Assessing impact of urban impervious surface on watershed hydrology using distributed object-oriented simulation and spatial regression

In this study, we investigated the relationship between watershed characteristics and hydrology using high spatial resolution impervious surface area (ISA), hydrologic simulations and spatial regression. We selected 20 watersheds at HUC 12 level with different degrees of urbanization and performed hydrologic simulation using a distributed object-oriented rainfall and runoff simulation model. We extracted the discharge per area and ratio of runoff to base flow from simulation results and used them as indicators of hydrology pattern. We derived percentage of ISA, distance from ISA to streams, and stream density as the watershed characteristics to evaluate the relationship with hydrology pattern in watersheds using ordinary least square, spatial error and spatial lag regression models. The comparison indicates that spatial lag regression model can achieve better performance for the evaluation of relationship between ratio of runoff to base flow and watershed characteristics, and that three models provide similar performance for the evaluation of relationship between discharge per area and watershed characteristics. The results from regression analyses demonstrate that ISA plays an important role in watershed hydrology. Ignorance of spatial dependence in analyses will likely cause inaccurate evaluation for relationship between ISA and watershed hydrology. The hydrologic model, regression methods and relationships between watershed characteristics and hydrology pattern provide important tools and information for decision makers to evaluate the effect of different scenarios in land management.     

An environmental risk assessment map of the Slovak Republic: application of data from geochemical atlases

A water budget analysis for the Cedar River watershed in northeastern Iowa was conducted to determine the water balance during the summer months of 2000. The watershed has eight major tributaries that comprise a drainage area of 20,242 km², of which 81% is agricultural land. Water budgets are essential when examining the movement of agricultural chemicals as well as nutrients within the system. The water budget was determined using the hydrologic mass-balance equation, which states that [inflow = outflow - storage]. The inflow components were measured individually and included precipitation, tributary and Cedar River baseflow. The outflow components included evaporation, transpiration, tributary and Cedar River discharge. The results of this study indicate a slightly larger volume of water leaving the watershed (6.24᎒⁹ m³) than entering (6.21᎒⁹ m³). The surplus of the outgoing water (0.5%) is most likely due to an overestimation of transpiration, or the contribution of water from the intermittent streams not measured during the study. Calculations of nutrient flux showed that approximately 2.99᎒⁶ kg of nitrogen and 2.39᎒⁵ kg of phosphorus were lost from the watershed during the study.     

贵州福泉市双眼井泉小流域流量估算及排洪方案建议

贵州双眼井泉小流域为一地表分水岭与地下分水岭不闭合的岩溶峰丛洼地小流域。双眼井泉主要通过落水洞、溶蚀裂隙接受大气降水直接补给,水量动态变化较大,幅度从枯季的0.2L/s到雨季的35.5L/s不等,最突出的是2007年暴雨期间水量骤增,曾导致流域内磷石膏堆场子坝溃坝。为解决该流域防洪工程设计问题,本文在岩溶水文地质调查分析的基础上,提出了在缺少长观资料的情况下,以隔水层作为双眼井泉地下汇水边界、以当地丰水期最大径流模数计算得到的流量27.5L/s再乘上相应的安全系数得到的流量作为防洪工程过水断面设计依据,并提出了在双眼井冲沟口940m高程处新建一座拦水坝的排洪方案。经3年多的实践检验,设计流量计算合理,方案制定科学,工程运营安全。      

Assessing distributed groundwater recharge rate using integrated surface water-groundwater modelling: application to Mihocheon watershed, South Korea

A method of estimating groundwater recharge, based on water-balance components using the SWAT-MODFLOW model (an integrated surface water-groundwater model), is described. A multi-reservoir storage routing module is suggested instead of a single storage routing module in SWAT; this represents a more realistic delay in the travel of water through the vadose zone. By using this module, the parameter related to the delay time can be optimized by checking the correlation between simulated recharge and observed groundwater levels. The final step of this procedure is to compare simulated groundwater levels as well as the simulated watershed stream flow with the observed groundwater levels and watershed stream flow. This method is applied to the Mihocheon watershed in South Korea to estimate spatio-temporal groundwater recharge distribution. The computed annual recharge rate is compared with the independently estimated recharge rate using BFLOW. The hydrologic modelling results show that the annual average recharge rate should be estimated by a long-term continuous simulation with a distributed hydrologic modelling technique.     

Erosion potential assessment of watersheds through GIS<Emphasis Type="Bold">-</Emphasis>based hypsometric analysis: a case study of Kurram Tangi Dam

Sediment discharge due to soil and rock erosion within the watersheds is the major cause of siltation in water reservoirs. Siltation in reservoirs reduces the capacity for power production, irrigation water supply, and other domestic purposes. Hypsometric analysis has widely been used to identifying the geomorphic development stages (stabilized, equilibrium, and un-stable) to assess the erosion proneness of watersheds. In this study, watershed of Kurram Tangi Dam and its four sub-watersheds (SWs) were considered to determine their sediment discharge capacity through hypsometric analysis. The boundaries of watershed and sub-watersheds were delineated from Digital Elevation Model (DEM). The hypsometric parameters i.e., hypsometric integral (HI) and curves were generated using Geographic Information System (GIS) techniques. The HI values of SW-1 (0.41) and SW-2 (0.36) indicated that these two SWs were relatively more prone to erosion and contributed higher sediment discharge in Dam siltation. The results were validated through sampling the main drainage channel (Kurram River) to determine the sediment concentration at 12 sites during summer, winter, and spring seasons. Comparison of HI and sediment concentration of SWs presented high correlation (R²?=?0.87). The results emphasized the effective watershed management, extensive afforestation, and construction of silt-control structures at appropriate locations in sub-watersheds. This will ultimately maintain the water and power generation capacity as well as extending the life span of the Dam.     

Automated extraction of watershed boundary and drainage network from SRTM and comparison with Survey of India toposheet

The recent development of digital representation has stimulated the development of automatic extraction of topographic and hydrologic information from digital elevation model input, using geographic information system (GIS) and hydrologic models that integrate multiple databases within a minimal time. The objective of this investigation is to compare the drainage extracted from Shuttle Radar Topography Mission (SRTM) data with the drainage digitized from topographic data (1:50,000) and also to draw attention to the functions of an add-on tool in ArcGIS 9.2 (Arc Hydro v.2) of Kuttiyadi River basin. The analysis reveals that the watershed extracted from the SRTM digital elevation model (DEM) (90 m resolution) is having an area of 668 km² and that from toposheet is 676 km². The river mouth in the drainage network from the SRTM DEM is found to be shifted to the northern side from where it actually exists. The drainage network from SRTM DEM at stream threshold 15 (0.0002 % of maximum flow accumulation) is delivering best results than the other threshold value in comparison with the drainage pattern derived from toposheets. The study reveals the importance, reliability, and quaintness of drainage network and watershed derived from the SRTM using the Arc Hydro Tool, an extension for Environmental Systems Research Institute ArcGIS. The advantage of the Arc Hydro Tool is that it would help a novice with little GIS knowledge to run the model to obtain watershed and drainage network.     

Assessing the impacts of rainfall intensity and urbanization on storm runoff in an arid catchment

In the past few decades, rapid urbanization has occurred in many regions of the Kingdom of Saudi Arabia due to increasing population and urban development. Additionally, the effects of global warming on rainfall characteristics have been observed. This rapid change in urbanization and climate change has cause significant changes in the nature of land surfaces and rainfall patterns, which affect the runoff process and the amount of surface runoff during floods. This study investigated the effect of urbanization and rainfall intensity for Hafr Al-Batin watershed located in Saudi Arabia. For this purpose, a hydrologic model, HEC-HMS, was adopted to simulate the flow of different rainfall intesities and urbanization levels. Simulated results showed that for a 100-year storm, a 24-h duration, and an urbanization level of 80%, the peak flow was 213% higher than the estimated current peak and the runoff volume was 112% higher than the current runoff volume. These results show a strong linear correlation between the level of urbanization and both peak discharge and runoff volume. Furthermore, the results indicate that for short return periods, the peak flow is more sensitive to the level of urbanization compared to long periods.     

An integrated methodology to assess future water resources under land use and climate change: an application to the Tahadart drainage basin (Morocco)

The assessment of freshwater resources in a drainage basin is not only dependent on its hydrologic parameters but also on the socio-economic system driving development in the watershed area; the socio-economic aspect, that is often neglected in hydrologic studies, is one of the novelties of this study. The aim of this paper is twofold: (1) presenting an integrated working methodology and (2) studying a local case of a North African watershed where scarce field data are available. Using this integrated methodology, the effects of climate and land use change on the water resources and the economic development of the Tahadart drainage basin in Northern Morocco have been evaluated. Water salinization, tourism, urbanization, and water withdrawals are a threat to water resources that will increase with future climate change. The Tahadart Basin (Morocco 1,145 km²) is characterized by rain-fed agriculture and by the presence of two water retention basins. Assessment of the effects of climate and land use change on this drainage basin was based on current and future land cover maps obtained from spatial interactions models, climate data (current and future; scenario A1b for the period 2080–2100), and hydrological models for water budget calculations. Land use suitability maps were designed assuming a A1b Special Report on Emissions Scenarios socio-economic development scenario. The most important conclusions for the period 2080–2100 are the following: (1) Freshwater availability within the watershed will likely be affected by a strong increase in evaporation from open water surface bodies due to increased temperature. This increase in evaporation will limit the amount of freshwater that can be stored in the surface reservoirs. (2) Sea level rise will cause flooding and salinization of the coastal area. (3) The risk for drought in winter is likely to increase. The methodology used in this paper is integrated into a decision support tool that is used to quantify change in land use and water resources.     

Determining the groundwater basin and surface watershed boundary of Dalinuoer Lake in the middle of Inner Mongolian Plateau,China and its impacts on the ecological environment

The surface watershed and groundwater basin have fixed recharge scale, which are not only the basic unit for hydrologic cycle research but also control the water resources formation and evolution and its corresponding eco-geological environment pattern. To accurately identify the boundary of the surface watershed and groundwater basin is the basis for properly understanding hydrologic cycle and conducting the water balance analysis at watershed scale in complicated geologic structure area, especially when the boundary are inconsistent. In this study, the Dalinuoer Lake located in the middle of the Inner Mongolian Plateau which has complicated geologic structure was selected as the representative case. Based on the multidisciplinary comprehensive analysis of topography, tectonics, hydrogeology, groundwater dynamics and stable isotopes, the results suggest the following: (1) The surface watershed ridge and groundwater basin divide of Dalinuoer Lake are inconsistent. The surface watershed was divided into two separate groundwater systems almost having no groundwater exchange by the SW-NE Haoluku Anticlinorium Fault which has obvious water-blocking effect. The surface drainage area of Dalinuoer Lake is 6139 km². The northern regional A is the Dalinuoer Lake groundwater system with an area of 4838 km², and the southern regional B is the Xilamulun Riverhead groundwater system with an area of 1301 km². (2) The groundwater in the southern of regional A and the spring-feeding river are the important recharge sources for the Dalinuoer Lake, and it has greater recharge effects than the northern Gonggeer River system. (3) It is speculated that the trend of Haoluku Anticlinorium Fault is the boundary of the westerlies and the East Asian summer Monsoon (EASM) climate systems, which further pinpoints the predecessor’s understanding of this boundary line. At present, the Dalinuoer Lake watershed is proved to have gone through a prominent warming-drying trend periods, which leads to the precipitation reduction, temperature rise, human activities water usage increasement. So the hydrological cycle and lake eco-environment at watershed scale will still bound to be change, which may pose the potential deterioration risk on the suitability of fish habitat. The results can provide basic support for better understanding water balance evolution and lake area shrinkage cause as well as the ecological protection and restoration implementation of Dalinuoer Lake watershed.© 2021 China Geology Editorial Office.     

Spatial distribution of soil erosion and suspended sediment transport rate for Chou-Shui river basin

In this study, a Physiographic Soil Erosion–Deposition Model (PSED) is applied for better management of a watershed. The PSED model can effectively evaluate the key parameters of watershed management: surface runoff discharge, suspended sediment transport rate, quantity of soil erosion, and spatial distribution of soil erosion and deposition. A basin usually contains multiple watersheds. These watersheds may have complex topography and heterogeneous physiographic properties. The PSED model, containing a physiographic rainfall-runoff model and a basin scale erosion–deposition model, can simulate the physical mechanism of the entire erosion process based on a detailed calculation of bed-load transportation, surface soil entrainment, and the deposition mechanism. With the assistance of Geographic Information Systems (GIS), the PSED model can handle and analyze extremely large hydrologic and physiographic datasets and simulate the physical erosion process without the need for simplification. We verified the PSED model using three typhoon events and 40 rainfall events. The application of PSED to Chou-Shui River basin shows that the PSED model can accurately estimate discharge hydrographs, suspended sediment transport rates, and sediment yield. Additionally, we obtained reasonable quantities of soil erosion as well as the spatial distribution of soil erosion and deposition. The results show that the PSED model is capable of calculating spatially distributed soil erosion and suspended sediment transport rates for a basin with multiple watersheds even if these watersheds have complex topography and heterogeneous physiographic properties.     

Modeling hydrologic responses of the Zwalm catchment using the REW approach: propagation of uncertainty in soil properties to model output

The research presented in this paper focuses on the application of a newly developed physically based watershed modeling approach, which is called representative elementary watershed approach. The study stressed the effects of uncertainty of input parameters on the watershed responses (i.e., simulated discharges). The approach was applied to the Zwalm catchment, which is an agriculture-dominated watershed with a drainage area of 114 km² located in East Flanders, Belgium. Uncertainty analysis of the model parameters is limited to the saturated hydraulic conductivity because of its high influence on the watershed hydrologic behavior and availability of the data. The assessment of output uncertainty is performed using the Monte Carlo method. The ensemble statistical watershed responses and their uncertainties are calculated and compared with measurements. The results show that the measured discharges fall within the 95% confidence interval of the modeled discharge. This provides the uncertainty bounds of the discharges that account for the uncertainty in saturated hydraulic conductivity. The methodology can be extended to address other uncertain parameters as far as the probability density function of the parameter is defined.     

三峡区间入库洪水实时预报系统研究

三峡区间的数字流域水系模型采用基于格网型的数字高程模型坡面流模拟方法和处理"洼地"的最短流程法构建,并以新安江模型为基础建立具有诸多特点的三峡区间流域水文模型;以水动力学理论为基础建立考虑水利工程影响的河川型水库洪水演进模型,并实现这两者的有机耦合。在GIS平台上,将三峡区间流域水文模型、库区洪水演进模型和流域水系生成模型在底层集成,研制了功能先进和完善的三峡水库实时洪水预报系统。该系统已安装在三峡总公司梯级水库调度中心,投入试运行。     

Remote sensing and GIS for artificial recharge study, runoff estimation and planning in Ayyar basin, Tamil Nadu, India

This paper focuses on artificial groundwater recharge study in Ayyar basin, Tamil Nadu, India. The basin is covered by hard crystalline rock and overall has poor groundwater conditions. Hence, an artificial recharge study was carried out in this region through a project sponsored by Tamil Nadu State Council for Science and Technology. The Indian Remote Sensing satellite 1A Linear Imaging Self Scanning Sensor II (IRS 1A LISS II) satellite imagery, aerial photographs and geophysical resistivity data were used to prioritize suitable sites for artificial recharge and to estimate the volume of aquifer dimension available to recharge. The runoff water available for artificial recharge in the basin is estimated through Soil Conservation Service curve number method. The land use/land cover, hydrological soil group and storm rainfall data in different watershed areas were used to calculate the runoff in the watersheds. The weighted curve number for each watershed is obtained through spatial intersection of land use/land cover and hydrological soil group through GeoMedia 3.0 Professional GIS software. Artificial recharge planning was derived on the basis of availability of runoff, aquifer dimension, priority areas and water table conditions in different watersheds in the basin.     

Hydro-morphometrical analyses of sub-himalyan region in relation to small hydro-electric power

The choice of site for small hydropower potentials in the inaccessible tracts of Himalayan region is a difficult task by the conventional methods. Present work suggests a site for developing a multipurpose small reservoir under GIS framework, in the Sub Himalayan region, India. Scarcity of geographical, climate and statistical data was the main problem for development of seasonal precipitation and runoff modeling for assessing water potentials and identification of possible small-scale hydropower sites. Small hydropower potential is mainly regulated by head and its durability available at site depending upon capacity of the watershed, underlying the reservoir, to produce the runoff. The study reveals that the Bari-Ka- Khad watershed (BKW) can be considered as a suitable site of interest for small-scale hydropower installation. It is having maximum drainage density (7.45 km/km²) and maximum available relief ratio (0.12), which demonstrates better capacity to produce runoff. According to drainage texture of BKW (R_t?=?2.35), it come under coarse texture and higher values of Rho coefficient (ρ?=?3.65), suggesting higher hydrologic storage during rainfall and attenuation of effects of erosion during elevated discharge.     

Natural and anthropogenic budgets of a small watershed in the massif central (France): Chemical and strontium isotopic characterization of water and sediments

A small watershed (160 km²) located in the Massif Central (France) has been chemically, isotopically and hydrologically studied through its dissolved load, bed sediments and soils. This watershed is underlain by basaltic bedrock and associated soils in which the vegetation is dominated mainly by meadows.Dissolved concentrations of major ions (Cl, SO₄, NO₃, HCO₃, Ca, Na, Mg, K, Al and Si), trace elements (Rb and Sr) and strontium isotopes have been determined for two different hydrologic periods on the main stream of the Allanche river and its tributaries.The major objectives of this study were to characterize the chemical and isotopic signatures of each reservoir occurring in the watershed. Changes in chemical and isotopic signatures are interpreted in terms of fluctuations of the different components inputs: rainwater, weathering products, anthropogenic addition.Water quality may be influenced by natural inputs (rainwater, weathering processes) and anthropogenic additions (fertilizers, road salts, etc.). Precipitation serves as a major vehicle for dissolved chemical species in addition to the hydrosystem and, in order to constrain rain inputs, a systematic study of rainwaters is carried out over a one year period using an automatic collector. Corrections of rainwater addition using chloride as an atmospheric input reference were computed for selected elements and the Sr/Sr ratio. After such corrections, the geochemical budget of the watershed was determined and the role of anthropogenic additions evaluated through the relationship between strontium isotopes and major and trace element ratios. Thus, 10% of Ca and Na originate in rainwater input, 40 to 80% in fertilizer additions and 15 to 50% in rock weatheringThe cationic denudation rates for this watershed are around 0.3 g s^–1 km² during low water discharge and 0.6 g s^–1 km² in high water stage. This led to a chemical denudation rate of 5.3 mm/1000 years.For solid matter, the normalization of chemical species relative to parent rocks shows the depletion or enrichment in soils and sediments. The use of K and Ca as mobile reference illustrates the weathering state of soils and sediments relative to parent rocks. This weathering state for bed sediments range from 15 to 45% for the K normalization and from 2 to 50% for the Ca normalization. For the soils, the weathering state ranges from 15 to 57% for the K normalization and from 17 to 90% for the Ca normalization.     

Spectrum of climate change and streamflow alteration at a watershed scale

Worldwide, evidences of water cycle alteration and fresh water resources depletion are frequently reported with various magnitudes. This alteration in the hydrologic cycle is often regarded as a signal of the actual climate change. However, the debate on climate change seems to have preferentially focused on global-scale patterns such that the rich knowledge gathered in the domain is virtually less integrated to decision making at the watershed level. Indeed, the watershed apprehension of climate change is probably an imperative for sustainable water resources planning. The scope of the present study aligns with that imperative as it aims at conciliating patterns of climate change with observations of hydrologic alterations at the watershed level. Specifically, the paper describes the interplay between land-cover changes and the terrestrial water cycle disturbances under climate change at the global level. Thereafter, it reports a watershed-level analysis of streamflow, land-cover, PET and precipitation alteration. Specially, the case study focused on the Brazos River basin, located in the USA and shared by the states of Texas and New Mexico. From both regional and watershed prospects, signals of hydrologic alteration during the time period 1955–2014 are highlighted and then implications of climate change are discussed. The results show an overall longitudinal gradient of precipitation changes and a latitudinal gradient of PET changes across the Brazos watershed. However, these gradients of changes seem to be driven by regional climate components which extend beyond the physical boundary of the Brazos watershed. Mann–Kendall’s analysis of discharge time series (annual average, minimum and maximum) at 10 different stations exhibits meaningful contrasts from upstream to downstream. An assessment of land-cover changes shows critical patterns of landscape change across the watershed. The analyses depicted signals of urbanization sprawl and land-cover degradation. Specially, the significant statistical relationships observed between the time series of maximum green vegetation fraction (MGVF) and streamflow also indicate that the origin of the observed hydrologic alteration is anthropogenic. Ultimately, the results are discussed within the scope of climate change.     

Rainfall-runoff modeling of ungauged Wadis in arid environments (case study Wadi Rabigh—Saudi Arabia)

Flash flood forecasting of catchment systems is one of the challenges especially in the arid ungauged basins. This study is attempted to estimate the relationship between rainfall and runoff and also to provide flash flood hazard warnings for ungauged basins based on the hydrological characteristics using geographic information system (GIS). Morphometric characteristics of drainage basins provide a means for describing the hydrological behavior of a basin. The study examined the morphometric parameters of Wadi Rabigh with emphasis on its implication for hydrologic processes through the integration analysis between morphometric parameters and GIS techniques. Data for this study were obtained from ASTER data for digital elevation model (DEM) with 30-m resolution, topographic map (1:50,000), and geological maps (1,250,000) which were subject to field confirmation. About 36 morphometric parameters were measured and calculated, and interlinked to produce nine effective parameters for the evaluation of the flash flood hazard degree of the study area. Based on nine effective morphometric parameters that directly influence on the hydrologic behavior of the Wadi through time of concentration, the flash flood hazard of the Rabigh basin and its subbasins was identified and classified into three groups (High, medium, and low hazard degree). The present work proved that the physiographic features of drainage basin contribute to the possibility of a flash flood hazard evaluation for any particular drainage area. The study provides details on the flash flood prone subbasins and the mitigation measures. This study also helps to plan rainwater harvesting and watershed management in the flash flood alert zones. Based on two historical data events of rainfall and the corresponding maximum flow rate, morphometric parameters and Stormwater Management and Design Aid software (SMADA 6), it could be to generate the hydrograph of Wadi Rabigh basin. As a result of the model applied to Wadi Rabigh basin, a rainfall event of a total of 22 mm with a duration of 5 h at the station nearby the study area, which has an exceedance probability of 50 % and return period around 2 years, produces a discharge volume of 15.2?×?10⁶ m³ at the delta, outlet of the basin, as 12.5 mm of the rainfall infiltrates (recharge).     

Assessing the impacts of land use changes on watershed hydrology using MIKE SHE

A fully distributed, physically-based hydrologic modeling system, MIKE SHE, was used in this study to investigate whole-watershed hydrologic response to land use changes within the Gyeongancheon watershed in Korea. A grid of 200 × 200 m was established to represent spatial variations in geology, soil, and land use. Initial model performance was evaluated by comparing observed and simulated streamflow from 1988 to 1991. Results indicated that the calibrated MIKE SHE model was able to predict streamflow well during the calibration and validation periods. Proportional changes in five classes of land use within the watershed were derived from multi-temporal Landsat TM imageries taken in 1980, 1990 and 2000. These imageries revealed that the watershed experienced conversion of approximately 10% non-urban area to urban area between 1980 and 2000. The calibrated MIKE SHE model was then programmed to repeatedly analyze an artificial dataset under the various land use proportions identified in the Landsat TM imageries. The analysis was made to quantitatively assess the impact of land use changes (predominantly urbanization) on watershed hydrology. There were increases in total runoff (5.5%) and overland flow (24.8%) as a response to the land use change.     

Influence of storm magnitude and watershed size on runoff nonlinearity

The inherent nonlinear characteristics of the watershed runoff process related to storm magnitude and watershed size are discussed in detail in this study. The first type of nonlinearity is referred to rainfall-runoff dynamic process and the second type is with respect to a Power-law relation between peak discharge and upstream drainage area. The dynamic nonlinearity induced by storm magnitude was first demonstrated by inspecting rainfall-runoff records at three watersheds in Taiwan. Then the derivation of the watershed unit hydrograph (UH) using two linear hydrological models shows that the peak discharge and time to peak discharge that characterize the shape of UH vary event-to-event. Hence, the intention of deriving a unique and universal UH for all rainfall-runoff simulation cases is questionable. In contrast, the UHs by the other two adopted nonlinear hydrological models were responsive to rainfall intensity without relying on linear proportion principle, and are excellent in presenting dynamic nonlinearity. Based on the two-segment regression, the scaling nonlinearity between peak discharge and drainage area was investigated by analyzing the variation of Power-law exponent. The results demonstrate that the scaling nonlinearity is particularly significant for a watershed having larger area and subjecting to a small-size of storm. For three study watersheds, a large tributary that contributes relatively great drainage area or inflow is found to cause a transition break in scaling relationship and convert the scaling relationship from linearity to nonlinearity.     

Seasonal Variability of Adsorption and Exchange Equilibria in Soil Waters

Chemical analyses for major ions have been conducted on waters,collected on an approximately weekly basis over the period April, 1993 toNovember, 1996, that drain three small experimental ecosystems(sandboxes) at Hubbard Brook, New Hampshire. One sandbox is planted withpine trees, another with grass, and the third is left bare (actually itis covered sporadically by bryophytes and lichens). Results show linearcorrelations, independent of discharge, between the concentrations ofdissolved Na⁺ and K⁺ on the one hand andCa⁺⁺ and Mg⁺⁺ on the other for all threesandboxes. No correlations between singly charged and doubly chargedcations were found. These correlations are interpreted to represent cationexchange equilibria between soil waters and clay minerals plus soil organicmatter. The correlation slope, representing the exchange constant, for Na vsK is different for the pine-covered sandbox than for the other two whereasfor Ca vs Mg the correlation is independent of the presence or absence oftrees. We interpret this as representing a shift of cation exchangeequilibria in the pine sandbox by the activities of growing trees.Concentrations of Na, K, Ca, Mg, and H₄SiO₄from the barren and grass-lined sandboxes were found to vary seasonally witha marked sinusoidal pattern which was independent of the discharge from eachsandbox. (The discernment of a similar pattern in the tree lined sandbox wasdifficult due to a lack of discharge over much of the year.) Concentrationmaxima occurred in August and minima in February, and there is a closeparallelism with soil temperature. We interpret this as representingtemperature induced variations in cation exchange equilibria and silicaadsorption. Independence from highly varying water discharge, e.g.,. thataccompanying severe rainstorms, indicates rapidly re-attained equilibrium.Variations in the concentrations of cations are likely due to exchange withunmeasured cations, probably H⁺ or dissolved Al species, as aresult of possible seasonal changes in internal acid production and externalinput of acid rain to the sandboxes. Internal production may represent aresponse to seasonal changes in respiration rate as it responds toseasonally varying temperature. Added to this is the effect of temperatureon exchange equilibrium. Seasonal variations in dissolved silica are mostlikely due to the dependence of adsorption/desorption equilibria ontemperature. The temperature dependence of a number of silica-consumingreactions are consistent with the measured values.