Formation Conditions and Distribution Regularities of Oil—gas Pools in Tertiary Volcanic Rocks in Western Huimin Depression,Shandong Province

The formation conditions and distribution regularities of oil-gas pools in volcanic rocks in western Huimin Depression have been studied in terms of geolgic,sesmic and well logging information,This paper discusses the types and lithofacies,development and distribution of Tertiary volcanic rocks in the area.The results demonstrate that volcanic activity occurred mainly during the period from the Sha-4 stage to the Guantao episode,i.e.,before the oil-generating period(before the end of the Guantao episode and the Minghuazhen episode).The activity did not destroy oil and gas formation and accumulation,but was favourable for the concentration of organic matter and its conversion to hydrocarbons;besides,volcanic rocks can serve as reservoir rocks and cap rocks,playing a role very similar to that of a syndepositional anticline,The volcanic rocks are distributed near the margins of the oil-generating depression;there are many secondary interstices in the rocks,which are connected with each other.These are the leading conditions for the formation of oil-generating period and their self-sealing or good combination with other cap rocks are important factors for forming volcanic rock-hosted oil and gas pools.The oil-gas pools associated with volcanic rocks in western Huimin are mainly distributed around the deep oil-generating depression,in the central up lift or the high structural levels on the margins of the depression.In particular,the sites where several faults cross are usually locatons where hith-yielding oil-gas pools in volcanic rocks are concentrated.     

Helium and Argon Isotopic Composition of Cenozoic Alkali Basalts and Mantle-Derived Xenoliths from Kuandian, Liaoning Province, China

The noble gas isotopic composition and content data of 2 alkali basalts, 3 Iherzolite xenoliths and one clinopyroxene megacryst from the Kuandian region have confirmed the occurrence of a fractionation of noble gases during magmatism. Light noble gases such as He and Ne are high in mobility and appear to be incompatible as compared with heavy ones ( such as Kr and Xe). Therefore, light noble gases are abundant in volcanics, especially in the volcanics with bubbles; lherzolite xenoliths have relatively high heavy noble gases. The clinopyroxene megacryst has the lowest abundance of noble gases, probably due to its high P-T origin. Noble gas isotopic composition of the clinopyroxene megacryst reveals that the mantle source beneath the Kuandian area has an MORB-like reservoir with^3 He/^4He ratio of—10 Ra(Ra: atmospheric^3 He/^4He ratio) and^40 Ar/^36 Ar ratio of 345.6. The Iherzolite xenoliths possess moderate^3 He/^4He ratios of 2.59 -4.53 Ra, reflecting the loss of primary helium during rock deformation or metasomatism caused by enriched mantle fluids during the up-lifting. The alkali volcanics have very low^3 He/^4 He ratios(0.47—0.61 Ra),indicating a contribution of radiogenic^4 He, probably having resulted from crust contamination. Most of the samples have excess^21 Ne and^22 Ne as compared with atmospheric neon, but Kr and Xe isotopic compositions are indistinguishable from atmospheric values within uncertainties with only individual samples having excess^129Xe,^134Xeand^136 Xe.     

Sr,Nd,Pb Isotope Geochemistry and Magma Evolution of the Potassic Volcanic Rocks,Wudalianchi,Northeast China

Wudalianchi volcanic rocks are the most typical Cenozoic potassic volcanic rocks in easten China.Compositional comparisons between whole rocks and glasses of various occurrences indicate that the magma tends to become rich in silica and alkalis as a result of crystal differentiation in the course of evolu-tion.They are unique in isotopic composition with more radiogenic Sr but less radiogenic Pb.^87Sr/^86Sr is higher and ^143Nd/^144Nd is lower than the undifferentiated global values.In comparison to continental pot-ash volcanic rocks,Pb isotopes are apparently lower.These various threads of evidence indicate that the rocks were derived from a primary enriched mantle which had not been subjected to reworking and shows no sign of incorporation of crustal material.The correlation between Pb and Sr suggests the regional heterogeneity in the upper mantle in terms of chemical composition.     

Mesozoic Bimodal Volcanic Suite in Zhalantun of the Da Hinggan Range and Its Geological Significance： Zircon U-Pb Age and Hf Isotopic Constraints

1 Introduction Mesozoic volcano-intrusive rocks are widely distributed in the Da Hinggan Range of northeastern China, and are considered as one of the most spectacular geological sights in eastern Asia. Recently, studies on granites with high εNd(t) values and Phanerozoic crustal growth in the Centra Asian Orogenic Belt have greatly promoted fundamental research into the geology of this area (Jahn et al., 2000, 2001, 2004; Wu et al., 2000, 2002, 2003). However, work on the eruption time,…     

Nd-Pb Isotopes of Basement Rocks, Granitoids and Basalts from the Western Margin of the Yangtze Craton. Implications for Crustal Evolution

INTRODUCTION TheYangtzecratonisoneofthemaingeotectonic blocksofChina'scontinent,connectingtheGanzi Song panblockwiththeLongmenMountainsinthewest Geologicalandtectonicstudieshaveshownthatthe basementoftheGanzi Songpanblockissimilartothe Yangtzecraton(Xuet…     

Rb—Sr Geochronology and Magma Source of the Mesozoic Fault—Granite Belt,East Shandong

Developed in the southeast coast of te East Shandong Peninsula,the Mesozoic fault-magma belt consists of five rock series:the syenite series;the monzonite series;the megaporphyritic monzogranite series;the biotite-granite series;and the alkali granite seres.Based on their Rb-Sr isochron ages(122-220Ma),these rock series may be divided into three magma subcycles dated at Triassic,Late Jurassic and Early Cretaceous.The initial ^87Sr/^86Sr ration in these rock series range from 0.70436 to 0.7155.The starting points of the Rb-Sr isochrons exhibit four different distribution trends on the(^87Sr/^86Sr)i-^87Rb/^86Sr diagram.These characteristics show that the multiple granitic rock series are different in genesis and derivation.The syenite series might be derived from the combination of mantle-derived magma and crustal material,and the others could be derived from granulite-facies and amphibilite-facies rocks in the deep crust.     

Isotope Geochemistry of the Dongchuan Copper Deposit,Yunnan,SW China： Stratigraphic Chronology and Application of Lead Isotopes in Geochemical Exploration

In this paper the Pb-Pb isochron method was used to determine the isotopic ages of the Luoxue Formation dolomites (1716 ±56 Ma), the Heishan Formation carbonaceous slates ( 1607 ±128 Ma) of the middle sub-group of the Kunyang Group and the Dayingpan Formation carbonaceous slates (1258 ±70Ma) of the upper sub-group of the Kunyang Group. The age of the middle sub-group of the Kunyang Group is about 1800 – 1600 Ma, belonging to the Late Paleo-Proterozoic, and that of the Dayingpan Formation in the upper sub-group of the Kunyang Group is about 1200 – 1300 Ma, belonging to the Middle Proterozoic. In addition, the Pb isotope chemical exploration techniques were used to study systematically the Pb isotopic compositions of rocks and ores across the No. 14 vein in the middle segment of the No. 1 pit of the Tangdan copper deposit and the result showed that the Pb isotope V₁ values are negatively correlated with the copper contents. It is the first trial to use the systematic section method to conduct Pb isotope chemical exploration. This research project was financially supported jointly by the National Natural Science Foundation of China (Grant Nos. 49702022, 40073001) and the State 973 Program (No.G1999043215).     

Cyclic Sequences, Events and Evolution of the Sino-Korean Plate, with a Discussion on the Evolution of Molar-tooth Carbonates, Phosphorites and Source Rocks

This paper gives an account of the research that the authors conducted on the cyclic sequences, events and evolutionary history from Proterozoic to Meso-Cenozoic in the Sino-Korean plate based on the principle of the Cosmos-Earth System. The authors divided this plate into 20 super-cyclic or super-mega-cyclic periods and more than 100 Oort periods. The research focused on important sea flooding events, uplift interruption events, tilting movement events, molar-tooth carbonate events, thermal events, polarity reversal events, karst events, volcanic explosion events and storm events, as well as types of resource areas and paleotectonic evolution. By means of the isochronous theory of the Cosmos-Earth System periodicity and based on long-excentricity and periodicity, the authors elaborately studied the paleogeographic evolution of the aulacogen of the Sino-Korean plate, the oolitic beach platform formation, the development of foreland basin and continental rift valley basin, and reconstructed the evolution     

Molar-tooth Carbonate Sequences and Sr Isotopes in the Neoproterozoic for Stratigraphic Correlation： Research in the JUin-Liaoning-Xuzhou-Huaiyang Area of the Sino-Korean Plate and Its Correlation with the Yangtze Plate

Based on a study of Neoproterozoic carbonates in the Jilin-Liaoning-Xuzhou-Huaiyang area, especially its cyclic sequence stratigraphy and Sr isotopes, two maximum sea flooding events (at 820 Ma and 835 Ma) have been identified. The resulting isochronous stratigraphic correlation proves that these Precambrian strata were connected between the Qingbaikou and the Nanhuan systems with a time range from 750 Ma to 850 Ma. The disappearance of microsparite carbonate and coming of a glacial stage offer important evidence for worldwide stratigraphic correlation and open a window for further correlation of the stratigraphic successions across the Sino-Korean and Yangtze Plates. A new correlation scheme is therefore provided based on our work.     

Age and Chemistry of Miocene Volcanic. Rocks from the Kiraz Basin of the Küçük Menderes Graben: Its Significance for the Extensional Tectonics of Southwestern Anatolia,Turkey'

Neogene volcanic rocks and granitoid plutons are among the most important geological components of western Turkey. Although they are voluminous north of the Gediz Graben, they are very scarce to the south, where volcanic rocks occur as isolated small exposures in a small number of localities. The Kiraz Basin of the Küçük Menderes Graben is a key locality, in which Tertiary volcanic rocks crop out at three locations. These rocks have been chemically analysed and dated (³⁹Ar-⁴⁰Ar whole rock and biotite analyses) in order to understand their tectonic setting of emplacement and its relation to the wider structure of western Anatolia. Whole rock and biotite ³⁹Ar-⁴⁰Ar ages vary between 13.9 ± 0.2 Ma and 14.6 ± 0.2 Ma.

The Kiraz volcanic rocks are calc-alkaline, with a compositional range from basaltic andesite to dacite. They are strongly enriched in the light ion lithophile elements (LILE) and have chemistries typical of lavas erupted in subduction-related settings. Their close association with rift-bounding faults suggests eruptions via conduits flanking grabens in an extensional environment. The difference in chemical composition and age between the Kiraz volcanic rocks and the slightly older calc-alkaline volcanic rocks north of the Gediz Graben is attributed to their relatively younger ages and greater proximity to the Aegean Arc. Their calc-alkaline chemistry reflects magma generation influenced by the slab descending beneath this arc and eruption/emplacement in an extensional setting.     

辽河盆地东部凹陷早第三纪火山岩地球化学及形成环境

中新生代频繁的岩浆活动是辽河盆地重要特征之一,东部凹陷作为各时期岩浆活动的中心,下第三系火山岩基本覆盖了整个凹陷。受构造运动差异影响,东部凹陷各地区不同时期岩浆活动强度不同,房身泡组火山岩分布最广,从沙三段到东营组沉积时期岩浆活动具有自中部向南、北转移的特征。岩石学和地球化学研究表明,主要火山熔岩类型为碱性玄武岩、粗面岩和辉绿玢岩;岩石化学组成上具有高碱、高铝和镁,较富集轻稀土元素,Eu异常不明显（δEu为0．70～1．05）,弱亏损Ti、P、Sr、Ta元素的特征。岩石εNd（t）和（N（^87Sr）／N（^86Sr））．组成分别为-2．8～2．8和0．7046～0．7067。综合研究表明,玄武质岩浆来源于岩石圈地幔,而粗面岩和辉绿玢岩可能源于幔源玄武质岩浆的分异,但辉绿岩受地壳物质污染较重;该火山岩形成于大陆裂谷环境,反映出早第三纪辽河盆地处于拉张构造背景。     

New Discovery of the Early Cretaceous Volcanic Rocks on the Barton Peninsula, King George Island,Antarctica and Its Geological Significance

Ages determined with the 40Ar/39Ar isotopic system affirms the Early Cretaceous volcanic activity in the Barton Peninsula, King George Island, Antarctica. Two specimens of basaltic andesite collected from the lowermost volcanic sequence of the peninsula were irradiated and analyzed in different experiments, yielding an identical age spectrum, and two magmatic thermal events of the Early Cretaceous (120.4± 1.6 Ma, 119± 1 Ma) and Early Tertiary (53.1± 1.5 Ma, 52± 1 Ma) are distinguished. The former is interpreted to represent the primary cooling age of basaltic andesite, whereas the latter is the thermal reset age caused by the intrusion of granitic pluton. These new ages clearly indicate that volcanism was active during the Early Cretaceous on the Barton Peninsula and that intensive hydrothermal alteration and mineralization of Mesozoic volcanic rocks resulted from Tertiary magmatism.     

西秦岭月照-琵琶寺地区火山岩地球化学特征及地质意义

月照-琵琶寺地区的变质火山岩出露于甘肃武都县境内,夹在泥盆系和前震旦碧口群地层之间.按地球化学分类,火山岩可划分为双峰式和碱性两个系列.双峰式火山岩系由低K富Na拉斑玄武岩和酸性英安岩、流纹岩组成.该玄武岩具有类似MORB的微量元素特征,平坦的稀土配分模式,但富Th贫Nb显示其受到陆壳混染的影响.该套火山岩总体特征指示其为大陆裂谷向成熟洋盆转化阶段的产物,从而推测本区火山岩可能为勉略古洋盆西延的分支产物.     

吉林省第三纪火山岩年代地层及构造环境

本文对吉林省第三纪年代地层、岩石地层、火山事件地层提出了新的划分方案。建立了15个火山事件地层序列。依据区域性地层角度不整合及构造岩浆活动的性质,划分出三个构造发展阶段。对比吉林省及邻区与日本列岛各阶段主要地质事件的特征,获得了第三纪的火山活动构造环境新认识：第一阶段（62～34Ma）总体上为挤压造山环境,由初期的弧后拉张转为后期的挤压,与太平洋板块的俯冲和斜冲地球动力学机制有关。第二阶段（34～5.2Ma）为拉张环境,受日本海盆的打开和演化直接控制。第三阶段（5.2～1.64Ma）为挤压抬升环境,对应着菲律宾海板块向日本岛弧下的俯冲。     

西天山备战铁矿火山岩地球化学特征、锆石U-Pb年代学及Hf同位素组成研究

备战铁矿是西天山阿吾拉勒成矿带新近发现的大型铁矿之一,矿区广泛发育下石炭统火山岩。本文对矿区火山岩进行了主量元素、微量元素、稀土元素地球化学特征分析、LA-ICP-MS锆石U-Pb测年以及锆石Lu-Hf同位素组成研究,以探讨矿区大哈拉军山组火山岩产出的构造环境、备战铁矿的成岩成矿时代和火山岩的来源。矿区火山岩主要由玄武岩、玄武安山岩、安山岩、流纹岩组成,以中基性岩为主,大多为高钾钙碱性系列;微量元素和稀土元素表明矿区火山岩产出构造环境为活动陆缘火山岛弧;锆石U-Pb测试结果显示矿区南部斜长花岗斑岩的形成时代为晚石炭世早期(301±0.93Ma),成矿时代为早石炭世晚期。结合地质背景认为该铁矿至少有两期成矿期,在成因上为火山沉积后期叠加矽卡岩化的磁铁矿矿床。锆石Lu-Hf同位素组成特征表明备战铁矿的岩石来源于元古代、太古代地壳物质的部分熔融,并且源区物质在地壳中存在较长的时间。     

山东沂水郯庐断裂带中段中生代火山岩特征及演化

山东沂水地区位于郯庐断裂带中段,中生代火山活动强烈。早期主要为一套高钾钙碱性系列的中型火山岩,年龄为110--125Ma,按安山岩K60估算的地壳厚度为58--62km,说明当时具造山岩石圈根,其代表的构造环境为活动大陆边缘。晚期为一套钾玄岩系列的中酸性火山岩及少量基性火山岩,年龄为69--101Ma,该期火山岩铕异常不明显,δEu=0.92（平均）,反映该期火山作用是在可能存在山根的条件下,在地幔岩石圈减薄、拉伸下形成的。郯庐断裂带内一套厚度达3200m的晚白垩世大盛群河湖相沉积岩,是造山带去根后地壳进一步拉张、伸展,在断陷盆地重兴冲冲的产物。     

内蒙古东升庙矿区变质火山岩的地质地球化学特征及其意义

为探讨东升庙矿区变质火山岩的地质地球化学特征及其意义,本文对其产出特征、岩石学、岩石化学、地球化学和同位素等方面进行了综合分析研究。结果表明,矿区变质火山岩为一套以玄武岩为主的双峰式火山岩,其原岩为基性的玄武岩和酸性的流纹岩。玄武岩属碱性玄武岩,流纹岩属钙碱性系列,它们具有与火山弧火山岩相似的地球化学特征。基性火山岩的稀土元素分配型式和Nd同位素特征表明其成岩物质来源于（亏损）地幔。构造环境分析表明,矿区变质火山岩的构造环境为大陆边缘火山弧造山带。     

鲁西临朐地区早白垩世青山群火山岩的年代学、地球化学及岩石成因

本文对鲁西临朐青山群火山岩进行了系统的年代学、元素地球化学和Sr-Nd-Hf同位素组成研究,据此探讨其岩石成因。临朐早白垩世青山群火山岩主要为一套中性岩(SiO2=52.43%~67.81%),岩石组合为安山岩-粗安岩-粗面岩-粗面英安岩,属于钙碱性岩类。锆石LA-ICP-MS U-Pb定年获得粗安岩的年龄为121.3±1.5 Ma,形成于早白垩世。岩石地球化学表现出富集轻稀土元素和Rb、Ba、K等大离子亲石元素,明显的亏损Nb、Ta、Ti等高场强元素的特征。临朐火山岩具有富集的Sr-Nd同位素特征,其(87Sr/86Sr)t值在0.704346~0.708656之间,εNd(t)值在-14.6~-9.2之间,并且具有低的Hf同位素组成,其锆石εHf(t)值在-29.3~-21.6。岩石具有与变基性岩熔融产生熔体相一致的Mg~#值,但镜下存在显著的矿物不平衡结构和变化范围较大的Cr(26.7×10~(-6)~239×10~(-6))和Ni(10×10~(-6)~69.7×10~(-6))含量。研究表明,临朐青山群火山岩形成于早白垩世伸展的构造背景下,是华北古老下地壳部分熔融熔体与富集地幔熔体发生岩浆混合形成的。     

西藏冈底斯地区早第三纪林子宗群火山岩地球化学特征及成因

西藏冈底斯地区广泛分布一套林子宗群(E1-2lz)的海陆交互相和陆相、以安山岩为主的火山岩。伴生的侵入岩为石英二长岩—花岗岩系列岩石。岩石地球化学研究表明,区内火山岩呈较好的钙碱性演化趋势。其FeO/MgO值＞20,K2O/Na2O＞06,K2O含量在138以上;微量分析结果表明,其含量具高钾火山岩特征;稀土配分呈右倾型,具明显的Eu负异常,同位素年龄在382～638 Ma之间。综合以上特征认为该火山岩是陆陆碰撞造山作用中大陆边缘火山活动的产物。     

鲁东胶莱盆地青山组火山岩的^40Ar—^39Ar定年——以五莲分岭山火山机构为例

以五莲分岭山火山机构为例，运用高精度的^40Ar－^39Ar定年技术，对胶莱盆地青山组火山岩的形成年龄进行了精确测定。结果表明。青山组第一旋回中偏碱性富钾火山岩的形成年龄为109．9±0．6Ma，第二旋回酸性流纹质火山岩形成年龄为108．2±0．6Ma，据此确定胶莱盆地青山组火山岩应为早白垩世岩浆活动的产物。根据该组火山岩在空间上具有自西向东年龄渐新的演变趋势，表明中生代伊泽奈崎板块向欧亚板块碰撞俯冲应是制约区内火山活动的主要动力因素。