Incidence of urban sewage disposal in the salt-ponds areas of the south of the Bay of Cadiz

The highest pollution indices in the marsh and tide-lands situated to the south of the Bay of Cadiz have been evaluated. At the present, the salt industry of this area is being transformed into mariculture installations. This study consisted of the systematic evaluation of different parameters at 26 sampling stations during the period 1976–1981. The results suggest that extensive zones are too seriously affected to make use of them as marine piscifactories.     

Interannual variability in western US precipitation

Low-frequency (interannual or longer period) climatic variability is of interest, because of its significance for the understanding and prediction of protracted climatic anomalies. Since precipitation is one of the key variables driving various hydrologic processes, it is useful to examine precipitation records to better understand long-term climate dynamics. Here, we use the multi-taper method of spectral analysis to analyze the monthly precipitation time series (both occurrence and amount) at a few stations along a meridional transect from Priest River, ID to Tucson, AZ. We also examine spectral coherence between monthly precipitation and widely used atmospheric indices, such as the central Northern Pacific (CNP) and southern oscillation index (SOI). This analysis reveals statistically significant ‘signals' in the time series in the 5–7 and 2–3 year bands. These interannual signals are consistent with those related to El-Niño southern oscillation (ENSO) and quasi-biennial variability identified by others.     

Groundwater recharge and palaeoclimate in the Sirte and Kufra basins, Libya

Stable and radio-isotope results (C, H, O) for groundwaters from the Sirte and northern Kufra basins are used to determine the recharge history during the Holocene and late Pleistocene. Radiocarbon ages have been corrected on the basis of their stable carbon isotope ratios and on environmental samples from the areas, and two groups may be recognised: (1) low ¹⁴C activity groundwaters (13000–34000 yr. BP) with δ ¹³C-5.6 to −11.7‰; and (2) higher ¹⁴C activity groundwaters (5000–7800 yr. BP) enriched in ¹³C up to δ ¹³C = −3.2‰. There is a general correlation of age with depth.

A well defined freshwater (< 50 mg/l Cl⁻) channel can be traced within the aquifer for some 130 km through the region, which is considered to represent recharge from a former wadi. This water with an age of ± 7800 yr. BP is chemically and isotopically distinct from the regional groundwaters and provides direct evidence of a significant recharge event during the Holocene.

The stable isotope (O and H) composition of groundwater from the Kufra and Sirte basins are all related by an evaporative line with slope δ D = 4.5δ ¹³O − 35 with an intercept on the meteoric line of -11‰. This suggests a recharge source continuing into the Holocene from air masses, analogous to current heavy monsoon rain derived from south of the Sahara. The spatial and temporal distribution of groundwaters in relation to the evaporative line suggests a progressive change in character of the recharge which is controlled by a shift towards strongly convective rainfall during the Holocene.

The direct hydrogeological and geochemical evidence supports climatic models proposed by several workers in which discrete humid episodes during the Holocene are inferred.     

Assessing benthic ecological impacts of bottom aquaculture using macrofaunal assemblages

Bottom aquaculture of bivalves is a high-yield culture method, which is increasingly adopted by shellfish farmers worldwide. However, the effects of bottom aquaculture on benthic ecosystems are not well-known. Manila clam (Ruditapes philippinarum), is a widely distributed bottom aquaculture mollusk species. To assess the ecological impacts of Manila clam bottom aquaculture, clams and other macrofaunal assemblages were investigated during four cruises (July and November 2011, February and May 2012) at six sampling sites in Jiaozhou Bay, China. Correlation analysis showed that macrofaunal assemblages had significant negative correlations with the abundance of Manila clams. However, according to the results of several biotic indices, a low disturbance was detected by Manila clam bottom aquaculture. In conclusion, AMBI (AZTI'S Marine Biotic Index) and M-AMBI (Multivariate AZTI Marine Biotic Index) indices are more suitable for assessing ecological quality than polychaete/amphipod ratios when the disturbance is slight, such as at a bivalve bottom aquaculture.     

Soil moisture variation in relation to topography and land use in a hillslope catchment of the Loess Plateau, China

The profile characteristics and the temporal dynamics of soil moisture variation were studied at 26 locations in Da Nangou catchment (3.5 km²) in the loess area of China. Soil moisture measurements were performed biweekly at five depths in the soil profile (0–5, 10–15, 20–25, 40–45 and 70–75 cm) from May to October 1998 using Delta-T theta probe. Soil moisture profile type and temporal variation type and their relationship to topography and land use were identified by detrended canonical correspondence analysis (DCCA) and correlation analysis. The profile distribution of time-averaged soil moisture content can be classified into three types i.e. decreasing-type, waving-type and increasing-type. The profile features of soil moisture (e.g. profile gradient and profile variability) are influenced by different environmental factors. The profile type of soil moisture is only attributed to land use while profile gradient and profile variability of soil moisture is mainly related to land use and topography (e.g. landform type and slope). The temporal dynamics of layer-averaged soil moisture content is grouped into three types including three-peak type, synchro-four-peak type and lagged-four-peak type. These types are controlled by topography rather than by land use. The temporal dynamic type of soil moisture shows significant correlation with relative elevation, slope, aspect, while temporal variance displays significant relation with slope shape. The mean soil moisture is related to both the profile and dynamics features of soil moisture and is controlled by both land use and topography (e.g. aspect, position, slope and relative elevation). The spatial variability of soil moisture across landscape varies with both soil depths and temporal evolution.     

Testing the applicability of a Marine Biotic Index (AMBI) to assessing the ecological quality of soft-bottom benthic communities, in the South America Atlantic region

Recently, several monitoring programmes have been undertaken to evaluate the impact of different anthropogenic activities, upon a range of coastal ecosystems located in the South-western Atlantic. In the present contribution, the applicability of the AZTI's Marine Biotic Index (AMBI) is tested, to establish the benthic health of the ecosystem using these data sets. As the AMBI was created previously for use in European estuarine and coastal environments, its general applicability to new geographical locations is discussed. In general, the results are in agreement with those obtained using traditional univariate and multivariate methods. Some inconsistent results are observed, when low abundances and/or number of taxa are recorded in the samples. Moreover, when the macrofauna samples are dominated by large nematodes, the classification of the benthic ecosystem health using AMBI is not consistent with previous results achieved applying other statistical techniques. Thus, parallel to the application of this index to a wider extend, the complementary use of different indices and/or methods is recommended to assess confidently the environmental quality of a coastal area.     

Spatio-temporal variation in some physical and chemical parameters over a 25-year period in the catchment of the river Adour

The catchment of the river Adour (SW France) has been examined in order to analyse spatio-temporal variations in a number of key variables (flow, suspended matter, nitrate and dissolved orthophosphate concentrations) over a 25-year period (1972–1996).

Within the catchment area, it has been possible to discern how hydroclimatic fluctuations have affected the watershed, with dry periods in 1972–1976 and 1983–1993 alternating with wetter phases in 1977–1982 and 1994–1995. The anthropogenic activity, primarily, involving the use of water for agricultural purposes, has also had a major impact during this period, particularly in the downstream areas of the catchment.

Suspended matter fluxes display regular downstream increases with significant erosion being evident in the mountainous region contrasting with retention in the floodplains area downstream. These fluxes exhibit temporal and spatial variations with peaks occurring every 3–5 years, 1975–1977, 1979, 1982, 1985, 1987 and 1992. Some of these peaks are suggested to be related to anthropogenic activity involving river management, including the cutting of meanders and the construction of dykes for flood prevention.

Nitrate concentrations evince a similar pattern to the suspended matter fluxes with enhanced levels of downstream. The confluence of the Adour with the Midouze appears not to have any major impact on the nitrate concentration. In the downstream areas, an uptake of nitrate is registered indicating the activity of the riparian vegetation. For the entire catchment, maximal nitrate concentrations are observed in 1979, 1982, 1987, 1991–1992 and 1995.     

Predicting copper toxicity in estuarine and marine waters using the Biotic Ligand Model

The Biotic Ligand Model (BLM) has proven efficient in predicting the toxicity of a variety of metals to freshwater organisms. Consequently, the US EPA has proposed its use for calculating freshwater copper criteria. This study evaluates the BLM for use in estuarine and marine waters. Studies were conducted using the bivalve, Mytilus sp. and 48-h embryo-larval development chronic estimator test methods. These are the most sensitive taxa and test in the US EPA saltwater copper criteria database. Samples from five locations around the USA were tested. There is a strong relationship between measured and BLM predicted copper EC50s (log transformed data, r² = 0.76, p < 0.001, n = 44). The BLM predicted within a factor ±2 of measured EC50s in 41 of 44 cases. However, the BLM tends to predict lower EC50s when measured EC50s are approximately 10 μg Cu/L. This may be due to limitations of the metal-dissolved organic matter interaction model.     

Assessment of a Mediterranean shallow lentic ecosystem (Lake Pamvotis, Greece) using benthic community diversity: Response to environmental parameters

Macroinvertebrates play a key role in freshwater lentic and lotic ecosystems. The macroinvertebrate benthic community of a shallow Mediterranean lake (Lake Pamvotis, NW Greece) was studied. The benthic assemblage was sampled monthly at five sites during a period of 1 year (Apr. 1998–Mar. 1999). In addition hypolimnetic water quality variables were monitored over the same period at each site.

The aim of the study was (a) to describe the intra-annual and spatial variability in benthic communities, (b) to relate possible community changes to environmental conditions and (c) to evaluate the responses of the lake's ecological status on community indices.

The benthic fauna of Lake Pamvotis was found to be very limited with a total of 10 species belonging to five taxonomic groups. The oligochaete community comprised 80% of the total benthic fauna with Potamothrix bavaricus as a new record for the Lake Pamvotis and Potamothrix hammoniensis, being the dominant benthic species represented more than 61% of the total benthic fauna. Chironomus plumosus was the most abundant chironomid species contributing with about 6% of the total benthic fauna, and Chaoborus flavicans with 19% was the important dipteran. Almost all benthic species showed the same intra-annual seasonal pattern, with peak population densities during spring and early summer except P. hammoniensis which predominated during the whole sampling period. Dissolved oxygen and temperature seemed to be the main environmental factors affecting community indices.

Benthic communities are affected by human disturbances in Lake Pamvotis shifting their composition to more tolerant taxa, reflecting also the eutrophic to hypertophic character of the lake.     

Modelling the water balance of a mesoscale catchment basin using remotely sensed land cover data

Hydrological modelling of mesoscale catchments is often adversely affected by a lack of adequate information about specific site conditions. In particular, digital land cover data are available from data sets which were acquired on a European or a national scale. These data sets do not only exhibit a restricted spatial resolution but also a differentiation of crops and impervious areas which is not appropriate to the needs of mesoscale hydrological models. In this paper, the impact of remote sensing data on the reliability of a water balance model is investigated and compared to model results determined on the basis of CORINE (Coordination of Information on the Environment) Land Cover as a reference. The aim is to quantify the improved model performance achieved by an enhanced land cover representation and corresponding model modifications. Making use of medium resolution satellite imagery from SPOT, LANDSAT ETM+ and ASTER, detailed information on land cover, especially agricultural crops and impervious surfaces, was extracted over a 5-year period (2000–2004). Crop-specific evapotranspiration coefficients were derived by using remote sensing data to replace grass reference evapotranspiration necessitated by the use of CORINE land cover for rural areas. For regions classified as settlement or industrial areas, degrees of imperviousness were derived. The data were incorporated into the hydrological model GROWA (large-scale water balance model), which uses an empirical approach combining distributed meteorological data with distributed site parameters to calculate the annual runoff components. Using satellite imagery in combination with runoff data from gauging stations for the years 2000–2004, the actual evapotranspiration calculation in GROWA was methodologically extended by including empirical crop coefficients for actual evapotranspiration calculations. While GROWA originally treated agricultural areas as homogeneous, now a consideration and differentiation of the main crops is possible. The accuracy was determined by runoff measurements from gauging stations. Differences in water balances resulting from the use of remote sensing data as opposed to CORINE were analysed in this study using a representative subcatchment. Resulting Nash–Sutcliff model efficiencies improved from 0.372 to 0.775 and indicate that the enhanced model can produce thematically more accurate and spatially more detailed local water balances. However, the proposed model enhancements by satellite imagery have not exhausted the full potential of water balance modelling, for which a higher temporal resolution is required.     

Esterases activities and lipid peroxidation levels in muscle tissue of the shanny Lipophrys pholis along several sites from the Portuguese Coast

This study is part of a project aiming to validate the use of the intertidal shanny Lipophorys pholis as a sentinel species in pollution monitoring in NW European marine ecosystems. To this end, a characterisation of acethylcholin (AChE), butyrylcholin (BChE) and propionylcholin (PrChE) esterases in L. pholis muscle was performed and the results indicated that AChE was predominant. Furthermore, the use of eserine sulphate and BW284c51 (0.64–800 μM), and iso-OMPA (0.08–16 mM), confirmed the measurement of true cholinesterases (ChEs) as well as the presence of pseudocholinesterases. The field application of these markers to L. pholis, sampled in seven locations along the Portuguese coast, revealed that fish were likely to be affected by neurotoxic compounds. This was indicated by the significant depletion of AChE (p < 0.05) in animals collected at urban and industrialised sites, compared with those from reference locations. The inclusion of a marker of effect, measured as lipid peroxidation levels in muscle tissue, also revealed the existence of site differences. Overall, the study further validates the utility of L. pholis in pollution monitoring studies.     

Biofouling confounds the uptake of trace organic contaminants by semi-permeable membrane devices (SPMDs)

The outer layers of layflat, low density polyethylene plastic tubing (the principal component of semi-permeable membrane devices, SPMDs) were biofouled at a clean site in Hong Kong coastal waters for periods of 1–4 weeks. Following pre-fouling, triolein was added to the SPMDs and, along with control (unfouled) devices, they were exposed to a range of organochlorine pesticides (-HCH, aldrin, p,p^′-DDT) and PAHs (anthracene, fluoranthene and benzo(a)pyrene) under laboratory conditions. Results showed that the uptake of contaminants by SPMDs was severely reduced by as much as 50% under fouling conditions in comparison to unfouled controls. The ultimate utility of SPMDs as passive monitors is thus reduced, although alternative measures, such as the use of permeability reference compounds may compensate, and allow for realistic evaluations of dissolved environmental concentrations in aquatic environments. However, due to the complexities involved in such procedures––especially as they need to be conducted on a case-by-case basis––the utility of SPMDs appears to be limited for estimates of bioavailability unless necessary calibrations are undertaken within each environment that the sampler is used.     

Chemical change in Antarctica—Significance? A perspective

The bitter confrontations of 20–25 years ago between a small environmental science community and several industries manufacturing chlorinated hydrocarbons are now only an historical footnote in the rapid evolution of an environmental consciousness. Regulations developed in industrial countries are being applied to protect the most pristine of the world's environments in Antarctica. Many of the proposed regulations, however, would serve no useful purpose; some of the reports of environmental damage are grossly exaggerated. A certain skepticism might be appropriate. Nevertheless, although monitoring is not a ‘scientific’ activity, the case is made for a monitoring programme in Antarctica that would measure temporal changes in the environmental levels of contaminants from both local and distant sources.     

Isotope geochemistry of Pantelleria volcanic fluids, Sicily Channel rift: a mantle volatile end-member for volcanism in southern Europe

Chemical and isotopic ratio (He, C, H and O) analysis of hydrothermal manifestations on Pantelleria island, the southernmost active volcano in Italy, provides us with the first data upon mantle degassing through the Sicily Channel rift zone, south of the African–European collision plate boundary. We find that Pantelleria fluids contain a CO₂–He-rich gas component of mantle magmatic derivation which, at shallow depth, variably interacts with a main thermal (100°C) aquifer of mixed marine–meteoric water. The measured ³He/⁴He ratios and δ¹³C of both the free gases (4.5–7.3 R_a and −5.8 to −4.2‰, respectively) and dissolved helium and carbon in waters (1.0–6.3 R_a and −7.1 to −0.9‰), together with their covariation with the He/CO₂ ratio, constrain a ³He/⁴He ratio of 7.3±0.1 R_a and a δ¹³C of ca. −4‰ for the magmatic end-member. These latter are best preserved in fluids emanating inside the active caldera of Pantelleria, in agreement with a higher heat flow across this structure and other indications of an underlying crustal magma reservoir. Outside the caldera, the magmatic component is more affected by air dilution and, at a few sites, by mixing with either organic carbon and/or radiogenic ⁴He leached from the U–Th-rich trachytic host rocks of the aquifer. Pantelleria magmatic end-member is richer in ³He and has a lower (closer to MORB) δ¹³C than all fluids yet analyzed in volcanic regions of Italy and southern Europe, including Mt. Etna in Sicily (6.9±0.2 R_a, δ¹³C=−3±1‰). This observation is consistent with a south to north increasing imprint of subducted crustal material in the products of Italian volcanoes, whose He and C (but also O and Sr) isotopic ratios gradually evolve towards crustal values northward of the African–Eurasian plate collision boundary. Our results for Pantelleria extend this regional isotopic pattern further south and suggest the presence of a slightly most pristine or ‘less contaminated’, ³He-richer mantle source beneath the Sicily Channel rift zone. The lower than MORB ³He/⁴He ratio but higher than MORB CO₂/³He ratio of Pantelleria volatile end-member are compatible with petro-geochemical evidence that this mantle source includes an upwelling HIMU–EM1-type asthenospheric plume component whose origin, according to recent seismic data, may be in the lower mantle.     

Time should be considered in developmental ecotoxicity test

Developmental toxicity tests are often used for the hazard assessment of chemicals and environmental media. One of the most widely used is the oyster embryo larval test (OEL), in which the development of oyster larvae is arrested at a single fixed time (e.g. 24 or 48 h) of toxic exposure, and the proportion of normal larvae measured. However, a major problem with this conventional approach is the lack of information on temporal trends in development. In this study, Pacific oyster Crassostrea gigas embryos were exposed to nominal concentrations of copper (CuSO₄) of <0.001 (control), 0.60, 1.25, 2.5, 5.0, 10.0 and 20.0 μg l⁻¹ (at 20 °C, salinity 35‰ and pH 8.1). Three replicates from each group were arrested and examined every 8 h during 24–72 h of exposure, and the number of viable larvae developed to D-shape was determined. The results revealed that the number of viable D-shape larvae in the control increased rapidly and reached an optimum at 32 h, before declining gradually due to starvation. Analysis of covariance (ANCOVA) showed that larval developmental rates during 0–32 h were significantly inhibited by Cu at all concentrations. This paper demonstrates that arrest and measurement at different time periods are important and should be incorporated into the OEL test. This would maximise the sensitivity of the test in detecting developmental effects in spiked or environmental samples.     

Antarctic tourism and environmental concerns

Increasing numbers of tourists are visiting the Antarctic. Totals from the past three seasons (1989–1990, 1990–1991, 1991–1992) were 2581, 4842, and 6495 respectively (Enzenbacher, 1992). Some environmental issues arising from Antarctic tourist activity include: wildlife tolerance, waste disposal, passenger education, tour operator management practices, personnel experience, frequency of visits and ship design. Current guidelines provide a practical approach to tourism, but do not address all issues arising from tourist activity. Antarctic Treaty Parties agreed to examine the question of a comprehensive regulation of tourist activities in the Antarctic Treaty Area and policies are under review. Some issues may prove difficult to resolve. Compliance with existing guidelines is to be encouraged, at least until more is known about the environmental effects of tourism. A management plan for tourism is needed along with more research on how tourism is conducted and the effects visits have on Antarctica's marine and terrestrial ecosystems. Cooperation between Treaty Parties and tour operators is important for the development of appropriate tourism regulations.     

Influence of oyster culture practices and environmental conditions on the ecological status of intertidal mudflats in the Pertuis Charentais (SW France): a multi-index approach

The ecological quality status (EcoQ) of intertidal mudflats constrained by Pacific oyster farming was assessed by single (H’, AMBI, BENTIX and BOPA) and multimetric (M-AMBI and average score) index approaches in the Pertuis Charentais (SW France). Fifteen sampling stations were monitored seasonally for sedimentological features and macrozoobenthos in 2004. Sediments affected by oyster biodeposits showed organic matter enrichment, and sediments from off-bottom culture sites had higher organic matter contents and lower redox potentials than sediments from on-bottom culture sites. Biotic indices consistently registered responses of macrozoobenthos to organic enrichment but there was only partial agreement between single index-derived EcoQs. The average score was better than M-AMBI and single indices for determining EcoQs. Accordingly, oyster farming alters intertidal macrozoobenthic assemblages moderately, and off-bottom cultures cause more disturbance than on-bottom cultures. Hydrodynamics and seasons may interact with culture practices in smothering/strengthening biodeposition-mediated effects through dispersal/accumulation of biodeposits.     

Levels of heavy metals along the Libyan coastline

A coastal survey off the east part of the Libyan coastline which has no river inputs was initiated to measure the existing level and distribution of selected heavy metals (Cu, Zn, Cd, Ni, and Mn) in surface sediments along Benghazi Bay. In order to place the finding of this survey in proper perspective and for practical terms a Pollution Load Index (PLI) was used. The results establish that of the sites examined only the harbour site exhibited relatively high levels particularly in the cases of cadmium and copper indicating a detectable anthropogenic input. The range of concentrations were 1.03%–1.96% μg g⁻¹ (dry wt) for organic content and 64.7%–93% for calcium carbonate while the range of heavy metals concentrations (μg g⁻¹ dry wt) were 8.7–42 for Cu, 2.3–27.3 for Zn, 5.7–19 for Ni, 37–76.7 for Mn, and below the detection limit-1.73 for Cd. A PLI score of 2.93 was obtained at the harbour site and a range of 6.11–7.63 for the other sites. The PLI score for the control site was 9.51 and the score for the overall studied area was 7.51 indicating a very clean environment. The index would be, with some modification, a step in the right direction from the management point of view in Libya due to the absence of environmental expertise.     

Meso-scale testing and development of test procedures to maintain mass balance

The Conrad Blucher Institute for Surveying and Science (Texas A&M University––Corpus Christi) has conducted numerous petroleum experiments at the Shoreline Environmental Research Facility (Corpus Christi, Texas, USA). The meso-scale facility has multiple wave tanks, permitting some control in experimental design of the investigations, but allowing for real-world conditions. This paper outlines the evolution of a materials balance approach in conducting petroleum experiments at the facility. The first attempt at a materials balance was during a 1998 study on the fate/effects of dispersant use on crude oil. Both water column and beach sediment samples were collected. For the materials balance, the defined environmental compartments for oil accumulation were sediments, water column, and the water surface, while the discharge from the tanks was presumed to be the primary sink. The “lessons learned” included a need to quantify oil adhesion to the tank surfaces. This was resolved by adhering strips of the polymer tank lining to the tank sides that could be later removed and extracted for oil. Also, a protocol was needed to quantify any floating oil on the water surface. A water surface (oil slick) quantification protocol was developed, involving the use of solid-phase extraction disks. This protocol was first tested during a shoreline cleaner experiment, and later refined in subsequent dispersant effectiveness studies. The effectiveness tests were designed to simulate shallow embayments which created the need for additional adjustments in the tanks. Since dispersant efficacy is largely affected by hydrodynamics, it was necessary to scale the hydrodynamic conditions of the tanks to those expected in our prototype system (Corpus Christi Bay, Texas). The use of a scaled model permits the experiment to be reproduced and/or evaluated under different conditions. To minimize wave reflection in the tank, a parabolic wave dissipater was built. In terms of materials balance, this design reduced available surface area as a sink for oil adsorption.