Coring tips

This commentary is intended as a practical guide for the non-motorized use of piston corers to obtain undisturbed sections of lake sediments. Good recovery is essential for accurate reconstruction of environmental and limnological history. Emphasis is placed on the square-rod piston corer, which is widely used for acquisition of sediment cores in meter-long sections from lakes as much as 30 m deep. Coring platforms for open water can be easily prepared on pairs of boats or canoes or (in water depth up to 15 m) even a single small rubber raft, but firm anchoring is essenial to maintain the vertical position of the casing and to assure re-entry into a single hole. Incomplete recovery on individual drives is not a result of sediment compaction but rather the build-up of friction on the tube interior, by which the core forms a plug that prevents further recovery.Short cores of soft sediment for the study of recent changes in lakes are also best acquired with a piston corer, for a gravity corer without a piston may be subject to the same type of plug formation. In cases in which the structure of the sediment must be preserved (e.g. annual laminations), freezing the sediment in place with a dry-ice solution is the best procedure.     

A rod-less piston corer for lake sediments; an improved, rope-operated percussion corer

A lightweight, percussion corer, suitable for use in remote lakes of moderate depth, is described. The operation of the corer and suggestions for securing and transporting long sediment cores are presented. In particular, the design and use of a recovery pot, which allows the retrieval of undisturbed cores from sediments of unknown depth, is detailed.     

Controls on loss-on-ignition variation in cores from two shallow lakes in the northeastern United States

Loss-on-ignition analysis of Quaternary lake sediments provides an inexpensive and easy way to investigate past environmental changes. The mass loss on ignition at 550 °C (LOI) from lake sediment cores may vary because of temporal changes in: (1) sediment composition controlled by factors such as productivity, inorganic inputs, and decomposition; and (2) the patterns of sediment accumulation controlled by factors such as basin morphology and water level. Climatic changes can alter both. Here, modern surface samples and transects of sediment cores, collected across small (<10 ha), shallow (<4 m) lakes in the northeastern United States, show that LOI varies little (2–5%) across the deep portions of these small lakes at a given time. Large changes in LOI occur only at the transition into the littoral (shallow) zone. LOI variations in sediment cores that exceed 2–5%, therefore, appear to represent meaningful environmental changes. However, because of the many possible controls, changes in the LOI of a single core are often hard to interpret. Multiple cores increase the interpretability. At lakes studied here, similar LOI trends among several cores confirm that some LOI changes resulted from basin-wide shifts in sediment composition. Differences among cores, however, developed during the early- and mid-Holocene and indicate that the edge of the littoral zone moved towards the centers of the lakes during two periods of low lake levels, at ca. 11 000–8000 and ca. 5400–3000 cal yr B.P. The basin-wide balance of sediment sources controlled the LOI from deep-water sediments, but sedimentation patterns, which changed as lake levels changed, were also important. LOI differences among cores may therefore help identify past lake-level changes in other lakes.     

The spatial and temporal distribution of fossil-fuel dervied pollutants in the sediment record of Lake Baikal, east Siberia

Spatial and temporal patterns of spheroidal carbonaceous particles (SCP) extracted from lake sediments provide an unambiguous record of the distributions of fossil-fuel derived pollutants. When applied to sediment cores taken from Lake Baikal spatial patterns show good agreement with the distribution of industry, with the highest concentrations found in the southern basin nearest to Irkutsk. SCP were found to occur in all cores from all areas of the lake in contrast to metal results where anthropogenically enhanced deposition was only demonstrable in the southern basin. SCP distribution within the sediments of Lake Baikal is seen to be distinctly regional and therefore long distance transport is not thought to be an important pathway for these pollutants. Temporal patterns of SCP show trends that reflect the development of industry in the area since the 1940s. Settling rates in the 1600 m water column suggest that the SCP sediment record may be approximately an order of magnitude more sensitive to depositional changes than that of trace metals.     

A lake sediment record of Pb mining from Ullswater,English Lake District,UK

Lake sediments can be significantly impacted by industrial activities. These impacts vary among sites and include both local point sources and atmospherically-derived pollution. Here we present results of a lake sediment pollution record from Ullswater, UK, where lead mining activities have taken place within the catchment since 1690, although large-scale mining did not begin until 1840. Metal concentration data from 12 cores taken along a lake bed transect illustrate that lead mining at Greenside Mine had a significant impact on the lake sediments. High Pb concentrations were identified throughout Ullswater, and exhibited a spatial gradient from south to north, with concentrations decreasing with greater distance from the main source of input at Glenridding. Furthermore, inter-element correlations exhibit spatial variation that reflects the processes by which they are incorporated into the lake sediment record. Together, these observations illustrate potential shortcomings in palaeoenvironmental reconstructions and pollution studies based on single cores from large and morphologically variable lakes. Sedimentation rates were estimated by matching this pollution record with the historical record of mining activities. Within Ullswater, sedimentation rates from 1840 to the present varied from 0.67 to 2.33 mm year⁻¹ with a mean of 1.4 mm year⁻¹; highest sedimentation rates were observed in the deepest section of the lake and close to the main inputs, and lowest sedimentation rates were observed in the northern part of the lake, furthest from the main input. Despite the considerable changes in mining techniques and production, there is little evidence to suggest significant changes in sedimentation rates over time.     

Holocene sedimentation in Lake Winnipeg, Manitoba, Canada: implications of compositional and textural variations

Two seismic facies were recognized in the sedimentary sequence overlying acoustic basement in Lake Winnipeg. The upper facies, which overlies a regional unconformity, is termed the Lake Winnipeg Sequence. Based on the seismostratigraphy, lithostratigraphy, and radiocarbon dates of approximately 4000 and 7000 yr BP from material collected directly over the unconformity in the southern and northern parts of the lake, respectively, this facies has been interpreted as representing Holocene sedimentation. Results of compositional and textural analyses of the Holocene sediment (Winnipeg sediment) from thirteen long (>2 m) cores indicate a transgressional sequence throughout the basin. In the South Basin, the generally fining upward sequence is characterized at the base by silt-sized detrital carbonate minerals, quartz and feldspar which decrease in concentration upward. In this basin, the high carbonate content and V/Al and Zn/Al ratios are indicative of a Paleozoic and Cretaceous provenance for sediment derived from glacial deposits through shoreline erosion and fluvial transport, via the Red River. Sedimentation in the central part of the lake and the North Basin is attributed to shoreline erosion of sand and gravel beaches. Consequently, the texture of these sediments is generally coarser than in the South Basin, and the composition primarily reflects a Paleozoic and Precambrian provenance. The basin-wide decrease in Ca, total carbonate minerals, dolomite and calcite concentrations upward in the cores is reflected by a decrease in the detrital carbonate component in all but the most northern cores. Other basin-wide trends show an upward increase in organic content in all cores. An increase in grain size near the top of most cores suggests a major, basin-wide change in sedimentation within the last, approximately 900 years in the South Basin.     

Environmental History of Lago di Tovel,Trento, Italy,Revealed by Sediment Cores and 3.5 kHz Seismic Mapping

Proxy data from a total of 30 sediment cores and information from a seismic survey show that the sedimentological and limnological history of Lago di Tovel (1178 m a.s.l.) has been significantly influenced by slope dynamics of its mountainous catchment. The lake represents a dead-ice lake with pro-glacial deposits at the base of its sedimentary record. A prominent lake level rise in 1597/1598 that increased maximum water depth from ∼20 to 39 m caused slope instabilities, leading to the deposition of mass-flow sediments with a maximum thickness of 2.5 m in the northern part of the lake and less than 50 cm in the southern part, resulting in a total volume of more than 113,000 m³. Consequently, a rough lake bottom morphology was produced, which led to distinct differences in sedimentation rates of 0.07 cm yr⁻¹ on sills and 0.18 cm yr⁻¹ within depressions. The age of the top of the mass-flow deposits was used to validate the ages of the younger, laminated sediments, which were dated by ²¹⁰Pb and ¹³⁷Cs. Lithological investigations showed that the sediments below the mass-flow deposits are also laminated and that they were not bioturbated. The long-term meromixis of Lago di Tovel is therefore mainly due to a combination of its topographic setting and the 5-month period of ice cover. Both prevent effective mixing of the lake by strong winds during spring and autumn. Distinct spatial differences in sediment distribution within the lake show that it is risky to interpret proxy data from only one coring site, even if the lake is very small. This is especially true in mountainous areas, where rock falls, mass movements, and slope instabilities of a significant size may have considerable effects on lakes.     

Sediment chemistry and diatom stratigraphy of two high arctic isolation lakes,Truelove Lowland,Devon Island,N.W.T., Canada

Three sediment cores from two lakes, Fish Lake and Phalarope Lake, in Truelove Lowland, Devon Island, N.W.T. were analyzed for diatoms and chemical composition. Multivariate statistical techniques using a range of chemical variables successfully isolated three sediment groupings in the cores. Allochthonous and autochthonous chemical components in the sediments have been used to reconstruct paleoenvironmental conditions. The two lakes began approximately 10600 years ago as shallow marine lagoons that were isolated from the sea as a result of glacio-isostatic rebound. Based on the presence of distinctive diatom assemblages, the three stratigraphic zones are identified as a basal marine zone, an intermediate and transitional brackish/marine zone and an upper freshwater zone. Following isolation from the sea, the lakes were flushed with freshwater produced by snow and ice melt. In Fish Lake, the period of transition from marine to freshwater, which began approximately 7000 years ago, lasted approximately 800 years. In Phalarope Lake, which was isolated from the sea approximately 5000 years ago, flushing by fresh water was completed only within the last 300 years. Fe, Cr, and Mo in the sediments are associated with the isolation phase when lake sedimentation is sensitive to the presence of brackish water and erosion within the lake catchments. In particular, the precipitation of Mo as MoS₂ reflects the presence of hypolimnetic anoxia associated with lake isolation. During the early post-isolation phase the response of lake biota to an influx of nutrients is reflected in an increase in biological silica and organic carbon in the lake sediments. On the other hand, the generally low organic content of the sediments indicates that sedimentation in these lakes has been largely determined by variations in non-biogenic factors through time. During the mid Holocene the progressive stabilization of surface materials within the lake catchments is marked by decreasing Cr, As and Na in the sediments. At the same time, an increase in allochthonous Mn and Fe is attributed to progressive soil development. During the last 2500 years the catchments have experienced decreased erosion resulting in a decrease in both allochthonous clastic input and lake productivity.     

Identifying sedimentation patterns in Lake Baikal using whole core and surface scanning magnetic suceptibility

Forty seven ca. 1 m sediment cores were collected from Lake Baikal during a summer cruise in 1996 and analysed for whole-core susceptibility. Fifteen of these cores were further analysed using a new prototype surface scanning sensor on board the ship R.V. Vereshchagin. The main purpose of this paper is to show that the measurement of Lake Baikal short cores using two susceptibility sensors gives valuable field data and can be used as a tool for identifying undisturbed sediment sequences. Four coring transects were sampled to identify sedimentation patterns reaching from the shelves and sub-basins of the near lake shore and across mainly the northern basin of Lake Baikal (water depth ca. 1500 m). Also in the sub-basins and in the southern basin other groups of cores were taken. One of the main sediment features of interest is that of turbidite sedimentation. Whole core magnetic susceptibility traces are used to identify turbidite fingerprints and correlate them between cores along the transects. The results from the two magnetic susceptibility sensors the whole-core sensor and the new prototype surface scanning sensor, both giving volume Kappa values, are compared and are found to be significantly correlated given the difference in resolution. The whole-core sensor gives a smoothed equivalent to a moving average curve of magnetic susceptibility while the surface scanner can give fine resolution (ca. 2 mm) results picking out fine peaks with Kappa values of between 150 to 650.The results show that most turbidite sedimentation can be clearly identified; they give a specific magnetic susceptibility fingerprint with larger Kappa values (up to 120) at the base of the turbidite corresponding with the settling of coarser sandy sediments and a steady and gradual decline in values to about 15 at the top of the turbidite where the fines settle incorporating the normal diatomaceous sedimentation. The main control on the magnetic susceptibility of the turbidite sediments is the concentration of ferrimagnetic minerals in different particle size fractions. The turbidites can be correlated between many of the cores collected along the transects but it must be noted that these correlations are partly speculative and will be confirmed with future dating, diatom analysis and geochemistry. Other very fine peaks of less than 5 mm in width identified using the surface scanning sensor may indicate concentrations of ferrimagnetic minerals, namely greigite, formed during the reduction phase.     

楚科奇海陆架沉积物中几种低环的多环芳烃的垂直分布特征

于2014年中国第6次北极科学考察期间,采集了楚科奇海陆架4根沉积物柱状样,据此开展了其中几种低环的多环芳烃(PAHs)的总体水平调查,并结合~(210)Pb测年,探讨了其垂直分布特征及历史沉降规律。结果表明,楚科奇海陆架沉积物中几种低环PAHs含量变化范围为50—1 553 ng·g~(–1),总体处于较低水平,且与粒径变化关系不明显。楚科奇海陆架区沉积物的沉积速率为0.05—0.19 cm·a~(–1),低环PAHs垂直变化较小,总体受人类影响极少,局部高值可能受到石油渗漏或成岩作用等过程的影响。     

A minimal lag time and continuous sedimentation in alpine lakes near Mount Rainier, Cascade Range, Washington, USA

Alpine lakes near Mount Rainier are dammed by late-glacial moraines. Multiple cores show that sedimentation started less than 350 years after deglaciation. Numerous tephra layers provide excellent marker horizons that allow comparison of the stratigraphy without the errors associated with radiocarbon dating. Cores from different locations within a lake display the same stratigraphy and basal sediments. Core location therefore is not crucial to obtaining the oldest sediments. Continuous sedimentation in all cores is interpreted as evidence for stable lake levels throughout the Holocene. The cores are valuable tools for reconstruction and dating of glacier advances and volcanic activity.     

Radiometric dating of recent sediments: beyond the boundary conditions

Most mathematical models for radiometric dating of recent sediments are particular solutions of a unique physical problem: the advective?Cdiffusive transport of a particle-bound radiotracer within a sediment profile that undergoes accretion. Regardless of the particular assumptions about fluxes, sedimentation rates and the diffusion term, all models assume ideal deposition as a boundary condition at the sediment water interface, i.e. new radioactive input will be deposited above the previously existing material. In sediments with very high porosities, this assumption may be unrealistic, because a fraction of the incoming flux may penetrate rapidly through the connected pore spaces. This process will be referred to as non-ideal deposition. This paper reviews evidence from literature data, discusses the basic processes involved, and establishes the mathematical basis to incorporate non-ideal deposition into one-phase radiometric dating models, as depth-distributed local sources. Through analytical and numerical solutions, this work demonstrates that such penetration patterns can explain excess ²¹⁰Pb subsurface maxima, often observed in sediment cores, as well as penetration of ¹³⁷Cs to depths greater than expected from sedimentation rates and diffusion. These ideas are illustrated using examples from the literature in which sediment porosities were >90?%. Implications for radiometric dating include: (1) spurious accelerations in sedimentation rate inferred when applying the constant rate of supply model, and (2) erroneous chronologies, developed when using the maximum depth at which ¹³⁷Cs can be measured as a chronostratigraphic marker.     

Changing sedimentation patterns due to historical land-use change in Frenchman’s Bay,Pickering, Canada: evidence from high-resolution textural analysis

This study examines the anthropogenic alteration of sedimentation in Frenchman’s Bay in Lake Ontario, using high-resolution particle size analysis in two 200 cm cores. Lithofacies were determined using the particle size data of both the terrigenous sediment and terrigenous sediment + diatom fractions. Terrigenous particle size data from the centre of the lagoon provided the most representative record of anthropogenic impacts. Three distinctive lithofacies were recognized: (1) a Natural Wetland (NW) lithofacies (106–200 cm) had an average mean particle size of 49.4 μm, a mode of 29.4 μm and an average standard deviation of 119.1 μm; (2) an Agricultural and Deforestation (AD) lithofacies (40–105 cm) had a statistically significant lower average mean (30.8 μm), mode (13.5 μm), and standard deviation (48.5) μm; (3) an Urbanized (U) lithofacies (0–40 cm) showed a continued trend towards smaller particle sizes with an average mean of 21.2 μm, a mode of 9.4 μm, and an average standard deviation of 32.7 μm. The lithofacies correlated with previously identified trends in thecamoebian biofacies and magnetic susceptibility data showing post-colonial lagoon eutrophication and increased overland soil erosion. The up-core trend towards finer and less variable particle sizes is attributed to erosion of fine-grained watershed sediments (glacial Lake Iroquois silts and clay) during land-clearance and modification of natural drainage patterns. The influx of silts and clays into the lagoon is also recorded by increased sediment accumulation rates and a reduction in seasonal sediment variability in the wetland. Based on the ²¹⁰Pb dates, sedimentation rates increased at 1850 ±56 AD (AD lithofacies) and suggest an exponentially increasing trend in accumulation rates. Increasing sedimentation rates can be attributed to the progressive loss of native vegetation and intensified erosion of Lake Iroquois deposits via stream and hillslope erosion. Ecologically, the increased input of fine-grained sediments into the wetland has resulted in reduced water clarity and has altered the wetland substrate contributing to wetland loss in Frenchman’s Bay.     

A record of accelerated erosion in the recent sediments of Blelham Tarn in the English Lake district

Two frozen cores from Blelham Tarn were subsampled and measured using mineral magnetic, loss-on-ignition (LOI), radiometric, granulometric and diatom analyses. A detailed chronology was established using varves, radioisotopes and diatoms. This has enabled an accurately dated reconstruction of sedimentation over the past forty years. Despite a large increase in lake productivity, evidence suggests that the observed exponential increase in sedimentation rates can be attributed to erosion within the catchment. The predominant sediment source has been identified as surface soil. A comparison between the trend of accelerated sedimentation and the record of increased sheep stocking density for the area within which the most of the catchment lies, as well as observations of contemporary surface processes within the catchment, both suggest that much of the recent erosion is a direct response to increased pressure from sheep grazing.     

Spatial uniformity of sediment accumulation in varved lake sediments in northern Sweden

As part of an investigation aimed at assessing the potential of northern Swedish varved lake sediments for fine-resolution reconstruction of past climatic conditions, the following questions were addressed; how representative is a single core, does the appearance of varves change as the sediment ages, and how can varve thickness and within-varve structures be digitized? Analyses of replicate cores from Kassjön, using sample sequences of seasonal, annual and centennial time resolution, show that spatial variability of sediment accumulation in the varved sediment is very low. Comparisons of intensity curves from image analysis of freeze cores of recent sediments from Lake Nylandssjön, sampled in 1980 and 1985, indicate that the varves acquire their appearance at the sediment-water interface during sedimentation and that the varve structures are preserved during diagenetic processes. Measurement of varve thicknesses with a tree-ring microscope and with image analysis gave similar results. However, with image analysis, within-varve structures such as colour variations and thicknesses of seasonal layers, can also be recorded, increasing the possibilities for palaeolimnological and palaeoclimatic inferences.     

The role of biogeochemical cycling for the formation and preservation of varved sediments in Soppensee (Switzerland)

We analyzed seasonally aggregated observations of temperature, conductivity, dissolved oxygen and dissolved inorganic carbon from Soppensee (District of Lucerne, Switzerland) for the yrs 1980 to 1993. Holomictic Soppensee is characterized by a strong summer stratification with a thin epilimnion separated from an anoxic hypolimnion by a strong pycnocline formed by thermal and chemical gradients. A vertical one-dimensional model was developed to simulate the observed seasonal cycles of carbon and oxygen. The processes of net community production, mineralization of organic matter, precipitation and dissolution of calcite, gas exchange, in- and outflow, sedimentation and vertical eddy diffusion are included. According to the model, the annual net community production is estimated to about 110 g C m^-2 yr^-1 and the annual net primary production to about 330 to 440 g C m^-2 yr^-1, which is a typical value for eutrophic lakes. A mass balance of the carbon cycle indicates that most of the inflow comes from groundwater which is super-saturated with respect to atmospheric CO₂. Therefore the surface waters exhibit a large capacity for calcite precipitation. The results of the model are used to constrain the conditions that favor the formation of varved sediments in Soppensee during thousands of yrs. Model calculations show that the deep waters would still turn anoxic even if the sedimentation rate of organic matter were decreased to 25%. Several physical factors such as biogenic stabilization of the deep waters due to calcite dissolution and low input of wind energy are responsible for the long term anoxia in Soppensee.     

Environmental records of carbonaceous fly-ash particles from fossil-fuel combustion

Analysis of fly-ash particles in lake sediments has become increasingly important in studies of environmental pollution and lake acidification history. Most fly-ash studies have concerned black spheroidal carbonaceous particles (SCP)(>5 m) produced from oil and coal combustion. This review paper provides a summary of this technique and its application, and focusses on our investigations in Sweden between 1979 and 1993. It consists of five parts: i) preparation and analysis methods, ii) historical trends in atmospheric deposition, iii) geographical surveys of atmospheric deposition, iv) sediment dating, and v) studies of sedimentation processes in lakes. Methods for preparation and analyses of SCP have been developed and applied to investigations using sediment, soil and snow samples. Stratigraphic trends of SCP concentrations in lake-sediment cores reflect the consumption history of fossil fuels. A characteristic temporal SCP pattern, with a marked concentration increase beginning after the 1940's and a peak in the early 1970's, has been recognized in most Swedish lakes and elsewhere in Europe. A survey of SCP concentrations in surface sediments of >100 lakes covering Sweden demonstrated that polluted areas in southern Sweden had >100 times higher SCP concentrations than clean areas in the north. The spatial distribution of SCP over Sweden is similar to the deposition pattern of long-range transported airborne pollutants, such as excess sulphate monitored by network stations. SCP also accumulate in soils, and soil analyses can be used for determining the integrated historical deposition of SCP at the local or regional scale. Finally, SCP have been used for indirect dating of sediment cores and as a marker to assess sediment distribution patterns within lake basins.     

Sedimentation patterns of diatoms in Lake Holzmaar, Germany - (on the transfer of climate signals to biogenic silica oxygen isotope proxies)

The seasonal sedimentation pattern of diatom valves in Lake Holzmaar was investigated during 1995 by deploying sediment traps at three different lake depths. According to the sedimentation pattern, the major reproduction zone of diatoms was restricted to the upper 6 m of the water body. The population growth started late in April and blooms of Cyclotella cf. comensis Grun., which dominates the plankton diatoms, and Fragilaria crotonensis Kitton were collected in traps during June and September, and July, respectively. During summer, the seasonal sedimentation pattern of each taxon, as collected in the upper traps, was reflected in the concentrations in the lowest trap. However, in May and from September onwards, the community composition in the lowest trap and augmented trapping rates suggest both sediment focusing and resuspension of bottom sediments.The temperature signals as recorded by 18O values of diatom valves should, therefore, reflect integrated temperatures between 0 and 6 m depth. However, temperatures during summer and autumn are expected to be accentuated in the sedimentary record since the isotopic signal is weighted by both the number and the weight-mass of the valves. During summer, the transfer of these signals by the sedimenting diatoms retains the information pattern recorded, while in spring and autumn/winter additional influxes caused by resuspension may somewhat alter those temperature informations. The proxy signals finally stored in the sediments, may, therefore, not precisely represent the successive temperatures currently recorded during 1995 within mid-lake.     

长江河口河槽近期沉积特征及影响因子分析

随着流域和河口水利工程建设,长江河槽沉积环境发生了巨大改变,对河势演变和河槽冲淤均产生重要影响。依据长江河口河槽大面积表层沉积物采样和各河槽定点水文观测资料,分析各河槽沉积特征,探讨其影响因子及作用机制。结果表明:河槽沉积物类型以砂质粉砂和粉砂质砂分布最广,粒径分布纵向上呈自西向东减小、横向上自北向南减小趋势,河槽总体主槽粗、边滩细。涨落潮泥沙输运和沉降过程影响河槽纵向沉积分布特征,风浪作用强化了口门段河槽南北沉积环境的差异,北支、北港口门段河槽受到偏北方向风浪作用强烈,沉积物粗化明显。不同泥沙来源是造成河槽整体沉积环境差异的主导因素,南支、南港上段表现为流域来沙的沉积特征,北港、南槽、北槽则表现为流域与海域来沙的混合沉积特征,口外沉积物对口内河槽的影响主要是为口内河槽提供细颗粒物质来源。     

Geochemical signatures of two different coastal depositional environments within the same catchment

The geochemistry of lake (Renstradträsket) and estuarine (Pieni Pernajanlahti Bay) sediment was investigated in a medium sized watershed draining to the Gulf of Finland, Baltic Sea. Catchment land-use types were compared and found similar. Sediment cores were dated using ²¹⁰Pb- and ¹³⁷Cs-chronologies and analyzed for Al, K, Cu, Zn, Fe, Mn, phosphorus fractions, TN, TC and biogenic silica (BSi). Differences between the sediment cores were studied by using linear regression analysis and principal components analysis (PCA). Despite similarities in catchment land-use and history, the sediment geochemical profiles of the sites varied significantly. Some of the differences could be related to differences in chemical sedimentation environment (lacustrine versus estuarine). TP concentration was found to be positively correlated with sediment iron content in estuarine sediment but negatively correlated with Fe in lake sediment. In the estuarine core sedimentary iron was not correlated to lithogenic potassium and aluminum but in the lake core the iron seemed to be lithogenic in origin, as suggested by the strong positive correlations (r ² = 0.95–0.96) between these three variables. Most similarities among the cores were found in Al concentrations. Estuarine nutrient profiles appeared relatively monotonous compared to the lake core. This is probably due to more vigorous mixing of the sediments that may ensure more rapid and complete consumption of the organic matter deposited on the bottom of the estuary. Therefore the lake sediment appeared to preserve the historical record of eutrophication better. Biologically less active and more particle-bound materials like the trace metals Cu and Zn seemed to retain good records of anthropogenic impact also in the estuarine core. The study highlights the need to take the sedimentation environment into account when interpreting geochemical record.