Probabilistic risk assessment of common booster biocides in surface waters of the harbours of Gran Canaria (Spain)

The presence of booster biocides in the aquatic environment has been associated with a risk to non-target species due to their proven toxicity. The aim of the present study was to determine the spatial and temporal distribution of common booster biocides in different harbours of the island of Gran Canaria (Spain) and evaluate, by means of a probabilistic risk assessment (PRA), the ecological risk posed by these compounds. With these objectives, a monitoring campaign was conducted between January 2008 and May 2009, collecting a total of 182 seawater samples. Four common booster biocides (TCMTB, diuron, Irgarol 1051 and dichlofluanid) were monitored. Diuron levels ranged between 2.3 and 203 ng/L and Irgarol 1051 between 2.4 and 146.5 ng/L. The ecological risk associated with these levels was always low, however, with probabilities of exceeding the 10th percentile of autotroph toxicity below 3.5%.     

Diagenesis and anthropogenesis of metals in the recent Holocene sedimentary record of the Ría de Vigo (NW Spain)

To contribute to establishing a historical baseline for future evaluations of the environmental quality of the Ría de Vigo (NW Spain), we report metal contents determined in eight gravity cores obtained at representative locations in 1990 - before the installation of any wastewater treatment plants - and in fractions thereof that were obtained by the BCR sequential extraction method. The results suggest that early diagenesis had been influenced by both hydrodynamic conditions and organic matter input (the latter especially in areas devoted to mariculture), and that anthropogenic inputs had also affected the concentrations and between-fraction distribution of Cu, Pb, Zn and other metals in surficial sediments.     

Seasonal contribution of living phytoplankton carbon to vertical fluxes in a coastal upwelling system (Ría de Vigo, NW Spain)

The aim of this study is to explore the contribution of living phytoplankton carbon to vertical fluxes in a coastal upwelling system as a key piece to understand the coupling between primary production in the photic layer and the transfer mechanisms of the organic material from the photic zone. Between April 2004 and January 2005, five campaigns were carried out in the Ría de Vigo (NW Iberian Peninsula) covering the most representative oceanographic conditions for this region. Measurements of particulate organic carbon (POC), chlorophyll-a (chl a), phaeopigments (phaeo), and identification of phytoplankton species were performed on the water column samples and on the organic material collected in sediment traps.The POC fluxes measured by the sediment traps presented no seasonal variation along the studied period ranging around a mean annual value of 1085±365 mg m⁻² d⁻¹, in the upper range of the previously reported values for other coastal systems. The fact that higher POC fluxes were registered during autumn and winter, when primary production rates were at their minimum levels points to a dominant contribution of organic carbon from resuspended sediments on the trap collected material. On the contrary, fluxes of living phytoplankton carbon (C_phyto) and chl a clearly presented a seasonal trend with maximum values during summer upwelling (546 mg m⁻² d⁻¹ and 22 mg chl a m⁻² d⁻¹, respectively) and minimum values during winter (22 mg m⁻² d⁻¹ and 0.1 mg chl a m⁻² d⁻¹, respectively). The contribution of C_phyto to the vertical flux of POC ranged between 2% and 49% in response to the pelagic phytoplankton community structure. Higher values of C_phyto fluxes were registered under upwelling conditions which favour the dominance of large chain-forming diatoms (Asterionellopsis glacialis and Detonula pumila) that were rapidly transferred to the sediments. By contrast, C_phyto fluxes decreased during the summer stratification associated with a pelagic phytoplankton community dominated by single-cell diatoms and flagellates. Minimal C_phyto fluxes were observed during the winter mixing conditions, when the presence of the benthic specie Paralia sulcata in the water column also points toward strong sediment resuspension.     

Hydrogeological Investigation of Hydrocarbon Contamination of Ground Water in Albolote (Granada, Spain)

In July 1988, hydrocarbons were detected in wells in the urban area of Albolote, near Granada, Spain, near the border of the "Vega de Granada" alluvial aquifer. According to available hydrogeological data, the contamination was attributed to leaks in the underground pipelines of a nearby (300m) industrial factory, where the loss of 40,000 to 50,000 liters of gasoline had been detected some weeks before. A complete hydrogeological investigation was then undertaken, involving, among other techniques: (a) an inventory of the existing wells in the area; (b) the preparation of piezometric maps; (c) the application of electrical geophysical methods; (d) the drilling of piezometers and new pumping wells between the urbanized area and the leak point; (e) the improvement of the pluviometric and piezometric control by the installation of a pluviograph and several limnigraphs; (f) the sampling, initially daily and finally weekly, in a 20-well observation network, also used for piezometric control; and (g) the geostatistical study of the analytical data. The contamination plume, extended in the direction of the flow lines, has a length of 500m and a width of less than 50m, and appears to have occurred mainly in a paleochannel. Hydrocarbons (1600 liters) were recovered by pumping and by using absorbent blankets, as well as by a gas and liquid suction method. Hydrocarbon concentrations have continuously decreased. However, sporadic increases, associated with rainfall, have been observed suggesting the presence of retained hydrocarbons in the unsaturated zone. The rate of decrease in hydrocarbon concentrations has currently slowed, particularly in the less affected zone. As a means of activating the cleaning up of the unsaturated zone, an artificial recharging method has been designed.     

Bloom forming and toxic phytoplankton in transitional and coastal waters of Cantabria region coast (Southeastern Bay of Biscay,Spain)

Phytoplankton monitoring has extended to practically all the regions of the European coast due to the implementation of the European Water Framework Directive. In this way, the study of phytoplankton taxonomic composition and dynamic is being performed in many areas poorly studied or not studied before. During the last years, a monitoring programme has been carried out at the coast of Cantabria region (SE Bay of Biscay); the presence of some potentially toxic and bloom forming species (>7.5 × 10⁵ cells per litre) has been observed. Diatoms and cryptophytes are the main blooming taxa in this region in the majority of the estuaries and in some of the coastal sites. All estuaries and coastal stations showed at least one potentially toxic species, being the dinoflagellates the group with the highest number of taxa observed. The potentially toxic species found in highest concentrations were the genera Pseudo-nitzschia and Chrysochromulina.     

Two-dimensional magnetotelluric characterization of the El Hito Anticline (Loranca Basin,Spain)

Magnetotelluric surveys were conducted to investigate the structure in the El Hito Anticline in the southern Loranca Basin, Spain. The structure of this anticline is partly known from nearby data (geological cross sections, geological maps, well-logs) from vintage geophysical and geological basin-scale surveys. Unfortunately, these surveys do not have the appropriate resolution to determine certain characteristics of the anticline accurately, such as the thickness or geometry of geological units. To address this deficiency, magnetotelluric data were acquired at 51 sites along three profiles to image the electrical resistivity of the anticline. To identify a geologically reasonable resistivity model, a conceptual model based on previous geological and geophysical information (cross sections and well-log data) was generated. Several inversions were performed using the conceptual model, which played a key role in the interpretation of the magnetotelluric data, and the construction of a suitable initial model was essential in producing geologically meaningful models. Using these results, we obtained 2-D resistivity models that provide information on the main geological units and structures. We also performed sensitivity tests to understand the morphology and structure of the resistive basement better. The results indicate the presence of basement highs that show different structural styles for the basement and its cover, and an increase in the basement depth towards the south. The final 2-D resistivity models provide new information regarding the structure of the anticline and demonstrate a clear correlation between the main geological units and resistivity, as well as correlations with mapped surface faults.     

Coupling of phytoplankton and ciliate biomasses to environmental factors along the north coast of Sfax (Tunisia,Eastern Mediterranean Sea)

The phytoplankton and ciliate biomasses coupled with environmental factors were investigated in 15 transects in north coasts of Sfax (Tunisia, Eastern Mediterranean Sea) in July 2007. The phytoplankton biomass was dominated by Bacillariophyceae (89.66%), followed by Dinophyceae (10.07%), Coccolithophorideae (0.96%), Cyanobacteriae (0.21%), Chlorophyceae (0.03%) and Euglenophyceae (0.01%). Coscinodiscus sp. (93.26%) was the most abundant species of Bacillariophyceae group and associated with a high nutrient availability. Ciliate biomass was highly variable, with a large dominance of Spirotrichea, up to 96.2%. Biomass followed distinct patterns because of differences in the observed organism biovolumes. The spatial distribution of the ciliates biomass seems to be dependent on environmental factors and probably on their capacity to exploit a wide range of food resources including phytoplankton. The pollution generated by the phosphate-treating manufactory influenced the spatial phytoplankton and ciliate community’s distribution and their diversity along the north coast of Sfax.     

Environmental transformation of the Bilbao estuary,N. Spain: microfaunal and geochemical proxies in the recent sedimentary record

The distribution and abundance of benthic foraminifera and a range of elements have been analysed in six long cores (up to 10 m long) from the Bilbao estuary, N. Spain, to document environmental transformation of this estuarine ecosystem and to determine sediment contamination levels. Three different environmental zones could be distinguished in the recent sedimentary record based on its microfaunal and geochemical contents. Initially, a pre-industrial zone containing very abundant and diverse foraminiferal assemblages together with baseline metal levels. Secondly, an older industrial zone exhibiting co-existence of abundant and diverse foraminiferal assemblages with high concentrations of metals. Finally, a younger industrial zone with extreme concentrations of metals and barren of indigenous foraminifera. This environmental transformation has been caused by the discharge of untreated domestic and industrial effluents during the last 150 years. The occurrence of foraminifera in the two industrial zones and along the estuary is not related to defined levels of metals, and this seems to confirm oxygen limitation as the key factor to explain complete estuarine defaunation during deposition of the younger industrial zone (period 1950-2000). Effectiveness of current regeneration schemes could be assessed using microfaunal and geochemical proxies as environmental quality indicators.     

Predictability of currents on a mesotidal estuary (Ria de Vigo, NW Iberia)

In this contribution, the implementation, validation and sensitivity analysis of an operational forecasting system (three-dimensional hydrostatic model) in the Ría de Vigo is presented. A set of sensitivity tests for different atmospheric and hydrodynamic typical periods was performed. The goal is to determine the relative importance of forcing mechanisms in order to evaluate the source of errors in predictions. Previously, validations for three periods of about 15 days were compared with measured data. Sea-level evolution reveals low errors and correlation values close to 1. Surface velocities were compared with high-frequency radar and horizontal Acoustic Doppler Current Profiler data, showing acceptable results on radar area, where tidal and wind circulation patterns are well reproduced by the model. Conductivity, temperature, and depth profiles were used to validate simulated temperature and salinity. While modelled temperature profiles show good agreement with measured profiles, eventual errors are detected on salinity. The sensitivity analysis took three variables into account: sea level, currents at open boundary conditions, and winds (two different configurations). The results show that the most important source of errors on simulated surface currents is wind. Errors on open boundary conditions seem to be limited on the outermost part of the Ría. Although the results presented mainly focus on the Ría de Vigo, the method and conclusions may be applied to other mesotidal estuaries. Moreover, this work will allow a more effective operational system focused on coastal management to be performed.     

Assessing the spatial variability,level and source of organic chemical contaminants in bivalve fishing grounds on the Galician coast (NW Spain)

Polychlorinated biphenyls, organochlorine pesticides, organotin compounds and triazines were quantified in sediments and bivalves collected in four areas on the Galician coast. One or several species were analysed at each site depending on their availability, including mussels (Mytilus galloprovincialis), cockles (Cerastoderma edule), clams (Venerupis pullastra and Ruditapes decussatus) and razor shells (Ensis siliqua). The general spatial distribution of contaminants was consistent in spite of the different sources of contamination. High inter-species variability was also observed. M. galloprovincialis and V. pullastra showed the highest levels of contaminants and intra-spatial variability, which highlights them as suitable species to be used as sentinel organisms. The area of O Burgo showed some worrisome results: PCB sediment concentrations were within the range that could cause biological effects. Also the level of heptachlor observed in V. pullastra was above limits accepted on edible seafood. Finally TBT concentration in mussels correlated with concentrations causing imposex in snails.     

Evolution and inheritance of a rock coast: western Galicia,northwestern Spain

There is increasing evidence that shore platforms and other elements of rock coasts may be inherited, at least in part, from interglacial stages when sea level was similar to today's. Most of this evidence, which includes ancient beaches and datable terrestrial deposits, has been obtained from areas of resistant, slowly eroding rock, where the platforms often appear to be much too wide to have developed since the sea reached its present level. It is much more dif?cult to demonstrate that inheritance has occurred in areas of weaker rock, which generally lack any datable material. The coast of western Galicia in northwestern Spain has shore platforms in igneous and metamorphic rocks that were deeply weathered during the Tertiary. These platforms are closely associated with ancient beaches from the last interglacial stage, and associated periglacial and ?uvio‐nival deposits that covered and fossilized most of the Eemian platforms and cliffs during the late middle and late Weichselian glacial stage. The sedimentary processes and the thickness and facies of the sediments were determined by the height, aspect and gradient of the coastal mountains, and their distance from the coast. Radiocarbon dating, sedimentary analysis and platform morphology indicate that the shore platforms of Galicia have been inherited from at least the last interglacial stage. They were fossilized in places beneath thick Weichselian deposits and then exhumed during the Holocene transgression. The abundant evidence for inheritance in Galicia has important implications for other coasts in fairly weak rocks where such evidence is generally lacking. Copyright © 2003 John Wiley & Sons, Ltd.     

3D magnetotelluric characterization of the geothermal anomaly in the Llucmajor aquifer system (Majorca, Spain)

In the Llucmajor aquifer system (Majorca Island, Spain) some geothermal evidences have appeared. This phenomenon is not isolated to Majorca and it is present in other areas, where it can be associated with structural conditions, especially to the extensional event suffered by the island after the Alpine Orogeny. However, the origin of this anomaly in Llucmajor is not well known, and there is no surface geological evidence of these structural conditions. With the aim of delineating the geoelectrical structure of the zone and identifying the geological structure that allows the presence of this anomaly, an audiomagnetotelluric (AMT) survey was carried out. The AMT data was processed using a Wavelet Transform-based scheme. Dimensionality analysis indicates that the geoelectrical structure is mainly 3D. The 3D model was obtained by trial and error forward modeling, taking accounting of the responses from the determinant of the impedance tensor. The model shows a vertical resistivity distribution with three horizons associated with different units: on the top, a shallow high resistive media related to an unconfined shallow aquifer; in the middle, a conductive layer related to the aquitard, and below it, another resistive media related to the confined deeper aquifer. The intermediate horizon shows a sudden thinning beneath the thermal anomalous zone that can be identified as a weakness zone (fault or fracture) connecting both aquifers. An exploratory well was drilled after the AMT survey and reached almost 700 m in depth. This allowed correlating the resistivity distribution of the 3D model with data logging and lithology obtained from the well, showing a proper agreement between them.     

Fecundity and spawning mode of three introduced fish species in Lake Banyoles (Catalunya, Spain) in comparison with other localities

Analysis was conducted during 1991 into the fecundity and oocyte size distribution of pumpkinseed, roach and rudd in Lake Banyoles. We found that individual fecundities of these species in Lake Banyoles were lower in comparison with other localities. In roach, there was a moderately significant negative relationship between latitude and egg number. The temporal pattern of the pumpkinseed's oocyte size distribution suggests that it is a multispawner fish that spawns several batches of eggs from mid-May to mid-August. In contrast, roach and rudd seem to be monospawners fish that release only one batch of eggs before mid-May. The monospawning behaviour of rudd in Lake Banyoles is in contrast to the evidence from other waters. Variations in fecundity and spawning mode are discussed on the basis that they are due mainly to differences in local conditions.     

Flood hazards at ford stream crossings on ephemeral channels (south‐east coast of Spain)

Most road‐stream crossings over ephemeral channels are vulnerable to extreme hydrologic events. Ford stream crossings (FSCs) are usually dangerous for the road traffic during periods of high flow, in particular under flash flood conditions. The present paper analyzes the flood hazards on the Mediterranean coast in the Region of Murcia (south‐east Spain), affecting this type of road‐stream crossing over dry channels, according to hydraulic variables and bedload transport rates estimated for discharges at bankfull and flood‐prone stages. Under such conditions, the safety of people and vehicles was obtained using numerical models, developed by previous researchers; in particular, water levels and flow velocities across ford reaches were compared with different trend curves between water depths and corresponding critical velocities for children and adults, and for various prototype vehicles. Specifically, two approaches to assess this type of hazards were proposed: a specific Hydraulic Hazard Index and an algorithm for estimating the flood hazard from criteria of bed stability and bedload transport capacity (Flood Hazard at Fords, FHF). In addition, different exposure levels were established, using a Flood Vulnerability Index, based on the FHF, the road category, and the annual average daily traffic. The FHF model gave the best results with regard to the magnitude of the damage observed in recent flash floods for flow stages similar to those simulated. According to the danger thresholds established for this index, half‐bankfull flows represent here a high risk: 27.3% of FSCs for mini‐cars and 18.2% for large cars. At bankfull, the FHF exhibits very high values for mini‐cars (77.3% of FSCs) and for large passenger vehicles (50% of FSCs), while at the floodprone stage, extreme FHF values are reached for all kinds of vehicles at most of the ford crossings.     

Occurrence and effects of organotins on adult common whelk (Buccinum undatum) (Mollusca, Gastropoda) in harbours and in a simulated dredging situation.

Transplanted common whelk (Buccinum undatum) (Mollusca, Gastropoda) accumulated fairly high levels of organotins (tributyltin (TBT) and triphenyltin (TPT)) during exposure in three harbours with different TBT contamination. This did not though lead to an increase in imposex frequency in the adult females studied. Simulating harbour dredging in an experiment using suspended sediment from one of the harbours only resulted in a low concentration of TBT in the tissues of the common whelk and subsequently no changes in the occurrence and degree of imposex. The common whelk seemed to receive the main part of TBT from the water column and the limited bioaccumulation in the experiment indicates that desorption of TBT from the suspended sediment was slow. After TBT has been totally banned, dredging of contaminated sediments will cause increased exposure of the biota to TBT. Due to slow desorption the increase may however, be slight and temporary to pelagic and epibenthic species unless the settled particles are resuspended.     

Water balance of tropical rainforest canopies in north Queensland,Australia

The water balance of four different rainforest types in the Wet Tropics region of north Queensland is inferred from measurements of canopy hydrological components undertaken for periods between 391 to 657 days. These measurements of rainfall, cloud interception, stem-flow, throughfall, canopy interception and transpiration have revealed considerable differences in the canopy water balance of different locations as a result of forest structural differences, altitude, exposure and climate. Cloud interception is a significant extra input of water to forests at high altitude sites (>1000 m) and varies between 7 and 29% of the total water input. At coastal and lower montane rainforests annual total evaporation is consistently around 50% of the total water input, but in upper montane cloud forest this drops dramatically to only 13% of the water input. At all sites actual evaporation is greater than potential evaporation for most of the year and on an annual basis exceeds potential by between 2 and 53%. The source of this additional energy is uncertain, but is likely to come from advection. Annual interception at all the rainforest sites was greater than annual transpiration, with transpiration dominating in the dry season and interception dominating in the wet season. All of the rainforests have a large annual net water balance to sustain runoff and recharge. Towards the end of the dry season runoff and recharge can cease in coastal lowland and lower mountain forests and they may have to draw on soil moisture and/or ground water at this time. In contrast, upper montane cloud forests have a positive net water balance throughout the year and are therefore an important source of dry season river flows. Furthermore, their exceptionally large annual runoff (∼6500 mm year⁻¹) is a major source of downstream water. Copyright © 2007 John Wiley & Sons, Ltd.