Declining Temporal Effectiveness of Carbon Sequestration: Implications for Compliance with the United National Framework Convention on Climate Change

Carbon sequestration is increasingly being promoted as a potential response to the risks of unrestrained emissions of CO₂, either in place of or as a complement to reductions in the use of fossil fuels. However, the potential role of carbon sequestration as an (at-least partial) substitute for reductions in fossil fuel use can be properly evaluated only in the context of a long-term acceptable limit (or range of limits) to the increase in atmospheric CO₂ concentration, taking into account the response of the entire carbon cycle to artificial sequestration. Under highly stringent emission-reduction scenarios for non-CO₂ greenhouse gases, 450 ppmv CO₂ is the equivalent, in terms of radiative forcing of climate,to a doubling of the pre-industrial concentration of CO₂. It is argued in this paper that compliance with the United Nations Framework Convention on Climate Change (henceforth, the UNFCCC) implies that atmospheric CO₂ concentration should be limited, or quickly returned to, a concentration somewhere below 450 ppmv. A quasi-one-dimensional coupled climate-carbon cycle model is used to assess the response of the carbon cycle to idealized carbon sequestration scenarios. The impact on atmospheric CO₂ concentration of sequestering a given amount of CO₂ that would otherwise be emitted to the atmosphere, either in deep geological formations or in the deep ocean, rapidly decreases over time. This occurs as a result of a reduction in the rate of absorption of atmospheric CO₂ by the natural carbon sinks (the terrestrial biosphere and oceans) in response to the slower buildup of atmospheric CO₂ resulting from carbon sequestration. For 100 years of continuous carbon sequestration, the sequestration fraction (defined as the reduction in atmospheric CO₂ divided by the cumulative sequestration) decreases to 14% 1000 years after the beginning of sequestration in geological formations with no leakage, and to 6% 1000 years after the beginning of sequestration in the deep oceans. The difference (8% of cumulative sequestration) is due to an eflux from the ocean to the atmosphere of some of the carbon injected into the deep ocean.The coupled climate-carbon cycle model is also used to assess the amount of sequestration needed to limit or return the atmospheric CO₂ concentration to 350–400 ppmv after phasing out all use of fossil fuels by no later than 2100. Under such circumstances, sequestration of 1–2 Gt C/yr by the latter part of this century could limit the peak CO₂ concentration to 420–460 ppmv, depending on how rapidly use of fossilfuels is terminated and the strength of positive climate-carbon cycle feedbacks. To draw down the atmospheric CO₂ concentration requires creating negative emissions through sequestration of CO₂ released as a byproduct of the production of gaseous fuels from biomass primary energy. Even if fossil fuel emissions fall to zero by 2100, it will be difficult to create a large enough negative emission using biomass energy to return atmospheric CO₂ to 350 ppmv within 100 years of its peak. However, building up soil carbon could help in returning CO₂ to 350 ppmv within 100 years of its peak. In any case, a 100-year period of climate corresponding to the equivalent of a doubled-CO₂ concentration would occur before temperatures decreased. Nevertheless, returning the atmospheric CO₂concentration to 350 ppmv would reduce longterm sea level rise due to thermal expansion and might be sufficient to prevent the irreversible total melting of the Greenland ice sheet, collapse of the West Antarctic ice sheet, and abrupt changes in ocean circulation that might otherwise occur given a prolonged doubled-CO₂ climate. Recovery of coral reef ecosystems, if not already driven to extinction, could begin.     

Global transport and inter-reservoir exchange of carbon dioxide with particular reference to stable isotopic distributions

A two-dimensional model of global atmospheric transport is used to relate estimated air-to-surface exchanges of carbon dioxide (CO₂) to spatial and temporal variations of atmospheric CO₂ concentrations and isotopic composition. The atmospheric model coupled with models of the biosphere and mixed layer of the ocean describes the gross features of the global carbon cycle. In particular this paper considers the change in isotopic composition due to interreservoir exchanges and thus the potential application and measurement requirements of new isotopic observational programs.A comparison is made between the model-generated CO₂ concentration variation and those observed on secular, interannual and seasonal time scales and spatially through the depth of the troposphere and meridionally from pole-to-pole.The relationship between isotopic and concentration variation on a seasonal time-scale is discussed and it is shown how this can be used to quantitatively estimate relative contributions of biospheric and oceanic CO₂ exchange. Further, it is shown that the interhemispheric gradient of concentration and isotopic ratio results primarily from the redistribution of fossil fuel CO₂. Both isotopic and concentration data indicate that tropical deforestation contributes less than 2 Gt yr^-1 of carbon to the atmosphere.The study suggests that changes in the rate of change of the ratio of ¹³C to ¹²C in the atmosphere of less than 0.03 yr^-1 might be expected if net exchanges with the biosphere are the cause of interannual variations of CO₂ concentrations.     

Oceanic transport and storage of carbon emissions

Using a global carbon cycle model (GLOCO) that considers seven terrestrial biomes, surface and deep ocean layers based on the HILDA model and a single mixed atmosphere, we analyzed the response of atmospheric CO₂ concentration and oceanic DIC and DOC depth profiles to additions of carbon to the atmosphere and ocean. The rate of transport of carbon to the deepest oceanic layers is rather insensitive to the atmosphereic-ocean surface gas exchange coefficient over a wide range, hence discrepancies between researchers on the precise global average value of this coefficient do not significantly affect predictions of atmospheric response to anthropogenic inputs. Upwelling velocity, on the other hand, amplifies oceanic response by increasing primary production in the upper ocean layers, resulting in a larger flux into DOC and sediments and increased carbon storage; experiments to reduce the uncertainty in this parameter would be valuable.The location of the carbon addition, whether it is released in the atmosphere or in the middle of the oceanic thermocline, has a significant impact on the maximum atmospheric CO₂ concentration (pCO₂) subsequently reached, suggesting that oceanic burial of a significant fraction of carbon emissions (e.g. via clathrate hydrides) may be an important management option for limiting pCO₂ buildup. Our analysis indicates that the effectiveness of ocean burial decreases asymptotically below about 1000 m depth. With a constant emissions scenario (at 1990 levels), pCO₂ at year 2100 is reduced from 501 ppmv considering all emissions go to the atmosphere, to 422 ppmv with ocean burial at a depth of 1000 m of 50% of the fossil fuel emissions. An alternative scenario looks at stabilizing pCO₂ at 450 ppmv; with no ocean burial of fossil fuel emissions, the rate of emissions has to be cut drastically after the year 2010, whereas oceanic burial of 2 GtC/yr allows for a smoother transition to alternative energy sources.     

Ocean dynamics determine the response of oceanic CO2 uptake to climate change

The increase of atmospheric CO₂ concentrations due to anthropogenic activities is substantially damped by the ocean, whose CO₂ uptake is determined by the state of the ocean, which in turn is influenced by climate change. We investigate the mechanisms of the ocean’s carbon uptake within the feedback loop of atmospheric CO₂ concentration, climate change and atmosphere/ocean CO₂ flux. We evaluate two transient simulations from 1860 until 2100, performed with a version of the Max Planck Institute Earth System Model (MPI-ESM) with the carbon cycle included. In both experiments observed anthropogenic CO₂ emissions were prescribed until 2000, followed by the emissions according to the IPCC Scenario A2. In one simulation the radiative forcing of changing atmospheric CO₂ is taken into account (coupled), in the other it is suppressed (uncoupled). In both simulations, the oceanic carbon uptake increases from 1 GT C/year in 1960 to 4.5 GT C/year in 2070. Afterwards, this trend weakens in the coupled simulation, leading to a reduced uptake rate of 10% in 2100 compared to the uncoupled simulation. This includes a partial offset due to higher atmospheric CO₂ concentrations in the coupled simulation owing to reduced carbon uptake by the terrestrial biosphere. The difference of the oceanic carbon uptake between both simulations is primarily due to partial pressure difference and secondary to solubility changes. These contributions are widely offset by changes of gas transfer velocity due to sea ice melting and wind changes. The major differences appear in the Southern Ocean (?45%) and in the North Atlantic (?30%), related to reduced vertical mixing and North Atlantic meridional overturning circulation, respectively. In the polar areas, sea ice melting induces additional CO₂ uptake (+20%).     

The millennial atmospheric lifetime of anthropogenic CO<Subscript>2</Subscript>

The notion is pervasive in the climate science community and in the public at large that the climate impacts of fossil fuel CO₂ release will only persist for a few centuries. This conclusion has no basis in theory or models of the atmosphere/ocean carbon cycle, which we review here. The largest fraction of the CO₂ recovery will take place on time scales of centuries, as CO₂ invades the ocean, but a significant fraction of the fossil fuel CO₂, ranging in published models in the literature from 20–60%, remains airborne for a thousand years or longer. Ultimate recovery takes place on time scales of hundreds of thousands of years, a geologic longevity typically associated in public perceptions with nuclear waste. The glacial/interglacial climate cycles demonstrate that ice sheets and sea level respond dramatically to millennial-timescale changes in climate forcing. There are also potential positive feedbacks in the carbon cycle, including methane hydrates in the ocean, and peat frozen in permafrost, that are most sensitive to the long tail of the fossil fuel CO₂ in the atmosphere.     

European CO2 fluxes from atmospheric inversions using regional and global transport models

Approximately half of human-induced carbon dioxide (CO₂) emissions are taken up by the land and ocean, and the rest stays in the atmosphere, increasing the global concentration and acting as a major greenhouse-gas (GHG) climate-forcing element. Although GHG mitigation is now in the political arena, the exact spatial distribution of the land sink is not well known. In this paper, an estimation of mean European net ecosystem exchange (NEE) carbon fluxes for the period 1998–2001 is performed with three mesoscale and two global transport models, based on the integration of atmospheric CO₂ measurements into the same Bayesian synthesis inverse approach. A special focus is given to sub-continental regions of Europe making use of newly available CO₂ concentration measurements in this region. Inverse flux estimates from the five transport models are compared with independent flux estimates from four ecosystem models. All inversions detect a strong annual carbon sink in the southwestern part of Europe and a source in the northeastern part. Such a dipole, although robust with respect to the network of stations used, remains uncertain and still to be confirmed with independent estimates. Comparison of the seasonal variations of the inversion-based net land biosphere fluxes (NEP) with the NEP predicted by the ecosystem models indicates a shift of the maximum uptake period, from June in the ecosystem models to July in the inversions. This study thus improves on the understanding of the carbon cycle at sub-continental scales over Europe, demonstrating that the methodology for understanding regional carbon cycle is advancing, which increases its relevance in terms of issues related to regional mitigation policies.     

Geoengineering climate by stratospheric sulfur injections: Earth system vulnerability to technological failure

We use a coupled climate–carbon cycle model of intermediate complexity to investigate scenarios of stratospheric sulfur injections as a measure to compensate for CO₂-induced global warming. The baseline scenario includes the burning of 5,000 GtC of fossil fuels. A full compensation of CO₂-induced warming requires a load of about 13 MtS in the stratosphere at the peak of atmospheric CO₂ concentration. Keeping global warming below 2°C reduces this load to 9 MtS. Compensation of CO₂ forcing by stratospheric aerosols leads to a global reduction in precipitation, warmer winters in the high northern latitudes and cooler summers over northern hemisphere landmasses. The average surface ocean pH decreases by 0.7, reducing the calcifying ability of marine organisms. Because of the millennial persistence of the fossil fuel CO₂ in the atmosphere, high levels of stratospheric aerosol loading would have to continue for thousands of years until CO₂ was removed from the atmosphere. A termination of stratospheric aerosol loading results in abrupt global warming of up to 5°C within several decades, a vulnerability of the Earth system to technological failure.     

The role of the individual air-sea flux components in CO2-induced changes of the ocean's circulation and climate

 In this study we investigate the role of heat, freshwater and momentum fluxes in changing the oceanic climate and thermohaline circulation as a consequence of increasing atmospheric CO₂ concentration. Two baseline integrations with a fully coupled ocean atmosphere general circulation model with either fixed or increasing atmospheric CO₂ concentrations have been performed. In a set of sensitivity experiments either freshwater (precipitation, evaporation and runoff from the continents) and/or momentum fluxes were no longer simulated, but prescribed according to one of the fully coupled baseline experiments. This approach gives a direct estimate of the contribution from the individual flux components. The direct effect of surface warming and the associated feedbacks in ocean circulation are the dominant processes in weakening the Atlantic thermohaline circulation in our model. The relative contribution of momentum and freshwater fluxes to the total response turned out to be less than 25%, each. Changes in atmospheric water vapour transport lead to enhanced freshwater input into middle and high latitudes, which weakens the overturning. A stronger export of freshwater from the Atlantic drainage basin to the Indian and Pacific ocean, on the other hand, intensifies the Atlantic overturning circulation. In total the modified freshwater fluxes slightly weaken the Atlantic thermohaline circulation. The contribution of the modified momentum fluxes has a similar magnitude, but enhances the formation of North Atlantic deep water. Salinity anomalies in the Atlantic as a consequence of greenhouse warming stem in almost equal parts from changes in net freshwater fluxes and from changes in ocean circulation caused by the surface warming due to atmospheric heat fluxes. Important effects of the momentum fluxes are a poleward shift of the front between Northern Hemisphere subtropical and subpolar gyres and a southward shift in the position of the Antarctic circumpolar current, with a clear signal in sea level. Received: 3 May 1999 / Accepted: 11 December 1999     

The importance of three centuries of land-use change for the global and regional terrestrial carbon cycle

Large amounts of carbon (C) have been released into the atmosphere over the past centuries. Less than half of this C stays in the atmosphere. The remainder is taken up by the oceans and terrestrial ecosystems. Where does the C come from and where and when does this uptake occur? We address these questions by providing new estimates of regional land-use emissions and natural carbon fluxes for the 1700–2000 period, simultaneously considering multiple anthropogenic (e.g. land and energy demand) and biochemical factors in a geographically explicit manner. The observed historical atmospheric CO₂ concentration profile for the 1700 to 2000 period has been reproduced well. The terrestrial natural biosphere has been a major carbon sink, due to changes in climate, atmospheric CO₂, nitrogen and management. Due to land-use change large amounts of carbon have been emitted into the atmosphere. The net effect was an emission of 35 Pg C into the atmosphere for the 1700 to 2000 period. If land use had remained constant at its distribution in 1700, then the terrestrial C uptake would have increased by 142 Pg C. This overall difference of including or excluding land-use changes (i.e. 177 Pg C) comes to more than half of the historical fossil-fuel related emissions of 308 Pg C. Historically, global land-use emissions were predominantly caused by the expansion of cropland and pasture, while wood harvesting (for timber and fuel wood) only played a minor role. These findings are robust even when changing some of the important drivers like the extent of historical land-use changes. Under varying assumptions, land-use emissions over the past three centuries could have increased up to 20%, but remained significantly lower than from other sources. Combining the regional land-use and natural C fluxes, North America and Europe were net C sources before 1900, but turned into sinks during the twentieth century. Nowadays, these fluxes are a magnitude smaller than energy- and industry-related emissions. Tropical regions were C neutral prior to 1950, but then accelerated deforestation turned these regions into major C sources. The energy- and industry-related emissions are currently increasing in many tropical regions, but are still less than the land-use emissions. Based on the presented relevance of the land-use and natural fluxes for the historical C cycle and the significance of fossil-fuel emissions nowadays, there is a need for an integrated approach for energy, nature and land use in evaluating possible climate change mitigation policies.     

Historical and future anthropogenic emission pathways derived from coupled climate�Ccarbon cycle simulations

Using a coupled climate?Ccarbon cycle model, fossil fuel carbon dioxide (CO₂) emissions are derived through a reverse approach of prescribing atmospheric CO₂ concentrations according to observations and future projections, respectively. In the second half of the twentieth century, the implied fossil fuel emissions, and also the carbon uptake by land and ocean, are within the range of observational estimates. Larger discrepancies exist in the earlier period (1860?C1960), with small fossil fuel emissions and uncertain emissions from anthropogenic land cover change. In the IPCC SRES A1B scenario, the simulated fossil fuel emissions more than double until 2050 (17 GtC/year) and then decrease to 12 GtC/year by 2100. In addition to A1B, an aggressive mitigation scenario was employed, developed within the European ENSEMBLES project, that peaks at 530 ppm CO₂(equiv) around 2050 and then decreases to approach 450 ppm during the twenty-second century. Consistent with the prescribed pathway of atmospheric CO₂ in E1, the implied fossil fuel emissions increase from currently 8 GtC/year to about 10 by 2015 and decrease thereafter. In the 2050s (2090s) the emissions decrease to 3.4 (0.5) GtC/year, respectively. As in previous studies, our model simulates a positive climate?Ccarbon cycle feedback which tends to reduce the implied emissions by roughly 1 GtC/year per degree global warming. Further, our results suggest that the 450 ppm stabilization scenario may not be sufficient to fulfill the European Union climate policy goal of limiting the global temperature increase to a maximum of 2°C compared to pre-industrial levels.     

The effect of optimization and the nesting domain on carbon flux analyses in Asia using a carbon tracking system based on the ensemble Kalman filter

To estimate the surface carbon flux in Asia and investigate the effect of the nesting domain on carbon flux analyses in Asia, two experiments with different nesting domains were conducted using the CarbonTracker developed by the National Oceanic and Atmospheric Administration. CarbonTracker is an inverse modeling system that uses an ensemble Kalman filter (EnKF) to estimate surface carbon fluxes from surface CO₂ observations. One experiment was conducted with a nesting domain centered in Asia and the other with a nesting domain centered in North America. Both experiments analyzed the surface carbon fluxes in Asia from 2001 to 2006. The results showed that prior surface carbon fluxes were underestimated in Asia compared with the optimized fluxes. The optimized biosphere fluxes of the two experiments exhibited roughly similar spatial patterns but different magnitudes. Weekly cumulative optimized fluxes showed more diverse patterns than the prior fluxes, indicating that more detailed flux analyses were conducted during the optimization. The nesting domain in Asia produced a detailed estimate of the surface carbon fluxes in Asia and exhibited better agreement with the CO₂ observations. Finally, the simulated background atmospheric CO₂ concentrations in the experiment with the nesting domain in Asia were more consistent with the observed CO₂ concentrations than those in the experiment with the nesting domain in North America. The results of this study suggest that surface carbon fluxes in Asia can be estimated more accurately using an EnKF when the nesting domain is centered in Asian regions.     

CO<Subscript>2</Subscript> dynamics on the shelf of the East Siberian Sea

Expedition data obtained in the coastal-shelf zone of the East Siberian Sea in September 2003, 2004, and 2008 are generalized. Studies of carbonate system in water and CO₂ fluxes between ocean and atmosphere in this region confirmed that it was reasonable to divide the water area studied into two biogeochemical provinces and that the ecosystem of its coastal part is mainly of a heterotrophic nature. In different years, the extent of water supersaturation in carbon dioxide in the East Siberian Sea and the area of the CO₂ release significantly changed. Geographic localization of the atmosphere action centers over the Arctic and their intensity were main determining factors; that told both on the formation of a basic character of the atmospheric and hydrological processes and on the dynamics of the CO₂ exchange between water and air.     

Managing atmospheric CO2

A coupled carbon cycle-climate model is used to compute global atmospheric CO₂ and temperature variation that would result from several future CO₂ emission scenarios. The model includes temperature and CO₂ feedbacks on the terrestrial biosphere, and temperature feedback on the oceanic uptake of CO₂. The scenarios used include cases in which fossil fuel CO₂ emissions are held constant at the 1986 value or increase by 1% yr^–1 until either 2000 or 2020, followed by a gradual transition to a rate of decrease of 1 or 2% yr^–1. The climatic effect of increases in non-CO₂ trace gases is included, and scenarios are considered in which these gases increase until 2075 or are stabilized once CO₂ emission reductions begin. Low and high deforestation scenarios are also considered. In all cases, results are computed for equilibrium climatic sensitivities to CO₂ doubling of 2.0 and 4.0 °C.Peak atmospheric CO₂ concentrations of 400–500 ppmv and global mean warming after 1980 of 0.6–3.2 °C occur, with maximum rates of global mean warming of 0.2–0.3 °C decade^–1. The peak CO₂ concentrations in these scenarios are significantly below that commonly regarded as unavoidable; further sensitivity analyses suggest that limiting atmospheric CO₂ to as little as 400 ppmv is a credible option.Two factors in the model are important in limiting atmospheric CO₂: (1) the airborne fraction falls rapidly once emissions begin to decrease, so that total emissions (fossil fuel + land use-induced) need initially fall to only about half their present value in order to stabilize atmospheric CO₂, and (2) changes in rates of deforestation have an immediate and proportional effect on gross emissions from the biosphere, whereas the CO₂ sink due to regrowth of forests responds more slowly, so that decreases in the rate of deforestation have a disproportionately large effect on net emission.If fossil fuel emissions were to decrease at 1–2% yr^–1 beginning early in the next century, emissions could decrease to the rate of CO₂ uptake by the predominantly oceanic sink within 50–100 yrs. Simulation results suggest that if subsequent emission reductions were tied to the rate of CO₂ uptake by natural CO₂ sinks, these reductions could proceed more slowly than initially while preventing further CO₂ increases, since the natural CO₂ sink strength decreases on time scales of one to several centuries. The model used here does not account for the possible effect on atmospheric CO₂ concentration of possible changes in oceanic circulation. Based on past rates of atmospheric CO₂ variation determined from polar ice cores, it appears that the largest plausible perturbation in ocean-air CO₂ flux due to changes of oceanic circulation is substantially smaller than the permitted fossil fuel CO₂ emissions under the above strategy, so tieing fossil fuel emissions to the total sink strength could provide adequate flexibility for responding to unexpected changes in oceanic CO₂ uptake caused by climatic warming-induced changes of oceanic circulation.     

Transient simulation of the last glacial inception. Part II: sensitivity and feedback analysis

The sensitivity of the last glacial-inception (around 115 kyr BP, 115,000 years before present) to different feedback mechanisms has been analysed by using the Earth system model of intermediate complexity CLIMBER-2. CLIMBER-2 includes dynamic modules of the atmosphere, ocean, terrestrial biosphere and inland ice, the last of which was added recently by utilising the three-dimensonal polythermal ice-sheet model SICOPOLIS. We performed a set of transient experiments starting at the middle of the Eemiam interglacial and ran the model for 26,000 years with time-dependent orbital forcing and observed changes in atmospheric CO₂ concentration (CO₂ forcing). The role of vegetation and ocean feedback, CO₂ forcing, mineral dust, thermohaline circulation and orbital insolation were closely investigated. In our model, glacial inception, as a bifurcation in the climate system, appears in nearly all sensitivity runs including a run with constant atmospheric CO₂ concentration of 280 ppmv, a typical interglacial value, and simulations with prescribed present-day sea-surface temperatures or vegetation cover—although the rate of the growth of ice-sheets growth is smaller than in the case of the fully interactive model. Only if we run the fully interactive model with constant present-day insolation and apply present-day CO₂ forcing does no glacial inception appear at all. This implies that, within our model, the orbital forcing alone is sufficient to trigger the interglacial–glacial transition, while vegetation, ocean and atmospheric CO₂ concentration only provide additional, although important, positive feedbacks. In addition, we found that possible reorganisations of the thermohaline circulation influence the distribution of inland ice.     

How long is coal's future?

Nearly all scenarios for future U.S. energy supply systems show heavy dependence on coal. The magnitude depends on assumptions as to reliance on nuclear fission, degree of electrification, and rate of GNP growth, and ranges from 700 million tons to 2300 million tons per year. However, potential climate change resulting from increasing atmospheric carbon dioxide concentrations may prevent coal from playing a major role. The carbon in the carbon dioxide produced from fossil fuels each year is about 1/10 the net primary production by terrestrial plants, but the fossil fuel production has been growing exponentially at 4.3% per year. Observed atmospheric CO₂ concentrations have increased from 315 ppm in 1958 to 330 ppm in 1974 - in 1900, before much fossil fuel was burned, it was about 290–295 ppm. Slightly over one-half the CO₂ released from fossil fuels is accounted for by the increase observed in the atmosphere; at present growth rates the quantities are doubling every 15–18 years. Atmospheric models suggest a global warming of about 2 K if the concentration were to rise to two times its pre-1900 value - enough to change the global climate in major (but largely unknown) ways. With the current rate of increase in fossil fuel use, the atmospheric concentration should reach these levels by about 2030. A shift to coal as a replacement for oil and gas gives more carbon dioxide per unit of energy; thus if energy growth continues with a concurrent shift toward coal, high concentrations can be reached somewhat earlier. Even projections with very heavy reliance on non-fossil energy (Neihaus) after 2000 show atmospheric carbon dioxide concentrations reaching 475 ppm.First presented to the symposium, Coal Science and our National Expectations, Annual Meeting of the American Association for the Advancement of Science, Boston, Massachusetts, February 20, 1976.     

The effects of carbon cycle model error in calculating future atmospheric carbon dioxide levels

Empirical investigations have indicated that projections of future atmospheric carbon dioxide concentrations of a quality quite adequate for practical questions regarding the environmental threat of anthropogenic carbon dioxide emissions and its relationship to energy use policy could be made with the simple assumption that a constant fraction of these emissions would be retained by the atmosphere. By analysis of the structural behavior of equations describing the transfer of carbon and carbon dioxide between their several reservoirs we have been able to demonstrate that this characteristic can be explained to result from approximately linear behavior and exponentially growing carbon dioxide release rates, combined with fitting of carbon cycle model parameters to the last twenty years of observed atmospheric carbon dioxide growth. These conclusions are independent of the details of carbon cycle model structure for projections up to 100 years into the future as long as the growth in atmospheric carbon dioxide release rates is sufficiently high, of the order of 1.5% per annum or more, as referenced to p re-industrial (steady state) conditions. At low rates of growth, when the longer response times of the carbon cycling system become important, for most energy use projections the resultant CO₂ induced climate changes are small and the uncertainties in predicted atmospheric carbon dioxide level are thus not important. A possible exception to this condition occurs for scenarios of future fossil fuel use rates designed to avoid atmospheric CO₂ levels exceeding a chosen threshold. In this instance details of carbon cycle model structure could significantly affect conclusions that might be drawn concerning future energy use policies; however, it is possible that such a result stems from inappropriate specification of a criterion for an environmental threat, rather than from inherent inadequacy of current carbon cycle models. Recent carbon cycle model developments postulate transfer processes of carbon into the deep ocean, large carbon storage reservoir at rates much higher than in the models we have analysed. If the existence of such mechanisms is confirmed, and they are found to be sufficiently rapid and large, some of our conclusions regarding the use of the constant fractional retention assumption may have to be modified. Currently at the Gas Research Institute, 8600 West Bryn, Mawr Ave., Chicago, IL 60631, U.S.A.     

Organic carbon accumulation rates in the Holocene and glacial Arabian Sea: implications for O2-consumption in the deep-sea and atmospheric CO2 variations

Variations in the deep-sea carbon reservoir have been invoked to explain the observed atmospheric carbon dioxide (CO₂) changes during glacial-interglacial cycles. In order to distinguish between the quantity of organic matter remineralized in the deep-sea and that permanently removed into sediments, we compared the bulk- and organic carbon-accumulation rates in Holocene and glacial sediments deposited below the oxygen minimum layer with total- and organic carbon fluxes to the deep Arabian Sea from continuous sediment trap deployments. This comparison shows that the mass of organic carbon remineralized at the sediment water interface is mainly a function of the bulk sediment flux. The oxygen consumed by the organic carbon remineralization is of the order of the observed oxygen deficiency of the modern deep Arabian Sea water. We use the evidence from the northern Indian Ocean to speculate on the possible effect of abiogenic mineral flux on the removal of organic carbon from upper layers of the world ocean to the deep-sea. We assume that if the bulk accumulation rate (not primary productivity) influences the flux of organic carbon (that is fixed from the atmosphere by marine organisms), then mineral matter flux will exert a significant control over atmospheric CO₂ contents. Model calculations incorporating transient changes in global bulk flux, caused by natural or anthropogenic changes, show that significant proportions of the observed changes in atmospheric CO₂ contents can be explained by this mechanism.This paper was presented at Clima Locarno 90, the International Conference on Past and Present Climate Dynamics: Reconstruction of Rates of Change, held in Locarno, Switzerland, September 24 to 28, 1991, organized by the Swiss National Climate Program — ProClim, with support from the Swiss Academy of Sciences. Guest editor for these papers is Dr. K. Kelts Offprint requests to: F Sirocko     

Millennial timescale carbon cycle and climate change in an efficient Earth system model

A new Earth system model, GENIE-1, is presented which comprises a 3-D frictional geostrophic ocean, phosphate-restoring marine biogeochemistry, dynamic and thermodynamic sea-ice, land surface physics and carbon cycling, and a seasonal 2-D energy-moisture balance atmosphere. Three sets of model climate parameters are used to explore the robustness of the results and for traceability to earlier work. The model versions have climate sensitivity of 2.8–3.3°C and predict atmospheric CO₂ close to present observations. Six idealized total fossil fuel CO₂ emissions scenarios are used to explore a range of 1,100–15,000 GtC total emissions and the effect of rate of emissions. Atmospheric CO₂ approaches equilibrium in year 3000 at 420–5,660 ppmv, giving 1.5–12.5°C global warming. The ocean is a robust carbon sink of up to 6.5 GtC year⁻¹. Under ‘business as usual’, the land becomes a carbon source around year 2100 which peaks at up to 2.5 GtC year⁻¹. Soil carbon is lost globally, boreal vegetation generally increases, whilst under extreme forcing, dieback of some tropical and sub-tropical vegetation occurs. Average ocean surface pH drops by up to 1.15 units. A Greenland ice sheet melt threshold of 2.6°C local warming is only briefly exceeded if total emissions are limited to 1,100 GtC, whilst 15,000 GtC emissions cause complete Greenland melt by year 3000, contributing 7 m to sea level rise. Total sea-level rise, including thermal expansion, is 0.4–10 m in year 3000 and ongoing. The Atlantic meridional overturning circulation shuts down in two out of three model versions, but only under extreme emissions including exotic fossil fuel resources.     

Role of the ocean in controlling atmospheric CO2 concentration in the course of global glaciations

Responses of ocean circulation and ocean carbon cycle in the course of a global glaciation from the present Earth conditions are investigated by using a coupled climate-biogeochemical model. We investigate steady states of the climate system under colder conditions induced by a reduction of solar constant from the present condition. A globally ice-covered solution is obtained under the solar constant of 92.2% of the present value. We found that because almost all of sea water reaches the frozen point, the ocean stratification is maintained not by temperature but by salinity just before the global glaciation (at the solar constant of 92.3%). It is demonstrated that the ocean circulation is driven not by the surface cooling but by the surface freshwater forcing associated with formation and melting of sea ice. As a result, the deep ocean is ventilated exclusively by deep water formation in southern high latitudes where sea ice production takes place much more massively than northern high latitudes. We also found that atmospheric CO₂ concentration decreases through the ocean carbon cycle. This reduction is explained primarily by an increase of solubility of CO₂ due to a decrease of sea surface temperature, whereas the export production weakens by 30% just before the global glaciation. In order to investigate the conditions for the atmospheric CO₂ reduction to cause global glaciations, we also conduct a series of simulations in which the total amount of carbon in the atmosphere?Cocean system is reduced from the present condition. Under the present solar constant, the results show that the global glaciation takes place when the total carbon decreases to be 70% of the present-day value. Just before the glaciation, weathering rate becomes very small (almost 10% of the present value) and the organic carbon burial declines due to weakened biological productivity. Therefore, outgoing carbon flux from the atmosphere?Cocean system significantly decreases. This suggests the atmosphere?Cocean system has strong negative feedback loops against decline of the total carbon content. The results obtained here imply that some processes outside the atmosphere?Cocean feedback loops may be required to cause global glaciations.     

Wind-driven changes in Southern Ocean residual circulation, ocean carbon reservoirs and atmospheric CO2

The effect of idealized wind-driven circulation changes in the Southern Ocean on atmospheric CO₂ and the ocean carbon inventory is investigated using a suite of coarse-resolution, global coupled ocean circulation and biogeochemistry experiments with parameterized eddy activity and only modest changes in surface buoyancy forcing, each experiment integrated for 5,000 years. A positive correlation is obtained between the meridional overturning or residual circulation in the Southern Ocean and atmospheric CO₂: stronger or northward-shifted westerly winds in the Southern Hemisphere result in increased residual circulation, greater upwelling of carbon-rich deep waters and oceanic outgassing, which increases atmospheric pCO₂ by ～20 μatm; weaker or southward-shifted winds lead to the opposing result. The ocean carbon inventory in our model varies through contrasting changes in the saturated, disequilibrium and biogenic (soft-tissue and carbonate) reservoirs, each varying by O(10–100) PgC, all of which contribute to the net anomaly in atmospheric CO₂. Increased residual overturning deepens the global pycnocline, warming the upper ocean and decreasing the saturated carbon reservoir. Increased upwelling of carbon- and nutrient-rich deep waters and inefficient biological activity results in subduction of unutilized nutrients into the ocean interior, decreasing the biogenic carbon reservoir of intermediate and mode waters ventilating the Northern Hemisphere, and making the disequilibrium carbon reservoir more positive in the mode waters due to the reduced residence time at the surface. Wind-induced changes in the model carbon inventory are dominated by the response of the global pycnocline, although there is an additional abyssal response when the peak westerly winds change their latitude, altering their proximity to Drake Passage and changing the depth extent of the southward return flow of the overturning: a northward shift of the westerly winds isolates dense isopycnals, allowing biogenic carbon to accumulate in the deep ocean of the Southern Hemisphere, while a southward shift shoals dense isopycnals that outcrop in the Southern Ocean and reduces the biogenic carbon store in the deep ocean.