ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd ratios, which suggest that the plutonic rocks of the gabbronorite-plagiogranite association in MAR at 5°10′S could be derived from the most strongly depleted mantle reservoir of all known to occur beneath the axial MAR zone. The COMAGMAT-5.2 numerical thermodynamic simulation of the possible crystallization links between the plagiogranite and gabbronorite from the MAR segment at 5°10′S led us to conclude that the leading role in the origin of the plagiogranite was played by a two-stage process: the partial melting of the gabbronorite and the subsequent fractionation of the newly generated melt. The regional differences between the isotopic-geochemical parameters of MAR plagiogranites can, perhaps, reflect local specifics of so-called hydrothermal anatexis, such as the geochemical features of the rocks involved in this process and the parameters of the hydrothermal process, for example, variations in the W/R ratio.     

Local earthquake tomography of the Andes at 20°S: Implications for the structure and building of the mountain range

Arrival-times of local events recorded in northern Chile and southern Bolivia were used to determine the P velocity structure above the subducted Nazca plate. The data were recorded between June and November 1994 by the French “Lithoscope” network: 41 vertical and 14 three-component short-period seismic stations were installed along a 700 km long profile crossing the main structures of the Andean chain, from the Coastal Cordillera to the Subandean Zone. The inversion method used is a modified version of Thurber’s 3D iterative simultaneous inversion code. The results were compared with a model obtained from previous German nearby refraction seismic studies and supplemented by field geological observations.The relocated seismicity is consistent with an ∼30° dipping slab between 0 and 170 km depth. We found a variation of about 30 km of the Moho depth along the profile. The crustal thickness is about 47 km under the Coastal Cordillera, 70 km under the Western Cordillera and the western part of the Eastern Cordillera, and 60–65 km beneath the Altiplano. Close to the surface, a good agreement between the velocity model and the geological structures is observed. Generally, in the upper crust, high velocities coincide with zones where basement is present near the surface. Low velocities are well correlated with the presence of very thick sedimentary basins or volcanic material. At greater depth, the trend of the velocity model is consistent with the existence of asymmetrical west-dipping imbricated blocks, overthrusting toward the east, which explain the asymmetrical pattern of the sedimentary basins. Beneath the Western Cordillera, the active volcanic arc, a large zone of low velocity is observed and interpreted to be due to partially molten material. A clear velocity contrast appears between the western and eastern parts of the upper mantle beneath the Andes; this geometry suggests the existence of a low velocity wedge in the mantle above the slab and the presence of a thick old lithosphere in the eastern part of the Andes.     

Geochemical and isotopic signatures of magmatic products in the MAR rift valley at 12°49′–17°23′ N and 29°59′–33°41′ N: Evidence of Two contrasting sources of the parental melts

Data presented in the paper suggest significant differences between the thermodynamic conditions under which magmatic complexes were formed in MAR at 29°–34° N and 12°–18° N. The melts occurring at 29°–34° N were derived by the melting of a mantle source with a homogeneous distribution of volatile components and arrived at the surface without significant fractionation, likely, due to their rapid ascent. The MAR segments between 12° and 18° N combine contrasting geodynamic environments of magmatism, which predetermined the development of a large plume region with the widespread mixing of the melting products of geochemically distinct mantle sources. At the same time, this region is characterized by conditions favorable for the origin of localized zones of anomalous plume magmatism. These sporadic magmatic sources were spatially restricted to MAR fragments with the Hess crust, whose compositional and mechanical properties were, perhaps, favorable for the focusing and localization of plume magmatism. The plume source between 12° and 18°N beneath MAR may be geochemically heterogeneous.     

Geochemistry and petrogenesis of mafic-ultramafic rocks from the Central Indian Ridge,latitude 8°–17° S: denudation of mantle harzburgites and gabbroic rocks and compositional variation of basalts

This study investigates the formation of lower oceanic crust and geochemical variations of basalts along the Central Indian Ridge (CIR, lat. 7°45′–17°10′ S). Harzburgites, various gabbroic cumulates, medium- to fine-grained oxide gabbros, diabases, and pillow basalts were recovered by dredging from segment ends such as ridge-transform intersections (RTIs), non-transform discontinuities (NTDs), and transform offset areas. The occurrence of both harzburgites and gabbroic rocks with minor basalts at all segments ends, and leucogabbro intrusive into harzburgite at the 12°45′ S NTD indicates that oceanic crust at segment ends exposes mantle-derived harzburgites and gabbroic intrusions with a thin basaltic cover due to sparse magmatic activity. Basalts collected along the entire ridge show wide compositional variations between N (normal)- and E (enriched)-mid-ocean ridge basalt (MORB). T (transitional)-MORBs with enriched affinities are more prominent than N-MORBs. There is no tendency of enrichment towards specific directions. (La/Sm)_N variations in MORB along the CIR (8°–21°S) fluctuates at a regional scale with local high positive anomalies reflecting compositional heterogeneity of the sub-CIR mantle domain.     

Sm-Nd and Rb-Sr isotopic systems and captured He and hydrocarbon gases as markers of melt sources and fluid regime under which the oceanic crust of the Mid-Atlantic Ridge was formed at 5°–6° N

The paper presents characteristics of the Nd and Sr isotopic systems of ultrabasic rocks, gabbroids, plagiogranites, and their minerals and data on He and hydrocarbons in fluid inclusions in the same samples. The materials presented in this publication were obtained by studying samples dredged from the MAR crest zone at 5°–6° N (U/Pb zircon dating, geochemical and petrological-mineralogical studies). It was demonstrated that the variations in the isotopic composition of He entrapped in the rocks and minerals were controlled by variable degrees of mixing of juvenile He, which is typical of basaltic glass of MAR (DM source) and atmospheric He. An increase in the fraction of atmospheric He in the plutonic rocks and, to a lesser degree, in their minerals reflects the involvement of seawater or the hydrated material of the oceanic crust in the magmatic and postmagmatic processes. This conclusion finds further support in a positive correlation between the fraction of mantle He (R) and the ⁸⁷Sr/⁸⁶Sr ratio. The high-temperature hydration of ultrabasic rocks (amphibolization) was associated with an increase in the fraction of mantle He, while their low-temperature hydration (serpentinization) was accompanied by a drastic decrease in this fraction and a significant increase in the ⁸⁷Sr/⁸⁶Sr ratio. The insignificant variations in the ¹⁴³Nd/¹⁴⁴Nd (close to 0.5130) and ⁸⁷Sr/⁸⁶Sr (0.7035) in most of the gabbroids and plagiogranites, as well as the fraction of mantle He in these rocks, amphibolites, and their ore minerals, indicate that the melts were derived from the depleted mantle. Similar?_Nd values of the gabbroids, plagiogranites, and fresh harzburgites (6.77–8.39) suggest that these rocks were genetically related to a single mantle source. The value of ?_Nd = 2.62 of the serpentinized lherzolites likely reflects relations of these relatively weakly depleted mantle residues to another source. The aforementioned characteristics of the rocks generally reflect the various degrees of mixing of components of the depleted mantle with crustal components (seawater) during the metamorphic and hydrothermal processes that accompanied the formation of the oceanic crust.     

Peridotite-gabbro-trondhjemite association of the Mid-Atlantic Ridge between 12°58′ and 14°45′N: Ashadze and Logachev hydrothermal vent fields

This study aimed at reconstructing the sequence of events in the magmatic and metamorphic evolution of peridotites, gabbroids, and trondhjemites of the oceanic core complexes of the Ashadze and Logachev hydrothermal vent fields. The study object was the collections of plutonic rocks made during cruises 22 and 26 of the R/V Professor Logachev, Cruise 41 of the R/V Akademik Mstislav Keldysh, and the Russian-French expedition Serpentine aboard the R/V Pourquoi pas? The data reported here suggest that the oceanic core complexes of the Ashadze and Logachev fields were formed via the same scenario in the two MAR regions. On the other hand, the analysis of petrological and geochemical characteristics of the rocks indicated that the oceanic core complexes of the MAR axial zone between 12°58′ and 14°45′N show a pronounced petrological and geochemical heterogeneity manifested in variations in the degree of depletion of mantle residues and the Nd isotopic compositions of the rocks of the gabbro-peridotite association. The trondhjemites of the Ashadze hydrothermal field can be considered as partial melting products of gabbroids under the influence of hydrothermal fluid. It was supposed that the presence of trondhjemites in the MAR oceanic core complexes can be used as a marker for the highest temperature deep-rooted hydrothermal systems. Perhaps, the region of the MAR axial zone in which petrologically and geochemically contrasting oceanic core complexes are spatially superimposed served as sites for the development of large hydrothermal clusters with a considerable ore-forming potential.     

Phase Chemistry Study of the Zabuye Salt Lake Brine: Isothermal Evaporation at 15°C and 25°C

Zabuye Salt Lake in Tibet, China is a carbonate-type salt lake, which has some unique characteristics that make it different from other types of salt lakes. The lake is at the latter period in its evolution and contains liquid and solid resources. Its brine is rich in Li, B, K and other useful minor elements that are of great economic value. We studied the concentration behavior of these elements and the crystallization paths of salts during isothermal evaporation of brine at 15°C and 25°C. The crystallization sequence of the primary salts from the brine at 25°C is halite (NaCl) → aphthitalite (3K2SO4·Na2SO4) → zabuyelite (Li2CO3)→ trona (Na2CO3·NaHCO3·2H2O) → thermonatrite (Na2CO3·H2O) → sylvite (KCl), while the sequence is halite (NaCl) → sylvite (KCl) → trona (Na2CO3·NaHCO3·2H2O) → zabuyelite (Li2CO3) → thermonatrite (Na2CO3·H2O) → aphthitalite (3K2SO4·Na2SO4) at 15°C. They are in accordance with the metastable phase diagram of the Na+, K+-Cl?, CO32?, SO42?-H2O quinary system at 25°C, except for Na2CO3·7H2O which is replaced by trona and thermonatrite. In the 25°C experiment, zabuyelite (Li2CO3) was precipitated in the early stage because Li2CO3 is supersaturated in the brine at 25°C, in contrast with that at 15°C, it precipitated in the later stage. Potash was precipitated in the middle and late stages in both experiments, while boron was concentrated in the early and middle stages and precipitated in the late stage.     

Geochemistry of mafic rocks and melt inclusions and their implications for the heat source of the 14.0°S hydrothermal field,South Mid-Atlantic Ridge

Fresh rocks sampled from the 14.0°S hydrothermal field of the South Atlantic Ridge can be divided into two categories： olivine-gabbro and basalt. The olivine-gabbro is composed mainly of three types of minerals： olivine, clinopyroxene and plagioclase, while a multitude of melt inclusions occur in the plagioclase phenocrysts of the basalts. We analyzed the whole-rock, major and trace elements contents of the basaks, the mineral chemistry of phenocrysts and melt inclusions in the basalts, and the mineral chemistry of olivine-clinopyroxene-plagioclase in the olivine-gabbro, then simulated magma evolution within the crust using the COMAGMAT program. The whole-rock geochemistry shows that all the basalts exhibit typical N-MORB characteristics. In addition, the mineral chemistry characteristics of the olivine-gabbro （low-Fo olivine, low-Mg# clinopyroxene, high-TiO2 clinopyroxene, low-An plagioclase）, show that strong magma differentiation occurred within the crust. Nevertheless, significant discrepancies between those minerals and phenocrysts in the basalts （high-Fo olivine, high-An plagioclase） reflect the heterogeneity of magma differentiation. High Mg# （-~0.72） melt inclusions isobaric partial crystallization simulations suggest that the magma differentiation occurred at the depth shallower than 13.03 km below the seafloor, and both the vertical differentiation column shows distinct discrepancies from that of a steady-state magma chamber. Instead, a series of independent magma intrusions probably occurred within the crust, and their corresponding crystallized bodies, as the primary high-temperature thermal anomalies within the off-axis crust, probably act as the heat source for the development of the 14.0°S hydrothermal system.     

An XRD study of the crystal structure of gearksutite and its stability during heating to 300°C

The crystal structure of gearksutite, Ca and Al hydrofluoride CaAlF₄(OH) · H₂O, was refined using the Rietveld method with power diffraction data. The thermal stability of its crystal structure was studied for the first time using high-temperature XRD. Thermal XRD study of the mineral in the temperature range from 25 to 300°C revealed its stability to temperatures of 300-310°C. The mineral began to decay at temperatures greater than 300°C. The increase in the unit-cell parameters was established and the coefficients of thermal expansion were calculated.     

Dependence of albite dissolution kinetics on ph and time at 25°c and 70°c

The dissolution rate of albite has been measured as a function of pH and time at 25°C and 70°C in a single-pass flow-through leaching apparatus. Run times extended to 50 days in each experiment. Limited data were obtained at 25°C in the pH range 4–10. More extensive data were obtained at 70°C over the pH range 1.39–11.75.Dissolution rates were defined by release of Si, and in some cases also by Al and Na releases. Speciationsolubility calculations indicate the solutions were well undersaturated for all the likely possible secondary minerals. The fluid was maintained far from equilibrium with albite in all runs. Analysis of the data shows a general consistency with the transition state theory model of Helgesonet al. (1984).Feldspars leached at low and high pH at 70°C showed extensive development of prismatic etch pits demonstrating a surface reaction-controlled dissolution process.     

Hydrosulfide/sulfide complexes of zinc to 250 °C and the thermodynamic properties of sphalerite

The solubility of synthetic ZnS_(cr) was measured at 25–250 °C and P = 150 bars as a function of pH in aqueous sulfide solutions (~ 0.015–0.15 m of total reduced sulfur). The solubility determinations were performed using a Ti flow-through hydrothermal reactor. The solubility of ZnS_(cr) was found to increase slowly with temperature over the whole pH range from 2 to ~ 10. The values of the Zn–S–HS complex stability constant, β, were determined for Zn(HS)₂⁰_(aq), Zn(HS)₃^?, Zn(HS)₄^2?, and ZnS(HS)^?. Based on the experimental values the Ryzhenko–Bryzgalin electrostatic model parameters for these stability constants were calculated, and the ZnS_(cr) solubility and the speciation of Zn in sulfide-containing hydrothermal solutions were evaluated. The most pronounced solubility increase, about 3 log units at m(S_total) = 0.1 for the temperatures from 25 to 250 °C, was found in acidic solutions (pH ~ 3 to 4) in the Zn(HS)₂⁰_(aq) predominance field. In weakly alkaline solutions, where Zn(HS)₃^? and Zn(HS)₄^2? are the dominant Zn–S–HS complexes, the ZnS_(cr) solubility increases by 1 log unit at the same conditions. It was found that ZnS(HS)^? and especially Zn(HS)₄^2? become less important in high temperature solutions. At 25 °C and m(S_total) = 0.1, these species dominate Zn speciation at pH > 7. At 100 °C and m(S_total) = 0.1, the maximum fraction of Zn(HS)₄^2? is only 20% of the total Zn concentration (i.e. at pH_t ~ 7.5), whereas at 350 °C and 3 <pH_t <10, the fraction of Zn(HS)₄^2? and ZnS(HS)^? is less than 0.05% and 2.5% respectively, of the total Zn concentration and Zn(HS)₂⁰ and Zn(HS)₃^? predominate. The measured equilibrium formation constants were combined with the literature data on the stability of Zn–Cl complexes in order to evaluate the concentration and speciation of Zn in chloride solutions. It was found that at acidic pH, and in more saline fluids having total chloride > 0.05 m, Zn–Cl complexes are responsible for hydrothermal Zn transport with no significant contribution of Zn–S–HS complexes. The hydrosulfide/sulfide complexes will play a more important role in lower salinity (< 0.05 m chloride) hydrothermal solutions which are characteristic of many epithermal ore depositing environments. The value of Δ_fG° (β-ZnS_(cr)) = ? 198.6 ± 0.2 kJ/mol at 25 °C was determined via solubility measurements of natural low-iron Santander (Spain) sphalerite.     

The Magmatic–Hydrothermal Transition and Origin of Brine in the Oceanic Core Complex of the Mid-Atlantic Ridge at 13° N

New data on local mineral associations and the microheterogeneity of minerals and fluid inclusions in gabbro were obtained for the gabbro–peridotite oceanic core complex with a long-lived detachment fault controlling the hydrothermal activity. It is assumed that the hydrothermal hydrogen-bearing fluid with a NaCl content of >30 wt % is formed in the seawater/harzburgite (~1/5) reaction of serpentinization. The brine residual after serpentinization interacted with gabbro at the final stages of crystallization of an intrusion and assimilated some components (K, REEs, and Ba) from the residual melt. The interaction was resulted in metamorphic transformations of gabbro at decreasing temperature below 500°C. The reaction of the decomposition of magmatic titanomagnetite with the transition of iron reduced to Fe²⁺ into newly formed chlorinebearing amphibole at 540–450°C and logf(O₂) from–20 to–24 is shown.

     

Growth of the Afanasy Nikitin seamount and its relationship with the 85°E Ridge,northeastern Indian Ocean

The Afanasy Nikitin seamount (ANS) is a major structural feature (400 km-long and 150 km-wide) in the Central Indian Basin, situated at the southern end of the so-called 85°E Ridge. Combined analyses of new multibeam bathymetric, seismic reflection and geochronological data together with previously described magnetic data provide new insights into the growth of the ANS through time, and its relationship with the 85°E Ridge. The ANS comprises a main plateau, rising 1200 m above the surrounding ocean floor (4800 m), and secondary elevated seamount highs, two of which (lie at 1600 and 2050 m water depths) have the morphology of a guyot, suggesting that they were formed above or close to sea-level. An unbroken sequence of spreading anomalies 34 through 32n.1 identified over the ANS reveal that the main plateau of the ANS was formed at 80–73 Ma, at around the same time as that of the underlying oceanic crust. The ⁴⁰Ar/³⁹Ar dates for two basalt samples dredged from the seamount highs are consistent, within error, at 67 Ma. These results, together with published results of late Cretaceous to early Cenozoic Indian Ocean plate reconstructions, indicate that the Conrad Rise hotspot emplaced both the main plateau of the ANS and Conrad Rise (including the Marion Dufresne, Ob and Lena seamounts) at 80–73 Ma, close to the India–Antarctica Ridge system. Subsequently, the seamount highs were formed by late-stage volcanism c. 6–13 Myr after the main constructional phase of the seamount plateau. Flexural analysis indicates that the main plateau and seamount highs of the ANS are consistent with Airy-type isostatic compensation, which suggest emplacement of the entire seamount in a near spreading-center setting. This is contrary to the flexural compensation of the 85°E Ridge further north, which is interpreted as being emplaced in an intraplate setting, i.e., 25–35 Myr later than the underlying oceanic crust. Therefore, we suggest that the ANS and the 85°E Ridge appear to be unrelated as they were formed by different mantle sources, and that the proximity of the southern end of the 85°E Ridge to the ANS is coincidental.