Post-entry and volcanic contaminant abundances of zinc,copper, selenium,germanium and gallium in stratospheric micrometeorites

Abstract— Some fraction of Zn, Cu, Se, Ga and Ge in chondritic interplanetary dust particles (IDPs) collected in the lower stratosphere between 1981 May and 1984 June has a volcanic origin. I present a method to evaluate the extent of this unavoidable type of stratospheric contamination for individual particles. The mass-normalised abundances for Cu and Ge as a function of mass-normalised stratospheric residence time show their time-integrated stratospheric aerosol abundances. The Zn, Se and Ga abundances show a subdivision into two groups that span approximately two-year periods following the eruptions of the Mount St. Helens (1980 May) and El Chichón (1982 April) volcanos. Elemental abundances in particles collected at the end of each two-year period indicate low, but not necessarily ambient, volcanic stratospheric abundances. Using this time-integrated baseline, I calculate the stratospheric contaminant fractions in nine IDPs and show that Zn, Se and Ga abundances in chondritic IDPs derive in part from stratospheric aerosol contaminants. Post-entry elemental abundances (i.e., the amount that survived atmospheric entry heating of the IDP) show enrichments relative to the CI abundances but in a smaller number of particles than previously suggested.     

A potentially new type of nonchondritic interplanetary dust particle with hematite,organic carbon,amorphous Na,Ca‐aluminosilicate,and FeO‐spheres

Abstract– We used a combination of different analytical techniques to study particle W7190‐D12 using microinfrared spectroscopy, micro‐Raman spectroscopy, and field emission scanning electron microscopy (FESEM) energy dispersive X‐ray spectroscopy (EDS). The particle consists mainly of hematite (α‐Fe₂O₃) with considerable variations in structural disorder. It further contains amorphous (Na,K)‐bearing Ca,Al‐silicate and organic carbon. Iron‐bearing spherules (<150 nm in diameter) cover the surface of this particle. At local sites of structural disorder at the hematite surface, the hematite spheres were reduced to FeO in the presence of organic carbons forming FeO‐spheres. However, metallic Fe spheres cannot be excluded based on the available data. To the best of our knowledge, this particle is the first detection of such spherules at the surface of a stratospheric dust particle. Although there is no definitive evidence for an extraterrestrial origin of particle W7190‐D12, we suggest that it could be an IDP that had moved away from the asteroid‐forming region of the early solar system into the outer solar system of the accreting Kuiper Belt objects. After it was released from a Jupiter family comet, this particle became part of the zodiacal cloud. Atmospheric entry flash‐heating caused (1) the formation of microenvironments of reduced iron oxide when indigenous carbon materials reacted with hematite covering its surface resulting in the formation of FeO‐spheres and (2) Na‐loss from Na,Al‐plagioclase. The particle of this study, and other similar particles on this collector, may represent a potentially new type of nonchondritic IDPs associated with Jupiter family comets, although an origin in the asteroid belt cannot be ignored.     

Tin in a chondritic interplanetary dust particle

Abstract— Submicron platey Sn-rich grains are present in chondritic porous interplanetary dust particle (IDP) W7029^*A and it is the second occurrence of a tin mineral in a stratospheric micrometeorite. Selected Area Electron Diffraction data for the Snrich grains match with Sn₂O₃ and Sn₃O₄. The oxide(s) may have formed in the solar nebula when tin metal catalytically supported reduction of CO or during flash heating on atmospheric entry of the IDP. The presence of tin is consistent with enrichments for other volatile trace elements in chondritic IDPs and may signal an emerging trend towards non-chondritic volatile element abundances in chondritic IDPs. The observation confirms small-scale mineralogical heterogeneity in fine-grained chondritic porous interplanetary dust.     

Organic matter from comet 81P/Wild 2, IDPs,and carbonaceous meteorites; similarities and differences

Abstract— During preliminary examination of 81P/Wild 2 particles collected by the NASA Stardust spacecraft, we analyzed seven, sulfur embedded and ultramicrotomed particles extracted from five different tracks. Sections were analyzed using a scanning transmission X‐ray microscope (SXTM) and carbon X‐ray absorption near edge structure (XANES) spectra were collected. We compared the carbon XANES spectra of these Wild 2 samples with a database of spectra on thirty‐four interplanetary dust particles (IDPs) and with several meteorites. Two of the particles analyzed are iron sulfides and there is evidence that an aliphatic compound associated with these particles can survive high temperatures. An iron sulfide from an IDP demonstrates the same phenomenon. Another, mostly carbon free containing particle radiation damaged, something we have not observed in any IDPs we have analyzed or any indigenous organic matter from the carbonaceous meteorites, Tagish Lake, Orgueil, Bells and Murchison. The carbonaceous material associated with this particle showed no mass loss during the initial analysis but chemically changed over a period of two months. The carbon XANES spectra of the other four particles varied more than spectra from IDPs and indigenous organic matter from meteorites. Comparison of the carbon XANES spectra from these particles with 1. the carbon XANES spectra from thirty‐four IDPs (<15 micron in size) and 2. the carbon XANES spectra from carbonaceous material from the Tagish Lake, Orgueil, Bells, and Murchison meteorites show that 81P/Wild 2 carbon XANES spectra are more similar to IDP carbon XANES spectra then to the carbon XANES spectra of meteorites.     

Pristine stratospheric collection of interplanetary dust on an oil‐free polyurethane foam substrate

We performed chemical, mineralogical, and isotopic studies of the first interplanetary dust particles (IDPs) collected in the stratosphere without the use of silicone oil. The collection substrate, polyurethane foam, effectively traps impacting particles, but the lack of an embedding medium results in significant particle fragmentation. Two dust particles found on the collector exhibit the typical compositional and mineralogical properties of chondritic porous interplanetary dust particles (CP‐IDPs). Hydrogen and nitrogen isotopic imaging revealed isotopic anomalies of typical magnitude and spatial variability observed in previous CP‐IDP studies. Oxygen isotopic imaging shows that individual mineral grains and glass with embedded metal and sulfide (GEMS) grains are dominated by solar system materials. No systematic differences are observed in element abundance patterns of GEMS grains from the dry collection versus silicone oil‐collected IDPs. This initial study establishes the validity of a new IDP collection substrate that avoids the use of silicone oil as a collection medium, removing the need for this problematic contaminant and the organic solvents necessary to remove it. Additional silicone oil‐free collections of this type are needed to determine more accurate bulk element abundances of IDPs and to examine the indigenous soluble organic components of IDPs.     

Depth-profiles and surface enrichment of the halogens in four Antarctic H5 chondrites and in two non-Antarctic chondrites

Abstract— Depth-profiles of F, Cl, Br and I concentrations were determined in four different Antarctic H5 chondrites from the Allan Hills and in the two chondrites Allende (C3) and Holbrook (L6). Pieces of the meteorites were studied by analysis of stepwise removed layers of 0.5–1.0 mm thickness up to a depth of 9 mm. Neutron activation analysis and ion-selective potentiometry were used for the determination of Cl, Br, I and for F, respectively. The Antarctic meteorites show higher concentrations of the halogens at the surface compared to the interior. The highest enrichment factors are found for I and Cl and the lowest for Br. In contrast, F shows the steepest concentration gradient and is only enriched in the first 2.5 mm below the surface. The other halogens have penetrated deeper into the meteorites. The measured enrichments at the surfaces are not correlated to the visible degree of weathering. The analysed non-Antarctic meteorites, which were recovered shortly after their observed fall, demonstrate similar halogen concentrations at the surface, including the fusion crust, as in the interior. Based on these results we present a model to estimate the degree of contamination and the relation to the duration of exposure at the surface of the Antarctic ice.     

CM-like interplanetary dust particles in lower stratosphere during 1989 October and 1991 June/July

Abstract— The stratospheric interplanetary dust particles L2005T12 and L2011O3 are linked to CM chondrite matrix. Particle L2005T12 is dominated by tabular grains of partially dehydrated greenalite-rich serpentine. Its amorphous matrix contains abundant smectite nanocrystals and annular Fe, Ni, S units. A uniquely stratified (partial) maghémite rim occurs only on S-rich parts of the matrix. Formation of this rim and Mg depletions in the matrix occurred during atmospheric entry heating of this particle. Particle L2011O3 has large iron sulfide and magnesiowüstite grains in an amorphous low-Al, ferromagnesiosilica matrix. Hydrous crystallisation of this matrix produced ultrafine-grained smectites and disseminated iron sulfides. Atmospheric entry heating of both particles is indicated by the partial iron oxide rim, vesicular sulfides, and the scatter of matrix compositions due to loss of Mg. While many uncertainties remain, the high incidence of chondritic rough particles, which include an unknown amount of CM-like particles, in the lower stratosphere during 1984, 1989, and 1991 suggests annual variations in their abundances. The timing of lower stratospheric dust samplings is critical to collect these particles.     

Mineralogy,chemistry, and oxygen isotopes of refractory inclusions from stratospheric interplanetary dust particles and micrometeorites

Abstract— Calcium, aluminum-rich inclusions (CAIs) are characteristic components in carbonaceous chondrites. Their mineralogy is dominated by refractory oxides and silicates like corundum, perovskite, spinel, hibonite, melilite, and Ca-pyroxene, which are predicted to be the first phases to have condensed from the cooling solar nebula. Allowing insights into processes occurring in the early solar system, CAIs in carbonaceous and ordinary chondrites were studied in great detail, whereas only a few refractory inclusions were found and studied in stratospheric interplanetary dust particles (IDPs) and micrometeorites. This study gives a summary of all previous studies on refractory inclusions in stratospheric IDPs and micrometeorites and will present new data on two Antarctic micrometeorites. The main results are summarized as follows: (a) Eight stratospheric IDPs and six micrometeorites contain Ca, Al-rich inclusions or refractory minerals. The constituent minerals include spinel, perovskite, fassaite, hibonite, melilite, corundum, diopside and anorthite. (b) Four of the seven obtained rare-earth-element (REE) patterns from refractory objects in stratospheric IDPs and micrometeorites are related to Group III patterns known from refractory inclusions from carbonaceous chondrites. A Group II related pattern was found for spinel and perovskite in two micrometeorites. The seventh REE pattern for an orthopyroxene is unique and can be explained by fractionation of Gd, Lu, and Tb at highly reducing conditions. (c) The O-isotopic compositions of most refractory objects in stratospheric IDPs and micrometeorites are similar to those of constituents from carbonaceous chondrites and fall on the carbonaceous chondrites anhydrous minerals mixing line. In fact, in most cases, in terms of mineralogy, REE pattern and O-isotopic composition of refractory inclusions in stratospheric IDPs and micrometeorites are in good agreement with a suggested genetic relation of dust particles and carbonaceous chondrites. Only in the case of one Antarctic micrometeorite does the REE pattern obtained for an orthopyroxene point to a link of this particle to enstatite chondrites.     

Melted micrometeorites from Antarctic ice with evidence for the separation of immiscible Fe-Ni-S liquids during entry heating

Abstract— We report the discovery of four large (>50 μm) cosmic spherules (CSs) and a single scoriaceous micrometeorite (SMM) that contain evidence for the separation of immiscible Fe-Ni-S liquids during atmospheric entry heating. The particles contain segregated Fe-rich regions dominated by either Ni-S-bearing Fe-oxides or iron sulphides and have textural relations that suggest these separated from the silicate portions of the particles as metallic liquids. The oxides, which may be hydrous, are thought to result from alteration of metal and sulphide. The compositions of the silicate portions of the CSs are equivalent to spherules without Fe-rich regions, implying that metallic liquids are exsolved during the heating of most spherules, but completely separate. The single SMM has a very different composition from other scoriaceous particles, and the occurrence of an exsolved metallic liquid probably indicates extreme reduction during entry heating. The pyrolysis of carbonaceous materials is the most likely explanation for reduction and suggests that the precursor material of this particle was unusually C-rich. This SMM might be, therefore, an appropriate candidate for a large melted anhydrous or smectite interplanetary dust particle (IDP). The exsolution of immiscible Fe-Ni-S liquids during entry heating will result in systematic changes in the compositions of the remaining silicate melt.     

Major element composition of stratospheric micrometeorites

Abstract— The elemental compositions of 200 interplanetary dust particles (IDPs) collected in the stratosphere have been determined by energy dispersive X-ray (EDX) analysis. The results reasonably define the normal compositional range of chondritic interplanetary dust particles averaging 10 micrometers in size, and constitute a database for comparison with individual IDPs, meteorites, and spacecraft data from comets and asteroids. The average elemental composition of all IDPs analyzed is most similar to that of CI chondrites, but the data show that there are small yet discernable differences between mean IDP composition and the CI norm. Individual particles were classified into broad morphological groups, and the two major groups show unambiguous compositional differences. The “porous” group is a close match to bulk CI abundances, but the “smooth” group has systematic Ca and Mg depletions, and contains stoichiometric “excess” oxygen consistent with the presence of hydrous phases. Similar depletions of Ca and Mg in CI and CM matrix have been attributed to leaching, and by analogy we suggest that particles in the smooth group have also been processed by aqueous alteration. The occurrence of carbonates, magnetite framboids, and layer silicates provides additional evidence that at least a significant number of the smooth-class IDPs have been substantially processed by aqueous activity. The presence or absence of aqueous modification in members of a particle sub-class is an important clue to the origin. Although it cannot be proven, we hypothesize that extensive aqueous activity only occurs in asteroids and that, accordingly, the smooth class of IDPs has an asteroidal origin. If both comets and asteroids are major sources of interplanetary dust, then by default the porous particles are inferred to be dominated by cometary material.     

Salts in two chondritic porous interplanetary dust particles

Abstract— Grain-by-grain analytical electron microscope analyses of two micrometeorites, or interplanetary dust particles (IDPs), of the chondritic porous subtype, show the presence of rare barite (BaSO₄) and magnesium carbonate, probably magnesite. Salt minerals in chondritic porous (CP) IDPs give evidence for in situ aqueous alteration in their parent bodies. The uniquely high barium content of CP IDP W7029^*C1 is consistent with barite precipitation from a mildly acidic (pH > ～5) aqueous fluid at temperatures below 417 K and low oxygen fugacity. The presence of magnesite in olivine-rich, anhydrous CP IDP W7010^*A2 is evidence that carbonate minerals occur in both the chondritic porous and chondritic smooth subtypes of chondritic IDPs. Citing Schramm et al. (1989) for putative asteroidal-type aqueous alteration in IDPs and probable sources of chondritic IDPs, salt minerals in CP IDPs could support low-temperature aqueous activity in nuclei of active short-period comets.     

Sampling interplanetary dust from Antarctic air

We built a collector to filter interplanetary dust particles (IDPs) larger than 5 μm from the clean air at the Amundsen Scott South Pole station. Our sampling strategy used long duration, continuous dry filtering of near‐surface air in place of short duration, high‐speed impact collection on flags flown in the stratosphere. We filtered ~10⁷ m³ of clean Antarctic air through 20 cm diameter, 3 µm filters coupled to a suction blower of modest power consumption (5–6 kW). Our collector ran continuously for 2 years and yielded 41 filters for analyses. Based on stratospheric concentrations, we predicted that each month’s collection would provide 300–900 IDPs for analysis. We identified 19 extraterrestrial (ET) particles on the 66 cm² of filter examined, which represented ~0.5% of the exposed filter surfaces. The 11 ET particles larger than 5 µm yield about a fifth of the expected flux based on >5 µm stratospheric ET particle flux. Of the 19 ET particles identified, four were chondritic porous IDPs, seven were FeNiS beads, two were FeNi grains, and six were chondritic material with FeNiS components. Most were <10 µm in diameter and none were cluster particles. Additionally, a carbon‐rich candidate particle was found to have a small ¹⁵N isotopic enrichment, supporting an ET origin. Many other candidate grains, including chondritic glasses and C‐rich particles with Mg and Si and FeS grains, require further analysis to determine if they are ET. The vast majority of exposed filter surfaces remain to be examined.     

E ring dust sources: Implications from Cassini's dust measurements

The Enceladus flybys of the Cassini spacecraft are changing our understanding of the origin and sustainment of Saturn's E ring. Surprisingly, beyond the widely accepted dust production caused by micrometeoroid impacts onto the atmosphereless satellites (the impactor-ejecta process), geophysical activities have been detected at the south pole of Enceladus, providing an additional, efficient dust source. The dust detector data obtained during the flyby E11 are used to identify the amount of dust produced in the impactor-ejecta process and to improve related modeling [Spahn, F., Schmidt, J., Albers, N., Hörning, M., Makuch, M., Seiß, M., Kempf, S., Srama, R., Dikarev, V.V., Helfert, S., Moragas-Klostermeyer, G., Krivov, A.V., Sremčević, M., Tuzzolino, A., Economou, T., Grün, E., 2006. Cassini dust measurements at Enceladus: implications for Saturn's E ring. Science, in press]. With this, we estimate the impact-generated dust contributions of the other E ring satellites and find significant differences in the dust ejection efficiency by two projectile families—the E ring particles (ERPs) and the interplanetary dust particles (IDPs). Together with the Enceladus south-pole source, the ERP impacts play a crucial role in the inner region, whereas the IDP impacts dominate the particle production in the outer E ring, possibly accounting for its large radial extent. Our results can be verified in future Cassini flybys of the E ring satellites. In this way poorly known parameters of the dust particle production in hypervelocity impacts can be constrained by comparison of the data and theory.     

Discriminating contamination from particle components in spectra of Cassini's dust detector CDA

The Chemical Analyser subsystem of the Cosmic Dust Analyser (CDA) aboard the Cassini spacecraft performs in situ measurements of the chemical composition of dust in space. The instrument records time-of-flight mass spectra of cations, extracted from the impact cloud that is created by high-velocity particle impacts onto the detector target. Thus, the spectra not only show signals of particle components but also of ions from the target material and target contamination. The aim of this work is to determine which non-particle ions are to be expected in the spectra obtained in space operation at Saturn.We present an analysis of the contamination state of the instrument's impact target. Beside investigations of the purity of the rhodium target surface, spectra from CDA calibration experiments at the dust accelerator facility are evaluated with regard to contamination signatures. Furthermore, contamination mass lines in spectra obtained by impacts of Jovian and Saturnian dust stream particles are analysed. Due to their small size and high speed, stream particle impacts predominantly produce ions from the target material and therefore the spectra are excellent probes of the contamination state of the target operating in space. With the exception of adsorbed hydrogen and carbon, the level of contamination is very low.Implications for CDA spectra of Saturnian E ring particle impacts are derived. The findings confirm the published interpretations. The low level of alkali metal contamination implies a significant sodium contribution in the composition of E ring ice particles. Additionally, ionisation thresholds for the occurrence of contamination mass lines can be utilised to set limits for the impact velocity.     

Organic compound alteration during hypervelocity collection of carbonaceous materials in aerogel

Abstract— The NASA Stardust mission brought to Earth micron‐size particles from the coma of comet 81P/Wild 2 using aerogel, a porous silica material, as the capture medium. A major challenge in understanding the organic inventory of the returned comet dust is identifying, unambiguously, which organic molecules are indigenous to the cometary particles, which are produced from carbon contamination in the Stardust aerogel, and which are cometary organics that have been modified by heating during the particle capture process. Here it is shown that 1) alteration of cometary organic molecules along impact tracks in aerogel is highly dependent on the original particle morphology, and 2) organic molecules on test‐shot terminal particles are mostly preserved. These conclusions are based on two‐step laser mass spectrometry (L²MS) examinations of test shots with organic‐laden particles (both tracks in aerogel and the terminal particles themselves).     

Comparison of GEMS in interplanetary dust particles and GEMS‐like objects in a Stardust impact track in aerogel

Comet 81P/Wild 2 dust, the first comet sample of known provenance, was widely expected to resemble anhydrous chondritic porous (CP) interplanetary dust particles (IDPs). GEMS, distinctly characteristic of CP IDPs, have yet to be unambiguously identified in the Stardust mission samples despite claims of likely candidates. One such candidate is Stardust impact track 57 “Febo” in aerogel, which contains fine‐grained objects texturally and compositionally similar to GEMS. Their position adjacent the terminal particle suggests that they may be indigenous, fine‐grained, cometary material, like that in CP IDPs, shielded by the terminal particle from damage during deceleration from hypervelocity. Dark‐field imaging and multidetector energy‐dispersive X‐ray mapping were used to compare GEMS‐like‐objects in the Febo terminal particle with GEMS in an anhydrous, chondritic IDP. GEMS in the IDP are within 3× CI (solar) abundances for major and minor elements. In the Febo GEMS‐like objects, Mg and Ca are systematically and strongly depleted relative to CI; S and Fe are somewhat enriched; and Au, a known aerogel contaminant, is present, consistent with ablation, melting, abrasion, and mixing of the SiO_x aerogel with crystalline Fe‐sulfide and minor enstatite, high‐Ni sulfide, and augite identified by elemental mapping in the terminal particle. Thus, GEMS‐like objects in “caches” of fine‐grained debris abutting terminal particles are most likely deceleration debris packed in place during particle transit through the aerogel.     

Applied focused ion beam techniques for sample preparation of astromaterials for integrated nanoanalysis

Abstract— Sample preparation is always a critical step in the study of micrometer‐sized astromaterials available for study in the laboratory, whether their subsequent analysis is by electron microscopy or secondary ion mass spectrometry. A focused beam of gallium ions has been used to prepare electron transparent sections from an interplanetary dust particle (IDP), as part of an integrated analysis protocol to maximize the mineralogical, elemental, isotopic, and spectroscopic information extracted from one individual particle. In addition, focused ion beam (FIB) techniques have been employed to extract cometary residue preserved on the rims and walls of microcraters in 1100 series aluminum foils that were wrapped around the sample tray assembly on the Stardust cometary sample collector. Non‐ideal surface geometries and inconveniently located regions of interest required creative solutions. These include support pillar construction and relocation of a significant portion of sample to access a region of interest. Serial sectioning, in a manner similar to ultramicrotomy, is a significant development and further demonstrates the unique capabilities of focused ion beam microscopy for sample preparation of astromaterials.     

Dynamics of Dust Particles of Different Structure: Application to the Modeling of Dust Motion in the Vicinity of the Nucleus of Comet 67P/Churyumov–Gerasimenko

We consider the estimates of the main forces acting on dust particles near a cometary nucleus. On the basis of these estimates, the motion of dust particles of different structure and mass is analyzed. We consider the following forces: (1) the cometary nucleus gravity, (2) the solar radiation pressure, and (3) the drag on dust particles by a flow of gas produced in the sublimation of cometary ice. These forces are important for modeling the motion of dust particles relative to the cometary nucleus and may substantially influence the dust transfer over its surface. In the simulations, solid silicate spheres and homogeneous ballistic aggregates are used as model particles. Moreover, we propose a technique to build hierarchic aggregates—a new model of quasi-spherical porous particles. A hierarchic type of aggregates makes it possible to model rather large dust particles, up to a millimeter in size and larger, while no important requirements for computer resources are imposed. We have shown that the properties of such particles differ from those of classical porous ballistic aggregates, which are usually considered in the cometary physics problems, and considering the microscopic structure of particles is of crucial significance for the analysis of the observational data. With the described models, we study the dust dynamics near the nucleus of comet 67P/Churyumov–Gerasimenko at an early stage of the Rosetta probe observations when the comet was approximately at 3.2 AU from the Sun. The interrelations between the main forces acting on dust aggregates at difference distances from the nucleus have been obtained. The dependence of the velocity of dust aggregates on their mass has been found. The numerical modeling results and the data of spaceborne observations with the Grain Impact Analyzer and Dust Accumulator (GIADA) and the Cometary Secondary Ion Mass Analyzer (COSIMA) onboard the Rosetta probe are compared at a quantitative level.     

On the uncertainty of the transmission function of the optically thick AGB dust shells

The uncertainty of the spectral transmission function due to the nonsphericity of cosmic dust particles is analysed for optically thick C-rich and O-rich dust shells. The transmission function directly prescribes the intensity of radiation that passes through a dust shell. It is shown that nonspherical particles affect the stellar spectra in a different way than a system of equally sized spherical particles. Discrepancies in the stellar spectra for both morphological models (spheres and irregular targets) grow with optical thickness of the dust shell and the spectral behaviour of the optical thickness depends on the particle size distribution function. In particular, two most frequently used distrubutions, a power law and Dirac’s delta function, are considered in the presented numerical runs. Light transmission through C-rich dust shells is strongly influenced by absorption which dominates in case of carbonaceous particles. Irregularly shaped carbonaceous particles reduce the intensity of stellar spectra more efficiently than spherical particles of the same composition (the difference is about 10–30%). MgO particles which may be present in O-rich dust shells are almost pure scatterers, thus the ratio of transmission functions for irregularly shaped particles and spherical ones show specific resonant features (especially at wavelengths below 0.4 μm).     

Formation of carbides and hydrocarbons in chondritic interplanetary dust particles: A laboratory study

Abstract— The reaction between kamacite grains and H₂ + CO gas mixture has been tested in the laboratory under experimental conditions presumed for interplanetary dust particle (IDP) formation in a nebular-type environment (H₂:CO = 250:1; 5 × 10^?4 atm total pressure, and 473 K). Carbon deposition, hydrocarbon production in the C₁–C₄ range, and the formation of an ?-carbide phase occur when well-defined model FeNi bcc alloy (kamacite) particles are exposed to a mixture of H₂ + CO during 10³ h. These results strongly support the idea that gas-solid reactions in the solar nebula during CO hydrogenation represent a plausible scenario for the formation of carbides and carbonaceous materials in IDPs, as well as for the production of hydrocarbons through Fischer-Tropsch-type reactions.