Nickel abundance in stony cosmic spherules: Constraining precursor material and formation mechanisms

Abstract– We report bulk and olivine compositions in 66 stony cosmic spherules (Na₂O < 0.76 wt%), 200–800 μm in size, from the Transantarctic Mountains, Antarctica. In porphyritic cosmic spherules, relict olivines that survived atmospheric entry heating are always Ni‐poor and similar in composition to the olivines in carbonaceous or unequilibrated ordinary chondrites (18 spherules), and equilibrated ordinary chondrites (one spherule). This is consistent with selective survival of high temperature, Mg‐rich olivines during atmospheric entry. Olivines that crystallized from the melts produced during atmospheric entry have NiO contents that increase with increasing NiO in the bulk spherule, and that range from values similar to those observed in chondritic olivines (NiO generally <0.5 wt%) to values characteristic of olivines in meteoritic ablation spheres (NiO > 2 wt%). Thus, NiO content in olivine cannot be used alone to distinguish meteoritic ablation spheres from cosmic spherules, and the volatile element contents have to be considered. We propose that the variation in NiO contents in cosmic spherules and their olivines is the result of variable content of Fe, Ni metal in the precursor. NiO contents in olivines and in cosmic spherules can thus be used to discuss their parent body. Ni‐poor spherules can be derived from C‐rich and/or metal‐poor precursors, either related to CM, CI, CR chondrites or to chondritic fragments dominated by silicates, regardless of the parent body. Ni‐rich spherules (NiO > 0.7 wt%) that represent 55% of the 47 barred‐olivine spherules we studied, were derived from the melting of C‐poor, metal‐rich precursors, compatible with ordinary chondrite or CO, CV, CK carbonaceous chondrite parentages.     

To be or not to be oxidized: A case study of olivine behavior in the fusion crust of ureilite A 09368 and H chondrites A 09004 and A 09502

Meteorite fusion crusts are quenched melt layers formed during meteoroid atmospheric entry, mostly preserved as coating on the meteorite surface. Antarctic ureilite Asuka (A) 09368 and H chondrites A 09004 and A 09502 exhibit well preserved thick fusion crusts, characterized by extensive olivine crystallization. As olivine is one of the major components of most meteorites and its petrologic behavior is well constrained, it can be roughly considered as representative for the bulk meteorite. Thus, in this work, the evolution of olivine in fusion crusts of the above‐listed selected samples is investigated. The different shape and chemistry of olivine crystallized in the fusion crust, both as overgrown rim on relic olivine clasts and as new crystals, suggest a general temperature and cooling rate gradient. The occurrence of reverse and oscillatory zoning in individual olivine grains within the fusion crust suggests complex redox reactions. Overall, the investigated fusion crusts exhibit a general oxidation of the relatively reduced initial material. However, evidence of local reduction is preserved. Reduction is likely triggered by the presence of carbon in the ureilite or by overheating during the atmospheric entry. Constraining these processes provides a potential analog for interpreting features observed in cosmic spherules and micrometeorites and for calibrating experiments and numerical models on the formation of fusion crusts.     

Fe and O isotope composition of meteorite fusion crusts: Possible natural analogues to chondrule formation?

Meteorite fusion crust formation is a brief event in a high‐temperature (2000–12,000 K) and high‐pressure (2–5 MPa) regime. We studied fusion crusts and bulk samples of 10 ordinary chondrite falls and 10 ordinary chondrite finds. The fusion crusts show a typical layering and most contain vesicles. All fusion crusts are enriched in heavy Fe isotopes, with δ⁵⁶Fe values up to +0.35‰ relative to the solar system mean. On average, the δ⁵⁶Fe of fusion crusts from finds is +0.23‰, which is 0.08‰ higher than the average from falls (+0.15‰). Higher δ⁵⁶Fe in fusion crusts of finds correlate with bulk chondrite enrichments in mobile elements such as Ba and Sr. The δ⁵⁶Fe signature of meteorite fusion crusts was produced by two processes (1) evaporation during atmospheric entry and (2) terrestrial weathering. Fusion crusts have either the same or higher δ¹⁸O (0.9–1.5‰) than their host chondrites, and the same is true for Δ¹⁷O. The differences in bulk chondrite and fusion crust oxygen isotope composition are explained by exchange of oxygen between the molten surface of the meteorites with the atmosphere and weathering. Meteorite fusion crust formation is qualitatively similar to conditions of chondrule formation. Therefore, fusion crusts may, at least to some extent, serve as a natural analogue to chondrule formation processes. Meteorite fusion crust and chondrules exhibit a similar extent of Fe isotope fractionation, supporting the idea that the Fe isotope signature of chondrules was established in a high‐pressure environment that prevented large isotope fractionations. The exchange of O between a chondrule melt and an ¹⁶O‐poor nebula as the cause for the observed nonmass dependent O isotope compositions in chondrules is supported by the same process, although to a much lower extent, in meteorite fusion crusts.     

Melted micrometeorites from Antarctic ice with evidence for the separation of immiscible Fe-Ni-S liquids during entry heating

Abstract— We report the discovery of four large (>50 μm) cosmic spherules (CSs) and a single scoriaceous micrometeorite (SMM) that contain evidence for the separation of immiscible Fe-Ni-S liquids during atmospheric entry heating. The particles contain segregated Fe-rich regions dominated by either Ni-S-bearing Fe-oxides or iron sulphides and have textural relations that suggest these separated from the silicate portions of the particles as metallic liquids. The oxides, which may be hydrous, are thought to result from alteration of metal and sulphide. The compositions of the silicate portions of the CSs are equivalent to spherules without Fe-rich regions, implying that metallic liquids are exsolved during the heating of most spherules, but completely separate. The single SMM has a very different composition from other scoriaceous particles, and the occurrence of an exsolved metallic liquid probably indicates extreme reduction during entry heating. The pyrolysis of carbonaceous materials is the most likely explanation for reduction and suggests that the precursor material of this particle was unusually C-rich. This SMM might be, therefore, an appropriate candidate for a large melted anhydrous or smectite interplanetary dust particle (IDP). The exsolution of immiscible Fe-Ni-S liquids during entry heating will result in systematic changes in the compositions of the remaining silicate melt.     

Major and trace element geochemistry of S‐type cosmic spherules

Micrometeorites that pass through the Earth's atmosphere undergo changes in their chemical compositions, thereby making it difficult to understand if they are sourced from the matrix, chondrules, or calcium–aluminum‐rich inclusions (CAIs). These components have the potential to provide evidence toward the understanding of the early solar nebular evolution. The variations in the major element and trace element compositions of 155 different type (scoriaceous, relict bearing, porphyritic, barred, cryptocrystalline, and glass) of S‐type cosmic spherules are investigated with the intent to decipher the parent sources using electron microprobe and laser ablation inductively coupled plasma‐mass spectrometry. The S‐type cosmic spherules appear to show a systematic depletion in volatile element contents, but have preserved their refractory trace elements. The trends in their chemical compositions suggest that the S‐type spherules comprise of components from similar parent bodies, that is, carbonaceous chondrites. Large fosteritic relict grains observed in this investigation appear to be related to the fragments of chondrules from carbonaceous chondrites. Furthermore, four spherules (two of these spherules enclose spinels and one comprised entirely of a Ca‐Al‐rich plagioclase) show enhanced trace element enrichment patterns that are drastically different from all the other 151 cosmic spherules. The information on the chemical composition and rare earth elements (REEs) on cosmic spherules suggest that the partially to fully melted ones can preserve evidences related to their parent bodies. The Ce, Eu, and Tm anomalies found in the cosmic spherules have similar behavior as that of chondrites. Distinct correlations observed between different REEs and types of cosmic spherules reflect the inherited properties of the precursors.     

COLLESCIPOLI: AN UNUSUAL FUSION CRUST GLASS

An electron microprobe study was conducted on glass fragments taken from the fusion crust and an internal glass-lined vein in the H-5 chondrite Collescipoli. Microprobe analyses of the glasses revealed an unusual fusion crust composition, and analyses of glass from inside the meteorite showed compositions expected for a melt of an H-group chondrite. Studies of fusion crusts by previous workers, e.g., Krinov and Ramdohr, showed that fusion crusts contain large amounts of magnetite and other oxidized minerals. The Collescipoli fusion crusts do contain these minerals, but they also contain relatively large amounts of reduced metal, sulphide, and a sodium-rich glass. This study seems to indicate that Collescipoli preserved an early type of fusion crust. Oxidation was incomplete in the fusion crust melt that drained into a crack. From this study it is concluded that fusion crust formation does not invariably result in complete oxidation of metal and sulphide phases.     

The Burnwell,Kentucky, low iron oxide chondrite fall: Description,classification and origin

Abstract— The Burnwell, Kentucky, meteorite fell as a single stone on 1990 September 4. The Burnwell meteorite has lower Fa in olivine (15.8 mol%), Fs in orthopyroxene (13.4 mol%), Co in kamacite (0.36 wt%), FeO from bulk chemical analysis (9.43 wt%), and Δ¹⁷O (0.51 ± 0.02%), and higher Fe, Ni, Co metal (19.75 wt% from bulk wet chemical analysis) than observed in H chondrites. The Burnwell meteorite plots on extensions of H-L-LL chondrite trends for each of these properties towards more reducing compositions than in H chondrites. Extensions of this trend have been previously suggested in the case of other low-FeO chondrites or silicate inclusions in the HE iron Netschaëvo, but interpretation of the evidence in these meteorites is complicated by terrestrial weathering, chemical disequilibrium or reduction. In contrast, the Burn-well meteorite is an equilibrated fall that exhibits no evidence for reduction. As such, it provides the first definitive evidence for extension of the H-L-LL ordinary chondrite trend beyond typical H values towards more reducing compositions.     

The fusion crust of the Winchcombe meteorite: A preserved record of atmospheric entry processes

Fusion crusts form during the atmospheric entry heating of meteorites and preserve a record of the conditions that occurred during deceleration in the atmosphere. The fusion crust of the Winchcombe meteorite closely resembles that of other stony meteorites, and in particular CM2 chondrites, since it is dominated by olivine phenocrysts set in a glassy mesostasis with magnetite, and is highly vesicular. Dehydration cracks are unusually abundant in Winchcombe. Failure of this weak layer is an additional ablation mechanism to produce large numbers of particles during deceleration, consistent with the observation of pulses of plasma in videos of the Winchcombe fireball. Calving events might provide an observable phenomenon related to meteorites that are particularly susceptible to dehydration. Oscillatory zoning is observed within olivine phenocrysts in the fusion crust, in contrast to other meteorites, perhaps owing to temperature fluctuations resulting from calving events. Magnetite monolayers are found in the crust, and have also not been previously reported, and form discontinuous strata. These features grade into magnetite rims formed on the external surface of the crust and suggest the trapping of surface magnetite by collapse of melt. Magnetite monolayers may be a feature of meteorites that undergo significant degassing. Silicate warts with dendritic textures were observed and are suggested to be droplets ablated from another stone in the shower. They, therefore, represent the first evidence for intershower transfer of ablation materials and are consistent with the other evidence in the Winchcombe meteorite for unusually intense gas loss and ablation, despite its low entry velocity.     

Black ordinary chondrites: An analysis of abundance and fall frequency

Abstract— Black ordinary chondrite meteorites sample the spectral effects of shock on ordinary chondrite material in the space environment. Since shock is an important regolith process, these meteorites may provide insight into the spectral properties of the regoliths on ordinary chondrite parent bodies. To determine how common black chondrites are in the meteorite collection and, by analogy, the frequency of shock-alteration in ordinary chondrites, several of the world's major meteorite collections were examined to identify black chondrites. Over 80% of all catalogued ordinary chondrites were examined and, using an optical definition, 61 black chondrites were identified. Black chondrites account for approximately 13.7% of ordinary chondrite falls. If the optically altered gas-rich ordinary chondrites are included, the proportion of falls that exhibit some form of altered spectral properties increases to 16.7%. This suggests that optical alteration of asteroidal material in the space environment is a relatively common process.     

The Leonard Award Address Presented 1996 July 25, Berlin,Germany: The elemental composition of stony cosmic spherules

Abstract— Five hundred stony cosmic spherules collected from deep-sea sediments, polar ice, and the stratosphere have been analyzed for major and some minor element composition. Typical spherules are products of atmospheric melting of millimeter sized and smaller meteoroids. The samples are small and modified by atmospheric entry, but they are an important source of information on the composition of asteroids. The spherules in this study were all analyzed in an identical manner, and they provide a sampling of the solar system's asteroids that is both different and less biased than provided by studies of conventional meteorites. Volatile elements such as Na and S are depleted due to atmospheric heating, while siderophiles are depleted by less understood causes. The refractory nonsiderophile elements appear not to have been significantly disturbed during atmospheric melting and provide important clues on the elemental composition of millimeter sized meteoroids colliding with the Earth. Typical spherules have CM-like composition that is distinctively different than ordinary chondrites and most other meteorite types. We assume that C-type asteroids are the primary origin of spherules with this composition. Type S asteroids should also be an important source of the spherules, and the analysis data provide constraints on their composition. A minor fraction of the spherules are melt products of precursor particles that did not have chondritic elemental compositions. The most common of these are particles that are dominated by olivine. The observed compositions of spherules are inconsistent with the possibility that an appreciable fraction of the spherules are simply chondrules remelted during atmospheric entry.     

The density and porosity of meteorites from the Vatican collection

Abstract— We have developed a nondestructive technique to measure the densities and porosities of large (50 g to several kilogram) meteorite samples and have begun a systematic measurement program starting with meteorites from the Vatican Observatory collection. Our technique utilizes a modified Archimedean method (40 μm glass spheres substituting for the fluid) to determine bulk density, and an unusually large He pycnometer to determine grain density. From these, the porosity is calculated. We report here our first results for 89 samples (nearly doubling the published database on porosities of meteorite hand samples), including porosities of 35 different meteorites. These include several types not previously reported: eight iron meteorites, six stony-iron meteorites, an enstatite chondrite, the CI carbonaceous chondrite Orgueil, and the shergottite-nakhlatite-chassignite (SNC) meteorite Nakhla.     

Solar-proton-produced neon in shergottite meteorites and implications for their origin

Abstract— Measured Ne isotopes in samples of shergottite ALHA77005 show variations in ²¹Ne/²²Ne ratios and ²¹Ne abundances that are consistent with the presence of two cosmogenic components: a component produced by nuclear interactions of galactic cosmic rays (GCR) and a component produced at shallow shielding depths (～0–3 cm) by energetic solar flare protons (SCR). We suggest that the ²¹Ne/²²Ne ratio generally can be used to distinguish between SCR and GCR components in many meteorite types. Analysis of cosmogenic Ne produced in chondrite mineral separates, eucrites, and anorthositic lunar rocks, all having diverse major element compositions, indicate that the GCR ²¹Ne/²²Ne ratio increases modestly with relative Mg content. Data for hundreds of chondrite analyses suggest that SCR Ne is present in no more than a very small fraction of chondrites. Examination of literature data for other shergottites, however, indicate that all of these meteorites contain SCR Ne but that it is apparently absent in other SNC meteorites. The ubiquitous presence of SCR Ne in shergottites, in contrast to most other types of meteorites, suggests that the martian origin of shergottites gave them different orbital parameters compared to other meteorites. This in turn may have contributed to slower entry velocities and lesser surface ablation in the atmosphere or even to higher SCR production rates.     

The entry heating and abundances of basaltic micrometeorites

Basaltic micrometeorites (MMs) derived from HED‐like parent bodies have been found among particles collected from the Antarctic and from Arctic glaciers and are to date the only achondritic particles reported among cosmic dust. The majority of Antarctic basaltic particles are completely melted cosmic spherules with only one unmelted particle recognized from the region. This paper investigates the entry heating of basaltic MMs in order to predict the relative abundances of unmelted to melted basaltic particles and to evaluate how mineralogical differences in precursor materials influence the final products of atmospheric entry collected on the Earth's surface. Thermodynamic modeling is used to simulate the melting behavior of particles with compositions corresponding to eucrites, diogenites, and ordinary chondrites in order to evaluate degree of partial melting and to make a comparison between the behavior of chondritic particles that dominate the terrestrial dust flux and basaltic micrometeroids. The results of 120,000 simulations were compiled to predict relative abundances and indicate that the phase relations of precursor materials are crucial in determining the relative abundances of particle types. Diogenite and ordinary chondrite materials exhibit similar behavior, although diogenite precursors are more likely to form cosmic spherules under similar entry parameters. Eucrite particles, however, are much more likely to melt due to their lower liquidus temperatures and small temperature interval of partial melting. Eucrite MMs, therefore, usually form completely molten cosmic spherules except at particle diameters <100 μm. The low abundance of unmelted basaltic MMs compared with spherules, if statistically valid, is also shown to be inconsistent with a low velocity population (12 km s^?1) and is more compatible with higher velocities which may suggest a near‐Earth asteroid source dominates the current dust production of basaltic MMs.     

Shock melts in QUE 94411, Hammadah al Hamra 237, and Bencubbin: Remains of the missing matrix?

Abstract— We have studied the CB carbonaceous chondrites Queen Alexandra Range (QUE) 94411, Hammadah al Hamra (HH) 237, and Bencubbin with an emphasis on the petrographical and mineralogical effects of the shock processing that these meteorite assemblages have undergone. Iron‐nickel metal and chondrule silicates are the main components in these meteorites. These high‐temperature components are held together by shock melts consisting of droplets of dendritically intergrown Fe,Ni‐metal/sulfide embedded in silicate glass, which is substantially more FeO‐rich (30–40 wt%) than the chondrule silicates (FeO <5 wt%). Fine‐grained matrix material, which is a major component in most other chondrite classes, is extremely scarce in QUE 94411 and HH 237, and has not been observed in Bencubbin. This material occurs as rare, hydrated matrix lumps with major and minor element abundances roughly similar to the ferrous silicate shock melts (and CI). We infer that hydrated, fine‐grained material, compositionally similar to these matrix lumps, was originally present between the Fe,Ni‐metal grains and chondrules, but was preferentially shock melted. Other shock‐related features in QUE 94411, HH 237, and Bencubbin include an alignment and occasionally strong plastic deformation of metal and chondrule fragments. The existence of chemically zoned and metastable Fe,Ni‐metal condensates in direct contact with shock melts indicates that the shock did not substantially increase the average temperature of the rock. Because porphyritic olivine‐pyroxene chondrules are absent in QUE 94411, HH 237, and Bencubbin, it is difficult to determine the precise shock stage of these meteorites, but the shock was probably relatively light (S2–S3), consistent with a bulk temperature increase of the assemblages of less than ?300 °C. The apparently similar shock processing of Bencubbin, Weatherford, Gujba (CB_a) and QUE 94411/HH 237 (CB_b) supports the idea of a common asteroidal parent body for these meteorites.     

FORMS OF NONTERRESTRIAL DUST ON THE EARTH

The author carried out a study of pulverised cosmic matter extracted from the soil at the fall locality of the Sikhote Alin iron meteorite shower. Three forms of dust were distinguishable: meteoritic, sharp-angled, irregular particles from the break-up of the meteorite; meteoric, spherical, magnetic particles from ablation; and micro meteorites. Meteoritic and meteoric dust was also discovered in the soil of the regions of fall of the Boguslavka and Yardymly iron meteorites. Experiments made by the author for the purpose of obtaining artificial meteoric dust from meteoritic matter of various types have shown that the meteoric dust obtained from stony meteorites is composed of spherules similar to those extracted from the soil in the areas of fall of the Sikhote Alin, Boguslavka and Yardymly iron meteorites. Cosmic dust, the particles of which are usually called micrometeorites, due to their small size, are not subjected to the influence of temperature as they pass through the Earth's atmosphere and they reach the Earth's surface unaltered. It is proposed that meteoric and cosmic dust comprises the largest part of the cosmic matter falling onto the Earth:     

Identifying meteorite source regions through near-Earth object spectroscopy

By virtue of their landing on Earth, meteorites reside in near-Earth object (NEO) orbits prior to their arrival. Thus the population of observable NEOs, in principle, gives important representation of meteorite source bodies. By linking meteorites to NEOs, and linking NEOs to their most likely main-belt source locations, we seek to gain insight into the original Solar System formation locations for different meteorite classes. To forge possible links between meteorites and NEOs, we have developed a three dimensional method for quantitative comparisons between laboratory measurements of meteorites and telescopic measurements of near-Earth objects. We utilize meteorite spectra from the Reflectance Experiment Laboratory (RELAB) database and NEO data from the SpeX instrument on the NASA Infrared Telescope Facility (IRTF). Using the Modified Gaussian Model (MGM) as a mathematical tool, we treat asteroid and meteorite spectra identically in the calculation of 1-μm and 2-μm Geometric Band Centers and their Band Area Ratios (BARs). Using these identical numerical parameters we quantitatively compare the spectral properties of S-, Sq-, Q- and V-type NEOs with the spectral properties of the meteorites in four classes: H, L, LL and HED. For each NEO spectrum, we assign a set of probabilities for it being related to each of these four meteorite classes. Our NEO-meteorite correlation probabilities are then convolved with NEO-source region probabilities to yield a final set of meteorite-source region correlations. While the ν6 resonance dominates the delivery for all four meteorite classes, an excess (significant at the 2.1-sigma level) source region signature is found for the H chondrites through the 3:1 mean motion resonance. This results suggest an H chondrite source with a higher than average delivery preference through the 3:1 resonance. A 3:1 resonance H chondrite source region is consistent with the short cosmic ray exposure ages known for H chondrites.     

Stony meteorite porosities and densities: A review of the data through 2001

Abstract— In this review, we summarize the data published up to December 2001 on the porosity and density of stony meteorites. These data were taken from 925 samples of 454 different meteorites by a variety of techniques. Most meteorites have densities on the order of 3 to 4 g/cm³, with lower densities only for some volatile‐rich carbonaceous meteorites and higher densities for stony irons. For the vast majority of stones, porosity data alone cannot distinguish between different meteorite compositions. Average porosities for most meteorite classes are around 10%, though individual samples can range as high as 30% porosity. Unbrecciated basaltic achondrites appear to be systematically less porous unless vesicles are present. The measured density of ordinary chondrites is strongly controlled by the amount of terrestrial weathering the sample has undergone with porosities steadily dropping with exposure to the terrestrial environment. A theoretical grain density based on composition can model “pre‐weathered” porosities. The average model porosity for H and LL chondrites is 10%, while L chondrite model porosities average only 6%, a statistically significant difference.     

Spectral properties and mineral compositions of acapulcoite–lodranite clan meteorites: Establishing S‐type asteroid–meteorite connections

Except for asteroid sample return missions, measurements of the spectral properties of both meteorites and asteroids offer the best possibility of linking meteorite groups with their parent asteroid(s). Visible plus near‐infrared spectra reveal distinguishing absorption features controlled mainly by the Fe²⁺ contents and modal abundances of olivine and pyroxene. Meteorite samples provide relationships between spectra and mineralogy. These relationships are useful for estimating the olivine and pyroxene mineralogy of stony (S‐type) asteroid surfaces. Using a suite of 10 samples of the acapulcoite–lodranite clan (ALC), we have developed new correlations between spectral parameters and mafic mineral compositions for partially melted asteroids. A well‐defined relationship exists between Band II center and ferrosilite (Fs) content of orthopyroxene. Furthermore, because Fs in orthopyroxene and fayalite (Fa) content in olivine are well correlated in these meteorites, the derived Fs content can be used to estimate Fa of the coexisting olivine. We derive new equations for determining the mafic silicate compositions of partially melted S‐type asteroid parent bodies. Stony meteorite spectra have previously been used to delineate meteorite analog spectral zones in Band I versus band area ratio (BAR) parameter space for the establishment of asteroid–meteorite connections with S‐type asteroids. However, the spectral parameters of the partially melted ALC overlap with those of ordinary (H) chondrites in this parameter space. We find that Band I versus Band II center parameter space reveals a clear distinction between the ALC and the H chondrites. This work allows the distinction of S‐type asteroids as nebular (ordinary chondrites) or geologically processed (primitive achondrites).     

Multi-zone fusion crust formation and classification of the 2004 Auckland meteorite (L6, S5, and W0)

On June 12, 2004, a meteorite passed through Earth's atmosphere and landed under the television in the living room of a house in Auckland, New Zealand. Textural characteristics, the chemistry of olivine (Fa_23–24) and orthopyroxene (Fs_20.7), and the bulk rock triple oxygen isotopes (δ¹⁷O + 3.1; δ¹⁸O + 4.2‰) from the interior of the completely unweathered (W0) 1.3 kg meteorite, hereafter referred to as Auckland, suggest it to be a strongly metamorphosed fragment from the interior of a low iron ordinary chondrite (L6) parent asteroid. The occurrence of maskelynite but shock fracturing of olivine and pyroxene indicates Auckland experienced extreme shock metamorphism (S5), likely during Ordovician fragmentation of the asteroid parent. The fusion crust consists of three zones: (1) an innermost zone containing narrow Fe-Ni-S-bearing veins that migrated along pre-existing shock fractures in olivine and pyroxene; (2) a middle zone in which the meteorite partially melted to form a silicate glass and immiscible blebs of metal and troilite, and is accompanied by unmelted silicate minerals; and (3) an approximately 0.1 mm wide vesicular-rich outermost layer that largely melted, volatilizing sulfides, before quenching to form glass and olivine. Oxygen isotope values of the bulk rock and/or maskelynite of melted rim and modified substrate are 2–3‰ greater than the meteorite interior and indicate that up to 19% of terrestrial atmospheric O₂ was incorporated into the fusion crust during the formation. The fusion crust migrated inwards as ablation occurred, enabling melting, migration, and re-precipitation ± loss of sulfide and metal components, with the prominent glassy rim therefore forming from an already chemically modified zone.