Nd and Sr isotopes in ultrapotassic volcanic rocks from the Leucite Hills,Wyoming

Nd and Sr isotopic compositions and Rb, Sr, Sm and Nd concentrations are reported for madupites, wyomingites and orendites from the Pleistocene volcanic field of the Leucite Hills, Wyoming. All Leucite Hills rocks have negative εNd signatures, indicating derivation or contribution from an old light rare earth element (LREE) enriched source. In this respect they are similar to all occurrences of high potassium magmas so far investigated. But Sr isotopic variations are comparatively small and ⁸⁷Sr/ ⁸⁶Sr ratios are unusually low for high-K magmas (0.7053–0.7061, one sample excluded). These values suggest that the light REE enrichment of the source was not accompanied by a strong increase in Rb/Sr. Wyomingites and orendites are isotopically indistinguishable which is consistent with chemical and petrographic evidence for their derivation from a common magma series depending on emplacement conditions. Basic to ultrabasic madupites and more silicic wyomingites/orendites are distinct in their Nd isotopic variations (madupites: εNd= ?10.5 to ?12.3; wyomingites/orendites: εNd= ?13.7 to ?17.0) despite similar Sm/Nd ratios and complete overlap in ⁸⁷Sr/⁸⁶Sr. Selective or bulk assimilation of crustal material is unlikely to have significantly affected the Nd and Sr isotopic compositions of the magmas. The measured isotopic ratios are considered to reflect source values. The distinct isotopic characteristics of madupite and wyomingite/orendite magmas preclude their derivation by fractional crystallization, from a common primary magma, by liquid immiscibility or by partial melting of a homogeneous source. Two isotopically distinct, LREE enriched and slightly heterogeneous sources are required. Heterogeneities were most pronounced between magma sources from each volcanic centre (butte or mesa). The relationship between the madupite and wyomingite/orendite sources and their evolution is discussed on the basis of two simple alternative sets of models:

1. a two-stage evolution model with an old enrichment event (a metasomatic event?) perhaps taking place during the stabilization of the Wyoming Craton 3.2 to 2.5 Gyr ago but not later than 1.2 Gyr ago or
2. a mixing model involving mixing between one endmember with εNd near zero and another end-member with a strong negative εNd signature.

     

The melting relationships of a madupite from the Leucite Hills,Wyoming, to 30 Kb

The water-undersaturated melting relationships of a mafic, peralkaline, potassic madupite (with about 3% H₂O as shown by chemical analysis) from the Leucite Hills, Wyoming, have been studied at pressures up to 30 kb. At low pressures (<5 kb) leucite is the dominant liquidus phase, but it is replaced at higher pressures by clinopyroxene plus olivine (<5–7 kb), clinopyroxene (7–12.5 kb), clinopyroxene plus minor spinel (12.5–17.5 kb), and clinopyroxene alone (17.5–> 30 kb). At all pressures there is a reaction relationship with falling temperature between melt, olivine and probably clinopyroxene to yield phlogopite. Apatite is stable within the melting interval to pressures above 25 kb. Electron microprobe analyses demonstrate that the clinopyroxene is diopsidic, with low aluminium and titanium contents. Pressure has relatively little effect on the composition of the pyroxene. Phlogopite is also aluminium-poor and has only a moderate titanium content. The experimental results indicate that madupite is not the partial melting product of hydrous lherzolite or garnet lherzolite in the upper mantle and it seems improbable that it is derived by melting of mantle peridotite with a mixed H₂O-CO₂ volatile component. Madupite could, however, be the partial melting product of mica-pyroxenite or mica-olivine-pyroxenite in the upper mantle. It is pointed out that the chemistry of some potassium-rich volcanics may have been affected by volatile transfer and other such processes during eruption and that experimental studies of material affected in this way have little bearing upon the genesis of potassic magmas. Finally, the experimental results enable constraints to be placed upon the P-T conditions of the formation of richterite-bearing mica nodules found in kimberlites and associated rocks. Maximum conditions are 25 kb and 1,100 ° C.     

The mineralogy and petrology of the volcanic rocks from the Leucite Hills,Wyoming

Examples of the three volcanic rock types, wyomingite, orendite and madupite from the Leucite Hills have been examined with the electron microprobe. The results show that leucite is non-stoichiometric as predicted byCross (1897), having an excess of potassium and silicon, and that the only feldspar found, a sanidine, contains up to 18 percent of the iron-feldspar molecule. The co-existing phlogopite, diopside and olivine together with the groundmass amphibole are all highly magnesian. Of the varied accessory minerals, priderite (K₂Ti₈O₁₆) and wadeite (K₄Zr₂Si₆O₁₈) have been identified and analyzed together with ubiquitous apatite and perovskite, both of which contain rare earths in abundance. Comparative mineralogical data has been obtained on a few representative specimens from West Australia and on the jumillite from Spain.The new rock analyses together with the existing data from the Leucite Hills show the rare but characteristic molecular excess of potassium over aluminium; this excess is considered to account for the ahsence of the iron-titanium oxides in the orendites and wyomingites, and of course for the unusual composition and species of the minerals. Exploratory melting experiments show that these potassic lavas have a comparable melting range to magnesian basalts, and a crustal origin is thereby considered precluded. There is no evidence that sialic contamination contributed notably to the composition of the oversaturated orendites and wyomingites, and their relationship by any process of crystal fractionation to the undersaturated madupite is obscure. The generation of madupite could be achieved by crystal fractionation at high pressure of a liquid derived by partial fusion of mantle material.     

Origin and Source Evolution of the Leucite Hills Lamproites: Evidence from Sr-Nd-Pb-O Isotopic Compositions

Whole-rock major and trace element and O, Sr, Nd and Pb isotopicdata are reported for 3·0–0·89 Ma lamproitesfrom the Leucite Hills, Wyoming, USA. The two main groups oflamproites, madupitic lamproites and phlogopite lamproites,are geochemically distinct and cannot be related to one anotherby either fractional crystallization or crustal contamination.It seems likely that the geochemical differences between thesetwo rock types are related to variations in source mineralogyand depth of partial melting. The high Mg-number and large ionlithophile element abundances and negative Nd values of thelamproites indicate a mantle source that has experienced stagesof both depletion and enrichment. The negative Nb, Ta and Tianomalies in mantle-normalized trace element diagrams and lowtime-integrated U/Pb, Rb/Sr and Sm/Nd ratios of both lamproitegroups and other Cenozoic igneous rocks from the Wyoming ArcheanProvince indicate an ancient metasomatic enrichment (>1·0Ga) of the mantle source associated with the subduction of carbonate-bearingsediments. Other chemical characteristics of the Leucite Hillslamproites, especially their high K₂O and volatile contents,are attributed to more recent metasomatism (<100 Ma) involvinginflux from upwelling mantle during back-arc extension or plumeactivity. KEY WORDS: isotopes; lamproites; metasomatism; Leucite Hills; Wyoming     

绿河油页岩中的开链醇化合物

研究了美国绿河盆地的23个未成熟的露头油页岩样品,其中 13个样品取自Laney组,为半温湿半干燥气候下沉积于较浅的封闭水体的盐湖中心,含有丰富的有机质;另外 10个样品取自LumanTongue组,为潮湿气候下沉积于近岸的水体开放的淡水环境,其有机质含量较低。所有样品均富含从C₁₁至C₂₀ 的同分异构体丰富的饱和类异戊二烯醇类化合物。此外还检出了一整套直链一元仲醇同系物,其碳数从 10至 33,而羟基可在任何理论上可能的碳位上。伯醇含量较低。研究结果表明,绿河油页岩中的有机质分别在沉积过程中和被抬升之后遭受了两次微生物降解。除伯醇的分布有生物来源特征外,其余的开链醇化合物是在绿河层系抬升至地表后微生物对其中烃类化合物降解的产物。文中将绿河油页岩有机质中异常高的氧指数归因于微生物降解,并探讨了其开链醇化合物的分布与物源、沉积环境及微生物降解程度的相关性。盐湖相Laney组的直链醇以低碳数组分为主,反映其有机质以菌藻为主的物源,与干燥的古气候相一致;淡水相LumanTongue组则以高碳数组分为主,有着明显优势的高等植物来源,与其潮湿的古气候相吻合。在沉积过程中,淡水相的LumanTongue组中的有机质遭受了比盐湖相的Laney组中的有机质更强的微生物降解,这意味着盐湖环境。     

Petrology of a 2.41 Ga remarkably fresh komatiitic basalt lava lake in Lion Hills,central Vetreny Belt,Baltic Shield

 In the central Vetreny Belt, southeastern Baltic Shield, an areally extensive 110 m deep lava lake is exposed consisting of remarkably fresh differentiated komatiitic basalt. During eruption, the liquid had a temperature of 1380–1400 °C and contained ∼15% MgO. The lava ponded in a large topographic depression soon after eruption. The differentiation of the lava lake was controlled by settling of transported olivine and chromite phenocrysts and caused the origin of prominent internal layering. The last portions of the trapped liquid crystallized at temperatures of 1250– 1070 °C. A Sm-Nd isochron of 2410±34 Ma for whole rock samples, olivine, augite and pigeonite separates from the lava lake provides a reliable estimate for the time of formation of the uppermost sequences in the Vetreny Belt. This age is in good agreement with the Sm-Nd and Pb-Pb isochron ages of 2449±35 and 2424±178 Ma for the volcanic rocks from the same stratigraphic level in the northwestern Vetreny Belt. Modeling of Nd-isotopes and major and trace elements shows that the komatiitic basalts at Lion Hills may have had a komatiite parent depleted in highly incompatible elements. It can be shown that this initial liquid was contaminated by 7–9% of Archaean upper crustal material from the adjacent Vodla and Belomorian Blocks en route to the surface thus acquiring the observed geochemical and isotope signatures including relative enrichment in Zr, Ba, and LREE, negative Nb- and Ti-anomalies and ɛNd(T) of −1. Received: 8 December 1995/Accepted: 26 March 1996     

A potassium-rich Alkalic Suite from the Deccan Traps,Rajpipla, India

The Rajpipla Alkalic Suite is the most potassium-enriched group of basaltic rocks so far described from the Deccan Traps. In the same area however early tholeiitic flows and late tholeiitic dykes show the potassium-poor nature characteristic of most Deccan Trap magmas. The rocks of the alkalic suite are highly porphyritic and their major element variation can be interpreted in terms of crystal fractionation dominated by clinopyroxene. Plagioclase, which is an important phenocryst phase, has fractionated only in relatively small amounts as a result of a lack of density contrast between it and the liquids. A dyke-like form for the magma chambers in which fractionation has taken place is postulated to account for the abundance of highly porphyritic types. The Rajpipla area is also notable as being one of the few Deccan localities where rhyolites are found.Abbreviations AB ankaramitic basalt - PB porphyritic basalt - PTB porphyritic trachybasalt - FPM feldsparphyric mugearite - M mugearite - TR trachyte - P. RHY potassic rhyolite - Th. B. tholeiitic basalt - Th. D. tholeiitic dolerite - Af alkali feldspar     

Control on the emplacement of the andesite lava dome of the Soufriere Hills volcano, Montserrat by degassing-induced crystallization

Lava solidification is controlled by two mechanisms: external cooling and gas exsolution, the latter inducing crystallization due to increasing liquidus temperature. The andesite lava dome of the Soufriere Hills Volcano, Montserrat, is an extrusion dominated by crystallization caused by gas exsolution where cooling is unimportant in controlling emplacement. In the magma chamber the magma has an estimated viscosity of 7 × 10⁶ Pa s. During ascent, gas exsolution caused the magma to extrude in a highly crystalline state, with only 5–15% residual melt, viscosities in the range 10¹³–10¹⁴ Pa s and mechanical strength > 1 MPa. Deformation can be heterogeneous with extrusion along shear zones. Rheological stiffening in the upper conduit also causes large overpressures, shallow seismicity, and cyclic patterns of dome extrusion. Gas-rich porphyritic andesites tend to be the least mobile kind of lava, because transition from magma into hot crystalline material was reached during ascent.     

Some clinopyroxenes from ultramafic inclusions in Dreiser Weiher,Eifel

Eight clinopyroxenes from wehrlites and clinopyroxenites and three clinopyroxenes of crystal lapilli in tuff of Dreiser Weiher in Eifel, Germany, have been separated and chemically analysed. One hornblende and two phlogopites from a wehrlite and clinopyroxenites have also been analysed. The rocks enclosing these inclusions are alkali basalts of basanite composition. The analysed clinopyroxenes contain considerable amounts of Al₂O₃ (3.87–10.84 wt%). The calculated Tschermak's component ranges from 5.9 to 18.4 mol per cent. All of the analysed clinopyroxenes are clearly different from chromian diopsides in lherzolite inclusions in basaltic rocks in Dreiser Weiher and other localities; the former has higher contents of total FeO, CaO and TiO₂ and lower contents of MgO and Cr₂O₃ than the latter. Two clinopyroxenes separated from apatite-bearing clinopyroxenites show high contents of Fe₂O₃ with about 2 per cent of Na₂O, indicating the presence of considerable amounts of acmite component in addition to Tschermak's component. The relative proportions of Al in the tetrahedral site and that in the octahedral site in the analysed clinopyroxenes are clearly different from those of the common igneous clinopyroxenes and eclogites, and similar to those of the clinopyroxenes from other inclusions in basaltic rocks and granulites. It is suggested that all the analysed clinopyroxenes and their host inclusions have crystallized from alkali basalt magmas in relatively deep levels of the continental crust.     

U–Pb ages of Neoarchean granitoids from the Black Hills, South Dakota, USA: implications for crustal evolution in the Archean Wyoming province

Zircons in basement rocks from the eastern Wyoming province (Black Hills, South Dakota, USA) have been analyzed by ion microprobe (SHRIMP) in order to determine precise ages of Archean tectonomagmatic events. In the northern Black Hills (NBH) near Nemo, Phanerozoic and Proterozoic (meta)sedimentary rocks are nonconformably underlain by Archean biotite–feldspar gneiss (BFG) and Little Elk gneissic granite (LEG), both of which intrude older schists. The Archean granitoid gneisses exhibit a pervasive NW–SE-trending fabric, whereas an earlier NE–SW-trending fabric occurs sporadically only in the BFG, which is intruded by the somewhat younger LEG. Zircon crystals obtained from the LEG and BFG exhibit double terminations, oscillatory zoning, and Th/U ratios of 0.6±0.3—thereby confirming a magmatic origin for both lithologies. In situ analysis of the most U–Pb concordant domains yields equivalent ²⁰⁷Pb/²⁰⁶Pb ages (upper intercept, U–Pb concordia) of 2559±6 and 2563±6 Ma (both ±2σ) for the LEG and BFG, respectively, which constrains a late Neoarchean age for sequential pulses of magmatism in the NBH. Unzoned (in BSE) patches of 2560 Ma zircon commonly truncate coeval zonation in the same crystals with no change in Th/U ratio, suggesting that deuteric, fluid-assisted recrystallization accompanied post-magmatic cooling. A xenocrystic core of magmatic zircon observed in one LEG zircon yields a concordant age of 2894±6 Ma (±2σ). This xenocryst represents the oldest crustal material reported thus far in the Black Hills. Whether this older zircon originated as unmelted residue of 2900 Ma crust that potentially underlies the Black Hills or as detritus derived from 2900 Ma crustal sources in the Wyoming province cannot be discerned. In the southern Black Hills (SBH), the peraluminous granite at Bear Mountain (BMG) of previously unknown age intrudes biotite–plagioclase schist. Zircon crystals from the BMG are highly metamict and altered, but locally preserve small domains suitable for in situ analysis. A U–Pb concordia upper intercept age of 2596±11 Ma (±2σ) obtained for zircon confirms both the late Neoarchean magmatic age of the BMG and a minimum age for the schist it intrudes. Taken together, these data indicate that the Neoarchean basement granitoids were emplaced at 2590–2600 Ma (SBH) and 2560 Ma (NBH), most likely in response to subduction associated with plate convergence (final assembly of supercontinent Kenorland?). In contrast, thin rims present on some LEG–BFG zircons exhibit strong U–Pb discordance, high common Pb, and low Th/U ratios—suggesting growth or modification under hydrothermal conditions, as previously suggested for similar zircons from SE Wyoming. The LEG–BFG zircon rims yield a nominal upper intercept date of 1940–2180 Ma, which may represent a composite of multiple rifting events known to have affected the Nemo area between 2480 and 1960 Ma. Together, these observations confirm the existence of a Paleoproterozoic rift margin along the easternmost Wyoming craton. Moreover, the 2480–1960 Ma time frame inferred for rifting in the Black Hills (Nemo area) corresponds closely to a 2450–2100 Ma time frame previously inferred for the fragmentation of supercontinent Kenorland.     

Metal and associated phases in Bishunpur,a highly unequilibrated ordinary chondrite

It appears that the highly unequilibrated Bishunpur ordinary chondrite preserves phase relations acquired during solar nebular processes to a relatively high degree; metamorphic temperatures may not have exceeded 300–350°C. The major categories of metal are: 3 kinds of metal in the metal matrix, three kinds in chondrule interiors and 2 kinds in chondrule rims. The fine-grained matrix metal is highly variable in composition: the kamacite Co content (7.8 ± 2.0 mg/g) is within the L-group range (6.7–8.2 mg/g) but extends well above and below; its Ni content (38 ± 5 mg/g) is considerably lower than in more equilibrated chondrites and taenite is Ni-rich ( > 450 mg/g) and unzoned. These compositions imply equilibration at very low temperatures of about 300–350°C. It seems unlikely that volume diffusion could account for the observed relatively unzoned phases; a better model involves mass transport by grain boundary diffusion and grain growth at the indicated temperatures. We find no evidence that the matrix was ever at higher temperatures. Large (50–650 μm) polycrystalline metal aggregates consisting of individually zoned crystals are also found in the matrix; they probably represent clusters formed in the solar nebula. A few large (50–250 μm) round monocrystalline grains are also present in the matrix.Metal-bearing chondrules tend to be highly reduced; they contain low-Ni metal that occasionally contains Si and/or Cr. Silicates in these chondrules tend to have low $\text{FeO}\text{(FeO + MgO)}$ ratios. The Si-rich metal grains are never in contact with silicates and are always surrounded by troilite with a poorly characterized Ca, Cr-sulfide at the metal-troilite interface; they appear to be high temperature nebular condensates that avoided oxidation even during the chondrule forming process. Silicon contents drop below our detection limit when the sulfide coating is absent. Much more common in chondrule interiors are Si-free spheroidal metal grains not associated with sulfides. These have Ni and Co contents very similar to the Si-bearing grains, and appear to be oxidized variants of the same material. The third class of chondrule metal is fine ( ~1 μm) dusty grains inside individual olivine grains. These seem to reflect high temperature in situ reduction of FeO from the olivine.The composition of kamacite is different in sulfide-rich and sulfide-poor chondrule rims and in both cases it is dissimilar to the compositions in the chondrule interiors and matrix; this indicates that chondrule rims could not have resulted from reactions with the matrix, but are primary features acquired prior to accretton.     

Harkerite from the Alban Hills,Italy

Harkerite, found in metamorphic ejecta of the Alban Hills associated with cuspidine, grossular, phlogopite, vesuvian, biotite, and minor amounts of diopside, aegirinaugite, leucite, magnetite and calcito, shows cubic Laue symmetry m3m, possible space groups Fm3m, F432, F43m, a₀ = 14.82 Å.On the basis of isomorphous replacements suggested by the crystal structure analysis, chemical data may be represented by the formula: Ca₄₈Mg₁₆(AlSi₄O₁₆)₄(BO₃)₁₂(CO₃)₂₀ · 4H₂O. Refractive index n_D = 1.6490.The relations between harkerite from Albano, harkerite from Skye and other known harkerites and sakhaites are discussed.     

川东北普光地区深层富钾卤水钾资源提取研究

四川盆地地下卤水资源丰富,尤其川东北地区地下卤水富含高品质钾资源。本项目以四川普光地区富钾卤水为研究对象,根据卤水组成,采用模拟计算并结合实验验证的方法,研究了高温蒸发时,氯化钠、氯化钾、光卤石、硼酸等矿物的析出阶段及特点。研究结果表明,当蒸失水率约80%时,体系中约85%的NaCl析出,同时KCl达到饱和,继续蒸发可获取钾石盐。控制总蒸失水率94%~95%时分离,体系中大于80%的钾可在这一阶段析出,且湿基中KCl品位可高达约45%;析出钾石盐后的卤水降至室温可获得NaCl、KCl、KCl·MgCl₂·6H₂O及H₃BO₃的混合物,硼的析出率可达到约80%。同时,研究表明,将蒸失水率约80%时分离石盐后的卤水直接降温可以获得湿基品位约高达70%的钾石盐矿,钾析出率约50%。综合对比分析,提出两条以钾资源开发为主的工艺路线:其一为“高温蒸发析氯化钠-高温蒸发析氯化钾-冷却析钾硼混盐”,通过加工获得KCl及H₃BO₃产品;其二为“高温蒸发析氯化钠-冷却析钾”,通过加工获得高端KCl产品。     

Geochemical relationships between anorthosite and associated iron-rich rocks,Laramie Range,Wyoming

Rocks enriched in iron oxide and mafic silicates are commonly present as minor volumes of Proterozoic anorthosite complexes. In the Laramie Range, Wyoming, anorthositic rocks, gabbros, and iron oxide ore have been chemically analyzed to determine if the spatial association is a result of genetic relationships between the rock types.Variations in abundances of REE, Th, Sc, and Sr in whole-rock and in mineral separates from anorthositic rocks provide evidence for the presence of trapped intercumulus liquid. Initial ⁸⁷Sr/⁸⁶Sr ratios in apatites separated from iron oxide ore (0.70535±0.00004) are analogous to initial ⁸⁷Sr/⁸⁶Sr ratios in Laramie Range anorthosite (0.70531 and 0.70537). In addition, REE abundances in calculated parental liquids for both anorthositic rocks and iron ore are similar, providing further evidence for a comagmatic relationship.Trace element and textural characteristics of spatially associated Laramie Range gabbros indicate that they are not mixtures of the trapped liquid and cumulus components which formed anorthositic rocks. It is suggested that gabbros are early differentiation products of a high-Al gabbroic magma which subsequently crystallized large volumes of plagioclase to produce the anorthosite massif.     

Evidence for an inverted metamorphic gradient associated with a Precambrian suture, southern Wyoming

Abstract An inverted metamorphic gradient associated with the northern mylonite zone of the Cheyenne belt, a deeply eroded Precambrian suture in southern Wyoming, has been documented within metasedimentary rocks of the Early Proterozoic Snowy Pass Supergroup. Metamorphic grade in the steeply dipping supracrustal sequence increases from the chlorite through the biotite, garnet, and staurolite zones both stratigraphically and structurally upward toward the northern mylonite zone. A minimum temperature increase of approximately 100° C over a km-wide zone is required for this transition. Parallelism of inverted isograds with the trace of the northern mylonite zone implies a genetic relationship between deformation associated with that zone and the inverted metamorphic gradient within the Snowy Pass Supergroup. Field evidence together with microstructural and petrofabric analysis indicate northward thrusting of amphibolite-grade rocks over rocks of the Snowy Pass Supergroup along the northern mylonite zone. Mineral equilibria and garnet-biotite geothermometry on synkinematic mineral assemblages within the Snowy Pass metasedimentary rocks indicate deformation at minimum temperatures of 480° C and pressures of 350–400 MPa (3°5–4°0 kbar). This implies tectonic burial or upper plate thickness of 13–15 km. The narrow character of metamorphic zonation and microtextures within the Snowy Pass Supergroup which indicate late synkine-matic growth of garnet and staurolite, preclude rotation of pre-existing isograds by folding as a mechanism for development of the inverted gradient. Conductive transport of heat from the upper into the lower plate across the originally low-angle thrust is insufficient to produce the necessary temperatures in the lower plate. Shear heating is considered insufficient to produce the observed metamorphic transition unless high shear stresses are postulated. Up-dip advection of metamorphic fluids is a feasible, but unproven, mechanism for heat transport. The possibility that rapid uplift due to stacking of several thrust sheets may have played a role in preserving the inverted metamorphic gradient cannot be evaluated at present.     

Tectonically induced change in lake evolution recorded by seismites in the Eocene Green River Formation,Wyoming

Seismogenic sedimentary structures – seismites – provide an opportunity to understand the effects of syndepositional tectonics on lacustrine sedimentation. The lowermost Wilkins Peak Member (Eocene Green River Formation, Wyoming, USA) contains laterally extensive intervals displaying folds, load structures, mixed brittle–ductile deformation, microfaults, breccias and sedimentary dykes, which formed intrastratally in a low‐energy, sublittoral lacustrine environment. They developed in situ by liquefaction and plastic or brittle behaviour of semi‐lithified sediment, or by remobilization and injection of granular material. Their morphological attributes and lateral extent, zonation in deformation intensity and the depositional setting all imply deformation triggered by earthquake‐induced stresses in shallow‐buried sediment. Their stratigraphic distribution coincides with a shift in hydrological conditions from a balanced‐filled to an underfilled lake type, independent of climate change. This study is the first to ascribe seismites to a pulse of tectonic activity that caused a synchronous change in lacustrine evolution.     

Petrology and geochemistry of the ignimbrites and associated lava domes from N.W. Sardinia

Cenozoic calc-alkaline ignimbrites and related lavas from N.W. Sardinia (Italy), which are closely associated with andesites, have dacitic to rhyolitic composition. The ignimbritic rocks underwent fractional crystallization dominated by plagioclase. The model calculations for REE, Ba, Sr, and Rb are consistent with the generation of ignimbritic magmas by partial melting of tonalitic rocks. P-T estimates for the crystallization of ignimbrites, which give temperatures in the range of 910 °–1070 ° C and P about 5 kb, imply a local increase of temperature in the crust, which is probably related to the ascending andesitic magma. The variations of trace elements indicate that associated andesitic rocks were contaminated by ignimbritic magma.     

大别山碧溪岭和黄镇榴辉岩中绿辉石的结构水：对原岩性质和动力学过程的制约

运用傅立叶变换红外光谱(FTIR)技术,对大别山碧溪岭和黄镇榴辉岩中的绿辉石进行了详细的结构水观察。绿辉石中普遍含有结构水,以OH~-的形式存在,含量可达～2000ppm(H_2O wt.)。碧溪岭绿辉石的水含量在露头尺度(-150km)上是不均一的,而黄镇绿辉石是均一的(至少在3km的尺度上)。碧溪岭绿辉石水含量的不均一分布和黄镇绿辉石水含量的均一分布都反映的是原岩特征,碧溪岭榴辉岩原岩经历的水-岩相互作用是“隧道式”的而黄镇是“弥散式”的碧溪岭榴辉岩的原岩可能是基性的侵入岩而黄镇榴辉岩的原岩可能是玄武岩。碧溪岭绿辉石的水含量(<1400ppm)明显低于黄镇绿辉石(～1850ppm),这是原岩水含量差异的体现,原岩性质的不同和经历的水-岩相互作用方式的不同造成了原岩水含量的差异。     

Five clinopyroxenes in the Hareidland eclogite,Western Norway

Five clinopyroxenes can be distinguished on petrographic and chemical grounds in the Hareidland eclogite. Of these, three are omphacites. It is suggested that all three were originally of the same composition and that their present chemical differences are due to differences in their immediate chemical environments during retrograde metamorphism of the eclogite. The other two clinopyroxenes are symplectitic, and chemically vary from sodic augite to jadeite-poor omphacite. They were formed by exsolution of a sodic component (sodic plagioclase) from a parental omphacite.Publication no. 49 in the Norwegian Geotraverse Project.