Conflicting structural and geochronological data from the Ibituruna quartz-syenite (SE Brazil): Effect of protracted “hot” orogeny and slow cooling rate?

The Ibituruna quartz-syenite was emplaced as a sill in the Ribeira-Araçuaí Neoproterozoic belt (Southeastern Brazil) during the last stages of the Gondwana supercontinent amalgamation. We have measured the Anisotropy of Magnetic Susceptibility (AMS) in samples from the Ibituruna sill to unravel its magnetic fabric that is regarded as a proxy for its magmatic fabric. A large magnetic anisotropy, dominantly due to magnetite, and a consistent magnetic fabric have been determined over the entire Ibituruna massif. The magmatic foliation and lineation are strikingly parallel to the solid-state mylonitic foliation and lineation measured in the country-rock. Altogether, these observations suggest that the Ibituruna sill was emplaced during the high temperature (~ 750 °C) regional deformation and was deformed before full solidification coherently with its country-rock. Unexpectedly, geochronological data suggest a rather different conclusion. LA-ICP-MS and SHRIMP ages of zircons from the Ibituruna quartz-syenite are in the range 530–535 Ma and LA-ICP-MS ages of zircons and monazites from synkinematic leucocratic veins in the country-rocks suggest a crystallization at ~ 570–580 Ma, i.e., an HT deformation > 35My older than the emplacement of the Ibituruna quartz-syenite. Conclusions from the structural and the geochronological studies are therefore conflicting. A possible explanation arises from ⁴⁰Ar–³⁹Ar thermochronology. We have dated amphiboles from the quartz-syenite, and amphiboles and biotites from the country-rock. Together with the ages of monazites and zircons in the country-rock, ⁴⁰Ar–³⁹Ar mineral ages suggest a very low cooling rate: < 3 °C/My between 570 and ~ 500 Ma and ~ 5 °C/My between 500 and 460 Ma. Assuming a protracted regional deformation consistent over tens of My, under such stable thermal conditions the fabric and microstructure of deformed rocks may remain almost unchanged even if they underwent and recorded strain pulses separated by long periods of time. This may be a characteristic of slow cooling “hot orogens” that rocks deformed at significantly different periods during the orogeny, but under roughly unchanged temperature conditions, may display almost indiscernible microstructure and fabric.     

The structure and timing of lateral escape during the Scandian Orogeny: A combined strain and geochronological investigation in Finnmark, Arctic Norwegian Caledonides

Determining the timing, duration and mechanism of tectonic events within an orogenic cycle, such as ocean subduction, continent–continent collision or gravitational collapse, is challenging, especially in ancient orogenic belts. Variations in the tectonic transport direction, however, can be used as a guide to these stages of orogeny. While thrust sheets within the Caledonian allochthon in north Norway were emplaced broadly eastwards perpendicular to the trend of the orogen, many features indicate material transport in other orientations. One dominant feature of the Magerøy Nappe, sitting above and infolded with the Kalak Nappe Complex, is the development of a strong N–S lineation orthogonal to the main transport direction. Strain measurements, in part determined by a new method, are used, in the context of the regional structural data to identify the critical stage in orogeny when compressional forces are balanced by orogen-parallel lateral escape. Quantitative 3-D strain estimation in the Magerøy Nappe indicates prolate deformation with c. 50% horizontal shortening parallel to the thrusting direction (E–W) and c. 200% extension along the orogenic strike (N–S) with c. 30% vertical shortening. Temporal constraint on this fabric is provided by Ar–Ar isotopic analysis of undeformed white mica in cross-cutting granitic pegmatites. These data show that prolate deformation occurred before the white mica cooling age of 416 ± 4 Ma, while the previously determined depositional age of the Hellefjord Schist indicates that it occurred after 438 ± 4 Ma. A granitic pegmatite that intruded the Hellefjord Schist after an initial deformation phase but during or prior to a later deformation, has been dated at 431 ± 2 Ma by U–Pb zircon. A previous lower age constraint on this deformation of 428 ± 5 Ma is given by metamorphic zircon overgrowths on fractured grains. These results constrain the continental collision between Baltica and Laurentia in Finnmark to the interval c. 431–428 Ma. Placed in a regional context, these results indicate that lateral escape was orthogonal to the thrusting direction and occurred during the continent–continent collision stage in the Scandian Orogeny before gravitationally driven collapse.     

Late Paleozoic–Early Triassic magmatism on the western margin of Gondwana: Collahuasi area, Northern Chile

The basement in the ‘Altiplano’ high plateau of the Andes of northern Chile mostly consists of late Paleozoic to Early Triassic felsic igneous rocks (Collahuasi Group) that were emplaced and extruded along the western margin of the Gondwana supercontinent. This igneous suite crops out in the Collahuasi area and forms the backbone of most of the high Andes from latitude 20° to 22°S. Rocks of the Collahuasi Group and correlative formations form an extensive belt of volcanic and subvolcanic rocks throughout the main Andes of Chile, the Frontal Cordillera of Argentina (Choiyoi Group or Choiyoi Granite-Rhyolite Province), and the Eastern Cordillera of Peru.Thirteen new SHRIMP U–Pb zircon ages from the Collahuasi area document a bimodal timing for magmatism, with a dominant peak at about 300 Ma and a less significant one at 244 Ma. Copper–Mo porphyry mineralization is related to the younger igneous event.Initial Hf isotopic ratios for the ~ 300 Ma zircons range from about − 2 to + 6 indicating that the magmas incorporated components with a significant crustal residence time. The 244 Ma magmas were derived from a less enriched source, with the initial Hf values ranging from + 2 to + 6, suggestive of a mixture with a more depleted component. Limited whole rock ¹⁴⁴Nd/¹⁴³Nd and ⁸⁷Sr/⁸⁶Sr isotopic ratios further support the likelihood that the Collahuasi Group magmatism incorporated significant older crustal components, or at least a mixture of crustal sources with more and less evolved isotopic signatures.     

Petrology and CHIME geochronology of Pan-African high K and Sr/Y granitoids in the Nkambe area, Cameroon

The Central African Belt in the Nkambe area, northwestern Cameroon represents a collisional zone between the Saharan metacraton and the Congo craton during the Pan-African orogeny, and exposes a variety of granitoids including foliated and massive biotite monzogranites in syn- and post-kinematic settings. Foliated and massive biotite monzogranites have almost identical high-K calc-alkaline compositions, with 73–67 wt.% SiO₂, 17–13 wt.% Al₂O₃, 2.1–0.9 wt.% CaO, 4.4–2.7 wt.% Na₂O and 6.3–4.4 wt.% K₂O. High concentrations of Rb (264–96 ppm), Sr (976–117 ppm), Ba (3680–490 ppm) and Zr (494–99 ppm), with low concentrations of Y (mostly< 20 ppm with a range 54–6) and Nb (up to 24 ppm) suggest that the monzogranites intruded in collisional and post-collisional settings. The Sr/Y ratio ranges from 25 to 89. K, Rb and Ba resided in a single major phase such as K-feldspar in the source. Garnet was present in the source and remained as restite at the site of magma generation. This high K₂O and Sr/Y granitic magma was generated by partial melting of a granitic protolith under high-pressure and H₂O undersaturated conditions where garnet coexists with K-feldspar, albitic plagioclase. CHIME (chemical Th–U-total Pb isochron method) dating of zircon yields ages of 569 ± 12–558 ± 24 Ma for the foliated biotite monzogranite and 533 ± 12–524 ± 28 Ma for the massive biotite monzogranite indicating that the collision forming the Central African Belt continued in to Ediacaran (ca 560 Ma).     

Brittle–ductile–brittle deformation during cooling of tonalite (Adamello, Southern Italian Alps)

Late- to post-magmatic deformation in slightly diachronous contiguous intrusions of the north-western Adamello batholith (Southern Alps, Italy) is recorded as, from oldest to youngest: (i) joints, (ii) solid-state ductile shear zones, (iii) faults associated with epidote-K-feldspar veins and (iv) zeolite veins and faults. Structures (ii) to (iv) are localized on the pervasive precursory network of joints (i), which developed during the earliest stages of pluton cooling. High temperature ( 500 °C), ductile overprinting of joints produced lineations, defined by aligned biotite and hornblende, on the joint surfaces and highly localized mylonites. The main phase of faulting, producing cataclasites and pseudotachylytes, occurred at  250 °C and was associated with extensive fluid infiltration. Cataclasites and pseudotachylytes are clustered along different E–W-striking dextral strike-slip fault zones correlated with the activity of the Tonale fault, a major tectonic structure that bounds the Adamello batholith to the north. Ductile deformation and cataclastic/veining episodes occurred at P = 0.25–0.3 GPa during rapid cooling of the batholith to the ambient temperatures ( 250 °C) that preceded the exhumation of the batholith. Timing of the sequence of deformation can be constrained by ³⁹Ar–⁴⁰Ar ages of  30 Ma on pseudotachylytes and various existing mineral ages. In the whole composite Adamello batholith, multiple magma pulses were intruded over the time span 42–30 Ma and each intrusive body shows the same ductile-to-brittle structural sequence localized on the early joint sets. This deformation sequence of the Adamello might be typical of intrusions undergoing cooling at depths close to the brittle–ductile transition.     

The Paleoproterozoic North Hebei Orogen: North China craton's collisional suture with the Columbia supercontinent

Understanding the geologic history and position of the North China craton in the Paleoproterozoic Columbia supercontinent has proven elusive. Paleoproterozoic orogenic episodes (2.00–1.85 Ga) are temporally associated with ultimate stabilization of the North China craton (NCC), followed by the development of extensive craton-wide rift systems at 1.85–1.80 Ga. The age difference between the sedimentary cover and the metamorphic basement is up to 500–700 Ma, suggesting that uplift and doming of cratonic basement occurred in the latest Paleoproterozoic. Mafic dike swarms (1.80–1.77 Ga) and anorogenic magmatism (1.80–1.70 Ga) record the extensional breakup and dispersal of the North China craton during this stage. The late Paleoproterozoic tectonic framework and geological events documented provide important constraints for reconstruction of the NCC within the Late Paleoproterozoic supercontinent of Columbia.An east-west striking thousand kilometer long belt of khondalites (granulite facies metapelites) stretches along the northern margin of the North China craton, on the cratonward side of the Northern Hebei orogenic belt. This granulite belt includes Mg–Al (sapphirine bearing) granulites that reached ultrahigh-temperature “peak” metamorphic conditions of  1000 °C at 10 kbars at 1927 ± 11 Ma. Following peak ultrahigh-temperature conditions, the rocks underwent initial isobaric cooling and subsequent isothermal decompression, and these trajectories are interpreted to be part of an overall anti-clockwise P-T evolution indicating that the northern margin of the craton experienced continental collision at 1.93–1.92 Ga. The position of the khondalite belt south of the Northern Hebei orogenic belt makes it analogous to Tibet, a continental collision-related plateau characterized by double crustal thicknesses and granulite facies metamorphism at depth. We suggest that the tectonic evolution of the NCC during this period was closely related to the assembly and break-up of the Columbia supercontinent, and that the NCC was adjacent to the Baltic and Amazonian cratons in the period 2.00–1.70 Ga. Craton-wide extension occurred within 100–150 Ma of collision along the northern margin of the craton at 1.93–1.92 Ga. It is concluded that mantle upwellings are chiefly responsible for the breakup of the NCC from the Paleoproterozoic supercontinent.     

The Early Triassic Indosinian orogeny in Vietnam (Truong Son Belt and Kontum Massif); implications for the geodynamic evolution of Indochina

New structural field data at various scale and ⁴⁰Ar–³⁹Ar geochronological results, from the basement rocks in the Truong Son belt and Kontum Massif of Vietnam, confirm that ductile deformation and high-temperature metamorphism were caused by the Early Triassic event of the Indosinian Orogeny in the range of 250–240 Ma. A compilation of isotopic data obtained in other countries along the Sibumasu–Indochina boundary broadly indicates same interval of ages. This tectonothermal event is interpreted as the result of a synchronous oblique collision of Indochina with both Sibumasu and South China, inducing dextral and sinistral shearing along E–W to NW–SE and N–S fault zones, respectively. The collision along Song Ma follows the northwards subduction of Indochina beneath South China and the subsequent development of the Song Da zone which in turn was affected by the Late Triassic Indosinian phase of shortening. Within the Indochina plate, internal collisions occurred coevally in the Early Triassic, as along the Poko suture, at the western border of the Kontum Massif.     

Ar/Ar thermochronology of the Kampa Dome, southern Tibet: Implications for tectonic evolution of the North Himalayan gneiss domes

Structural and thermochronological studies of the Kampa Dome provide constraints on timing and mechanisms of gneiss dome formation in southern Tibet. The core of Kampa Dome contains the Kampa Granite, a Cambrian orthogneiss that was deformed under high temperature (sub-solidus) conditions during Himalayan orogenesis. The Kampa Granite is intruded by syn-tectonic leucogranite dikes and sills of probable Oligocene to Miocene age. Overlying Paleozoic to Mesozoic metasedimentary rocks decrease in peak metamorphic grade from kyanite + staurolite grade at the base of the sequence to unmetamorphosed at the top. The Kampa Shear Zone traverses the Kampa Granite — metasediment contact and contains evidence for high-temperature to low-temperature ductile deformation and brittle faulting. The shear zone is interpreted to represent an exhumed portion of the South Tibetan Detachment System. Biotite and muscovite ⁴⁰Ar/³⁹Ar thermochronology from the metasedimentary sequence yields disturbed spectra with 14.22 ± 0.18 to 15.54 ± 0.39 Ma cooling ages and concordant spectra with 14.64 ± 0.15 to 14.68 ± 0.07 Ma cooling ages. Petrographic investigations suggest disturbed samples are associated with excess argon, intracrystalline deformation, mineral and fluid inclusions and/or chloritization that led to variations in argon systematics. We conclude that the entire metasedimentary sequence cooled rapidly through mica closure temperatures at  14.6 Ma. The Kampa Granite yields the youngest biotite ⁴⁰Ar/³⁹Ar ages of  13.7 Ma immediately below the granite–metasediment contact. We suggest that this age variation reflects either varying mica closure temperatures, re-heating of the Kampa Granite biotites above closure temperatures between 14.6 Ma and 13.7 Ma, or juxtaposition of rocks with different thermal histories. Our data do not corroborate the “inverse” mica cooling gradient observed in adjacent North Himalayan gneiss domes. Instead, we infer that mica cooling occurred in response to exhumation and conduction related to top-to-north normal faulting in the overlying sequence, top-to-south thrusting at depth, and coeval surface denudation.     

Contrasted tectonic styles for the Paleoproterozoic evolution of the North China Craton. Evidence for a 2.1 Ga thermal and tectonic event in the Fuping Massif

Structural analysis along with ⁴⁰Ar–³⁹Ar and U–Pb datings in the Fuping massif provide new insight into the evolution of the eastern part of the Trans-North China Belt (North China Craton), from 2.7 Ga to 1.8 Ga. D1 is responsible for the development of a dome-and-basin structure coeval with crustal melting giving rise to migmatite and Nanying gneissic granites at 2.1 Ga. This dome-and-basin architecture resulted from the interference between a N–S compression of a weak ductile crust and gravity-driven vertical flow, in a high thermal regime. The next events involved flat lying ductile thrusting (D2) and normal faulting (D3) dated at around 1880 Ma and 1830 Ma, respectively. The D2 and D3 events belong to the Trans-North China Orogeny that results in the final amalgamation of the North China Craton. The D1 deformation is considered as evidence for an earlier orogen developed around 2.1 Ga prior to the Trans-North China Orogeny. The change in the deformation style between the 2.1 Ga and 1.8 Ga could be viewed as a consequence of the cooling of the continental crust in the North China Craton.     

华熊地块马超营断裂走滑特征及演化

对华熊地块南部的马超营断裂带的几何样式、组成特征及其变形特点等研究结果表明,马超营断裂带经历了韧性变形和脆性变形期。韧性变形分布于该断裂带的南侧,并发生了绿片岩相的动力变质作用,其中的S-C组构特征所指示的运动方向在其南北两侧,分别为向南和向北逆冲,呈现正花状特点,反映了该断裂带具有走滑逆冲性质的断裂。韧性变形主要发生于前印支期。燕山期,全面陆-陆碰撞期间其主要表现为脆性变形特征。脆性变形主要发育于其北侧,北东向的康山-七里坪断裂、红庄-陶村断裂是其次一级的派生断裂。通过对北东向断裂运动方向和前人的成果分析,以及这些构造的平面分布样式对比认为该断裂为一条左行走滑特征的断裂带。在此基础上,结合区域动力学背景,进而讨论了它的演化特征。     

Cratonic reactivation and orogeny: An example from the northern margin of the North China Craton

Reactivation of cratonic basement involves a number of processes including extension, compression, and/or lithospheric delamination. The northern margin of the North China Craton (NCC), adjacent to the Inner Mongolian Orogenic Belt, was reactivated in the Late Paleozoic to Early Mesozoic. During this period, the northern margin of the NCC underwent magmatism, N–S compression, regional exhumation, and uplift, including the formation of E–W-trending thick-skinned and thin-skinned south-verging folds and south-verging ductile shear zones. zircon U–Pb SHRIMP ages for mylonite protoliths in shear zones which show ages of 310–290 Ma (mid Carboniferous–Early Permian), constraining the earliest possible age of deformation. Muscovite within carbonate and quartz–feldspar–muscovite mylonites from the Kangbao–Weichang and Fengning–Longhua shear zones defines a stretching lineation and gives ⁴⁰Ar/³⁹Ar ages of 270–250 Ma, 250–230 Ma, 230–210 Ma, and 210–190 Ma. Deformation developed progressively from north to south between the Late Paleozoic and Triassic. Exhumation of lower crustal gneisses, high-pressure granulites, and granites occurred at the cratonic margin during post-ductile shearing (~ 220–210 Ma). An undeformed Early Jurassic (190–180 Ma) conglomerate overlies the deformed rocks and provides an upper age limit for reactivation and orogenesis. Deformation was induced by convergence between the southern Mongolia and North China cratonic blocks, and the location of this convergent belt controlled later deformation in the Yanshan Tectonic Province. This province formed as older E–W-trending Archean–Proterozoic sequences were reactivated along the northern margin of the NCC. This reactivation has features typical of cratonic basement reactivation: compression, crustal thickening, remelting of the mid to lower crust, and subsequent orogenesis adjacent to the orogenic belt.     

He–Ar and Nd–Sr isotopic compositions of late Pleistocene felsic plutonic back arc basin rocks from Ulleungdo volcanic island, South Korea: Implications for the genesis of young plutonic rocks in a back arc basin

We report analyses of noble gases and Nd–Sr isotopes in mineral separates and whole rocks of late Pleistocene (< 0.2 Ma) monzonites from Ulleungdo, South Korea, a volcanic island within the back arc basin of the Japan island arc. A Rb–Sr mineral isochron age for the monzonites is 0.12 ± 0.01 Ma. K–Ar biotite ages from the same samples gave relatively concordant ages of 0.19 ± 0.01and 0.22 ± 0.01 Ma. ⁴⁰Ar/³⁹Ar yields a similar age of 0.29 ± 0.09 Ma. Geochemical characteristics of the felsic plutonic rocks, which are silica oversaturated alkali felsic rocks (av., 12.5 wt% in K₂O + Na₂O), are similar to those of 30 alkali volcanics from Ulleungdo in terms of concentrations of major, trace and REE elements. The initial Nd–Sr isotopic ratios of the monzonites (⁸⁷Sr/⁸⁶Sr = 0.70454–0.71264, ¹⁴³Nd/¹⁴⁴Nd = 0.512528–0.512577) are comparable with those of the alkali volcanics (⁸⁷Sr/⁸⁶Sr = 0.70466–0.70892, ¹⁴³Nd/¹⁴⁴Nd = 0.512521–0.512615) erupted in Stage 3 of Ulleungdo volcanism (0.24–0.47 Ma). The high initial ⁸⁷Sr/⁸⁶Sr values of the monzonites imply that seawater and crustally contaminated pre-existing trachytes may have been melted or assimilated during differentiation of the alkali basaltic magma.A mantle helium component (³He/⁴He ratio of up to 6.5 RA) associated with excess argon was found in the monzonites. Feldspar and biotite have preferentially lost helium during slow cooling at depth and/or during their transportation to the surface in a hot host magma. The source magma noble gas isotopic features are well preserved in fluid inclusions in hornblende, and indicate that the magma may be directly derived from subcontinental lithospheric mantle metasomatized by an ancient subduction process, or may have formed as a mixture of MORB-like mantle and crustal components. The radiometric ages, geochemical and Nd–Sr isotopic signatures of the Ulleungdo monzonites as well as the presence of mantle-derived helium and argon, suggests that these felsic plutonic rocks evolved from alkali basaltic magma that formed by partial melting of subcontinental lithospheric mantle beneath the back arc basin located along the active continental margin of the southeastern part of the Eurasian plate.     

Permian plate margin volcanism and tuffs in adjacent basins of west Gondwana: Age constraints and common characteristics

Increasing evidence of Permian volcanic activity along the South American portion of the Gondwana proto-Pacific margin has directed attention to its potential presence in the stratigraphic record of adjacent basins. In recent years, tuffaceous horizons have been identified in late Early Permian–through Middle Permian (280–260 Ma) sections of the Paraná Basin (Brazil, Paraguay, and Uruguay). Farther south and closer to the magmatic tract developed along the continental margin, in the San Rafael and Sauce Grande basins of Argentina, tuffs are present in the Early to Middle Permian section. This tuff-rich interval can be correlated with the appearance of widespread tuffs in the Karoo Basin. Although magmatic activity along the proto-Pacific plate margin was continuous during the Late Paleozoic, Choiyoi silicic volcanism along the Andean Cordillera and its equivalent in Patagonia peaked between the late Early Permian and Middle Permian, when extensive rhyolitic ignimbrites and consanguineous airborne tuffaceous material erupted in the northern Patagonian region. The San Rafael orogenic phase (SROP) interrupted sedimentation along the southwestern segment of the Gondwana margin (i.e., Frontal Cordillera, San Rafael Basin), induced cratonward thrusting (i.e., Ventana and Cape foldbelts), and triggered accelerated subsidence in the adjacent basins (Sauce Grande and Karoo) located inboard of the deformation front. This accelerated subsidence favored the preservation of tuffaceous horizons in the syntectonic successions. The age constraints and similarities in composition between the volcanics along the continental margin and the tuffaceous horizons in the San Rafael, Sauce Grande, Paraná, and Karoo basins strongly suggest a genetic linkage between the two episodes. Radiometric ages from tuffs in the San Rafael, Paraná, and Karoo basins indicate an intensely tuffaceous interval between 280 and 260 Ma.     

Phanerozoic upper crustal tectono-thermal development of basement rocks from central Madagascar: An integrated fission-track and structural study

An integrated study of fission-track (FT) dating and structural geology revealed a complex tectono-thermal history preserved in basement rocks of central Madagascar since the amalgamation of Gondwana at the end of the Cambrian. A detailed study of five domains argues for several cooling steps with associated brittle deformations during the separation of Madagascar.Titanite and apatite FT ages range between 483 Ma and 266 Ma and between 460 Ma and 79 Ma, respectively. The titanite FT data indicate that the final cooling after the latest metamorphic overprint was terminated at c. 500 Ma (FC1). A 150 Myr phase of minor cooling (SC2), possibly related to a phase of tectonic quiescence and isostatic compensation, followed episode FC1. Between the Carboniferous and Early Jurassic, when an intracontinental rift developed between East Africa and Madagascar, complex brittle deformation effected the western margin of Madagascar and led to differential cooling of small basement blocks (FC3–FC5). During this period, ductile structural trends were reactivated at the western basement margin and in the centre of the island.A Late Cretaceous thermal event (T1) affected apatite FT data of samples from western–central and the eastern margin of Madagascar. These ages are related to the Madagascar–India/Seychelles break-up, whereby the thermal penetration along the eastern coast was restricted to the west by the Angavo shear zone (AGSZ). The Cretaceous evolution of the eastern margin was associated with minor erosion and was triggered by vertical displacements along brittle structures.     

Geochronological framework and Pb, Sr isotope geochemistry of the Qingchengzi Pb–Zn–Ag–Au orefield, Northeastern China

The Qingchengzi orefield in northeastern China, is a concentration of several Pb–Zn, Ag, and Au ore deposits. A combination of geochronological and Pb, Sr isotopic investigations was conducted. Zircon SHRIMP U–Pb ages of 225.3 ± 1.8 Ma and 184.5 ± 1.6 Ma were obtained for the Xinling and Yaojiagou granites, respectively. By step-dissolution Rb–Sr dating, ages of 221 ± 12 Ma and 138.7 ± 4.1 Ma were obtained for the sphalerite of the Zhenzigou Zn–Pb deposit and pyrargyrite of the Ag ore in the Gaojiabaozi Ag deposit, respectively. Pb isotopic ratios of the Ag ore at Gaojiabaozi (²⁰⁶Pb/²⁰⁴Pb = 18.38 to 18.53) are higher than those of the Pb–Zn ores (²⁰⁶Pb/²⁰⁴Pb = 17.66 to 17.96; Chen et al. [Chen, J.F., Yu, G., Xue, C.J., Qian, H., He, J.F., Xing, Z., Zhang, X., 2005. Pb isotope geochemistry of lead, zinc, gold and silver deposit clustered region, Liaodong rift zone, northeastern China. Science in China Series D 48, 467–476.]). Triassic granites show low Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb = 17.12 to 17.41, ²⁰⁷Pb/²⁰⁴Pb = 15.47 to 15.54, ²⁰⁸Pb/²⁰⁴Pb = 37.51 to 37.89) and metamorphic rocks of the Liaohe Group have high ratios (²⁰⁶Pb/²⁰⁴Pb = 18.20 to 24.28 and 18.32 to 20.06, ²⁰⁷Pb/²⁰⁴Pb = 15.69 to 16.44 and 15.66 to 15.98, ²⁰⁸Pb/²⁰⁴Pb = 37.29 to 38.61 and 38.69 to 40.00 for the marble of the Dashiqiao Formation and schist of the Gaixian Formation, respectively).Magmatic activities at Qingchengzi and in adjacent regions took place in three stages, and each contained several magmatic pulses: ca. 220 to 225 Ma and 211 to 216 Ma in the Triassic; 179 to 185 Ma, 163 to 168 Ma, 155 Ma and 149 Ma in the Jurassic, as well as ca. 140 to 130 Ma in the Early Cretaceous. The Triassic magmatism was part of the Triassic magmatic belt along the northern margin of the North China Craton produced in a post-collisional extensional setting, and granites in it formed by crustal melting induced by mantle magma. The Jurassic and Early Cretaceous magmatism was related to the lithospheric delamination in eastern China. The Triassic is the most important metallogenic stage at Qingchengzi. The Pb–Zn deposits, the Pb–Zn–Ag ore at Gaojiabaozi, and the gold deposits were all formed in this stage. They are temporally and spatially associated with the Triassic magmatic activity. Mineralization is very weak in the Jurassic. Ag ore at Gaojiabaozi was formed in the Early Cretaceous, which is suggested by the young Rb–Sr isochron age, field relations, and significantly different Pb isotopic ratios between the Pb–Zn–Ag and Ag ores. Pb isotopic compositions of the Pb–Zn ores suggest binary mixing for the source of the deposits. The magmatic end-member is the Triassic granites and the other metamorphic rocks of the Liaohe Group. Slightly different proportions of the two end-members, or an involvement of materials from hidden Cretaceous granites with slightly different Pb isotopic ratios, is postulated to interpret the difference of Pb isotopic compositions between the Pb–Zn–(Ag) and Ag ores. Sr isotopic ratios support this conclusion. At the western part of the Qingchengzi orefield, hydrothermal fluid driven by the heat provided by the now exposed Triassic granites deposited ore-forming materials in the low and middle horizons of the marbles of the Dashiqiao Formation near the intrusions to form mesothermal Zn–Pb deposits. In the eastern part, hydrothermal fluids associated with deep, hidden Triassic intrusions moved upward along a regional fault over a long distance and then deposited the ore-forming materials to form epithermal Au and Pb–Zn–Ag ores. Young magmatic activities are all represented by dykes across the entire orefield, suggesting that the corresponding main intrusion bodies are situated in the deep part of the crust. Among these, only intrusions with age of ca. 140 Ma might have released sufficient amounts of fluid to be responsible for the formation of the Ag ore at Gaojiabaozi.Our age results support previous conclusions that sphalerite can provide a reliable Rb–Sr age as long as the fluid inclusion phase is effectively separated from the “sulfide” phase. Our work suggests that the separation can be achieved by a step-resolution technique. Moreover, we suggest that pyrargyrite is a promising mineral for Rb–Sr isochron dating.     

Biotite and muscovite <Superscript>40</Superscript>Ar–<Superscript>39</Superscript>Ar geochronological constraints on the post-Svecofennian tectonothermal evolution,Forsmark site,central Sweden

In order to characterize the post-Svecofennian tectonothermal evolution of the Fennoscandian Shield, ⁴⁰Ar–³⁹Ar biotite and some ⁴⁰Ar–³⁹Ar muscovite geochronological data are reported from a total of 30 surface outcrop and 1,000 m long borehole samples at Forsmark, central Sweden. The 13 surface samples were collected across 3 branches of a major WNW to NW trending system of deformation zones, whereas the boreholes were drilled within a tectonic lens, in between two of these zones. The ⁴⁰Ar–³⁹Ar biotite ages indicate that the present erosion surface, in central Sweden, cooled below c. 300°C at 1.73–1.66 Ga, and that the rocks could have accommodated strain in a brittle manner between 1.8 and 1.7 Ga. The variation in surface ages is suggested to be due to fault along the large WNW to NW trending deformation zones, following the establishment of a sub-Cambrian peneplain. The minor variation of ages within a single crustal block may be due to disturbance along ENE to NNE trending fracture zones. Possible cooling paths, derived from ⁴⁰Ar–³⁹Ar hornblende, muscovite and biotite ages, were calculated for the time interval from 1.80 to 1.67 Ga, when the area cooled from c. 500 to 300°C. Cooling rates of 1.9–4°C/m.y. have been attained. Between 1.68 and 1.64 Ga, uplift rates of c. 22 m/m.y. were calculated from borehole ⁴⁰Ar–³⁹Ar biotite data. Tectonothermal histories, inferred from the combined cooling and uplift rates, are related to simple cooling after the Svecofennian orogeny, to crustal movement in response to far-field effects of c. 1.7 Ga orogenic activities further to the west or to a combination of these possibilities.     

Porphyry Cu–Au and associated polymetallic Fe–Cu–Au deposits in the Beiya Area, western Yunnan Province, south China

The Alkaline porphyries in the Beiya area are located east of the Jinshajiang suture, as part of a Cenozoic alkali-rich porphyry belt in western Yunnan. The main rock types include quartz-albite porphyry, quartz-K-feldspar porphyry and biotite–K-feldspar porphyry. These porphyries are characterised by high alkalinity [(K₂O + Na₂O)% > 10%], high silica (SiO₂% > 65%), high Sr (> 400 ppm) and ⁸⁷Sr/⁸⁶Sr (> 0.706)] ratio and were intruded at 65.5 Ma, between 25.5 to 32.5 Ma, and about 3.8 Ma, respectively. There are five main types of mineral deposits in the Beiya area: (1) porphyry Cu–Au deposits, (2) magmatic Fe–Au deposits, (3) sedimentary polymetallic deposits, (4) polymetallic skarn deposits, and (5) palaeoplacers associated with karsts. The porphyry Cu–Au and polymetallic skarn deposits are associated with quartz–albite porphyry bodies. The Fe–Au and polymetallic sedimentary deposits are part of an ore-forming system that produced considerable Au in the Beiya area, and are characterised by low concentrations of La, Ti, and Co, and high concentrations of Y, Yb, and Sc.The Cenozoic porphyries in western Yunnan display increased alkalinity away from the Triassic Jinshajiang suture. Distribution of both the porphyries and sedimentary deposits in the Beiya area are interpreted to be related to partial melting in a disjointed region between upper mantle lithosphere of the Yangtze Plate and Gondwana continent, and lie within a shear zone between buried Palaeo-Tethyan oceanic lithosphere and upper mantle lithosphere, caused by the subduction and collision of India and Asia.     

Structural reworking and heat transfer related to the late-Panafrican Angavo shear zone of Madagascar

The basement of central Madagascar displays two contrasted structural patterns. The first one (D1) is characterized by north-striking foliations that are gently dipping to the west and carry W- to WSW-plunging lineations, whereas the second one (D2) is characterized by steeper foliations that are striking to the NNE and lineations that are either subhorizontal or gently plunging to the SSW. The younger pattern is related to late-Panafrican tectonics along the major Angavo shear zone that is about 1000 km in length and 40 km in width with apparently little offset. Deformation in the Angavo zone induced interference folding on both sides. The D2 event is characterized by low pressures (ca 400 MPa) and high temperatures (up to 790 °C) responsible for prograde granulite facies conditions, that resulted from heat transfer due to magma and fluid advection in the Angavo shear zone. The D2 event is pinned at 550 ± 11 Ma by a new monazite age from a reoriented Andringitrean granite near Ankaramena. A new suite of amphibole and biotite Ar–Ar geochronological data enables to retrace the thermochronogical evolution inside and outside the Angavo shear zone. Combined with new structural results from the western interference zone, these ages yield a better understanding of the late-Panafrican history of central Madagascar. No diachronism is observed along the strike of the Angavo shear zone. Conversely, amphibole and especially biotite ages decrease from West to East, i.e. towards the shear zone. These new ages range from 511 to 469 Ma. A 1-D conductive model constrains the thermal effect in relation with the Angavo shear zone to be restricted to a lateral distance of ca 60 km (in map view) for a maximum heating duration of 20 Myr. This is in agreement with the Ar–Ar data and with the width of the observed interference zone. Following this episode of deformation and heat transfer, the estimated cooling rates of the Angavo shear zone range from to 15 to 6 °C/Myr, respectively before and after 515 Ma. A post-collision intracontinental setting is suggested for the Angavo shear zone, which is regarded as a remote effect of the Kuunga Orogeny between India and Antarctica.     

Geochemistry and geochronology of the Neoproterozoic Pan-African Transcaucasian Massif (Republic of Georgia) and implications for island arc evolution of the late Precambrian Arabian–Nubian Shield

The Transcaucasian Massif (TCM) in the Republic of Georgia includes Neoproterozoic–Early Cambrian ophiolites and magmatic arc assemblages that are reminiscent of the coeval island arc terranes in the Arabian–Nubian Shield (ANS) and provides essential evidence for Pan-African crustal evolution in Western Gondwana. The metabasite–plagiogneiss–migmatite association in the Oldest Basement Unit (OBU) of TCM represents a Neoproterozoic oceanic lithosphere intruded by gabbro–diorite–quartz diorite plutons of the Gray Granite Basement Complex (GGBC) that constitute the plutonic foundation of an island arc terrane. The Tectonic Mélange Zone (TMZ) within the Middle-Late Carboniferous Microcline Granite Basement Complex includes thrust sheets composed of various lithologies derived from this arc-ophiolite assemblage. The serpentinized peridotites in the OBU and the TMZ have geochemical features and primary spinel composition (0.35) typical of mid-ocean ridge (MOR)-type, cpx-bearing spinel harzburgites. The metabasic rocks from these two tectonic units are characterized by low-K, moderate-to high-Ti, olivine-hypersthene-normative, tholeiitic basalts representing N-MORB to transitional to E-MORB series. The analyzed peridotites and volcanic rocks display a typical melt-residua genetic relationship of MOR-type oceanic lithosphere. The whole-rock Sm–Nd isotopic data from these metabasic rocks define a regression line corresponding to a maximum age limit of 804 ± 100 Ma and εNd_int = 7.37 ± 0.55. Mafic to intermediate plutonic rocks of GGBC show tholeiitic to calc-alkaline evolutionary trends with LILE and LREE enrichment patterns, Y and HREE depletion, and moderately negative anomalies of Ta, Nb, and Ti, characteristic of suprasubduction zone originated magmas. U–Pb zircon dates, Rb–Sr whole-rock isochron, and Sm–Nd mineral isochron ages of these plutonic rocks range between  750 Ma and 540 Ma, constraining the timing of island arc construction as the Neoproterozoic–Early Cambrian. The Nd and Sr isotopic ratios and the model and emplacement ages of massive quartz diorites in GGBC suggest that pre-Pan African continental crust was involved in the evolution of the island arc terrane. This in turn indicates that the ANS may not be made entirely of juvenile continental crust of Neoproterozoic age. Following its separation from ANS in the Early Paleozoic, TCM underwent a period of extensive crustal growth during 330–280 Ma through the emplacement of microcline granite plutons as part of a magmatic arc system above a Paleo-Tethyan subduction zone dipping beneath the southern margin of Eurasia. TCM and other peri-Gondwanan terranes exposed in a series of basement culminations within the Alpine orogenic belt provide essential information on the Pan-African history of Gondwana and the rift-drift stages of the tectonic evolution of Paleo-Tethys as a back-arc basin between Gondwana and Eurasia.     

40Ar/39Ar geochronological constraints on the formation of the Dayingezhuang gold deposit: New implications for timing and duration of hydrothermal activity in the Jiaodong gold province,China

China's largest gold resource is located in the highly endowed northwestern part of the Jiaodong gold province. Most gold deposits in this area are associated with the NE- to NNE-trending shear zones on the margins of the 130–126 Ma Guojialing granite. These deposits collectively formed at ca. 120 ± 5 Ma during rapid uplift of the granite. The Dayingezhuang deposit is a large (> 120 t Au) orogenic gold deposit in the same area, but located along the eastern margin of the Late Jurassic Linglong Metamorphic Core Complex. New ⁴⁰Ar/³⁹Ar geochronology on hydrothermal sericite and muscovite from the Dayingezhuang deposit indicate the gold event is related to evolution of the core complex at 130 ± 4 Ma and is the earliest important gold event that is well-documented in the province. The Dayingezhuang deposit occurs along the Linglong detachment fault, which defines the eastern edge of the ca. 160–150 Ma Linglong granite–granodiorite massif. The anatectic rocks of the massif were rapidly uplifted, at rates of at least 1 km/m.y. from depths of 25–30 km, to form the metamorphic core complex. The detachment fault, with Precambrian metamorphic basement rocks in the hangingwall and the Linglong granitoids and migmatites in the footwall, is characterized by early mylonitization and a local brittle overprinting in the footwall. Gold is associated with quartz–sericite–pyrite–K-feldspar altered footwall cataclasites at the southernmost area of the brittle deformation along the detachment fault. Our results indicate that there were two successive, yet distinct gold-forming tectonic episodes in northwestern Jiaodong. One event first reactivated the detachment fault along the edge of the Linglong massif between 134 and 126 Ma, and then a second reactivated the shears along the margins of the Guojialing granite. Both events may relate to a component of northwest compression after a middle Early Cretaceous shift from regional NW–SE extension to a NE–SW extensional regime.