湘西黔东寒武纪重晶石矿成矿规律与成矿模式

贵州天柱-湖南贡溪一带沉积了世界级重晶石矿床,初步探明资源量2.4亿吨。通过野外调查,寒武纪重晶石矿床具有热水沉积特征,如喷流角砾、泉华结构等。此外,在重晶石矿中发现大量的菌藻类化石,类似海底喷口生物群。含矿岩系元素地球化学分析也显示重晶石矿属于热水沉积成因,上述特征支持重晶石属于海底喷流沉积成矿。分析了该区域重晶石矿矿层展布,认为可能存在2个断陷盆地,同生断裂控制矿体展布。基于基底地层富含Ba、S元素特征,认为在岩浆热液作用下,基底地层中Ba、S元素被萃取出来,并沿着同生断裂喷流而出形成重晶石矿,建立了天柱-贡溪一带寒武系重晶石矿成矿模式。     

贵州镇宁乐纪泥盆系重晶石矿热水沉积特征

贵州镇宁乐纪泥盆系重晶石矿床地质储量3 302万t,属大型矿床类型。通过对矿床沉积结构、构造特征研究发现,矿床（体）中分布:纹层状构造、条带状构造、角砾状构造、碎屑状构造、块状构造等,它们与天柱-大河边重晶石矿、广西古潭热水沉积重晶石岩及北秦岭二郎坪群热水沉积重晶石岩类似,海底热水喷流形成的热水喷流通道相、单一热水沉积岩相及热水混合同生沉积相在镇宁重晶石矿层中广泛分布,共同构成了热水浊流沉积相,这与秦岭泥盆系热水沉积岩（矿）类似,矿层沉积结构、构造及岩相特征很好的记录了海底热水喷流、演化的信息,沉积韵律特征说明了热水喷流由弱-强-弱的变化过程。海底热水喷流沉积形成的镇宁重晶石矿中热水沉积结构、构造及热水沉积岩相发育,是研究古热水喷流沉积成岩、成矿、划分热水沉积岩相的理想场所。     

贵州天柱云洞地区铅锌矿的发现及其找矿意义

通过贵州天柱重晶石矿整装勘查,在天柱云洞重晶石矿床下部发现铅锌矿体,矿体产于陡山沱组地层中,呈层状产出,规模较大,具有"上部重晶石矿,下部铅锌矿"的分布规律。从矿床地质、地化特征等方面研究,获得该矿床属于热水喷流沉积成因的初步证据。通过与典型SEDEX铅锌矿床对比,云洞地区铅锌矿的矿体形态、矿物组合、矿石组构、围岩蚀变,以及沉积、构造环境等,都与典型SEDEX铅锌矿床具有相似性。根据沉积、构造背景分析,认为湘西黔东具备热水喷流沉积(SEDEX)型铅锌矿床的成矿条件,预测天柱坪地—新晃—玉屏一带具有寻找大型铅锌矿床的前景。     

对福建李坊重晶石矿床成因的新认识——来自矿石构造、矿物学和流体包裹体的证据

福建李坊重晶石矿床是东南沿海地区发现的一个大型独立重晶石矿床,已有30余年的开采历史,在沉积重晶石矿床中占有重要地位,然而对该矿床的成因和成矿时代仍众说纷纭。本文通过对福建李坊重晶石矿床中矿石组构的野外调查、电子探针分析和重晶石的流体包裹体测温,取得如下发现和认识:①首次在重晶石矿石中发现了管孔状构造、角砾状构造、蜂窝状构造等热水喷流通道相沉积构造;②首次在重晶石矿石中发现具有热水成因指示意义的同生钡冰长石矿物;③140个重晶石的流体包裹体均一温度值为89.3～208.5℃,均值为162.7℃,表明李坊重晶石矿床属于低温热水沉积矿床;综合矿石构造、矿物学和流体包裹体测温等证据,提出李坊重晶石矿床为"白烟囱型"热水沉积矿床的新认识,为华南地区早古生代热水沉积矿床的研究和找矿勘探提供了重要新资料。     

大河边—新晃超大型重晶石矿床地球化学特征及形成的地质背景

本文从矿物岩石学、地球化学和沉积盆地分析角度，研究贵州天柱大河边－湖南贡溪两个超大型重晶石矿床中重晶石（矿）岩及其共生岩石的地球化学特征及构造地质背景。天柱－新晃－玉屏寒武纪热水沉积成矿盆地是发育在大陆斜坡上的断陷型热水沉积成矿盆地，由于同生断层作用将盆地切割成一系列次级盆地，大河边－碧林及龙背－铜盆盖三级热水沉积成矿盆地是大型重晶石矿床的构造定位空间。重晶石矿层主要赋存于下寒武统牛蹄塘组第一岩性段的黑色岩系中。 重晶石矿层是由海底低温热水同生沉积作用形成（105－192℃），古热水场的地球化学类型为硫酸盐型热水。硫酸盐型热水发生大规模同生沉积成岩成矿作用形成超大型重晶石矿床，重晶石矿层之上的黑色碳质粘土岩可能形成于封闭、还原、滞流的深水沉积环境，黑色碳质粘土岩构成矿层的封闭保存条件。     

贵州寒武系底部黑色岩系型矿床沉积构造特征研究

在中国南方地区早寒武世广泛分布着一套黑色岩系型矿床,其矿物组成和沉积地球化学都表现出明显的热水沉积特征,该黑色岩系沉积构造方面的研究却很少。通过对贵州寒武系底部3个不同黑色岩系型矿带Ni-Mo多金属成矿带、V成矿带、重晶石成矿带的宏观和微观构造的研究,总结了其沉积构造特征,发现其中存在大量类喷溢和喷流过程形成的沉积构造、气-水热液作用形成的沉积构造、胶体及生物化学沉积构造、准同生变形构造等沉积构造和沉积构造序列,分析了不同成矿带之间的沉积构造异同,这对该类型矿床成矿理论的研究具有重要意义。     

天柱大河边-新晃重晶石矿床矿物组成特征的电子探针研究

通过对天柱大河边—新晃重晶石矿床系统的剖面勘查和采样分析,对矿石和围岩进行了系统的电子探针研究。发现在该矿床的矿石中广泛分布有钡冰长石。在研究钡冰长石及其共生矿物（重晶石、黄铁矿等）的化学组成、光学性质及其相互关系的基础上,对钡冰长石的成因进行了分析,进而对矿床的成因作了进一步探讨,为天柱大河边—新晃重晶石矿床热水沉积成因提供了新的证据。     

华南早寒武世黑色岩系重晶石矿床环带钡冰长石 新发现及其意义

华南早寒武世黑色岩系重晶石矿床是全球著名的沉积型层状矿床。本文报道了我们最近的一项新发现,在该区天柱大河边重晶石矿床中首次发现了环带钡冰长石,环带的外带BaO含量1653%～1786%,K2O含量777%～819%,相比而言,核部BaO含量1204%～1421%,K2O含量860%～979%。结合成矿地质背景和已有工作报道,讨论了这一新发现的地质意义。认为这种环带钡冰长石的出现,反映了重晶石成矿受到热水作用影响,且其形成过程中经历了不同期富钡流体的影响,成矿可能属于一种热水、断控、幕式、渐进的过程,这不仅进一步揭示了矿床的热水（液）喷流沉积成因,而且加深了对成矿过程的刻画。该认识还可供全球沉积型重晶石矿床成因研究时类比参考。     

贵州天柱寨脚重晶石成矿地质特征及成矿模式

通过天柱寨脚重晶石矿大精查,在寨脚-甲木冲一带老堡组顶部发现顺层产出的火山凝灰岩夹碳酸盐岩(灰岩)透镜,为重晶石海底喷流成因提供新的证据.通过钻孔岩心和露头沉积学特征观察,在重晶石矿床中见到丰富的滑塌构造、碎屑流构造和浊流构造,表明重晶石在喷流口初步堆积后,受到同沉积地质营力如地震、风暴作用形成震积岩,沿着斜坡向沉积盆...     

贵州天柱大河边重晶石矿实物地质资料采集及意义

贵州重晶石矿点多面广,资源相对集中,并且类型多,质量好,是我国重晶石矿资源非常丰富的省份之一,并长期排名全国第一.主要有沉积型、热液型、残坡积型三大类重晶石矿,其中以沉积型规模最大,占累计查明资源储量的89.26％.天柱大河边重晶石矿是寒武系早期喷流沉积型矿床,具规模大、矿层厚和品位高等特点,被贵州省地质资料馆列为重点...     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.