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1.
Investigations undertaken in 2013 at a foreshore site that was historically used for ship repairs in Korea indicated that soil and groundwater were contaminated with petroleum hydrocarbons over an area of 10,000 m2. Groundwater investigations and modelling were undertaken to determine the characteristics of aquifers beneath the site, including the direction and rate of groundwater flow and the extent of dispersion of total petroleum hydrocarbon contamination. To identify petroleum products residing in contaminated soils, the hump of an unresolved complex mixture on the baseline found in the data of gas chromatography was used as a new method. Based on objective facts obtained from basic investigation, the current state of contamination, and discrimination of oil species, the polluter as specified in the Korean Soil Environment Conservation Act was identified.  相似文献   

2.
Bioremediation strategies continue to be developed to mitigate the environmental impact of petroleum hydrocarbon contamination. This study investigated the ability of soil microbiota, adapted by prior exposure, to biodegrade petroleum. Soils from Barrow Is. (W. Australia), a class A nature reserve and home to Australia’s largest onshore oil field, were exposed to Barrow production oil (50 ml/kg soil) and incubated (25 °C) for successive phases of 61 and 100 days. Controls in which oil was not added at Phase I or II were concurrently studied and all treatments were amended with the same levels of additional nutrient and water to promote microbial activity. Prior exposure resulted in accelerated biodegradation of most, but not all, hydrocarbon constituents in the production oil. Molecular biodegradation parameters measured using gas chromatography–mass spectrometry (GC–MS) showed that several aromatic constituents were degraded more slowly with increased oil history. The unique structural response of the soil microbial community was reflected by the response of different phospholipid fatty acid (PLFA) sub-classes (e.g. branched saturated fatty acids of odd or even carbon number) measured using a ratio termed Barrow PLFA ratio (B-PLFAr). The corresponding values of a previously proposed hydrocarbon degrading alteration index showed a negative correlation with hydrocarbon exposure, highlighting the site specificity of PLFA-based ratios and microbial community dynamics. B-PLFAr values increased with each Phase I and II addition of production oil. The different hydrocarbon biodegradation rates and responses of PLFA subclasses to the Barrow production oil probably relate to the relative bioavailability of production oil hydrocarbons. These different effects suggest preferred structural and functional microbial responses to anticipated contaminants may potentially be engineered by controlled pre-exposure to the same or closely related substrates. The bioremediation of soils freshly contaminated with petroleum could benefit from the addition of exhaustively bioremediated soils rich in biota primed for the impacting hydrocarbons.  相似文献   

3.
Four seep sites located within an ∼20 km2 area offshore Georgia (Batumi seep area, Pechori Mound, Iberia Mound, and Colkheti Seep) show characteristic differences with respect to element concentrations, and oxygen, hydrogen, strontium, and chlorine isotope signatures in pore waters, as well as impregnation of sediments with petroleum and hydrocarbon potential. All seep sites have active gas seepage, near surface authigenic carbonates and gas hydrates. Cokheti Seep, Iberia Mound, and Pechori Mound are characterized by oil-stained sediments and gas seepage decoupled from deep fluid advection and bottom water intrusion induced by gas bubble release. Pechori Mound is further characterized by deep fluid advection of lower salinity pore fluids. The Pechori Mound pore fluids are altered by mineral/water reactions at elevated temperatures (between 60 and 110 °C) indicated by heavier oxygen and lighter chlorine isotope values, distinct Li and B enrichment, and K depletion. Strontium isotope ratios indicate that fluids originate from late Oligocene strata. This finding is supported by the occurrence of hydrocarbon impregnations within the sediments. Furthermore, light hydrocarbons and high molecular weight impregnates indicate a predominant thermogenic origin for the gas and oil at Pechori Mound, Iberia Mound, and Colkheti Seep. C15+ hydrocarbons at the oil seeps are allochtonous, whereas those at the Batumi seep area are autochthonous. The presence of oleanane, an angiosperm biomarker, suggests that the hydrocarbon source rocks belong to the Maikopian Formation. In summary, all investigated seep sites show a high hydrocarbon potential and hydrocarbons of Iberia Mound, Colkheti Seep, and Pechori Mound are predominantly of thermogenic origin. However, only at the latter seep site advection of deep pore fluids is indicated.  相似文献   

4.
Number 6 fuel oil is one of the most used energy sources for electricity generation. However, leaks can contaminate soil and also groundwater due to leaching. At old sites, the oil may have low toxicity but still contaminate groundwater with foul-tasting compounds even at low concentrations. The purpose of this study was to evaluate the feasibility of applying H2O2 to reduce the leaching potential of a fuel oil contaminated soil. A silt-loam soil was collected from a contaminated thermal-electric plant with a hydrocarbon concentration of 3.2% in soil producing 4.3 mg/l in leachate. Hydrogen peroxide was applied (0.1, 0.2, 0.3, 0.6, 1.2% dry weight basis), and petroleum hydrocarbons were measured in soil and leachate pre- and post-treatment (72 h). At first, the soil and leachate concentrations diminished linearly (24.4 and 27.3% in soil and leachate, respectively). This was followed by a phase in which the concentration in leachate diminished greatly (75.8%) although the concentration in soil was reduced only moderately (15.1%). Overall, hydrocarbons in leachates were reduced 82.4% even though concentrations in soil were only reduced 35.8%. Correlation analysis showed that at only 1.0% w/w H2O2 a concentration of petroleum hydrocarbons in leachate safe for human consumption (≤ 1 mg/l) could be obtained even with a final hydrocarbon concentration in soil > 2%. Thus, this study presents an alternative strategy for remediation of fuel oil contaminated soils in urban environments that protects water sources by focusing on contamination in leachates, without spending extra financial resources to reduce the hydrocarbon concentration in low-toxicity soil.  相似文献   

5.
许锦  席斌斌  蒋宏 《岩矿测试》2016,35(4):389-396
油气包裹体广泛应用于油气成藏研究,但油气包裹体能否继承母油荧光及地球化学特征等,尚缺乏直接的实验证据。本文在开放体系下用NaCl挥发结晶法对一轻质原油进行合成烃类包裹体实验,通过镜下观察和激光剥蚀色谱-质谱技术分析合成的烃包裹体和母油的荧光特征、成分特征及地化特征,研究两者的异同点。结果表明,在NaCl合成烃类包裹体中共发现三种相态的包裹体:纯液相烃包裹体、气液两相烃包裹体和气油水三相包裹体;共有绿黄色荧光、蓝色荧光两种不同颜色的荧光特征。相对于母油,合成包裹体的饱和烃和芳烃类化合物中的轻质组分含量较低,可以推测在母油被捕获成为包裹体的过程中,不同的化学成分存在差异性捕获。但合成包裹体的Pr/Ph等地化参数和不同系列化合物相对含量与母油相差不大,能很好地反映母油的沉积环境等地化特征。因此,包裹体成分信息可以应用于油源对比分析。  相似文献   

6.
Surface sediments from the Outer Continental Shelf of Alaska were analyzed for hydrocarbons as part of an environmental survey sponsored by NOAA/BLM. Sediments were collected from the proposed oil lease areas of Beaufort Sea, southeastern Bering Sea, Norton Sound, Navarin Basin, Gulf of Alaska, Kodiak Shelf and lower Cook Inlet. Data on normal and branched alkanes and di- and triterpenoids from capillary gas chromatography (GC) and gas chromatography-mass spectrometry (GC/ MS) indicate that the area displays little evidence of petroleum hydrocarbons (i.e., seeps) except at a few isolated stations. Beaufort Sea sediments have the highest hydrocarbon budget, whereas Kodiak Shelf sediments have the lowest. The molecular markers of the hydrocarbons are of a mixed marine autochthonous and terrestrial allochthonous origin. Norton Sound and Cook Inlet sediments contain the highest levels of terrigenous lipids and Kodiak Shelf the lowest. The abundance of alkenes implies that relatively low oxidizing conditions exist in some of the depositional areas studied, suggesting that extraneous petroleum hydrocarbons introduced into these sediments would be expected to have a relatively long residence time. The distribution of polynuclear aromatic hydrocarbons (PAH) is complex and shows a pyrolytic origin. The data on perylene strongly favor the hypothesis that it is “performed” from terrigenous precursors and transported into the marine environment with no apparent in situ generation. Polynuclear aromatic hydrocarbons of diagenetic origin are probably dominant in Gulf of Alaska and Kodiak Shelf sediments.Two stations, north of Kalgin Island, in lower Cook Inlet and one in southeastern Bering Sea show typical weathered petroleum distribution of n-alkanes and triterpenoids. Probable pathways of transport and fate of petroleum hydrocarbons in case of an oil spill are also briefly discussed.  相似文献   

7.
The purpose of this study was to investigate the effect of phytoremediation on soils contaminated with heavy crude oil using plants infected by mycorrhizal fungi. Five plant species, Vetiveria zizanioides, Bidens pilosa, Chloris barbata, Eleusine indica, and Imperata cylindrica, infected with the species of mycorrhizal fungi Glomus mosseae, were selected for this study. The degradation of total petroleum hydrocarbons in soils and several physiological parameters of plants such as shoot length and biomass were analyzed. Out of the 5 plant species tested, only V. zizanioides, B. pilosa, and E. indica could take up the G. mosseae. Out of these three, V. zizanioides showed the greatest growth (biomass) in soils with 100,000 mg kg?1 total petroleum hydrocarbons. In addition, B. pilosa infected with G. mosseae was found to be able to increase degradation by 9 % under an initial total petroleum hydrocarbons concentration of 30,000 mg kg?1 in soils after 64 days. We conclude that plants infected with mycorrhizal fungi can enhance the phytoremediation efficiency of soils contaminated with high concentrations of heavy oil.  相似文献   

8.
鄂尔多斯盆地延长组油源一直存在争议,尤以长8~长10油藏的油源问题最为突出。通过吴堡地区延长组长6~长10原油的物理性质、族组成、生物标志化合物等特征,油-油、油-源对比等综合分析,探讨延长组原油的成因,明确各油层组石油来源,为该区的油气勘探与预测提供地质依据。结果显示,长6~长10原油族组分具有饱和烃含量最高,芳香烃次之,非烃和沥青质含量最低的特征。长6~长10均为成熟原油,显示出低等水生生物和高等植物混合成因,但长6原油与长7~长10原油族组成特征存在明显差异。长6原油为长7烃源岩早期烃类运移的结果,其成熟度最低,长7~长10原油为生烃高峰阶段石油运移结果,成熟度较高。长6和长7油藏的原油主要为长7底部张家滩页岩贡献,此外,长7中上部和长6地层中发育的有效烃源岩也有一定贡献。长8油藏原油为混合成因原油,主要为长7底部烃源岩向下运移结果,其次为长8内部烃源岩和长9顶部李家畔页岩之贡献。长9油藏原油主要为李家畔页岩向下倒灌形成,长10油藏可能主要为长92有效烃源岩向下运移成藏。热成熟度不同是导致远离主力烃源岩原油族组分之间差异性的主要原因。  相似文献   

9.
热液烃的生成与深部油气藏   总被引:25,自引:1,他引:25  
热液烃不仅分布于洋底,在大陆也有广泛分布,实验表明:热液对碳酸盐岩和沉积有机质的作用均有油气生成;洋底火山岩流体包裹体、原油、有机质Pb、Sr、Nd同位素均表明地幔流体在油气生成中的作用。认识热液烃的存在对开拓深部油气藏的勘探有重要意义。  相似文献   

10.
Cape Kalamba oil seeps occur at the south end of the Ubwari Peninsula, at the intersection of faults controlling the morphology of the northern basin of the Tanganyika Rift, East Africa. Oil samples collected at the surface of the lake 3-4 km offshore from Cape Kalamba have been studied. The aliphatic hydrocarbon and biomarker compositions, with the absence of the typical suite of polynuclear aromatic hydrocarbons, indicate an origin from hydrothermal alteration of immature microbial biomass in the sediments. These data show a similarity between a tar sample from the beach and the petroleum from the oil seeps, and confirm that the source of these oils is from organic matter consisting mainly of bacterial and degraded algal biomass, altered by hydrothermal activity. The compositions also demonstrate a < 200 degrees C temperature for formation/generation of this hydrothermal petroleum, similar to the fluid temperature identified for the Pemba hydrothermal site located 150 km north of Cape Kalamba. The 14C age of 25.6 ka B.P. obtained for the tar ball suggests that Pleistocene lake sediments could be the source rock. Hydrothermal generation may have occurred slightly before 25 ka B.P., during a dry climatic environment, when the lake level was lower than today. These results also suggest that the Cape Kalamba hydrothermal activity did not occur in connection with an increased flux of meteoric water, higher water tables and lake levels as demonstrated in the Kenya Rift and for the Pemba site. Hydrothermal petroleum formation is a facile process also in continental rift systems and should be considered in exploration for energy resources in such locales.  相似文献   

11.
为探究长庆油田污染土壤中微生物对石油的降解特性,在该油田多个油井附近采集了10处含油污染土壤进行石油烃降解菌的筛选、分离及降解实验。通过对筛选出的四株石油烃降解菌株5-5、5-X、9-2、10-3进行革兰氏染色、菌落形态观察、生化理化试验及16S rDNA测序,鉴定出这四株菌株分别为醋酸钙不动杆菌(Acinetobacter calcoaceticus)、不动杆菌(Acinetobacter sp.)、蒙氏假单胞菌(Pseudomonas monteilii)和乳酸不动杆菌(Acinetobacter lactucae)。14 d降解实验结果显示,这四种菌株对总石油烃的降解率分别为50.92%、51.27%、78.30%和44.39%;尤其菌株Pseudomonas sp.9-2表现出优异的降解性能,且对不同组分石油烃(正构烷烃、异构烷烃及芳烃)的降解率分别达到了94.65%、69.73%和59.07%,对长链正构烷烃也体现出了较好的降解性能。另外,抗逆性试验结果表明菌株Pseudomonas sp.9-2对pH和盐度的耐受范围分别为5.0~10.0、0.5%~6.0%,表明该菌株对盐碱环境具有较好的适应性,可用于盐碱石油污染土壤的微生物修复研究。  相似文献   

12.
西非塞内加尔盆地深水区油气地球化学特征与油气成藏   总被引:1,自引:0,他引:1  
孙涛  王建新  孙玉梅 《沉积学报》2017,35(6):1284-1292
塞内加尔盆地是西非面积最大、勘探程度最低的含盐被动大陆边缘型盆地。2010年之前仅有少量非商业性的油气和重质油发现,近几年在深水区获得油气勘探的重大突破。对深水区油气进行详细地球化学分析及油源对比,结果表明:深水区发育下白垩统阿普特-阿尔布阶和上白垩统赛诺曼-土伦阶两套烃源岩,下白垩统阿普特-阿尔布阶烃源岩的碳同位素组成偏轻,含硫量低,处于成熟-高成熟演化阶段,局部达到过成熟演化阶段;上白垩统赛诺曼-土伦阶烃源岩碳同位素组成偏重,含硫量中等,处于低成熟度-成熟演化阶段。油源对比的结果显示深水区F-1井阿尔布阶储层原油来自阿普特-阿尔布阶烃源岩,F-1土伦阶储层原油来自赛诺曼-土伦阶烃源岩,而S-1井阿尔布阶储层油样性质介于二者之间,为混源的原油。  相似文献   

13.
中国非常规油气勘探与研究新进展   总被引:2,自引:0,他引:2  
全球油气勘探目标的转移和石油地质学的发展,具有从毫-微米孔喉的圈闭油气,逐渐向纳米孔喉的连续型油气聚集发展的趋势。近十年非常规油气资源在全球能源格局中的地位愈发重要,致密气、煤层气、重油、沥青砂等已成为勘探开发的重点领域,致密油成为亮点领域,页岩气成为热点领域。中国致密气、页岩气、致密油、煤层气等非常规油气资源勘探开发取得重要突破,油页岩、天然气水合物、油砂矿等有重要进展。中国非常规油气研究也取得重大进展,陆相敞流湖盆大型浅水三角洲砂体、湖盆中心砂质碎屑流沉积和湖相碳酸盐岩等,提供了湖盆中心储集体形成和分布的理论依据;创新发展了连续型油气聚集理念,明晰了连续型油气聚集的10个基本地质特征和2项关键标志,为大面积非常规油气规模勘探开发奠定了理论基础;系统表征了致密油气储层的纳米级微观孔喉结构,首次发现了纳米孔喉中油气的赋存,推动了纳米孔喉中油气流动机制和分布规律的研究。随着全球石油工业和纳米等技术的快速发展,提出了"纳米油气"概念,并指出这是未来石油工业的发展方向,需要发展纳米油气透视观测镜、纳米油气驱替剂、纳米油气开采机器人等换代技术,油气智能化时代即将到来。  相似文献   

14.
从长江经济带某在役石化场地采集了3个点位不同深度的土壤样品,测定了石油烃等污染物的含量和微生物的群落结构,以揭示污染物分布规律和微生物特征。结果显示,3个点位污染程度不同,但污染物含量均随深度先升高后降低,最高含量均出现在埋深4.0 m左右,即地下水位附近。土壤中C6-C9高达5 302 mg/kg,C10-C40高达625.6 mg/kg,芳烃高达455.2 mg/kg,卤代烃高达41.54 mg/kg。土壤微生物的丰富度和多样性随深度增加而降低,同一深度土壤微生物的丰富度和多样性随污染物含量增大而降低。门水平上Actinobacteria、Firmicutes和Spirochaetes的相对丰度和石油烃含量显著正相关(p<0.05),属水平上Streptomyces、SCADC1-2-3、DesulfitobacteriumCryptanaerobacter的相对丰度和石油烃含量显著正相关(p<0.05)。  相似文献   

15.
A crude contaminated soil, arising from an oil production zone in Tabasco, Mexico was studied. A sample of about 40 kg was dried and screened through meshes 10–100. Total petroleum hydrocarbons and 6 metals (Cd, Cu, Cr, Ni, V and Zn) were determined to the different portions. For soil which passed mesh 10, six non-ionic, three anionic and one zwitterionic surfactant solutions (0.5%) were employed to wash the soil. Additional tests using surfactant salt mixtures and surfactants mixtures were carried out. Once the best soil washing conditions were identified, these experimental conditions were applied for washing the rest of the soil portions obtained (meshes 4, 6, 20, 40, 60, 80, 100). Total petroleum hydrocarbons values were in the range of 51, 550 to 192, 130 mg/kg. Cd was not found in any of the soils portions, and the rest of the metals were found at different concentrations, for every soil mesh. Treatability tests applied to the soils indicated that it is possible to get removals between 9.1 to 20.5%. For the case of a sodium dodecyl sulphate 1% solution, total petroleum hydrocarbons removal was as high as 35.4%. Combinations of sodium docecyl sulphate and salts, gave removal rates up to 49.5%. Total petroleum hydrocarbons concentrations for the whole soil were about 150,600 mg/kg. The higher the particle size, the lower the washing removal rate. The combined effect of particle size and total petroleum hydrocarbons concentration, determines the total petroleum hydrocarbons removal efficiencies. These facts are very important for designing an appropriate soil washing remediation process.  相似文献   

16.
在探讨高邮凹陷断层发育时期和分布特点的基础上,结合油气分布特点,分析了断层在油气成藏中的作用类型,并探讨了其作用机理。依据断层在油气生成、运移、聚集和分布环节中的作用,把断层分为控源断层、供烃断层、改向断层、成圈断层和调整破坏断层。控源断层控制有效烃源岩展布和生烃时期的早晚,高邮凹陷控源断层下降盘为有效烃源岩分布区,而且西部地区早于东部地区生烃;供烃断层控制油气主运移通道的走势,其陡断面和凸断面为高邮凹陷断裂带油气的主运移通道;改向断层影响油气的富集层位和油气富集区的位置,其对高邮凹陷油气分布的影响存在“分散”和“富集”两种效应;成圈断层控制圈闭的类型及分布;调整破坏断层导致圈闭充满程度和原油物性的改变,高邮凹陷调整破坏断层为盐城期和三垛期活动断层。高邮凹陷断层的多期性和多样性导致断层体系中各断层封闭性在时空上的差异性和多变性,从而形成对油气控制的多面性和复杂性。  相似文献   

17.
A comprehensive study of authigenic carbonates and associated fauna in Late Albian organic‐rich, deep‐water deposits (the Black Flysch Group) reveals that carbonate precipitation was a by‐product of the anaerobic oxidation of hydrocarbon‐rich hydrothermal fluids. The authigenic carbonates are exposed along the Kardala and Alkolea sea cliffs in the western Pyrenees. The two vent carbonates occur 1 km apart adjacent to the synsedimentary, right‐reverse Mutriku fault, but in contrasting structural domains: the Kardala carbonates occur on a structural ridge (hangingwall) and the Alkolea carbonates are positioned at the base of an erosional scarp (folded downward footwall). The similarity in pattern of the carbonate phases and complex paragenetic events for both vent precipitates implies that hydrothermal fluid generation processes and pore‐water evolution during early and late diagenesis were similar. Nevertheless, a comparison of the geochemistry, fossil fauna and morphology of carbonate structures of both precipitates suggests that the vented hydrocarbon type, flow intensity and temperature of hydrothermal fluids were different. At the Kardala vent, intense focused flow of hot (up to 109 °C), oil‐rich fluids were generated, allowing the development of a relatively abundant chemosynthesis‐based fauna. In contrast, at the Alkolea vent, diffuse flows of warm, thermogenic methane‐rich fluids were expelled to the sea floor and no chemosynthetic fauna developed. These differences are related to the contrasting structural setting of each locality. Similar δ13Corg values for both pyrobitumen‐fills and host unit organic matter suggest that the hydrocarbon source was the Black Flysch Group. Contact alteration of these organic‐rich sediments by syndepositional hydrothermal fluids generated hydrothermal petroleum (oil and gas hydrocarbons) which probably migrated updip to the sea floor by contemporary compression tectonics.  相似文献   

18.
Processes that control the distribution and natural attenuation (NA) of petroleum hydrocarbons dissolved from the released diesel fuel in a bench-scale model aquifer were evaluated. The experimental results obtained in two-dimensional aqueous-phase petroleum hydrocarbon concentrations indicated that the total petroleum hydrocarbon (TPH) in the aquifer migrated in longitudinal and lateral directions. The TPH plume of 2 mg L?1 spread to the entire area of the aquifer, and the maximum concentration at the center of the plume was 44.15 mg L?1 after 90 days of release. After diesel fuel release, the NA of TPH was evaluated and quantified. Experimental data indicated that the NA of TPH was immediately implemented to prevent migration of the plume into the downgradient of the aquifer, but controlling the TPH plumes using NA mechanisms requires a long time.  相似文献   

19.
High concentrations of hydrocarbons (500–3000 μg/g dry weight) together with a complex and wide molecular weight range of composition, and low 14C activity of δ14C = ?833 ± 50%. strongly indicate that fossil fuel hydrocarbons make up the bulk of hydrocarbons in and near the New York Bight dump site areas. The composition and concentrations of hydrocarbons in Hudson Channel sediments suggest some transport of dump site hydrocarbons to areas in the channel midway to the edge of the continental shelf. Sediments at 16 stations in other areas of the continental shelf, continental slope and abyssal plain have hydrocarbon concentrations and compositions indicating that no more than 1 μg/g dry weight of fossil fuel hydrocarbons are present.N-alkanes from land sources were among the most predominant hydrocarbons in all samples except those in the New York Bight region. Their presence in abyssal plain surface sediments documents transport of some land derived organic matter to these deep ocean areas. Two 25-carbon cycloalkenes are among the more predominant hydrocarbons in continental shelf surface sediments except for the dump site areas. These two compounds are present in lower concentrations in slope sediments and are not detected in abyssal plain sediments.  相似文献   

20.
环境温度影响石油黏滞性,改变石油污染土的力学特性。借助无侧限抗压强度试验,研究不同温度条件下石油污染滨海盐渍土的强度及变形特性。结果证实:温度对石油污染盐渍土力学性质影响显著,温度越高,污染土抗压强度越低,20℃时,含油率15%污染土的抗压强度较未污染土下降近70%;石油污染滨海盐渍土的抗压强度随含油率的增加先增大后减小,环境温度与污染土强度峰值点处的含油率反相关,10℃、20℃、30℃条件下,强度峰值点处的含油率分别为15%、10%和5%;石油污染盐渍土表现为应变软化型破坏,含油率及环境温度影响石油污染盐渍土的抗变形能力,土样的破坏面积和裂缝宽度随含油率增加及温度升高而增大。  相似文献   

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