Metal concentrations in the milk and tissues of a nursing Tursiops truncatus female

Metal concentrations measured in the organs of beached whales are published regularly. Few of these, however, describe metal levels in nursing females. In the present study, mercury, lead, copper and zinc levels were measured in the milk and tissues of a female Bottlenose dolphin. Results reveal that metal pollutants pass from the tissue into the milk.     

Seismic hazard assessment of the Province of Murcia (SE Spain): analysis of source contribution to hazard

A probabilistic seismic hazard assessment of the Province of Murcia in terms of peak ground acceleration (PGA) and spectral accelerations [SA(T)] is presented in this paper. In contrast to most of the previous studies in the region, which were performed for PGA making use of intensity-to-PGA relationships, hazard is here calculated in terms of magnitude and using European spectral ground-motion models. Moreover, we have considered the most important faults in the region as specific seismic sources, and also comprehensively reviewed the earthquake catalogue. Hazard calculations are performed following the Probabilistic Seismic Hazard Assessment (PSHA) methodology using a logic tree, which accounts for three different seismic source zonings and three different ground-motion models. Hazard maps in terms of PGA and SA(0.1, 0.2, 0.5, 1.0 and 2.0 s) and coefficient of variation (COV) for the 475-year return period are shown. Subsequent analysis is focused on three sites of the province, namely, the cities of Murcia, Lorca and Cartagena, which are important industrial and tourism centres. Results at these sites have been analysed to evaluate the influence of the different input options. The most important factor affecting the results is the choice of the attenuation relationship, whereas the influence of the selected seismic source zonings appears strongly site dependant. Finally, we have performed an analysis of source contribution to hazard at each of these cities to provide preliminary guidance in devising specific risk scenarios. We have found that local source zones control the hazard for PGA and SA(T ≤ 1.0 s), although contribution from specific fault sources and long-distance north Algerian sources becomes significant from SA(0.5 s) onwards.     

Levels of persistent organic pollutants and residual pattern of DDTs in small cetaceans from the coast of São Paulo, Brazil

The State of São Paulo is the most developed area in Brazil and was impacted by persistent organic pollutants for several decades. This study investigated organochlorines in five species of small cetaceans (Pontoporia blainvillei, Stenella frontalis, Sotalia guianensis, Tursiops truncatus and Steno bredanensis) found dead along the coast of São Paulo between 1997 and 2003. DDTs (15.9 μg g⁻¹ lipid; mean for all pooled individuals) and PCBs (8.08 μg g⁻¹) exhibited the highest concentrations in the animals, reflecting large amounts formerly used in Brazil. Lower levels of mirex (0.149 μg g⁻¹), HCB (0.051 μg g⁻¹), CHLs (0.008 μg g⁻¹) and HCHs (0.007 μg g⁻¹) were detected in all species. Residual pattern of DDTs in dolphins suggests that o,p′-DDT is more recalcitrant than p,p′-DDT in the body of the animals and/or the environment. In contrast to p,p′-DDT, residues of o,p′-DDT seem to be preferentially converted into o,p′-DDD rather than o,p′-DDE.     

Isomer specific determination of hexabromocyclododecanes (HBCDs) in small cetaceans from the South China Sea--Levels and temporal variation

A diastereoisomer (alpha, beta, and gamma) specific analytical method for measuring hexabromocyclododecanes (HBCDs) was developed using liquid chromatography-tandem mass spectrometry (LC-MS-MS). The method developed was applied to analyze blubber of small cetaceans to divulge the distribution and temporal variation of HBCDs in the Asian marine environment. HBCDs were detected in all the blubber samples of finless porpoises (Neophocaena phocaenoides) and Indo-Pacific humpback dolphins (Sousa chinensis) collected from the South China Sea during 1990-2001. Concentrations of HBCDs were higher in humpback dolphins (31-380 ng/g lipid) than in finless porpoises (4.7-55 ng/g lipid), which can be attributed to habitat differences. Average concentrations of alpha-HBCD in finless porpoises increased from 9.5 ng/g lipid in 1990 to 35 ng/g lipid in 2000/01. alpha-HBCD was predominant among the three isomers with some exceptions in finless porpoises collected in 1990. This is the first report on HBCDs contamination in marine mammals from Southeast Asia.     

Estimate of earthquake hazard in the Vrancea (Romania) region

A maximum likelihood method is used to estimate the earthquake hazard parameters maximum magnitudeM _max, annual activity rate , and theb value of the Gutenberg-Richter equation in the Vrancea (Romania) region. The applied procedure permits the use of mixed catalogs with incomplete historical as well as complete instrumental parts, the consideration of variable detection thresholds, and the incorporation of earthquake magnitude uncertainty.Our imput data, comprises 105 historical earthquakes which occurred between 984 and 1934, and a complete data file containing 1067 earthquakes which occurred during the period 1935–30 August, 1986. The complete part was divided into four subcatalogs according to different thresholds of completeness. Only subcrustal events were considered, and dependent events were removed.The obtained value (=0.65) is at the lower range of the previously reported results, but it appears concurrent with conceptual and observational facts. The same concerns inferred value of _max = 7.8 and activity rate _4.0 = 5.34.     

Polybrominated diphenyl ethers (PBDEs) and organochlorines in small cetaceans from Hong Kong waters: levels, profiles and distribution

Polybrominated diphenyl ethers (PBDEs) and organochlorine compounds (OCs) were determined in the blubber, liver and kidney of Indo-Pacific humpback dolphins (Sousa chinensis) and finless porpoises (Neophocaena phocaenoides) stranded in Hong Kong coastal waters during 1995–2001. Among the organohalogen compounds analyzed, DDTs were the most dominant contaminants with concentrations ranging from 9.9 to 470 μg/g lipid wt. PBDEs in Hong Kong cetaceans, which are reported for the first time, were detected in all the samples with values ranging from 0.23 to 6.0 μg/g lipid wt., with a predominance of BDE-47. Results from this study suggest PBDEs should be classified as priority pollutants in Asia. Higher concentrations were found in humpback dolphins than in finless porpoises, and this was attributed mainly to differences in habitat. Elevated residues of PCBs and DDTs in some cetaceans suggest these species may be at risk.     

The use of a non-lethal tool for evaluating toxicological hazard of organochlorine contaminants in Mediterranean cetaceans: new data 10 years after the first paper published in MPB

In the Mediterranean Sea, top predators, and particularly cetacean odontocetes, accumulate high concentrations of organochlorine contaminants and toxic metals, incurring high toxicological risk. In this paper we investigate the use of the skin biopsies as a non-lethal tool for evaluating toxicological hazard of organochlorines in Mediterranean cetaceans, presenting new data 10 years after the paper published by Fossi and co-workers [Mar. Poll. Bull. 24 (9) (1992) 459] in which this new methodology was first presented. Some organochlorine compounds, now with worldwide distribution, are known as endocrine disrupting chemicals (EDCs). Here the unexplored hypothesis that Mediterranean cetaceans are potentially at risk due to organochlorines with endocrine disrupting capacity is investigated. High concentrations of DDT metabolites and PCB congeners (known as EDCs) were found in the different Mediterranean species (Stenella coeruleoalba, Delphinus delphis, Tursiops truncatus and Balaenoptera physalus). In this paper we also propose benzo(a)pyrene monooxygenase (BPMO) activity in marine mammal skin biopsies (non-lethal biomarker) as a potential indicator of exposure to organochlorines, with special reference to the compounds with endocrine disrupting capacity. A statistically significant correlation was found between BPMO activity and organochlorine levels (DDTs, pp(')DDT, op(')DDT, PCBs and PCB99) in skin biopsies of males of B. physalus. Moreover a statistical correlation was also found between BPMO activity and DDT levels in skin biopsies of the endangered Mediterranean population of D. delphis. These results suggest that BPMO induction may be an early sign of exposure to organochlorine EDCs and can be used for periodic monitoring of Mediterranean marine mammal toxicological status.     

Modelling the environmental behaviour of pollutants in Algeciras Bay (south Spain)

An environmental study of Algeciras Bay is carried out through numerical modelling. First, a 2D barotropic model is applied to calculate tides and mean circulation. Results of this model are used by a sediment transport model which provides suspended matter concentrations and sedimentation rates in the Bay. It includes three particle classes. An effective diffusion coefficient has been calibrated simulating temperature distribution inside the Bay. An additional validation is obtained from an independent nitrate dispersion simulation. Then heavy metal dispersion patterns are investigated using a model which includes water-sediment metal interactions and uses the outputs of the hydrodynamic and sediment transport models. The metal transport model has been applied to simulate the dispersion of Zn, Cu and Ni. Results from the hydrodynamic, sediment and metal transport models have been compared with measurements. Model results also indicate that transport inside the Bay is relatively weak. Numerical experiments have been carried out to determine flushing times for conservative and non-conservative pollutants. Flushing time is about 20 days for a conservative tracer, and this value is mainly due to the M(2) residual current. Tides are not effective in removing pollutants.     

A review of pollutants in the sea-surface microlayer (SML): a unique habitat for marine organisms

Boundary layers between different environmental compartments represent critical interfaces for biological, chemical and physical processes. The sea-surface microlayer (uppermost 1-1000 microm layer) forms the boundary layer interface between the atmosphere and ocean. Environmental processes are controlled by the SML, and it is known to play a key role in the global distribution of anthropogenic pollutants. Due to its unique chemical composition, the upper organic film of the SML represents both a sink and a source for a range of pollutants including chlorinated hydrocarbons, organotin compounds, petroleum hydrocarbons, polycyclic aromatic hydrocarbons (PAH) and heavy metals. These pollutants can be enriched in the SML by up to 500 times relative to concentrations occurring in the underlying bulk water column. The SML is also a unique ecosystem, serving as an important habitat for fish eggs and larvae. Concentration ranges and enrichment factors of pollutants in the SML in different areas of the world's oceans have been critically reviewed, together with available toxicity data for marine biota found within the SML. Overall, the SML is highly contaminated in many urban and industrialized areas of the world, resulting in severe ecotoxicological impacts. Such impacts may lead to drastic effects on the marine food web and to fishery recruitment in coastal waters. Studies of the toxicity of fish eggs and larvae exposed to the SML contaminants have shown that the SML in polluted areas leads to significantly higher rates of mortality and abnormality of fish embryos and larvae.     

A new seismic hazard assessment in the region of Andalusia (Southern Spain)

A probabilistic seismic hazard assessment of Andalusia (Southern Spain) in terms of peak ground acceleration, PGA, and spectral accelerations, SA(T), is presented in this paper. In contrast to most of the previous studies in the region, which were performed for PGA, making use of Intensity-to-PGA relationships, hazard was here calculated in terms of magnitude, using published spectral ground-motion models. Moreover, we considered different ground-motion models for the Atlantic sources, since the attenuation of those motions seems to be slower, as evidenced in the case of the extensive macroseismic areas of earthquakes like those occurred in the years 1755, 1969 and 2007. A comprehensive review of the seismic catalogue and of the seismogenic models proposed for the region was carried out, including those for Northern Africa, which is part of the influence area. Hazard calculations were performed following the Probabilistic Seismic Hazard Assessment (PSHA) methodology using a logic tree, which accounts for six different seismic source zonings and five different ground-motion attenuation relationships. Hazard maps in terms of PGA and SA (0.2 s) and SA (1 s) and coefficient of variation (COV) maps, for the 475-year return period were first obtained in rock sites. A geotechnical classification and amplification factors were proposed and new hazard maps including local effects were represented, showing PGA values ranging from 24 to 370 cm/s² for the whole Andalusian territory, with the highest expected values (PGA > 300 cm/s²) in some parts of the Granada Province and in the town of Vélez Málaga. Lowest values (PGA < 50 cm/s²) correspond to some towns of the Huelva and Córdoba provinces. The inclusion of soil effects provides a more detailed picture of the actual hazard the region is subjected to.     

Seismic risk and damage prediction: case of the buildings in Constantine city (Algeria)

Located at the North-Eastern part of Algeria (Tellian Atlas), Constantine has crucial administrative, economic, scientific and cultural importance. It has continuously experienced significant urban evolutions during the different periods of its history. The city is located in an active seismic region within Algeria and has been struck in the past by several moderate and strong earthquakes. The strongest earthquake recorded since the beginning of instrumental seismology took place on October 27, 1985 with a magnitude M \(_\mathrm{S}=\) 5.9. Constantine presents a high seismic risk, because of its dense housing and high population density (2,374 inhabitants/km \(^{2})\) . This requires a risk assessment in order to take preventive measures and reduce the losses in case of potential major earthquake. For this purpose, a scenario based approach is considered. The building damage assessment methodology adopted for the Algerian context is adapted from HAZUS approach. In the present case, the effective Algerian seismic code response spectrum (RPA 99/2003) is considered as a seismic hazard model. The prediction of the expected damages is performed for a set of almost 29,000 buildings.     

Carbon dioxide and radon gas hazard in the Alban Hills area (central Italy)

The sudden and catastrophic, or slow and continuous, release at surface of naturally occurring toxic gases like CO₂, H₂S and Rn poses a serious health risk to people living in geologically active regions. In general this problem receives little attention from local governments, although public concern is raised periodically when anomalous toxic-gas concentrations suddenly kill humans or livestock. For example, elevated CO₂ concentrations have been linked to the death of at least 10 people in the central Italian region of Lazio over the last 20 years, while it was the CO₂ asphyxiation of 30 cows in a heavily populated area near Rome in 1999 which prompted the present soil-gas study into the distribution of the local health risk. A detailed geochemical survey was carried out in an area of about 4 km² in the Ciampino and Marino districts, whereby a total of 274 soil-gas samples were collected and analysed for more than 10 major and trace gas species. Data were then processed using both statistical and geostatistical methods, and the resulting maps were examined in order to highlight areas of elevated risk. General trends of elevated CO₂ and Rn concentrations imply the presence of preferential pathways (i.e. faults and fractures) along which deep gases are able to migrate towards the surface. The CO₂ and Rn anomalous trends often correspond to and are usually elongated parallel to the Apennine mountain range, the controlling structural feature in central Italy. Because of this fundamental anisotropy in the factors controlling the soil-gas distribution, it was found that a geostatistical approach using variogram analysis allowed for a better interpretation of the data. With regard to the health risk to local inhabitants, it was found that although some high risk areas had been zoned as parkland, others had been heavily developed for residential purposes. For example, many new houses were found to have been built on ground which has soil-gas CO₂ concentrations of more than 70% and radon values of more than 250 kBq m⁻³. It is recommended that land-use planners incorporate soil-gas and/or gas flux measurements in environmental assessments in areas of possible risk (i.e. volcanic or structurally active areas).     

Slope instabilities triggered by the 11th May 2011 Lorca earthquake (Murcia,Spain): comparison to previous hazard assessments and proposition of a new hazard map and probability of failure equation

The Lorca Basin has been the object of recent research aimed at studying the phenomena of earthquake-induced landslides and its assessment in the frame of different seismic scenarios. However, it has not been until the 11th May 2011 Lorca earthquakes when it has been possible to conduct a systematic approach to the problem. In this paper we present an inventory of slope instabilities triggered by the Lorca earthquakes which comprises more than 100 cases, mainly rock and soil falls of small size (1–100  \(\hbox {m}^{3}\) ). The distribution of these instabilities is here compared to two different earthquake-triggered landslide hazard maps: one considering the occurrence of the most probable earthquake for a 475-years return period in the Lorca Basin \((\hbox {M}_{\mathrm{w}}=5.0)\) based on both low- and high-resolution digital elevation model (DEM); and a second one matching the occurrence of the \(\hbox {M}_{\mathrm{w}}=5.2\) 2011 Lorca earthquake, which was performed using the higher resolution DEM. The most frequent Newmark displacements related to the slope failures triggered by the 2011 Lorca earthquakes are lower than 2 cm in both the hazard scenarios considered. Additionally, the predicted Newmark displacements were correlated to the inventory of slope instabilities to develop a probability of failure equation. The fit seems to be very good since most of the mapped slope failures are located on the higher probability areas. The probability of slope failure in the Lorca Basin for a seismic event similar to the \(\hbox {M}_{\mathrm{w}}\) 5.2 2011 Lorca earthquake can be considered as very low (0–4 %).     

Slope instability induced by volcano-tectonics as an additional source of hazard in active volcanic areas: the case of Ischia island (Italy)

Ischia is an active volcanic island in the Gulf of Naples whose history has been dominated by a caldera-forming eruption (ca. 55 ka) and resurgence phenomena that have affected the caldera floor and generated a net uplift of about 900 m since 33 ka. The results of new geomorphological, stratigraphical and textural investigations of the products of gravitational movements triggered by volcano-tectonic events have been combined with the information arising from a reinterpretation of historical chronicles on natural phenomena such as earthquakes, ground deformation, gravitational movements and volcanic eruptions. The combined interpretation of all these data shows that gravitational movements, coeval to volcanic activity and uplift events related to the long-lasting resurgence, have affected the highly fractured marginal portions of the most uplifted Mt. Epomeo blocks. Such movements, mostly occurring since 3 ka, include debris avalanches; large debris flows (lahars); smaller mass movements (rock falls, slumps, debris and rock slides, and small debris flows); and deep-seated gravitational slope deformation. The occurrence of submarine deposits linked with subaerial deposits of the most voluminous mass movements clearly shows that the debris avalanches impacted on the sea. The obtained results corroborate the hypothesis that the behaviour of the Ischia volcano is based on an intimate interplay among magmatism, resurgence dynamics, fault generation, seismicity, slope oversteepening and instability, and eruptions. They also highlight that volcano-tectonically triggered mass movements are a potentially hazardous phenomena that have to be taken into account in any attempt to assess volcanic and related hazards at Ischia. Furthermore, the largest mass movements could also flow into the sea, generating tsunami waves that could impact on the island’s coast as well as on the neighbouring and densely inhabited coast of the Neapolitan area.     

Prediction of rockburst probability given seismic energy and factors defined by the expert method of hazard evaluation (MRG)

In this paper we suggest that conditional estimator/predictor of rockburst probability (and rockburst hazard, P ^T (t)) can be approximated with the formula P ^T (t) = P ₁(θ ₁)…P _N (θ _N )·P _dyn ^T (t), where P _dyn ^T (t) is a time-dependent probability of rockburst given only the predicted seismic energy parameters, while P _i (θ _i ) are amplifying coefficients due to local geologic and mining conditions, as defined by the Expert Method of (rockburst) Hazard Evaluation (MRG) known in the Polish mining industry. All the elements of the formula are (approximately) calculable (on-line) and the resulting P ^T value satisfies inequalities 0 ≤ P ^T (t) ≤ 1. As a result, the hazard space (0–1) can be always divided into smaller subspaces (e.g., 0–10⁻⁵, 10⁻⁵–10⁻⁴, 10⁻⁴–10⁻³, 10⁻³–1), possibly named with symbols (e.g., A, B, C, D, …) called “hazard states” — which saves the prediction users from worrying of probabilities. The estimator P ^T can be interpreted as a formal statement of (reformulated) Comprehensive Method of Rockburst State of Hazard Evaluation, well known in Polish mining industry. The estimator P ^T is natural, logically consistent and physically interpretable. Due to full formalization, it can be easily generalized, incorporating relevant information from other sources/methods.     

Increasing levels and biomagnification of persistent organic pollutants (POPs) in Antarctic biota

Representatives of the Antarctic food web (krill, cephalopod, fish, penguin, seal) of the area around Elephant Island and from the Weddell Sea were analysed for the most recalcitrant organochlorine compounds. Due to sorption of the compounds to sinking particles and accumulation in sediments, two benthic fish species (Gobionotothen gibberifrons, Chaenocephalus aceratus) feeding on benthos invertebrates and fish reflected significantly increasing concentrations within a decade (1987-1996), while a benthopelagic species (Champsocephalus gunnari) feeding on krill did not. In the pelagic food chain, lipid normalised concentrations of all compounds increased from Antarctic krill to fish proving that biomagnification of highly lipophilic pollutants (log octanol-water partition coefficient>5) occurs in water-breathing animals. As top predators Weddell and southern elephant seals (Leptonychotes weddellii, Mirounga leonina) biomagnified the persistent organic pollutants relative to krill 30-160 fold with the exception of hexachlorobenzene, the levels of which were lower than in fish indicating its intense specific elimination.