Toxic effect of Pb, Cd, Ni and Zn on Azolla filiculoides in the International Anzali Wetland

The limitation of plant growth in the polluted mediums can be used as a factor to determine of plant tolerance and the toxic effect of these mediums. In this work, the effect of Pb²⁺, Cd²⁺, Ni²⁺and Znsu2+ (individually) on Azolla filiculoides growth in the aqueous solution and using this method to water post treatment were studied. During 15 days the biomass the fresh Azolla with initial mass of 20 g was grown on the nutrient solution containing these metal ions, each in a concentration 4 mg/l. The presence of these ions, caused about 25%, 42%, 31% and 17% inhibition of biomass growth, respectively, in comparison to Azolla control weight which had not heavy metals. The water salinity of 1, 2 and 4 g. NaCl/l decreased the removal of these heavy metals about 4–7%, 20–24% and 40–55%, respectively. The addition of total dissolved solids (TDS) from 50 to 300 ppm. (as CaCO₃) into the samples of containing heavy metals increased Azolla growth, but decreased the control Azolla growth.     

基于综合识别方法的河北白洋淀湿地提取研究

湿地作为地球上宝贵的自然资源,在维持自然生态平衡、改善生态环境、防治污染等方面具有极其重要的功能。基于Landsat 8 OLI遥感数据,通过对比分析关于湿地和水体的不同提取方法及结果,确定了适合于白洋淀淀区湿地和开阔水体的最佳提取方法,并利用改进的指数方法和谱间关系法分别对淀区湿地和开阔水体进行了定量化提取。鉴于白洋淀淀区湿地主要包括开阔水体和芦苇区两部分,将淀区内湿地和开阔水体进行几何拓扑后,得到淀区内芦苇区的范围。总结出一套适用于白洋淀湿地及其组成部分提取的综合方法,为利用遥感技术在白洋淀淀区内提取湿地及相关信息提供了方法借鉴。     

Metal pollution assessment and multivariate analysis in sediment of Anzali international wetland

Anzali international wetland located in southwestern Caspian Sea coast is one of the most important wetlands of Iran from environmental and ecological points of view. Metal concentrations (Cu, Zn, Cr, Fe, Mn, Pb, Ni, Cd, and Li) in 41 surface sediment samples from Anzali wetland were determined. Assessment of ecological risk of sediment samples as well as their degree of contamination revealed considerable ecological risk and moderate degree of contamination in eastern part of the study area. Multivariate statistical analyses were used to identify metal content relationship and their origin. Higher enrichment factors of Cd, Pb, and Zn exhibited probable effects on human activities. Based on sediment quality guidelines (SQGs), moderate potential toxicity levels of sediment samples were identified. A new sediment quality index named sediment toxicity degree was developed based on the results of the multivariate statistical analysis to assess metal toxicity in surface sediments of aquatic systems. Results showed higher sensitivity of the new index (ST_d) to assess toxic effect of heavy metals on sediments and better capability to differentiate zones with different levels of risk within the study area than that of some other indices such as SQG-Q.     

沉湖湿地近50年退化过程识别

沉湖湿地作为长江中下游平原典型湖泊湿地,1960s以来退化严重.收集1964、1975、1987、1997、1998、2007、2016、2018年8期航拍照片或遥感影像,运用遥感技术、动态度模型和转移矩阵模型分析,揭示武汉市沉湖湿地近50年退化过程及机理.结果表明,1964~2018年沉湖湿地由北向南退缩为鱼塘及耕地,总湿地面积缩小77%;湿地退化过程可分为3个阶段,1964~1975年围湖活动主导湿地湖泊向耕地退化,耕地面积以141%的年变幅扩张,1975~1997年湖泊改造工程迫使湖泊向沼泽退化,1997~2018年由湖泊退化而来的沼泽被进一步开垦为耕地或鱼塘;人口数量的增加及土地利用政策改变导致湿地生态服务功能退化,包括洪水调蓄、自净化功能衰退及生物多样性锐减,其退化模式可为长江中下游平原乃至全国湖泊湿地的退化提供类比参考.      

Identification and geochemical significance of polarized macromolecular compounds in lacustrine and marine oils

Polarized macromolecular compounds in typical lacustrine and marine shale oils collected from the Ordos Basin and Tarim Basin of China were analyzed by FT-ICR-MS. Maturity was taken into consideration by diagenesis physical simulation experiments on shale oils, which had been collected at various temperature and pressure stages. The results showed that similar components existed in non-hydrocarbon and asphaltenes and the main peak compound classes of Nl and 02 were potential parameters for identifying typical marine oil and lacustrine oil in China. Nitrogen compounds/（nitrogen compounds and oxygen compounds）, such as Nl/（O2＋Nt）, NL/（Oa＋Nt）, Ni/（NiO1＋N1O2） are the maturity indicators, which are related with C-N and C-O bond energy. Differences in molecular components and weights between marine and lacustrine oils are the effective index to identify source maturity and sedimentary environment.     

冻土中微裂纹尺寸的识别与确认

在对冻土微观结构试验观测的基础上,提出了对冻土中微裂纹尺寸进行识别和确认的方法,给出了3种典型土质在不同温度下的微裂纹尺寸参考值,为应用冻土强度破坏准则进行定量计算与分析提供依据。将冻土微裂纹损伤区作为冻土体的缺陷处理,并按“当量化裂纹”原则,把冻土微裂纹损伤区简化为“当量裂纹”,如此给出了理论估算微裂纹尺寸的新途径。把理论计算与试验观测结果进行比较,二者符合较好。     

湿地溶解性有机质（DOM）源识别方法研究

湿地是位于水陆生态系统之间的重要生态交错带,而溶解性有机质(DOM)是陆地向水生生态系统输送营养物质的重要载体物质。湿地中DOM的来源分为内源和外源。对湿地中DOM的来源进行识别有助于认识湿地中营养物质的生物化学循环特征,从而进一步了解水陆生态系统之间的物质循环。目前,对湿地DOM进行源识别的方法较多。根据各种方法在研究中应用的广泛性和可用性,本文主要介绍了光学法、同位素法、C/N比值法和生物标志法在湿地DOM源识别中的应用。综合分析表明,光学法、同位素法和C/N比值法在湿地DOM源识别研究中的应用较多。近几年,由于生物标志物(特别是木质素)不仅能够对来源进行识别,而且对源的变化很敏感,因此生物标志法在湿地DOM源识别中的应用成为研究的热点。论文在分析各种湿地DOM源识别方法的基础上,指出了目前研究中存在的问题,并提出进一步研究的方向。     

Evaluating the accuracy of ANN and LR models to estimate the water quality in Zarivar International Wetland,Iran

One of the most important qualitative aspects of wetland ecosystem management is preserving the natural quality of water in such environments. This would not be achievable unless continuous water quality monitoring is implemented. With the recent advances in remote sensing technology, this technology could assist us to produce accurate models for estimating water quality variables in the ecosystem of wetlands. The present study was carried out to evaluate the capability of remote sensing data to estimate the water quality variables [pH, total suspended solids (TSS), total dissolved solids (TDS), turbidity, nitrate, sulfate, phosphate, chloride and the concentration of chlorophyll a] in Zarivar International Wetland using linear regression (LR) and artificial neural network (ANN) models. For this purpose, spectral reflectance of bands 2, 3, 4 and 5 of the OLI sensor of Landsat 8 was utilized as the input data and the collected chemical and physical data of water samples were selected as the objective data for both ANN and LR models. Based on our results overall, ANN model was the proper model compared with LR model. The spectral reflectance in bands 5 and 4 of OLI sensor revealed the best results to estimate TDS, TSS, turbidity and chlorophyll in comparison with other used bands in ANN model, respectively. We conclude that OLI sensor data are an excellent means for studying physical properties of water quality and comparing its chemical properties.     

多环芳烃生物恢复技术的研究进展

多环芳烃是一大类广泛存在于环境中的有机污染物，本文介绍了多环芳烃生物恢复的三种不同方法：就地耕作法，场外耕作法和塞流式污泥生物反应器，并对其研究现状和最新研究成果进行了归纳，总结和探讨。     

中国不同地区典型河流中多环芳烃分布特征研究

为了调查研究我国大面积不同流域河流系统中多环芳烃分布特征以及不同地区之间的来源差异,选择了分别代表中国中部、西部和东北部的长江武汉段、涪江及松花江为研究区域,测定了河流水体中16种优先PAHs的含量,并进行了其污染来源识别。结果表明,16种多环芳烃含量范围为N.D.～317.56 ng/L,最高值出现在长江武汉段;在16种多环芳烃单体中,不同地区呈现出不同的组成特征,涪江和松花江以低环PAH组成为主,而长江武汉段高环PAH含量增加;其组分含量高低及特征比值分析结果显示松花江和涪江的来源主要是燃烧源,而长江武汉段来源复杂。     

湖州市不同土地利用类型土壤中多环芳烃的分布及来源

近年来我国长江河口有关沉积物中多环芳烃（PAHs）污染的研究主要集中在长江口近海及上海主城区滨岸等区域,而长江口航道则鲜有报道。本文在长江口启东—崇明岛航道区域采集表层（0~20 cm）沉积物样品,利用加速溶剂萃取技术提取,用高效液相色谱-荧光检测器对14种PAHs进行测定,研究其分布特征、环境来源和潜在的生态风险。研究结果显示,PAHs在所有沉积物样品中均有不同程度的检出,浓度范围为83.43~5206.97 ng/g,平均值736.95 ng/g。就PAHs单体而言,含量较高的是2~4环污染物,其中菲的含量最高,占各点位PAHs总量的9.04%~24.06%;其次为荧蒽和芘;具有高致癌性的苯并（a）芘在各个点位均能检出,占PAHs总量的0.94%~10.68%。与国内外类似河口和近海海域相比,本研究区PAHs处于中等污染水平。利用比值法解析PAHs的来源,菲/蒽（Phe/Ant） < 10且荧蒽/芘（Fla/Pyr）≥1的点位占所有采样点位的56.25%,表明区域内PAHs的主要来源是化石燃料的高温燃烧;位于航运码头附近采样点位的PAHs以石油源为主,部分点位呈化石燃料源和石油源混合污染特征。对照风险效应低值（ERL）和风险效应中值（ERM）进行初步风险评价,表明研究区域部分采样点位的PAHs具有潜在的生态风险。

     

浅谈城市开发建设中湿地的保护与利用

湿地是人类赖以生存的宝贵资源,具有重要的生态和社会价值。但在城市化进程中,由于不合理的开发建设行为,导致大量湿地被破坏,功能退化。因此,必须落实科学发展观,采取切实措施,有效保护和利用城市湿地。要强化全社会的环保意识,增强保护湿地的责任感和使命感,科学地搞好城市土地利用规划及城市湿地景观设计,切实加强对城市湿地的监测评估及湿地保护的法制建设,推动经济社会全面协调可持续发展。     

湿地地表水—地下水交互作用的研究综述

湿地地表水—地下水之间的水量与水质交互作用是影响湿地水文过程及其生态环境效应的重要机制。从湿地地表水—地下水交互作用的内涵、影响因素、界面效应及其研究方法与模型等5个方面,归纳总结了国内外相关的研究成果。分析认为:湿地地表水—地下水交互作用受到地质/水文地质条件与水文情势共同控制,对未来变化环境尤其是气候变化的响应机制是其影响因素研究关注的焦点,在此背景下物理—化学—生物多层次环境界面之间的"激励—响应"更加显著,将成为理解湿地—地下水交互作用过程及其环境反馈的重要内容。结合多学科交叉理论与方法,利用不同界面特征的响应变化反馈指示湿地地表水—地下水交互作用是未来研究方法发展与创新的基本思路。结合湿地水文特性整合不同尺度的数据信息、耦合交互过程的不同机制等是模型构建的关键科学问题,实现交互作用过程中的地表水—地下水耦合、水量—水质联合模拟是模型研究的发展趋势。     

Preferential flow and segregation of porewater solutes in Wetland sediment

Sediment macropores (with effective diameters larger than 100 μm) comprise 11% of the bulk sediment volume in a tidal freshwater wetland vegetated withPeltandra virginica. In order to determine effects of macroporous sediment structure on solute transport, we conducted a solute tracer experiment in the sediment. The effective transport volume (θ_eff, the volume of sediment through which solute was transported normalized to sediment bulk volume) was 0.15 cm³ cm^?3, which is considerably smaller than the total pore space that is potentially available for transport (porosity of sediment is 0.63 cm³ cm^?3). A mean transport time of 13 d was required to flush preferential flow paths inPeltandra hummocks; hydrologic turnover of the volumetrically dominant matrix pores (0.53 cm³ cm^?3) was apparently much slower. Based on porewater sampler design and hydrological principles, we suggest that N₂-purged tension solution samplers and diffusion equilibrators preferentially sample porewater from macropore and matrix domains, respectively. Dissolved ammonium and orthophosphate concentrations were three-fold higher in matrix pores compared to macropores, which is consistent with our finding that more rapid hydrological flushing occurred in macropores compared to matrix pores. Further evaluation of porewater sampler designs in macroporous sediment is needed to improve studies of hydrologic transport and biogeochemical cycling in wetlands.     

青海高原湿地特征及其保护

青海省地处青藏高原东北部,是我国长江、黄河和澜沧江的发源地,素有"江河源"之称.青海高原湿地类型包括自然湿地和人工湿地两大类型,湿地总面积约55662.7km²,占全省土地总面积的7.7%.高原湿地分布特点主要表现为3种形式:1)以湖泊或浅塘为中心的环带状分布;2)以河流为中心的条带状分布;3)河源区的斑块状镶嵌分布.高原湿地生物种类较为丰富,有湿地种子植物约428种;湿地动物约151种,其中鸟类约73种、鱼类约55种、哺乳类约14种以及两栖类9种.湿地植被有水生植被、沼泽植被和沼泽草甸3大基本类型.近几十年来,青海高原湿地出现湖泊水位下降、湖泊面积萎缩、河流出现断流以及沼泽湿地退化等方面的明显变化.鉴于高原湿地的生态功能和作用,应加强青海高原湿地的保护.     

Concentrations and possible sources of PAHs in sediments from Bohai Bay and adjacent shelf

Concentrations, spatial distribution and sources of 16 polycyclic aromatic hydrocarbons (PAHs) listed by the United States Environmental Protection Agency as priority pollutants were investigated in surface sediments of Bohai Bay, North China. Total concentrations of PAHs were in the range of 140.6–300.7 ng/g (dry wt), with an average of 188.0 ng/g. The three predominant PAHs were phenanthrene, acenaphthene and naphthalene. Sedimentary PAH concentrations of the north and central Bohai Bay were higher than those of the southern side of this bay. PAHs source analysis suggested that PAHs in most of the sediments were mainly from grass, wood and coal incomplete combustion. At other stations near the estuaries (Luanhe River Estuary and Chaohe River Estuary) or the oil drilling platform, both petrogenic and pyrogenic inputs were significant. The pyrogenic PAHs close to the oil drilling platform were mainly from petroleum combustion.     

扎龙湿地土地利用类型评价研究

扎龙湿地属于典型的芦苇沼泽湿地,由于扎龙湿地水环境的变化,扎龙湿地土地利用类型的变化为:耕地、居民地、盐碱地总体上略呈增加趋势,草地呈减少趋势,湖泊和水库、明水沼泽、芦苇沼泽等湿地面积变化与来水量的丰枯变化相关,明水沼泽和芦苇沼泽的变化趋势呈反相关.土地利用类型对湿地面积的影响程度最大的是居民地面积,其次是耕地、盐碱地、草地面积的变化.     

清水泉地下河多环芳烃来源及分配动态

城市化进程的不断加快,使得南宁市地下水多环芳烃（PAHs）污染日益严重,作为城市主要饮用水源地的清水泉地下河,对当地的经济和社会发展具有重要的支撑作用。文章选择南宁市清水泉地下河作为岩溶地下河的代表,以前人多年测试数据为基础,结合本次采样数据,分析水环境中PAHs的含量、分布特征和来源的多年变化情况,重点研究PAHs的分配规律。结果表明：地下水PAHs以2~3环为主,沉积物PAHs以4~6环为主,且由于污染源的增多,使得水环境中PAHs含量从上游到下游逐渐增大;不同区域的PAHs来源多年变化规律有差异,上游PAHs来源一直为生物质燃烧源,中游的PAHs来源由石油源转变为混合源,下游PAHs来源由以化石燃料燃烧源为主转变为以混合源为主;随着环数的增加,分配系数逐渐增加,且环数越大的PAHs更趋向被沉积物吸附;下游大部分采样点的PAHs在颗粒物上吸附能力较强,剩余采样点在分配过程中受溶解性有机质的影响。     

湿地景观格局与生态过程研究进展

20世纪70年代以来,湿地研究成为国际环境科学和生态学研究的热点领域之一。尤其是景观生态学的兴起为湿地研究注入了新的活力,为在区域尺度上开展湿地的综合研究起到了启发和指导作用。空间格局、生态过程与尺度之间的相互关系是景观生态学研究的核心内容。同样,从景观尺度上来研究湿地空间格局与生态过程及其相互关系是当前湿地科学的研究热点。对景观格局与生态过程的研究方法、湿地主要生态过程、湿地景观格局与生态过程相互关系等方面的国内外研究进展进行了综述。最后分析了目前湿地景观格局与生态过程相互关系研究中存在的问题与不足,未来湿地生态过程以及湿地格局与生态过程相互关系的研究热点及发展趋势。     

Effects of geosorbent and solution properties on sorption and desorption of PAHs

Characteristics of phenanthrene and pyrene’s sorption and desorption on two local soils in solutions of simulated groundwater, simulated lung fluid, and simulated saliva were studied with batch equilibrium experiments to understand the fate of PAHs in the karst region of southwestern China and to assess the environmental exposure and the health risk of PAHs. The results showed that the sorption and desorption isotherms of phenanthrene and pyrene on two target soils in the three solution systems could be adequately described by the Freundlich model, while the fitted isotherm parameters for the simulated groundwater solution distinguished notably from those for the simulated body fluid solutions. For the sorption experiments, in the simulated groundwater, the n values were 0.722 and 0.672 for phenanthrene and were 0.724 and 0.663 for pyrene, respectively, on the yellow soil and the limestone soil; The log K_F values were 3.118 and 3.323 for phenanthrene and were 3.648 and 3.846 for pyrene, respectively, on the yellow soil and the limestone soil. In the simulated body fluids, the n values for phenanthrene and pyrene ranged from 0.622 to 0.836 and from 0.590 to 0.865, respectively, and the log K_F values of phenanthrene and pyrene ranged from 2.845 to 3.327 and from 3.344 to 3.779, respectively. For the desorption experiments, in the simulated groundwater, the n values were 0.662 and 0.744 for phenanthrene and were 0.702 and 0.647 for pyrene, respectively, on the yellow soil and the limestone soil. The log K_F values were 3.666 and 3.686 for phenanthrene and were 4.128 and 4.225 for pyrene, respectively, on the yellow soil and the limestone soil. In the simulated body fluids, the n values for phenanthrene and pyrene ranged from 0.612 to 0.668 and from 0.631 to 0.819, respectively, and the log K_F values of phenanthrene and pyrene ranged from 3.134 to 3.407 and from 3.533 to 3.839, respectively. The limestone soil had relatively higher log K_F values but lower K_OC values compared to those of the yellow soil, indicated that the nature of sorbent soils played the dominant role in sorption and desorption behaviors of PAHs. The experimental results showed a remarkable differences in sorption and desorption behaviors of PAHs in simulated body fluids and groundwater. The nonlinearities of measured isotherms and the measured sorption capacities of soils in simulated body fluids were significantly lower than corresponding those in the simulated groundwater, and HI values for simulated body fluids systems were significantly smaller than corresponding those for the simulated groundwater systems. The results underscore cautions in assessing environmental exposure and health risks of PAHs based on their sorption–desorption data in simulated groundwater as this is traditionally done.