Analysis of water stable isotopes fingerprinting to inform conservation management: Lake Urema Wetland System,Mozambique

The present study focusses on the analysis of water stable isotopes to contribute to understanding the hydrology of the Lake Urema wetland system in central Mozambique towards conservation management.Lake Urema Wetland is located in the Gorongosa National Park at the southernmost extent of the East African Rift System and is situated entirely within the Urema catchment. Of particular concern to the park’s management is the understanding of hydrological processes as these may trigger transformations of ecosystems, habitat losses and wildlife migrations. Concerns over the Lake Urema wetland’s drying up and the trapping of sediments in the floodplain have been raised for some time by conservationists.Water samples were collected for stable water isotope analyses during the wet and the dry seasons for the period 2006–2010 from springs, boreholes, rivers, and Lake Urema. In addition monthly composite precipitation was collected at two rain gauges.The results show that Lake Urema is maintained throughout the dry season merely from water generated during the wet season. It receives water from wet season precipitation and the runoff generated from this precipitation. The water source areas of the lake are the Gorongosa Mountain and the Barue Basement geomorphological units. Consequently, the source of the sediments which have been trapped into the lake and the floodplain has to be identified in these two catchment areas and urgent action is required to rescue the lake. This water body constitutes a groundwater buffer system which supports a unique wetland landscape. The annual inundations’ processes leading to the recharge-drainage cycle in the floodplain are most sensitive to the deposition of sediments, changing hydraulic gradients, and reducing wet season inflows and increasing drainage rates.     

Characterizing spatial and temporal variation in 18O and 2H content of New Zealand river water for better understanding of hydrologic processes

Time series of hydrogen and oxygen stable isotope ratios (δ²H and δ¹⁸O) in rivers can be used to quantify groundwater contributions to streamflow, and timescales of catchment storage. However, these isotope hydrology techniques rely on distinct spatial or temporal patterns of δ²H and δ¹⁸O within the hydrologic cycle. In New Zealand, lack of understanding of spatial and temporal patterns of δ²H and δ¹⁸O of river water hinders development of regional and national-scale hydrological models. We measured δ²H and δ¹⁸O monthly, together with river flow rates at 58 locations across New Zealand over a two-year period. Results show: (a) general patterns of decreasing δ²H and δ¹⁸O with increasing latitude were altered by New Zealand's major mountain ranges; δ²H and δ¹⁸O were distinctly lower in rivers fed from higher elevation catchments, and in eastern rain-shadow areas of both islands; (b) river water δ²H and δ¹⁸O values were partly controlled by local catchment characteristics (catchment slope, PET, catchment elevation, and upstream lake area) that influence evaporation processes; (c) regional differences in evaporation caused the slope of the river water line (i.e., the relationship between δ²H and δ¹⁸O in river water) for the (warmer) North Island to be lower than that of the (cooler, mountain-dominated) South Island; (d) δ²H seasonal offsets (i.e., the difference between seasonal peak and mean values) for individual sites ranged from 0.50‰ to 5.07‰. Peak values of δ¹⁸O and δ²H were in late summer, but values peaked 1 month later at the South Island sites, likely due to greater snow-melt contributions to streamflow. Strong spatial differences in river water δ²H and δ¹⁸O caused by orographic rainfall effects and evaporation may inform studies of water mixing across landscapes. Generally distinct seasonal isotope cycles, despite the large catchment sizes of rivers studied, are encouraging for transit time analysis applications.     

Groundwater–surface water interactions in a lowland watershed: source contribution to stream flow

The lower coastal plain of the Southeast USA is undergoing rapid urbanisation as a result of population growth. Land use change has been shown to affect watershed hydrology by altering stream flow and, ultimately, impairing water quality and ecologic health. However, because few long‐term studies have focused on groundwater–surface water interactions in lowland watersheds, it is difficult to establish what the effect of development might be in the coastal plain region. The objective of this study was to use an innovative improvement to end‐member mixing analysis (EMMA) to identify time sequences of hydrologic processes affecting storm flow. Hydrologic and major ion chemical data from groundwater, soil water, precipitation and stream sites were collected over a 2‐year period at a watershed located in USDA Forest Service's Santee Experimental Forest near Charleston, South Carolina, USA. Stream flow was ephemeral and highly dependent on evapotranspiration rates and rainfall amount and intensity. Hydrograph separation for a series of storm events using EMMA allowed us to identify precipitation, riparian groundwater and streambed groundwater as main sources to stream flow, although source contribution varied as a function of antecedent soil moisture condition. Precipitation, as runoff, dominated stream flow during all storm events while riparian and streambed groundwater contributions varied and were mainly dependent on antecedent soil moisture condition. Sensitivity analyses examined the influence of 10% and 50% increases in analyte concentration on EMMA calculations and found that contribution estimates were very sensitive to changes in chemistry. This study has implications on the type of methodology used in traditional forms of EMMA research, particularly in the recognition and use of median end‐member water chemistry in hydrograph separation techniques. Potential effects of urban development on important hydrologic processes (groundwater recharge, interflow, runoff, etc.) that influence stream flow in these lowland watersheds were qualitatively examined. Copyright © 2011 John Wiley & Sons, Ltd.     

Characterizing replenishment water,lake water and groundwater interactions by numerical modelling in arid regions: a case study of Shahu Lake

In order to maintain the scenic and eco-environmental values of a lake, we need to characterize its water interactions. Shahu Lake was used as a case study to show the interactions among replenishment water, lake water and groundwater in an arid region. Shahu Lake is located in the Ningxia Hui Autonomous Region of northwest China and has an area of 13.96 km² and an average depth of 2.2 m. The groundwater modelling software MODFLOW was used. The analysis results show that hydraulic connectivity among replenishment water, lake water and groundwater is the crucial driving factor that affects the water level in Shahu Lake. The lake water level is highly sensitive to the volume of replenishment water. The groundwater is of great importance in balancing the water level in the lake and preventing it from drying up. It was determined that 13.8 × 10⁶ m³/yr is the optimal volume of replenishment water for Shahu Lake in order to maintain the lake level at its normal state and also to make the best use of available water resources on a long-term basis. Understanding of the water interactions can promote effective management of water resources in Shahu Lake.

EDITOR D. Koutsoyiannis

ASSOCIATE EDITOR D. Hughes     

Enhancing remote sensing research on global change to improve our understanding on Earth system processes

正Global Change includes climate change and other environmental changes caused by the joint interaction among various layers of Earth. From the positive side, global change provides new opportunities to human and other living forms on Earth. In the meantime, it creates tremendous challenges and negative impact. At present, the negative impacts have reached all primary processes of the global ecosystem and every aspect of human society, especially causing degradation of the ecosystem. For instance, intensive deforestation causes decline of biodiversity; global warming causes sea level rise and increases     

Ballast water: A threat to the Amazon Basin

Ballast water exchange (BWE) is the most efficient measure to control the invasion of exotic species from ships. This procedure is being used for merchant ships in national and international voyages. The ballast water (BW) salinity is the main parameter to evaluate the efficacy of the mid-ocean ballast water exchange. The vessels must report to the Port State Control (PSC), via ballast water report (BWR), where and how the mid-ocean BWE was performed. This measure allows the PSC to analyze this information before the ship arrives at the port, and to decide whether or not it should berth.Ship BW reporting forms were collected from the Captaincy of Santana and some ships were visited near the Port of Santana, located in Macapá (Amazon River), to evaluate the BW quality onboard. We evaluated data submitted in these BWR forms and concluded that the BWE efficacy might be compromised, because data contained in these BWR indicate that some ships did not change their BW. We found mistakes in filling the BWR forms and lack of information. Moreover, these ships had discharged BW with high level of salinity, Escherichia coli and total coliforms into the Amazon River. We concluded that the authorities of the Amazon Region need to develop more efficient proceedings to evaluate the ballast water reporting forms and BW quality, as there is potential risk of future invasion of exotic species in Brazilian ports.     

Introduction to special issue on connectivity in water and sediment dynamics

Connectivity has emerged in recent years as a significant conceptual framework within which to address the spatial and temporal variability in runoff and sediment transport. This special issue draws together several of the papers that were presented in the session “Connectivity in water and sediment dynamics: how do we move forwards?” at the 2012 General Assembly of the European Geosciences Union in Vienna, Austria. The papers submitted for this special issue fall into three groups: empirical studies, modelling studies, and conceptual development. Although it may be evident that the concept of connectivity helps us to express the complexity (in terms of water and sediment yields) of landscape responses to rainfall inputs, does it improve our ability to understand or predict those responses? There would still seem to be some way to go in connectivity research before this nagging concern can be assuaged. That it can be will undoubtedly be an important task for a number of ongoing research initiatives. Copyright © 2015 John Wiley & Sons, Ltd.     

Calibration and identifiability analysis of a water quality model to evaluate the contribution of different processes to the short-term dynamics of suspended sediment and dissolved nutrients in the surface water of a rural catchment

A method that combines calibration and identifiability analysis of a dynamic water quality model to evaluate the relative importance of various processes affecting the dynamic aspects of water composition is illustrated by a study of the response of suspended sediment and dissolved nutrients to a flood hydrograph in a rural catchment area in the Netherlands. Since the water quality model simulates the observed concentrations of suspended sediment and dissolved nutrients reasonably well, the most important processes during the observed flood hydrograph could be determined. These were erosion, exchange between dissolved phase and bed sediments and denitrification. It is concluded that the method is very useful for identifying the most significant model parameters and processes that are essential for water quality modelling. © 1998 John Wiley & Sons, Ltd.     

Use of stable water isotopes to identify hydrological processes of meteoric water in montane catchments

This study analyzes the stable isotopic compositions of hydrogen and oxygen (δ²H, δ¹⁸O) in montane meteoric waters including precipitation and stream water of central Taiwan to identify hydrological processes in montane catchments. Results of precipitation demonstrate that monsoon and altitude effects are two principal processes affecting δ and deuterium excess (d^E) values of inland precipitation in central Taiwan. Furthermore, slope and intercept values of summer and winter local meteoric water line are modified by secondary evaporation effects such as moisture recycling and raindrop evaporation. Additionally, stream water's results indicate that differences in δ values among stream waters reflect isotopic altitude effect whereby lower values are more evident in stream water originating from high‐elevation catchments than low‐elevation catchments. Comparison of the isotopic results between precipitation and stream water indicates that summer precipitation containing recycled moisture is the most important water source for the studied stream waters and indicates that catchment effect and base flow contribution are the two major hydrological processes affecting mountain stream hydrology. The hydrological processes identified by the isotopic study re‐stress the important role of forests in mountain hydrology. Copyright © 2015 John Wiley & Sons, Ltd.     

Surface water-groundwater exchange dynamics in buried-valley aquifer systems

Groundwater is a primary source of drinking water worldwide, but excess nutrients and emerging contaminants could compromise groundwater quality and limit its usage as a drinking water source. As such contaminants become increasingly prevalent in the biosphere, a fundamental understanding of their fate and transport in groundwater systems is necessary to implement successful remediation strategies. The dynamics of surface water-groundwater (hyporheic) exchange within a glacial, buried-valley aquifer system are examined in the context of their implications for the transport of nutrients and contaminants in riparian sediments. High conductivity facies act as preferential flow pathways which enhance nutrient and contaminant delivery, especially during storm events, but transport throughout the aquifer also depends on subsurface sedimentary architecture (e.g. interbedded high and low conductivity facies). Temperature and specific conductance measurements indicate extensive hyporheic mixing close to the river channel, but surface water influence was also observed far from the stream-aquifer interface. Measurements of river stage and hydraulic head indicate that significant flows during storms (i.e., hot moments) alter groundwater flow patterns, even between consecutive storm events, as riverbed conductivity and, more importantly, the hydraulic connectivity between the river and aquifer change. Given the similar mass transport characteristics among buried-valley aquifers, these findings are likely representative of glacial aquifer systems worldwide. Our results suggest that water resources management decisions based on average (base) flow conditions may inaccurately represent the system being evaluated, and could reduce the effectiveness of remediation strategies for nutrients and emerging contaminants.     

River energy budgets with special reference to river bed processes

This paper uses detailed hydrometeorological data to evaluate the influence of channel bed processes on the river energy budget at an experimental site on the regulated River Blithe, Staffordshire, UK. Results from a pilot study are presented for eight days during July, September, October and November 1994. Total energy gains were dominated by net short-wave radiation (97·60%) with significant contributions from sensible heat exchange and friction (1·17 and 1·06%, respectively) and minor additions from condensation and bed conduction (0·16 and 0·01%, respectively). Net long-wave radiation, evaporation, conduction into the river bed, sensible heat transfer and the energy advected during evaporation accounted for 53·98, 23·56, 16·27, 5·25 and 0·94% of the total heat losses. On average, over 82% of the total energy transfers occurred at the air–water interface. Approximately 15% of the total energy exchanges occurred at the channel bed, but maximum daily heat exchanges accounted for up to 24% of the daily total energy transfer. The amount of short-wave radiation attenuated in the water column, and values measured at the channel bed varied considerably from those calculated using a standard coefficient. Values of bed conduction varied in response to different vertical thermal profiles in the channel bed, reflecting the variable influence of sedimentology and groundwater flux. Fluctuations in levels of periphyton and macrophyte cover were also shown to have a significant effect on energy fluxes at the channel bed. © 1998 John Wiley & Sons, Ltd.     

Impacts of urbanisation on hydrological and water quality dynamics,and urban water management: a review

ABSTRACT

As urban space continues to expand to accommodate a growing global population, there remains a real need to quantify and qualify the impacts of urban space on natural processes. The expansion of global urban areas has resulted in marked alterations to natural processes, environmental quality and natural resource consumption. The urban landscape influences infiltration and evapotranspiration, complicating our capacity to quantify their dynamics across a heterogeneous landscape at contrasting scales. Impervious surfaces exacerbate runoff processes, whereas runoff from pervious areas remains uncertain owing to variable infiltration dynamics. Increasingly, the link between the natural hydrological cycle and engineered water cycle has been made, realising the contributions from leaky infrastructure to recharge and runoff rates. Urban landscapes are host to a suite of contaminants that impact on water quality, where novel contaminants continue to pose new challenges to monitoring and treatment regimes. This review seeks to assess the major advances and remaining challenges that remain within the growing field of urban hydrology.

Editor M.C. Acreman; Associate editor E. Rozos     

Tracing water resources flows by complementary use of hydrological and water accounting models

Historically, there has been a dispute over water allocation between users and policymakers in Iran's Zayandeh-Roud Basin (ZRB). In this study, we used the “System of Environmental-Economic Accounting for Water” (SEEAW) framework in combination with the hydrologic model “Soil and Water Assessment Tool” (SWAT) to achieve the water balance in ZRB. We used SEEAW to combine a wide range of water-related statistics across stakeholders and SWAT to evaluate the unknown agricultural water use. The SWAT model is calibrated based on the stream flows and crop yields in the basin. The model assess the renewable water of the basin into two components, about 363 and 70 mm as green and blue water, respectively. Also results from the physical water supply and water use tables demonstrates that the agricultural sector uses 78% of the total renewable freshwater, followed by the residential, 16%, and the industrial sector, 6%. The flows of water from source to services in ZRB are traced based on the water supply and water use tables. The flow diagram shows that 8 MCM of industrial reused water was transferred to the agricultural sector, and 137 MCM and 18 MCM of water from the wastewater treatment plants to the agricultural and industrial sectors, respectively. Furthermore, the results show that the index of the basin dependence on groundwater resources is high (61%), the value of water stress is high (0.88) and the dependence of the basin on transboundary water resources is 30%. Therefore, this method is highly beneficial for achieving a conceptual water balance in disputed basins without enough agricultural water uses data.     

Linking tracers,water age and conceptual models to identify dominant runoff processes in a sparsely monitored humid tropical catchment

Assessing catchment runoff response remains a key research frontier because of limitations in current observational techniques to fully characterize water source areas and transit times in diverse geographical environments. Here, we report a study that combines empirical data with modelling to identify dominant runoff processes in a sparsely monitored humid tropical catchment. The analysis integrated isotope tracers into conceptual rainfall–runoff models of varying complexity (from 5 to 11 calibrated parameters) that are able to simulate discharge and tracer concentrations and track the evolving age of stream water exiting the catchment. The model structures can be seen as competing hypotheses of catchment functioning and were simultaneously calibrated against uncertain streamflow gaugings and a 2‐year daily isotope rainfall–runoff record. Comparison of the models was facilitated using global parameter sensitivity analysis and the resulting effect on calibration. We show that a variety of tested model structures reproduced water and tracer dynamics in stream, but the simpler models failed to adequately reproduce both. The resulting water age distributions of the tested models varied significantly with little similarity between the stream water age and stored water age distributions. The sensitivity analysis revealed that only some of the more complex models (from eight parameters) could be better constrained to infer more plausible water age distributions and catchment storage estimates. These models indicated that the age of water stored in the catchment is generally older compared with the age of water fluxes, with evapotranspiration age being younger compared with streamflow. However, the water age distributions followed a similar temporal behaviour dominated by climatic seasonality. Stream water ages increased during the dry season (greater than 1 year) and decreased with increased streamflow (a few weeks old) during the wet season. We further show that the ratios of the streamwater age to stored water age distribution and the water age distribution of actual evapotranspiration to the stored water age distribution from constrained models could potentially serve as useful hydrological indicators of catchment functioning. Copyright © 2016 John Wiley & Sons, Ltd.     

Characterizing hydrological processes within kettle holes using stable water isotopes in the Uckermark of northern Brandenburg,Germany

Understanding the hydrologic connectivity between kettle holes and shallow groundwater, particularly in reaction to the highly variable local meteorological conditions, is of paramount importance for tracing water in a hydro(geo)logically complex landscape and thus for integrated water resource management. This article is aimed at identifying the dominant hydrological processes affecting the kettle holes' water balance and their interactions with the shallow groundwater domain in the Uckermark region, located in the north-east of Germany. For this reason, based on the stable isotopes of oxygen (δ¹⁸O ) and hydrogen (δ²H ), an isotopic mass balance model was employed to compute the evaporative loss of water from the kettle holes from February to August 2017. Results demonstrated that shallow groundwater inflow may play the pivotal role in the processes taking part in the hydrology of the kettle holes in the Uckermark region. Based on the calculated evaporation/inflow (E/I) ratios, most of the kettle holes (86.7%) were ascertained to have a partially open, flow-through-dominated system. Moreover, we identified an inverse correlation between E/I ratios and the altitudes of the kettle holes. The same holds for electrical conductivity (EC) and the altitudes of the kettle holes. In accordance with the findings obtained from this study, a conceptual model explaining the interaction between the shallow groundwater and the kettle holes of Uckermark was developed. The model exhibited that across the highest altitudes, the recharge kettle holes are dominant, where a lower ratio of E/I and a lower EC was detected. By contrast, the lowest topographical depressions represent the discharge kettle holes, where a higher ratio of E/I and EC could be identified. The kettle holes existing in between were categorized as flow-through kettle holes through which the recharge takes place from one side and discharge from the other side.     

Evaluation of snow models in terrestrial biosphere models using ground observation and satellite data: impact on terrestrial ecosystem processes

Snow is important for water management, and an important component of the terrestrial biosphere and climate system. In this study, the snow models included in the Biome‐BGC and Terrestrial Observation and Prediction System (TOPS) terrestrial biosphere models are compared against ground and satellite observations over the Columbia River Basin in the US and Canada and the impacts of differences in snow models on simulated terrestrial ecosystem processes are analysed. First, a point‐based comparison of ground observations against model and satellite estimates of snow dynamics are conducted. Next, model and satellite snow estimates for the entire Columbia River Basin are compared. Then, using two different TOPS simulations, the default TOPS model (TOPS with TOPS snow model) and the TOPS model with the Biome‐BGC snow model, the impacts of snow model selection on runoff and gross primary production (GPP) are investigated. TOPS snow model predictions were consistent with ground and satellite estimates of seasonal and interannual variations in snow cover, snow water equivalent, and snow season length; however, in the Biome‐BGC snow model, the snow pack melted too early, leading to extensive underpredictions of snow season length and snow covered area. These biases led to earlier simulated peak runoff and reductions in summer GPP, underscoring the need for accurate snow models within terrestrial ecosystem models. Copyright © 2007 John Wiley & Sons, Ltd.     

近30年洞庭湖季节性水情变化及其对江湖水量交换变化的响应

江湖水量交换的变化影响着通江湖泊洞庭湖的水情,进而影响湖区社会经济及生态的可持续发展.以洞庭湖城陵矶站、南咀站以及长江干流宜昌站、螺山站1981-2012年逐日水位、流量观测数据为基础,采用单位根检验、方差分析和水位-流量绳套曲线等方法对洞庭湖季节性水情变化特征进行提取,并探究江湖水量交换变化对其产生的影响.研究表明:近30年来洞庭湖水情呈阶段性特征,与相对稳定的1981-2002年相比,2003-2012年湖泊水位总体呈下降趋势,年均水位下降0.43 m;枯、涨、丰、退水期各季水情变化特征为:2003年以后洞庭湖丰水期水位平均下降0.60 m,呈现出"高水不高"现象;退水期水位平均下降1.49 m,退水加快;枯水期水位略有上升,平均上升0.18 m;涨水期水位变化不明显.湖泊退水期水位降幅最为明显,尤其是10月大幅下降,平均下降2.03 m,有提前进入枯水期的趋势.水情变化与江湖水量交换变化密切相关:丰水期,三口(松滋、太平和藕池)分流量减小在一定程度上降低湖泊水位;退水期,三口分流量减小叠加城陵矶出口长江水位下降对洞庭湖产生拉空作用,湖泊出流加快水位被拉低;枯水期,主要是1 3月,城陵矶出口长江水位上升对湖泊顶托作用增强,湖泊出流减缓水位略有抬升.     

Heterogeneity in ground water–surface water interactions in the hyporheic zone of a salmonid spawning stream

Spatial and temporal variability in ground water–surface water interactions in the hyporheic zone of a salmonid spawning stream was investigated. Four locations in a 150‐m reach of the stream were studied using hydrometric and hydrochemical tracing techniques. A high degree of hydrological connectivity between the riparian hillslope and the stream channel was indicated at two locations, where hydrochemical changes and hydraulic gradients indicated that the hyporheic zone was dominated by upwelling ground water. The chemistry of ground water reflected relatively long residence times and reducing conditions with high levels of alkalinity and conductivity, low dissolved oxygen (DO) and nitrate. At the other locations, connectivity was less evident and, at most times, the hyporheic zone was dominated by downwelling stream water characterized by high DO, low alkalinity and conductivity. Substantial variability in hyporheic chemistry was evident at fine (<10 m) spatial scales and changed rapidly over the course of hydrological events. The nature of the hydrochemical response varied among locations depending on the strength of local ground water influence. It is suggested that greater emphasis on spatial and temporal heterogeneity in ground water–surface water interactions in the hyporheic zone is necessary for a consideration of hydrochemical effects on many aspects of stream ecology. For example, the survival of salmonid eggs in hyporheic gravels varied considerably among the locations studied and was shown to be associated with variation in interstitial chemistry. River restoration schemes and watershed management strategies based only on the surface expression of catchment characteristics risk excluding consideration of potentially critical subsurface processes. Copyright © 2002 John Wiley & Sons, Ltd.     

Groundwater–surface‐water interactions in a braided river: a tracer‐based assessment

Natural tracers (alkalinity and silica) were used to infer groundwater–surface‐water exchanges in the main braided reach of the River Feshie, Cairngorms, Scotland. Stream‐water samples were collected upstream and downstream of the braided section at fortnightly intervals throughout the 2001–2002 hydrological year and subsequently at finer resolution over two rainfall events. The braided reach was found to exert a significant downstream buffering effect on the alkalinity of these waters, particularly at moderate flows (4–8 m³ s^?1/?Q_30–70). Extensive hydrochemical surveys were undertaken to characterize the different source waters feeding the braids. Shallow groundwater flow systems at the edge of the braided floodplain, recharged by effluent streams and hillslope drainage, appeared to be of particular significance. Deeper groundwater was identified closer to the main channel, upwelling through the hyporheic zone. Both sources contributed to the significant groundwater–surface‐water interactions that promote the buffering effect observed through the braided reach. Their impact was less significant at higher flows (>15 m³ s^?1/>Q₁₀) when acidic storm runoff from the peat‐covered catchment headwaters dominated, as well as under baseflow conditions (<4 m³ s^?1/<Q₇₀), when upstream alkalinity was already buffered owing to headwater groundwater sources assuming dominance. The significant temporally and spatially dynamic influence of these groundwater–surface‐water interactions was therefore seen to have important implications for both catchment functioning and instream ecology. Copyright © 2004 John Wiley & Sons, Ltd.