冀北张家口地区汉诺坝玄武岩中麻粒岩捕虏体的硫化物相

捕虏体麻粒岩是了解下地壳形成和演化的重要样品.汉诺坝新生代玄武岩中的二辉麻粒岩捕虏体样品中富含各种硫化物相,主要类型有:①孤立产出的球状出溶硫化物;②矿物颗粒之间或颗粒内的粗晶硫化物;③次生硫化物包裹体群;④裂隙充填硫化物.电子探针分析表明,硫化物的矿物成分均为贫镍磁黄铁矿,(Ni Co Cu)/Fe(原子比)远小于0.2;(Fe Cu Co Ni)/S(原子比)比地幔岩的磁黄铁矿小,多小于0.875,反映了一种S过饱和环境.各种产状的磁黄铁矿中Au、Ag都有一定的含量,其平均值分别为0.19%～0.22%(Au)、0.01%～0.02%(Ag),反映下地壳的麻粒岩化与金矿化的成因联系.磁黄铁矿的Ni、Co、Cu含量与S正相关,说明微量重金属元素与S具有同源的关系,由于地幔去气伴随S而进入下地壳.     

冀北张家口地区汉诺坝玄武岩中麻粒岩捕虏体的硫化物相

捕虏体麻粒岩是了解下地壳形成和演化的重要样品。汉诺坝新生代玄武岩中的二辉麻粒岩捕虏体样品中富含各种硫化物相,主要类型有:①孤立产出的球状出溶硫化物;②矿物颗粒之间或颗粒内的粗晶硫化物;③次生硫化物包裹体群;④裂隙充填硫化物。电子探针分析表明,硫化物的矿物成分均为贫镍磁黄铁矿,(Ni+Co+Cu)/Fe(原子比)远小于0.2;(Fe+Cu+Co+Ni)/S(原子比)比地幔岩的磁黄铁矿小,多小于0.875,反映了一种S过饱和环境。各种产状的磁黄铁矿中Au、Ag都有一定的含量,其平均值分别为0.19%～0.22%(Au)、0.01%～0.02%(Ag),反映下地壳的麻粒岩化与金矿化的成因联系。磁黄铁矿的Ni、Co、Cu含量与S正相关,说明微量重金属元素与S具有同源的关系,由于地幔去气伴随S而进入下地壳。     

汉诺坝麻粒岩捕虏体锆石U-Pb 分析初步结果及讨论

本文报道了汉诺坝玄武岩中麻粒岩捕虏体的锆石 U-Pb 初步分析结果，并讨论了其成因的两种可能性。     

汉诺坝捕虏体辉石岩和麻粒岩的成因探讨

汉诺坝新生代玄武岩中含有丰富的地幔和地壳岩石捕虏体,其中捕虏体辉石岩和庥粒岩由于外观上具有一定的相似性,两者容易混淆,导致研究上的误区.本文以辉石岩和麻粒岩捕虏体作为研究对象,通过岩相学观察结合矿物主量元素分析、单斜辉石微量元素和Sr-Nd同位素分析,对两种捕虏体进行深入的研究和对比以探讨其成因意义.结果表明,上述各方面二者都存在明显的差别,捕虏体麻粒岩具有层状堆晶构造,两种辉石矿物(次透辉石和古铜辉石)相对贫MgO富FeO,单斜辉石的REE相对富集,以高87Sr/86 Sr低143Nd/144Nd为特征;而捕虏体辉石岩一般呈块状构造,两种辉石矿物(透辉石和古铜辉石-顽火辉石)相对富MgO贫FeO,单斜辉石REE总量极低呈亏损模式,同位素组成上介于捕虏体橄榄岩和麻粒岩之间.捕虏体麻粒岩特征表明它是幔源岩浆底侵作用形成,岩浆受到了下地壳的混染;而捕虏体辉石岩明显不同于橄榄岩和麻粒岩的成因,来自于富集地幔.     

汉诺坝玄武岩中麻粒岩类捕掳体的岩石学特征

根据矿物组合特征,汉诺坝玄武岩中的麻粒岩捕掳体可划分为四种类型：长英质麻粒岩、苏长质麻粒岩、二辉二长麻粒岩和二辉麻粒岩,其中以二辉麻粒岩最为常见。麻粒岩捕掳体均具变质重结晶结构以及块状或条带状构造。不同种类的麻粒岩捕掳体在矿物组成和矿物成分上存在明显差别,但各主要矿物之间存在一定的成分相关性。应用Ｗｏｏｄ和Ｂａｎｎｏ二辉石温度计的计算结果表明,含二辉石麻粒岩捕掳体的平衡温度分布于８００°～９５０℃之间,主要集中于９００°±５０℃范围内,具Ｏｐｘ＋Ｃｐｘ＋Ｐｌ矿物组合的二辉麻粒岩捕掳体的形成压力范围约为０．６～１．１ＧＰａ。二辉二长麻粒岩落在相似的温压范围内。麻粒岩捕掳体在９５０℃处的突然消失指示了第三纪时汉诺坝地区岩石学壳幔边界的温度。     

汉诺坝玄武岩中熔体-捕虏体相互作用初步研究

汉诺坝新生代玄武岩捕获的地幔橄榄岩及其解体矿物橄榄石、单斜辉石、斜方辉石捕虏晶,普遍发育反应边结构,提供了玄武岩浆在上升穿越岩石圈地幔过程中橄榄岩-熔体相互作用的重要信息。橄榄石和单斜辉石捕虏晶反应边的成分变化一致,由核部富镁向边部富铁变化,趋同于玄武岩中相应斑晶的成分。斜方辉石捕虏晶反应边一般由橄榄石+单斜辉石+玻璃构成,多为双层结构,反应边矿物橄榄石、单斜辉石较相应的地幔矿物富铁,其富硅、碱的中酸性玻璃成分,为中国东部地幔矿物包裹体中存在的富硅、碱熔体的来源提供了重要信息。同时发现橄榄岩捕虏体中尖晶石颜色、成分的变化与温度的关系。地幔矿物捕虏晶反应边结构(非平衡结构)得以保存,暗示了玄武岩浆的快速上升。而大规模的熔体-捕虏体相互作用,改变着岩石圈地幔的性质。     

河北汉诺坝玄武岩中幔源捕虏体中的水

本文对河北汉诺坝玄武岩内的幔源捕虏体矿物进行了系统地红外光谱学研究。结果表明,来自该地区约75km以上的地幔捕虏体普遍含有微量水(0.45×10~(-2)％～11.6×10~(-2)％,以H_2O计算,下同),以OH~-形式主要赋存在辉石(及橄榄石?)中,而不是在角闪石或金云母中。捕虏体中的水可能首先进入橄榄石、石榴石及辉石晶格,角闪石或金云母晶出在后。虽然角闪石及金云母晶格中含有比辉石高百倍的水,但它们所含的水可能是局部水的富集,与相对规模较小的岩浆事件或交代作用有关。早期研究估计的75km以上原始地幔岩中含0.1％水的数据可能偏高。汉诺坝玄武岩捕虏体含水量(多数1.11×10~(-2)％～3.01×10~(-2)％)比大洋中脊玄武岩和南非金伯利岩中捕虏体含水量(多数低于1.00×10~(-2)％)略高。反映了水在上地幔中时间、空间分布的不均匀性。幔源无水硅酸盐矿物中含有微量水这一事实,为了解上地幔中水的分布,水在地幔中的动力学、地球化学过程所起的作用提供了重要基础数据。     

下地壳及壳幔过渡带化学不均一性──河北汉诺坝地区深源捕虏体元素地球化学证据

河北汉诺坝玄武岩中长英质麻粒岩、镁铁质麻粒岩和辉石岩捕虏体的主量元素和微量元素特征,反映了下地壳及壳幔过渡带组成具有高度化学不均一性。不相容元素原始地幔标准化曲线特征的差异表明捕虏体成因复杂。MgO与不相容元素无或仅有很弱的相关性,与相容元素的相关性则相对较明显。这些特征反映了下地壳及壳幔过渡带存在较强和多元的混合作用。捕虏体的加权平均值比基于麻粒岩地体资料估算的下地壳平均组成偏基性,揭示了二者可能的成因差异。     

张家口汉诺坝玄武岩K-Ar年龄计时

汉诺坝玄武岩分布在蒙古高原东南边缘，面积约18000km^2.分为东西两区：东区玄武岩处于赤峰-康保深断裂东部，主要分布于赤峰、围场以北；西区玄武岩出露在建平-承德-赤城深断裂西段，分布于张家口-大同西北。(图1)。     

河北汉诺坝玄武岩中橄榄岩包体矿物的含水性研究——微区红外光谱分析

对12个来自河北汉诺坝玄武岩的橄榄岩包体中的单斜辉石和斜方辉石进行了详细的微区傅立叶变换红外光谱(Micro-FTIR)分析。结果显示,所有的单斜辉石和斜方辉石颗粒都含有以OH形式存在的结构水。对部分粒径较大的辉石颗粒内部的多点分析表明,结构水含量表现出中心高边缘低的不均一分布。这种不均一分布的特征应该来自于包体上升过程中由于压力降低而引起的H扩散。如果用每个样品多个测定颗粒的中心部位的平均值来代表该样品,12个样品的单斜辉石水含量为48×10-6~152×10-6,斜方辉石水含量20×10-6~55×10-6。根据矿物水含量(假设橄榄石的水含量为2×10-6)和它们的体积分数计算的全岩水含量为11×10-6~48×10-6。结合已经发表的橄榄岩包体数据来看,在岩石圈地幔的物理化学条件下,单斜辉石与斜方辉石之间水的平衡分配系数大约为2.2±0.6;岩石圈中水的分布可能具有纵向和横向上的不均一性。     

汉诺坝长英质麻粒岩包体同位素年代学及其地球动力学意义

汉诺坝地区周坝长英质麻粒岩包体的岩石学、地球化学特征指示它们部分为变沉积岩。从周坝麻粒岩相变沉积岩包体的 Sm- Nd同位素分析结果获得了 (424± 10) Ma的全岩-单矿物 Sm- Nd同位素等时线年龄。全岩 Sm- Nd同位素组成指示这些包体可能与地表出露的太古宙麻粒岩有亲缘关系，但二者的 Pb- Pb与 U- Pb锆石年龄又反映二者成因不同。周坝长英质麻粒岩包体可能为残留于大陆下地壳的古老物质。 424 Ma的 Sm- Nd年龄可能反映了与加里东运动时期蒙古板块向华北地台俯冲而发生的变质与再就位抬升作用。     

汉诺坝新生代玄武岩中下地壳麻粒岩包体的变形显微构造特征及其地质意义

新生代玄武岩中的下地壳包体,由于从下地壳被快速携带至地表,因此保留了下地壳的直接信息.华北北部汉诺坝新生代玄武岩中除了含有丰富的幔源包体之外,还含有许多下地壳麻粒岩包体.本文的主要目的是通过对该区下地壳麻粒岩包体的变形显微构造和位错亚构造特征的详细研究,探讨下地壳的变形特征和变形机制.光学显微镜下观测表明,下地壳麻粒岩包体的低温(＜800℃)样品中确实发育显微破裂,但变形双晶、变形条带、扭折带也同样发育,动态重结晶作用也开始出现.随着温度、压力的升高,变形双晶、变形条带、变形纹、扭折带和重结晶新晶粒等塑性变形特征占主导地位,而显微破裂则主要表现为由塑性失配引起的显微破裂以及流体包裹体面.而明显不同于Ivrea带地体麻粒岩,在这些包体中未发现与韧性剪切有关的变形显微构造特征.透射电镜观测表明,包体中的斜长石和辉石颗粒普遍发育自由位错、位错列、亚晶界、新晶界、变形双晶、包裹体列和出溶片晶等位错亚构造.上述观测结果表明,下地壳变形作用以塑性变形为主而不是准脆性变形,其变形机制主要为位错的滑移和攀移机制,其中包括机械双晶作用和动态重结晶作用.     

冀北晚侏罗世张家口组段的划分

4冀北晚侏罗世张家口组的岩石地层单位长期以来一直没有一个较统一的划分方案,划分较为混乱,影响了其合理的地层层序的建立及区域地层对比。根据《冀北中生代陆相火山-沉积盆地1∶25万填图方法研究》项目的工作成果,提出张家口组以相序的岩石组合为基本单元将其依次划分为3个岩性段的方案。一段主要为弱喷发相序的岩石组合;二段主要为爆发相序的岩石组合;三段主要为喷发沉积相序的岩石组合。三者分别代表该组某破火山的初始爆发阶段、大规模爆发阶段和破火口塌陷沉积阶段。由此划分的岩性段可以较好地反映火山构造特征,建立合理的地层层序,有助于火山演化历史的研究,使岩石地层单位的划分与火山-沉积盆地的研究有机地结合在一起。     

Continental crust and lithospheric mantle interaction beneath North China: isotopic evidence from granulite xenoliths in Hannuoba, Sino-Korean craton

Mafic granulite and pyroxenite xenoliths from Cenozoic alkaline basalts at Hannuoba, Hebei Province, North China have been selected for a systematic geochemical and Sr–Nd–Pb isotopic study, which provides a unique opportunity to explore nature of the lower crust and the interaction between the continental crust and lithospheric mantle beneath an Archean craton. The major, compatible and incompatible elements and radiogenic isotopes of these xenoliths suggest great chemical heterogeneity of the lower crust beneath the Hannuoba region. Petrological and geochemical evidences indicate a clear cumulate origin, and most likely, they are related to basaltic underplating in different geological episodes. However, the Sr–Nd–Pb isotopic compositions of the xenoliths reveal a profound enriched source signature (EM I) with some influence of EM II, which implies that some portion of pre-existing, old metasomatized subcontinental lithospheric mantle could have played an important role in their genesis. It is suggested that the interaction between continental crust and subcontinental mantle as manifested by basaltic underplating would be closely related to regional tectonic episodes and geodynamic processes in the deep part of subcontinental lithospheric mantle.     

Chemical and Isotopic Characteristics of Gabbroic Xenoliths from Hannuoba,China

Nine pieces of gabbroic xenoliths from Hannuoba were examined for their major and trace elements and Nd,Sr and Pb isotopes.The results show that the gab-broic xenoliths are of more mafic basaltic composition .Their abundances show narrow variations in major elements.The trace element contents are highly variable in contrast with those of host basalts and lherzolite xenoliths.The gabbroic xenoliths are rich in Nd(0.51159-0.51249),Sr(0.70491-0.70768) and low in radiogenic Pb(16.283-17.046, 15.191-15.381 and 36.999-37.476),significantly different from basalts and lherzolites in isotopic space.The calculated Nd and Pb model ages are about 3.0-3.5 Ga.The rocks have relatively low equilibrium T(-850℃) and P(0.8-0.9 Gpa).They could be inter-preted to be the product of upper mantle melting at the boundary between the lower crust and the upper mantle.Their chemical and isotopic variations can be ascribed to different degrees of melting,segregation and long-term evolution.     

Petrology and geochemistry of spinel peridotite xenoliths from Hannuoba and Qixia, North China craton

We report mineralogical and chemical compositions of spinel peridotite xenoliths from two Tertiary alkali basalt localities on the Archean North China craton (Hannuoba, located in the central orogenic block, and Qixia, in the eastern block). The two peridotite suites have major element compositions that are indistinguishable from each other and reflect variable degrees (0–25%) of melt extraction from a primitive mantle source. Their compositions are markedly different from typical cratonic lithosphere, consistent with previous suggestions for removal of the Archean mantle lithosphere beneath this craton. Our previously published Os isotopic results for these samples [Earth Planet. Sci. Lett. 198 (2002) 307] show that lithosphere replacement occurred in the Paleoproterozoic beneath Hannuoba, but in the Phanerozoic beneath Qixia. Thus, we see no evidence for a compositional distinction between Proterozoic and Phanerozoic continental lithospheric mantle. The Hannuoba xenoliths equilibrated over a more extensive temperature (hence depth) interval than the Qixia xenoliths. Neither suite shows a correlation between equilibration temperature and major element composition, indicating that the lithosphere is not chemically stratified in either area. Trace element and Sr and Nd isotopic compositions of the Hannuoba xenoliths reflect recent metasomatic overprinting that is not related to the Tertiary magmatism in this area.     

Thermal and petrological structure of the lithosphere beneath Hannuoba, Sino-Korean Craton, China: evidence from xenoliths

Deep-seated xenoliths entrained in the Hannuoba basalts of the northern Sino-Korean Craton include mafic and felsic granulites, mantle wall-rock from spinel– and garnet–spinel peridotite facies, and basaltic crystallisation products from the spinel-pyroxenite and garnet-pyroxenite stability fields. The mineral compositions of the xenoliths have been used to estimate temperatures and, where possible, pressures of equilibration, and to construct a geothermal framework to interpret the upper mantle and lower crustal rock-type sequences for the region. The xenolith-derived paleogeotherm is constrained in the depth interval of 45–65 km and like others from areas of young basalt magmatism, is elevated and strongly convex toward the temperature axis. Two-pyroxene granulites give the lowest temperatures and garnet pyroxenites the highest, while the spinel lherzolites fall between these two groups. The present-day Moho beneath the Hannuoba area is defined at 42 km by seismic data, and coincides with the deepest occurrence of granulite. Above this boundary, there is a lower crust–upper mantle transition zone about 10-km thick, in which spinel lherzolites and mafic granulites (with variable plagioclase contents) are intermixed. It is inferred that this underplating has resulted in a lowering of the original pre-Cenozoic Moho (then coinciding with the crust–mantle boundary, CMB) from about 30 km to its present-day position and was due to intrusions of basaltic magmas that displaced peridotite mantle wall-rock and equilibrated to mafic granulites. Trace element patterns of the diopsides (analysed by laser ablation-ICPMS) from the Cr-diopside series spinel lherzolites and associated layered xenoliths (spinel lherzolites and pyroxenites) indicate a fertile uppermost mantle with moderate depletion by low degrees of partial melting and little evidence of metasomatic activity. The similarity in major and trace element compositions of the minerals in both rock types suggests that the layered ultramafic xenoliths formed by mantle deformation processes (metamorphic segregation), rather than by melt veining or metasomatism.