The geothermal regime of the northern Yukon and Mackenzie delta regions of northwest Canada — studies of two regional profiles

Temperature data from deep petroleum exploration wells and thermal conductivity estimates based on net rock analysis data have been used to make terrestrial heat flow estimates along two profiles across the sedimentary strata of the Mackenzie Delta, northern Yukon, and offshore Beaufort Sea regions.Both profiles exhibit low heat flow values that range from 34 mWm^–2 to 58 mWm^–2, and little change occurs over large distances in the continental part of the area. Low heat flow values (<40 mWm^–2) occur in the Beaufort-Mackenzie Basin and Rapid Depression, both of which are areas of thick successions of Cretacecus and Tertiary clastic sedimentary strata. High heat flow values of almost 80 mWm^–2 occur to the south in the Taiga Nahoni Foldbelt and values as high as 60 mWm^–2 are indicated along the Aklavik Arch Complex, northeast of Aklavik.The regional variations of effective thermal conductivity are insufficient to account for the heat flow variations along the profiles, and so these may indicate deep radiogenic or other heat sources.     

Two heat flow profiles across the Atlantic Ocean

Measurements of the terrestrial heat flux at 76 localities along 2 profiles across the Mid-Atlantic Ridge at 19.5°N and 8.5°S latitude are presented. Two high heat-flow values were measured 800 to 1000 km east of the ridge crest at 8.5°S, but no high values were found at the ridge crest at this latitude. Detailed surveys and heat-flow measurements near the ridge crests on both profiles indicate that bottom topography influences the heat-flow variability. The average heat flow on both profiles, about 1.4 to 1.5 × 10⁻⁶ cal/cm² sec, is close to the average for other ocean basins, in contrast to previous studies indicating lower heat flow for the Atlantic.     

Terrestrial heat flow from project CESAR, Alpha Ridge, Arctic Ocean

During two months in spring, 1983, a multidisciplinary study, project CESAR, was undertaken from the sea ice across the eastern Alpha Ridge, Arctic Ocean. In the geothermal program, 10 gradiometer profiles were obtained; 63 determinations of in situ sediment thermal conductivity were obtained with the same probe, and 714 measurements of conductivity using the needle probe method were obtained on nearby core.Weighted means of the thermal conductivity of the sediment are 1.26 W/mK (in situ) and 1.34 W/mK (core), consistent with the compacted sediment encountered across the ridge and with the lithology. Calculated terrestrial heat flow values, corrected for the regional topography, range from 37 to 72 mWm⁻²; the average is 56+/−8 mWm⁻².Some temperature and heat flow versus depth profiles exhibit non-linearities that can be explained by physically reasonable (but otherwise unsubstantiated) variations in bottom water temperatures preceding the measurements; models are hypothesized that reduce the curvatures. Two heat flow values considerably higher than others in the area may be explained by higher bottom water temperature over several years, while the low value is consistent with a recent deposition from a slump. This hypothetical modelling reduces the scatter of heat flows and reduces the average to 53+/−6 mWm⁻².The CESAR heat flow is somewhat greater than expected for a purely continental fragment but is consistent with crust of oceanic origin. The heat flow is similar to values obtained in Cretaceous back-arc basins. Based on the oceanic heat flow-age relationship, the heat flow constrains the age of the ridge to 60–120 million years. The heat flow observed on other aseismic features in the world's oceans suggests that the Alpha Ridge has experienced no significant tectono-thermal event in the last 100 million years.     

Temperature modelling along the Taratashskiy profile crossing the ural mountains

Summary The temperature-depth distribution was calculated to a depth of 70 km along the 520 km long Taratashskiy refraction profile crossing the Ural Mts., approximately along latitude 56°N. The steady-state model was solved numerically using the finite-difference method, the vertical distribution of heat production was derived from the observed seismic velocities. It was shown that at the Moho boundary, the mantle heat flow varied between 10 and 25 mWm^–2, and the Moho temperature amounted to 300–550°C for the two versions studied.     

Drifter observations of the Hebrides slope current and nearby circulation patterns

The mean flow at and around the Hebrides and Shetland Shelf slope is measured with ARGOS tracked drifters. Forty-two drifters drogued at 50 m were deployed in three circles over the Hebrides slope at 56.15°N in two releases, one on 5th December, 1995 and the second on 5–9th May, 1996. The circles span a distance of some 20 km from water depths of 200 m to 1200 m. Drifters are initially advected poleward along-slope by the Hebrides slope current at between 0.05 and 0.70 m s^–1 in a laterally constrained (25–50 km wide) jet-like flow. Drifters released in winter remained in the slope current for over 2000 km whilst summer drifters were lost from the slope current beyond the Wyville-Thomson Ridge, a major topographic feature at 60°N. Dispersion from the slope region into deeper waters occurs at bathymetric irregularities, particularly at the Anton Dohrn Seamount close to which the slope current is found to bifurcate, both in summer and winter, and at the Wyville-Thomson Ridge where drifters move into the Faeroe Shetland Channel. Dispersion onto the continental shelf occurs sporadically along the Hebrides slope. The initial dispersion around the Hebrides slope is remarkably sensitive to initial position, most of the drifters released in shallower water moving onto the shelf, whilst those in 1000 m or more are mostly carried away from the slope into deeper water near the Anton Dohrn Seamount. The dispersion coefficients estimated in directions parallel and normal to the local direction of the 500 m contour, approximately the position of the slope current core, are approximately 8.8 × 10³ m² s^–1 and 0.36 × 10³ m² s^–1, respectively, during winter, and 11.4 × 10³ m² s^–1 and 0.36 x 10³ m² s^–1, respectively, during summer. At the slope there is a minimum in across-slope mean velocity, Reynolds stress, and across-slope eddy correlations. The mean across-slope velocity associated with mass flux is about 4 × 10^–3 m s^–1 shelfward across the shelf break during winter and 2 × 10^–3 m s^–1 during summer. The drifters also sampled local patterns of circulation, and indicate that the source of water for the seasonal Fair Isle and East Shetland currents are the same, and drawn from Atlantic overflows at the Hebrides shelf.     

Chemical geothermometry and fluid–mineral equilibria for the Ömer–Gecek thermal waters, Afyon area, Turkey

Thermal waters of the Ömer–Gecek geothermal field, Turkey, with temperatures ranging from 32 to 92°C vary in chemical composition and TDS contents. They are generally enriched in Na–Cl–HCO₃ and suggest deep water circulation. Silica and cation geothermometers applied to the Ömer–Gecek thermal waters yield reservoir temperatures of 75–155°C. The enthalpy–chloride mixing model, which approximates a reservoir temperature of 125°C for the Ömer–Gecek field, accounts for the diversity in the chemical composition and temperature of the waters by a combination of processes including boiling and conductive cooling of deep thermal water and mixing of the deep thermal water with cold water. It is also determined that the solubility of silica in most of the waters is controlled by the chalcedony phase. Equilibrium states of the Ömer–Gecek thermal waters studied by means of the Na–K–Mg triangular diagram, Na–K–Mg–Ca diagram, K–Mg–Ca geoindicator diagram, activity diagrams in the systems composed of Na₂O–CaO–K₂O–Al₂O₃–SiO₂–CO₂–H₂O phases, log SI diagrams, and finally the alteration mineralogy indicate that most of the spring and low-temperature well waters in the area can be classified as shallow or mixed waters which are likely to be equilibrated with calcite, chalcedony and kaolinite at predicted temperature ranges similar to those calculated from the chemical geothermometers. It was also observed that mineral equilibrium in the Ömer–Gecek waters is largely controlled by CO₂ concentrations.     

The hydrothermal system of Volcan Puracé, Colombia

This paper presents chemical and isotopic data for thermal waters, gases and S deposits from Volcan Puracé (summit elevation 4600 m) in SW Colombia. Hot gas discharges from fumaroles in and around the summit crater, and thermal waters discharge from three areas on its flanks. The waters from all areas have D values of-75±1, indicating a single recharge area at high elevation on the volcano. Aircorrected values of³He/⁴He in thermal waters range from 3.8 to 6.7 R_A, and approach those for crater fumarole gas (6.1–7.1 R_A), indicating widespread addition of magmatic volatiles. An economic S deposit (El Vinagre) is being mined in the Rio Vinagre fault zone at 3600 m elevation. Sulfur isotopic data are consistent with a magmatic origin for S species in thermal waters and gases, and for the S ore deposit. Isotopic equilibration between S species may have occurred at 220±40°C, which overlaps possible equilibration temperatures (170±40°C) determined by a variety of other geothermometers for neutral thermal waters. Apparent CH₄–CO₂ equilibration temperatures for gases from thermal springs (400±50°C) and crater fumaroles (520±60°C) reflect higher temperatures deeper in the system. Hot magmatic gas ascending through the Rio Vinagre fault zone is though to have precipitated S and generated thermal waters by interaction with descending meteoric waters.     

Geochemistry of the magmatic–hydrothermal system of Kawah Ijen volcano, East Java, Indonesia

Samples from Kawah Ijen crater lake, spring and fumarole discharges were collected between 1990 and 1996 for chemical and isotopic analysis. An extremely low pH (<0.3) lake contains SO₄–Cl waters produced during absorption of magmatic volatiles into shallow ground water. The acidic waters dissolve the rock isochemically to produce “immature” solutions. The strong D and ¹⁸O enrichment of the lake is mainly due to enhanced evaporation at elevated temperature, but involvement of a magmatic component with heavy isotopic ratios also modifies the lake D and ¹⁸O content. The large Δ_SO4–S⁰ (23.8–26.4‰) measured in the lake suggest that dissolved SO₄ forms during disproportionation of magmatic SO₂ in the hydrothermal conduit at temperatures of 250280°C. The lake δ¹⁸O_SO4 and δ¹⁸O_H2O values may reflect equilibration during subsurface circulation of the water at temperatures near 150°C. Significant variations in the lake's bulk composition from 1990 to 1996 were not detected. However, we interpret a change in the distribution and concentration of polythionate species in 1996 as a result of increased SO₂-rich gas input to the lake system.Thermal springs at Kawah Ijen consist of acidic SO₄–Cl waters on the lakeshore and neutral pH HCO₃–SO₄–Cl–Na waters in Blawan village, 17 km from the crater. The cation contents of these discharges are diluted compared to the crater lake but still do not represent equilibrium with the rock. The SO₄/Cl ratios and water and sulfur isotopic compositions support the idea that these springs are mixtures of summit acidic SO₄–Cl water and ground water.The lakeshore fumarole discharges (T=170245°C) have both a magmatic and a hydrothermal component and are supersaturated with respect to elemental sulfur. The apparent equilibrium temperature of the gas is 260°C. The proportions of the oxidized, SO₂-dominated magmatic vapor and of the reduced, H₂S-dominated hydrothermal vapor in the fumaroles varied between 1979 and 1996. This may be the result of interaction of SO₂-bearing magmatic vapors with the summit acidic hydrothermal reservoir. This idea is supported by the lower H₂S/SO₂ ratio deduced for the gas producing the SO₄–Cl reservoir feeding the lake compared with that observed in the subaerial gas discharges. The condensing gas may have equilibrated in a liquid–vapor zone at about 350°C.Elemental sulfur occurs in the crater lake environment as banded sediments exposed on the lakeshore and as a subaqueous molten body on the crater floor. The sediments were precipitated in the past during inorganic oxidation of H₂S in the lake water. This process was not continuous, but was interrupted by periods of massive silica (poorly crystallized) precipitation, similar to the present-day lake conditions. We suggest that the factor controlling the type of deposition is related to whether H₂S- or silica-rich volcanic discharges enter the lake. This could depend on the efficiency with which the lake water circulates in the hydrothermal cell beneath the crater. Quenched liquid sulfur products show δ³⁴S values similar to those found in the banded deposits, suggesting that the subaqueous molten body simply consists of melted sediments previously accumulated at the lake bottom.     

Determination of the Geopotential Scale Factor from TOPEX/POSEIDON Satellite Altimetry

The geopotential scale factor R _o = GM/W _o (the GM geocentric gravitational constant adopted) and/or geoidal potential Wo have been determined on the basis of the first year's (Oct 92 – Dec 93) ERS-1/TOPEX/POSEIDON altimeter data and of the POCM 4B sea surface topography model: R _o °=(6 363 672.58°±0.05) m, W _o °=(62 636 855.8°±0.05)m ² s ^–2 . The 2°–°3 cm uncertainty in the altimeter calibration limits the actual accuracy of the solution. Monitoring dW _o /dt has been projected.     

Landsat Thematic Mapper observations of debris avalanche deposits in the Central Andes

Remote sensing studies of the Central Andean volcanic province between 18°–27°S with the Landsat Thematic Mapper have revealed the presence of 28 previously undescribed breached volcanic cones and 14 major volcanic debris avalanche deposits, of which only 3 had previously been identified. Several of the debris avalanche deposits cover areas in excess of 100 km² and have volumes of the order of 10 km³. H/L ratios for the deposits have a median of 0.1 and a mean of 0.11, values similar to those determined for deposits described in other regions. Surface morphologies commonly include the hummocky topography of small hillocks and enclosed basins that is typical of avalanche deposits, but some examples exhibit smoother surfaces characterised by longitudinal grooves and ridges. These differences may result from the effects of flow confinement by topography or from variations in resistance to shearing in the materials involved. Breached composite cones and debris avalanche deposits tend to occur at right angles to regional tectonic elements, suggesting possible seismic involvement in triggering collapse and providing an additional consideration for assessment of areas at risk from collapse. The low denudation rate in the Central Andes, coupled with the predominance of viscous dacite lavas in volcanic edifices, produces unusually steep cones which may result in a higher incidence of volcano collapse than in other regions. A statistical survey of 578 composite volcanoes in the study area indicates that a majority of cones which achieve edifice heights between 2000–3000 m may undergo sector collapse.     

Evaluation of gases,condensates, and SO2 emissions from Augustine volcano,Alaska: the degassing of a Cl-rich volcanic system

After the March–April 1986 explosive eruption a comprehensive gas study at Augustine was undertaken in the summers of 1986 and 1987. Airborne COSPEC measurements indicate that passive SO₂ emission rates declined exponentially during this period from 380±45 metric tons/day (T/D) on 7/24/86 to 27±6 T/D on 8/24/87. These data are consistent with the hypothesis that the Augustine magma reservoir has become more degassed as volcanic activity decreased after the spring 1986 eruption. Gas samples collected in 1987 from an 870°C fumarole on the andesitic lava dome show various degrees of disequilibrium due to oxidation of reduced gas species and condensation (and loss) of H₂O in the intake tube of the sampling apparatus. Thermochemical restoration of the data permits removal of these effects to infer an equilibrium composition of the gases. Although not conclusive, this restoration is consistent with the idea that the gases were in equilibrium at 870°C with an oxygen fugacity near the Ni–NiO buffer. These restored gas compositions show that, relative to other convergent plate volcanoes, the Augustine gases are very HCl rich (5.3–6.0 mol% HCl), S rich (7.1 mol% total S), and H₂O poor (83.9–84.8 mol% H₂O). Values of D and ¹⁸O suggest that the H₂O in the dome gases is a mixture of primary magmatic water (PMW) and local seawater. Part of the Cl in the Augustine volcanic gases probably comes from this shallow seawater source. Additional Cl may come from subducted oceanic crust because data by Johnston (1978) show that Cl-rich glass inclusions in olivine crystals contain hornblende, which is evidence for a deep source (>25km) for part of the Cl. Gas samples collected in 1986 from 390°–642°C fumaroles on a ramp surrounding the inner summit crater have been oxidized so severely that restoration to an equilibrium composition is not possible. H and O isotope data suggest that these gases are variable mixtures of seawater, FMW, and meteoric steam. These samples are much more H₂O-rich (92%–97% H₂O) than the dome gases, possibly due to a larger meteoric steam component. The 1986 samples also have higher Cl/S, S/C, and F/Cl ratios, which imply that the magmatic component in these gases is from the more degassed 1976 magma. Thus, the 1987 samples from the lava dome are better indicators than the 1986 samples of degassing within the Augustine magma reservoir, even though they were collected a year later and contain a significant seawater component. Future gas studies at Augustine should emphasize fumaroles on active lava domes. Condensates collected from the same lava-dome fumarole have enrichments ot 10⁷–10² in Cl, Br, F, B, Cd, As, S, Bi, Pb, Sb, Mo, Zn, Cu, K, Li, Na, Si, and Ni. Lower-temperature (200°–650°C) fumaroles around the volcano are generally less enriched in highly volatile elements. However, these lower-termperature fumaroles have higher concentration of rock-forming elements, probably derived from the wall rock.     

A fracture mechanics study of subcritical tensile cracking of quartz in wet environments

Load relaxation and cross-head displacement rate-change experiments have been used to establish log₁₀ stress intensity factor (K) versus log₁₀ crack velocity (v) diagrams for double torsion specimens, of synthetic quartz cracked on thea plane in liquid water and moist air.For crack propagation normal toz and normal tor at 20°C,K _Ic (the critical stress intensity factor) was found to be 0.852±0.045 MN·m^–3/2 and 1.002±0.048 MN·m^–3/2, respectively.Subcritical crack growth at velocities from 10^–3 m·s^–1 to 10^–9 m·s^–1 at temperatures from 20°C to 80°C is believed to be facilitated by chemical reaction between the siloxane bonds of the quartz and the water or water vapour of the environment (stress corrosion). The slopes, of isotherms in theK-v diagrams are dependent upon crystallographic orientation. The isotherms have a slope of 12±0.6 for cracking normal tor and 19.9±1.7 for cracking normal toz. The activation enthalpy for crack propagation in the former orientation in liquid water at temperatures from 20°C to 80°C is 52.5±3.8 kJ·mole^–1.A discussion is presented of the characteristics of theK-v diagrams for quartz.     

Rupture process of the 19 August 1992 Susamyr, Kyrgyzstan, earthquake

The Susamyr earthquake of August 19, 1992 in Kyrgyzstan is one of the largest events (M_s = 7.4, M_b = 6.8) of this century in this region of Central Asia. We used broadband and long period digital data from IRIS and GEOSCOPE networks to investigate the source parameters, and their space-time distribution by modeling both body and surface waves. The seismic moment (M₀ = 6.8 × 10¹⁹ N m) and the focal mechanism were determined from frequency-time analysis (FTAN) of the fundamental mode of long period surface waves (100–250 s). Then, the second order integral moments of the moment-rate release were estimated from the amplitude spectra of intermediate period surface waves(40–70 s). From these moments we determined a source duration of 11–13 s, major and minor axes of the source of 30 km and 10–22 km, respectively; and an instant centroid velocity of 1.2 km/s. Finally, we performed a waveform inversion of P and SH waves at periods from 5–60 s. We found a source duration of 18–20 s, longer than the integral estimate from surface wave amplitudes. All the other focal parameters inverted from body waves are similar to those obtained by surface waves ( = 87° ± 6°, = 49° ± 6°, = 105° ± 3°, h = 14 ± 2 km, and M₀ = 5.8 ± 0.7 × 10¹⁹ N m). The initial rupture of this shallow earthquake was located at the south-west border of Susamyr depression in the western part of northern Tien Shan. A finite source analysis along the strike suggests a westward propagation of the rupture. The main shock of this event was preceded 2 s earlier by small foreshock. The main event was almost immediately followed by a very strong series of aftershocks. Our surface and body wave inversion results agree with the general seismotectonic features of the region.     

The solubility of iron sulphides in synthetic and natural waters at ambient temperature

A critical evaluation of literature values for the solubility products, K _sp ^NBS = [Fe²⁺][HS^–] Fe²⁺ HS^– (H _NBS ⁺ )^–1, of various iron sulphide phases results in consensus values for the pKs of 2.95 ± 0.1 for amorphous ferrous sulphide, 3.6 ± 0.2 for mackinawite, 4.4 ± 0.1 for greigite, 5.1 ± 0.1 for pyrrhotite, 5.25 ± 0.2 for troilite and 16.4 ± 1.2 for pyrite.Where the analogous ion activity products have been measured in anoxic freshwaters in which there is evidence for the presence of solid phase FeS, the values lie within the range of 2.6–3.22, indicating that amorphous iron sulphide is the controlling phase. The single value for a groundwater of 2.65 (2.98 considering carbonate complexation) agrees. In seawater four values range between 3.85 to 4.2, indicating that mackinawite or greigite may be the controlling phase. The single low value of 2.94 is in a situation where particularly high fluxes of Fe (II) and S (–II) may result in the preferential precipitation of amorphous iron sulphide. Formation of framboidal pyrite in these sulphidic environments may occur in micro-niches and does not appear to influence bulk concentrations. Calculations show that the formation of Fe₂S₂ species probably accounts for very little of the iron or sulphide in most natural waters. Previously reported stability constants for the formation of Fe (HS)₂ and (Fe (HS)₃)^– are shown to be suspect, and these species are also thought to be negligible in natural waters. In completely anoxic pore waters polysulphides also have a negligible effect on speciation, but in tidal sediments they may reach appreciable concentrations and lead to the direct formation of pyrite. Concentrations of iron and sulphide in pore waters can be controlled by the more soluble iron sulphide phase. The change in the IAP with depth within the sediment may reflect ageing of the solid phase or a greater flux of Fe (II) and S (–II) nearer the sediment surface. This possible kinetic influence on the value of IAPs has implications for their use in geochemical studies involving phase formation.     

Effect of displacement rate on the real area of contact and temperatures generated during frictional sliding of Tennessee sandstone

Summary The real area of contact has been determined, and measurements of the maximum and average surface temperatures generated during frictional sliding along precut surfaces in Tennessee sand-stone have been made, through the use of thermodyes. Triaxial tests have been made at 50 MPa confining pressure and constant displacement rates of 10^–2 to 10^–6 cm/sec, and displacements up to 0.4 om. At 0.2 cm of stable sliding, the maximum temperature decreases with decreasing nominal displacement rate from between 1150° to 1175°C at 10^–2 cm/sec to between 75° to 115°C at 10^–3 cm/sec. The average temperature of the surface is between 75 and 115°C at 10^–2 cm/sec, but shows no rise from room temperature at 10^–3 cm/sec. At 0.4 cm displacement, and in the stick-slip mode, as the nominal displacement rate decreases from 10^–3 to 10^–6 cm/sec, the maximum temperature decreases from between 1120° to 1150°C to between 1040° to 1065°C. The average surface temperature is 115° to 135°C at displacement rates from 2.6×10^–3 to 10^–4 cm/sec.With a decrease in the displacement rate from 10^–2 to 10^–6 cm/sec, the real area of contact increases from about 5 to 14 percent of the apparent area; the avergge area of asperity contact increases from 2.5 to 7.5×10^–4 cm². Although fracture is the dominate mechanism during stick-up thermal softening and creep may also contribute to the unstable sliding process.     

Untersuchung der CO2-Konzentration im Tropopausenniveau

Zusammenfassung Zwischen 50° bis 85°N Breite wurde die atmosphärische CO₂-Konzentration während mehrerer Messflüge registriert. Diese war oberhalb der Tropopause bis zu 7 ppm (im Mittel etwa 2 ppm) niedriger als in der oberen Troposphäre. Im Jahresmittel entspricht diese CO₂-Konzentrationsdifferenz einem Fluss von etwa 10^–2 g CO₂/cm² Jahr aus der nördlichen Troposphäre in die Stratosphäre. Die Bedeutung dieser CO₂-Konzentrationsunterschiede für den atmosphärischen CO₂-Haushalt sowie für die Strahlungsbilanz im Tropopausenniveau kann erst nach Vorlage weiterer, über das ganze Jahr verteilter Messdaten erfolgen.

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Summary CO₂-concentration was measured during several flights in northern latitudes (50°–85°). Above Tropopause CO₂-concentration was up to 7 ppm (as a mean some 2 ppm) smaller than in upper troposphere. As a mean this difference in CO₂-concentration cm² year conforms to a CO₂-flux of some 10^–2 g CO₂/cm² year from northern troposphere into stratosphere. The importance of these CO₂-differences for atmospheric CO₂-system and for radiation balance in tropopause-height may be considered as soon as more CO₂-concentration data for the whole year are available.

     

The Nevados de Payachata volcanic region (18°S/69°W,N. Chile)

Subduction-related volcanism in the Nevados de Payachata region of the Central Andes at 18°S comprises two temporally and geochemically distinct phases. An older period of magmatism is represented by glaciated stratocones and ignimbrite sheets of late Miocene age. The Pleistocene to Recent phase (0.3 Ma) includes the twin stratovolcanoes Volcan Pomerape and Volcan Parinacota (the Nevados de Payachata volcanic group) and two small centers to the west (i. e., Caquena and Vilacollo). Both stratovolcanoes consist of an older dome-and-flow series capped by an andesitic cone. The younger cone, i. e., V. Parinacota, suffered a postglacial cone collapse producing a widespread debris-avalanche deposit. Subsequently, the cone reformed during a brief, second volcanic episode. A number of small, relatively mafic, satellitic cinder cones and associated flows were produced during the most recent activity at V. Parinacota. At the older cone, i. e., V. Pomerape, an early dome sequence with an overlying isolated mafic spatter cone and the cone-forming andesitic-dacitic phase (mostly flows) have been recognized. The two Nevados de Payachata stratovolcanoes display continuous major- and trace-element trends from high-K₂O basaltic andesites through rhyolites (53%–76% SiO₂) that are well defined and distinct from those of the older volcanic centers. Petrography, chemical composition, and eruptive styles at V. Parinacota differ between pre- and post-debris-avalanche lavas. Precollapse flows have abundant amphibole (at SiO₂ > 59 wt%) and lower Mg numbers than postcollapse lavas, which are generally less silicic and more restricted in composition. Compositional variations indicate that the magmas of the Nevados de Payachata volcanic group evolved through a combination of fractional crystallization, crustal assimilation, and intratrend magma mixing. Isotope compositions exhibit only minor variations. Pb-isotope ratios are relatively low (²⁰⁶Pb/²⁰⁴Pb = 17.95–18.20 and²⁰⁸Pb/²⁰⁴Pb = 38.2–38.5);⁸⁷Sr/⁸⁶Sr ratios range 0.70612–0.70707,¹⁴³Nd/¹⁴⁴Nd ratios range 0.51238–0.51230, and ¹⁸O_SMOW values range from + 6.8%_o to + 7.6%_o SMOW. A comparison with other Central Volcanic Zone centers shows that the Nevados de Payachata magmas are unusually rich in Ba (up to 1800 ppm) and Sr (up to 1700 ppm) and thus represent an unusual chemical signature in the Andean arc. These chemical and isotope variations suggest a complex petrogenetic evolution involving at least three distinct components. Primary mantle-derived melts, which are similar to those generated by subduction processes throughout the Andean arc, are modified by deep crustal interactions to produce magmas that are parental to those erupted at the surface. These magmas subsequently evolve at shallower levels through assimilation-crystallization processes involving upper crust and intratrend magma mixing which in both cases were restricted to end members of low isotopic contrast.     

Gas phase spectra of HOBr and Br2O and their atmospheric significance

The HOBr molecule is a potential reservoir of Br compounds in the atmosphere. In this work, the UV-visible spectrum of HOBr was measured over the range 242–400 nm. Its absorption consists of two maxima at 280 nm (_max=2.7±0.4×10^-19 cm² molecules⁻¹) and 355 nm (_max=7.0±1.1×10^-20 cm² molecules⁻¹), respectively, where the error is ±1. Atmospheric photolysis lifetime calculations for HOBr in the lower stratosphere have been made using the PHOTOGT model. The results show a strong dependence on the solar zenith angle (SZA) implying a longer lifetime at high latitudes and a relatively short lifetime at low latitudes for example 714 s (albedo of 25%, SZA of 20^° and an altitude of 17 km), and 3226 s (albedo of 25%, SZA of 88^° and an altitude of 17 km). The UV-visible absorption spectrum of Br₂O, which is an intermediate in the preparation, used in this study and is together with H₂O in equilibrium with HOBr, was measured from 205 to 450 nm. The spectrum shows a maximum at 315 nm (_max=2.3±0.3×10^-18 cm² molecules⁻¹) with a shoulder at 355 nm. From the results of the atmospheric lifetime calculations for Br₂O, it is clear that this molecule has a short stratospheric lifetime and is not likely to have a large daytime concentration, for example, 20 s (albedo of 25%, SZA of 20^° and an altitude of 17 km), and 83 s (albedo and 25%, SZA of 88^° and an altitude of 17 km).     

Magnetic properties,self-reversal remanence and thermal alteration products of smythite

Summary This study is a follow up of the investigation of some magnetic properties and metastability of greigite in samples obtained from Miocene claystones in the Kruné hory (Erzgebirge) Piedmont basins (Bohemia). Three different methods of upgrading the smythite were applied; the magnetic properties of the concentrates are compared. The thermal conversion of smythite sets in at 200°C while greigite converts at 250°C. The first intermediate products to be formed are iron sulphides, marcasite clearly dominating over pyrite and pyrrhotite. Apart from a Fe³⁺ sulphate with a composition of Fe₂(SO₄)₃, oxidation of these sulphides gives rise to -Fe₂O₃. The result of the subsequent decomposition of the mentioned sulphate is the formation of -Fe₂O₃, which retains the sulphate structure. The final product of the thermal decomposition at 800°C is -Fe₂O₃. In the smythite concentrate the conversion to Fe³⁺ sulphate and -Fe₂O₃ is about twice as intensive as in greigite. No direct conversion to -Fe₂O₃ was found. During the thermal process self-reversals of remanence were observed, in various samples as many as four reversals in the temperature interval from 340 to 590°C. The occurrences of self-reversals of remanence were only observed at high degrees of thermal demagnetization, of the order of 10^–2 down to 10^–3 in the temperature interval of sulphide origin (below 400°C), and of the order of 10^–4 down to 10^–6 in the temperature interval of Fe-oxides origin (above 400°C).Presented at the 3rd Conference on New Trends in Geomagnetism, Castle of Smolenice, Czechoslovakia, June 22–29, 1992     

Water-saturated oceanic lavas from the Manus Basin: volatile behaviour during assimilation–fractional crystallisation–degassing (AFCD)

We have analysed volatiles (H₂O, He, Ar, CO₂) in differentiated (basaltic andesite, dacite) volcanic glasses dredged at a depth of ca. 2000 m in the eastern part of the Manus Basin between 151°20′ and 152°10′ E. These samples have Sr–O–B isotopic ratios that show that they most likely represent lavas evolved from a common magma source. Since these glasses are very fresh, they provide a unique opportunity to study the behaviour of magmatic volatiles during assimilation–fractional crystallisation–degassing (AFCD). The samples are highly vesicular (up to 18%) and the volatiles trapped in vesicles consist predominantly of H₂O with minor amounts of CO₂, and the concentration of water in the glasses indicates that H₂O saturation was attained. Rare gases except helium are atmospheric in origin, and the ³He/⁴He ratios and the CO₂/³He ratios are respectively lower and higher than those typical of Mid-Ocean Ridge Basalt (MORB), and appear to correlate with the degree of differentiation. AFCD allows efficient degassing of mantle-derived volatiles and contribution of crust-derived and atmosphere-derived volatiles. Given the widespread occurrence of differentiated magmatism at arcs, we suggest that AFCD is responsible for large-scale occurrence of ³He-rich crustal fluids and of atmospheric-like rare gases in arc emanations, and that most of the volatiles are lost continuously during fractional crystallisation, rather than catastrophically during eruptions.