Tectonic environment of mesozoic volcanic rocks in the coastal areas of SE China

Mesozoic volcanic rocks in the coastal areas of SE China consist predominantly of rhyolites and pyroclastic rocks, obviously distinct from island-arc volcanic rocks which consist mainly of andesitic rocks. Volcanic rocks in these areas mostly belong to the cale-alkaline series, and their geochemical characteristics are dissimilar to those of island-arc rocks. For example, the SiO₂ content varies greatly from 47 to 81 percent, Fe₂O₃+FeO/MgO>2, K₂O/Na₂O>0.8, the contents of Rb, Sr, Ba, Th, U, and Zr are higher than those of island-arc calc-alkaline rocks, and K/Rb <400. Andesite in the coastal areas of SE China, for the most part, belongs to the alkali-calcic series (CaO<Na₂O+K₂O), typical of a continental tectonic environment. Geotectonic studies have shown that the ancient Eurasian continental margin in Mesozoic times was located to the east of the line linking Japan and Taiwan, and the present location of Mesozoic rocks is not an island-arc. area. In the light of their characteristically high alkalinity, the Mesozoic volcanic rocks are considered to have been formed in a continental environment rather in an island-arc environment. Their formation was controlled by a compresso-shear tranform fault system.     

河南箕山登封岩群变质中基性火山岩的地球化学及年代学研究

对登封岩群 TTG杂岩区内的斜长角闪质表壳岩包体以及绿岩区的变质中基性火山岩对比研究表明 ,其主元素、微量元素、稀土元素和同位素地球化学特征等指示该区的变质中基性火山岩同时同源 ,具有由拉斑玄武岩向钙碱性玄武岩演变的趋势.登封岩群上下部 2件 Sm Nd等时线年龄极为一致 ,可以合并为一条等时线 ,年龄为 (2 512± 19) Ma,ε Nd(t)=2.40± 0.16.综合分析认为 ,箕山地区的登封岩群稍晚于嵩山地区 ,是在新太古代末期一个非常短暂的时间内形成的 ,形成于类似现代岛弧的构造环境.     

浙南龙泉地区晚侏罗世火山岩的厘定及成因探讨

浙江晚中生代大规模火山活动始于晚侏罗世还是早白垩世,长期以来存在争议。本文对浙南龙泉地区火山岩进行了锆石U-Pb定年,获得一批高精度的年代学数据,其SHRIMP锆石U-Pb和LA-ICP-MS锆石U-Pb年龄集中于163～145 Ma,确认浙江晚中生代火山活动始于晚侏罗世。地球化学特征和Sr-Nd同位素特征表明这套晚侏罗世火山岩具有高硅、高钾、低磷、贫铁镁的特征,属于过铝质高钾钙碱性岩石系列。由于晚中生代太平洋板块的俯冲作用,导致了下部地壳物质(基底变质岩)广泛熔融,形成了本区晚侏罗世火山岩浆活动。为了便于表达、对比,笔者建议新建"晚侏罗世黄茅尖群"地层单位。     

辽西凌源地区义县组火山岩锆石U—Pb年代学和地球化学特征

对辽西凌源地区义县组的1件流纹岩样品进行锆石U—Pb年代学研究,获得的年龄为（124．4±1．4）Ma,与前人对辽西北票、义县、凌源等地区通过K—Ar、Ar—Ar、U—Pb等定年方法获得的义县组年龄基本一致,时代为早白垩世。7件典型火山岩样品的地球化学研究结果表明,该火山岩的SiO2=65．6％-73．4％,MgO=0．35％～1．23％,Mg^#=16～41,Al2O3=13．40％～16．79％,Na2O=3．54％-4．26％。Sr=（445～774）×10^-6,Yb=（0．51-0．97）×10^-6,V=（7～14）×10^-6,Sr／Y=49-66,LaN／YbN=33-48,高Sr和Sr／Y比值,低Y和Yb,轻重稀土元素分异明显,显示出埃达克岩的地球化学特征,但其Mg^#较低。它们可能是加厚的基性下地壳部分熔融的产物。     

浙江省西北部白垩纪火山岩Nd-Sr同位素特征

浙江省白垩纪火山岩叠置在扬子地块和华夏地块两个不同的基底构造单元之上，不同构造单元的火山岩Nd同位素组成存在重大差异，其中扬子地块火山岩Nd初始值较高，εNd值介于-8．9～-0．9之间，平均为-4.6（n=33）；华夏地块火山岩εNd值介于-14．1～＋1．2之间，平均为-6．7（n=69）。同时，两个地块火山岩的εNd值均随时间增高、模式年龄均随时间降低的趋势十分明显。扬子地块区从135～124Ma形成的第Ⅰ旋回至110～90Ma形成的第Ⅲ旋回酸性火山岩εNd和t2DM平均值分别为-6.2、-2．4、-2.2和1.42Ga、1．11Ga、1．09Ga；华夏地块区内同时代3个旋回酸性火山岩的εNd和t2DM平均值则为-10．1、-7．2、-5．5和1．75Ga、1，49Ga、1．35Ga。推测浙江省广泛发育的白垩纪流纹质火山岩可能是基底变质岩部分熔融形成，由于持续的玄武岩底侵作用，造成幔源物质的加入量显著地随时间增加。     

内蒙古正蓝旗地区中生代火山岩锆石U-Pb年龄与板内伸展环境成因讨论

内蒙古东南部正蓝旗地区中生代火山岩广泛出露,岩性主要包括流纹岩、粗面岩、碎斑熔岩、熔结凝灰岩以及黑曜岩等,以碎斑熔岩发育为显著特征。本次研究测得流纹岩、霏细质碎斑熔岩及熔结凝灰岩的LA-ICP-MS锆石U-Pb年龄分别为(141.4±0.7)Ma、(141.6±0.6)Ma和(139.4±0.7)Ma,三者在误差范围内一致,表明研究区火山活动(从溢流、爆发到侵出)持续的时间很短,时代为早白垩世早期,属张家口组。除个别样品,正蓝旗地区晚期侵出的碎斑熔岩与早期溢流相的流纹岩、粗面岩在地球化学特征上极为一致,均为富硅富钾,贫Ca、Mg和Al,属粗面岩-流纹岩组合,部分样品具有碱性流纹岩的特征;富集Rb、Th、U等大离子亲石元素,而强烈亏损Ba、Sr、Ti、P;轻稀土元素(LREE)富集,Eu强烈亏损,轻、重稀土元素分馏较强(LaN/YbN主要介于6.87~42.74)。碎斑熔岩体相较于早期熔岩更加富硅贫碱,表明流纹岩-粗面岩喷溢之后,岩浆房中剩余岩浆又经过一定程度的分异,向更为富硅贫碱方向演化之后侵出地表。正蓝旗地区火山岩具有A型花岗岩的特征,为A_1型为主,A_1—A_2过渡的地球化学特征。碎斑熔岩体与流纹岩-粗面岩的Nb/Ta介于10.46~24.02,在地壳和地幔岩浆Nb/Ta比值之间;Y/Nb、Ti/Yb、Ti/Zr均体现出壳幔混合的特点;Rb/Sr介于0.61~64.51,为壳源特征。因此,研究区火山岩是造山后向板内非造山转换并以板内非造山为主的伸展环境下,经较为强烈地幔物质改造的下地壳部分熔融的产物。     

浙江庆元地区早——中侏罗世火山岩LA-ICP-MS锆石U-Pb年龄及其地质特征

在浙江庆元大面积白垩纪火山岩分布区,首次发现层位可归入毛弄组的早—中侏罗世火山岩,用LA-ICP-MS技术测得其中流纹英安岩和流纹质弱熔结凝灰岩中的锆石U-Pb年龄分别为176.0±1.2Ma和169.1±3.3Ma。结合闽北地区发现的中侏罗世火山岩,推断东南沿海地区在早—中侏罗世时已开始进入古太平洋板块俯冲的构造体制。     

Nd, Sr and O Isotopic Study on Spilite-Keratophyre in Xiqiu,,Zhejiang Province, China

Nd, Sr and O isotopic study on the spilite-keratophyre sequence in Xiqiu shows that its ∈_(Nd) values are inthe range of 4.02-5.26, and its ∈_(Sr) values, +1.4-2.6. According to the points of these data in the ∈_(Nd)-T,∈_(Sr)-T and ∈_(Nd)-∈_(Sr) diagrams, the spilite-keratophyre is interpreted as being slightly contaminated by crustalmaterials. Its δ~(18)O values are 3.9-5.0‰. The depletion of ~(18)O in the rocks resulted from the influence ofseawater hydrothermal alteration during or soon after the rock formation. Based on the isotopic characteristicsand available geochemical data, it is believed that the spilite-keratophyre was formed in the well-developedisland-arc environment during the Late Proterozoic subduction of the palaeo-Pacific plate beneath thesoutheastern margin of the Yangtze massif.     

K-Ar ages and Pb,Sr isotopic characteristics of Cenozoic volcanic rocks in Shandong Province,China

28 samples of Cenozoic volcanic rocks collected from Shandong Province have been dated by K-Ar method. They are mainly Neogene with an age range of 4–19 m. y. The basalts from Linqu and Yishui in west Shandong Province are Miocene and those from Penglai and Qixia in east Shandong Province are Miocene and Pliocene in age. The basalts from Wudi in north Shandong Province are Middle-Early Pleistocene in age. In each area the duration of volcanic eruption was estimated at about 2–3 m. y. Pb and Sr isotopic compositions and U, Th, Pb, Rb, Sr, and major elements in most of the samples were determined. The isotopic compositions are:²⁰⁶Pb/²⁰⁴Pb—16.92-18.48,²⁰⁷Pb/²⁰⁴Pb—15.30-15.59,²⁰⁸Pb/²⁰⁴Pb—37.83-38.54, and (⁸⁷Sr/⁸⁶Sr)_i—0.70327-0.70632. There are some positive or negative linear correlations between²⁰⁶Pb/²⁰⁴Pb and²⁰⁷Pb/²⁰⁴Pb, Pb isotopes and Pb content, Pb isotopes and Sr isotopes, and Sr isotopes and other elements. The basaltic rocks from east and west Shandong Province have somewhat differences in isotopic composition and element content. The basalts probably are products of multi-stage evolution of the mantle. They have preserved the primary features of the source, although they were influenced, to some extent, by the contamination of crustal materials.     

Geochemical Characteristics of Volcanic Rocks of the Laochang Ag Polymetallic Deposit,Lancang,Yunnan Province,China

In terms of major element, trace element and REE geochemical characteristics ofvolcanic rocks in the area studied and by making use of the TiO2-K2O-P2O5,The-Hf-Ta and Zr-Nb-Y trianglar diagrams and the environmental discrimination diagrams of incompatible ele-ment distribution pattems,the authors have drawn some conclusions that are different from those by previous workers.It is concluded that volcanic rocks in the Laochang Ag polymetallic deposit at Lancang,Yunnan belong to continental within-plate alkali basalts, and that their geotectonic setting seems to be at the northeastern margin of East Gondwana Land.     

可可西里湖地区新生代火山岩同位素地球化学特征及火山成因、源区性质讨论

在青藏高原腹地可可西里地区发育一套新生代碱性、高钾钙碱性——钾玄岩火山岩类,由于该时期正是亚洲大陆内部岩石圈发生剧烈变形,青藏高原强烈隆升的重大变革时期,火山岩的形成在这些重大事件中扮演什么角色?很值得探讨。通过对区内火山岩Rb、Sr、Sm、Nd、Pb同位素的研究,在火山岩的岩浆来源、成因等方面获得了大量信息。研究表明:新生代火山岩主要来源于富集 型地幔区,部分为具极高εSr和极低εNd的酸性火山岩,它是与区内钾质熔岩同源的晚期分异产物;碱性火山岩在成因上与板内初始裂谷有关。研究成果为青藏高原特有的"壳-幔混合层"的形成提供了证据。     

东天山企鹅山群火山岩锆石U-Pb年代学

企鹅山群是指分布于东天山觉罗塔格地区康古尔塔格断裂和大草滩断裂之间的一套火山-沉积岩系。新近发现的土屋-延东大型斑岩型铜矿含矿斑岩的围岩为企鹅山群第二组的火山岩系,同时由于该火山岩系与其上覆和下伏岩系均呈断层接触,因而企鹅山群火山岩的形成时代备受关注。对该火山岩系组合中的基性火山岩和酸性火山岩进行锆石U-Pb同位素年龄测定,测得基性火山岩的成岩年龄为322.6Ma±2.0Ma,酸性火山岩的成岩年龄为319.9Ma±1.6Ma。该年龄对认识东疆地区石炭纪构造演化历史和成矿作用具有重要价值。     

青海省俄昌公仁地区尕笛考组火山岩地球化学特征及构造环境

俄昌公仁地区地处西金乌兰—金沙江构造混杂岩带与北羌塘—昌都地体的交汇部位。文章通过对乌丽—开心岭尕笛考组火山岩岩石学、主量元素、稀土元素、微量元素等地质地球化学研究表明:尕笛考组火山岩为典型的钙碱性岩石组合,推断尕笛考组火山岩属于与板块俯冲作用有关的岩浆岛弧带的产物,形成于与板块俯冲作用有关的岛弧构造环境;锆石U-Pb同位素年代为258.5 Ma±4.6 Ma,属晚二叠世早期。     

Diffusion versus recrystallization processes in Rb-Sr geochronology: Isotopic relics in eclogite facies rocks, Western Gneiss Region, Norway

Rb-Sr and U-Pb isotopic data for granulite facies rocks, forming textural relics with respect to eclogite facies metamorphism in the Western Gneiss Region (WGR) of Norway, highlight the importance of textures and mineral reaction kinetics for the interpretation of geochronological data. Studied rocks from Bårdsholmen, southern WGR, were subjected to granulite facies metamorphism at 955 ± 3 Ma (U-Pb, zircon). Later on, they experienced a subduction-related, kinetically stranded eclogitization (T > 650 °C at ∼20 kbar) at 404 ± 2 Ma (Rb-Sr multimineral internal isochron data), followed by exhumation through amphibolite facies conditions. Full conversion of granulite to eclogite was restricted to zones of fluid infiltration and deformation. Despite the fact that metamorphic temperatures vastly exceeded the commonly assumed ‘closure temperature’ for Rb-Sr in submillimeter-sized biotite for several Ma during eclogite facies overprint, Sr-isotopic signatures of relic biotite have not been fully reset. Large biotite crystals nearly record their Sveconorwegian (Grenvillian) crystallization age. Sr signatures of other granulite facies phases (feldspar, pyroxenes, amphibole) remained unchanged, with the exception of apatite. The results imply that isotopic signatures much closer correspond to the P, T conditions of formation recorded by a dated phase and its paragenesis, than to a temperature history. In texturally well-equilibrated high-grade rocks which experienced no mineral reactions and remained devoid of free fluids during exhumation, like granulites or eclogites, isotopic resetting during cooling is either kinetically locked, or restricted to sluggish intermineral diffusion which demonstrably does not lead to full isotopic homogenization. In texturally unequilibrated rocks, textural relics are likely to represent isotopic relics. It is shown that for both high-grade rocks and for rocks with textural disequilibria, geologically meaningful isotopic ages based on isochron methods can only be derived from sub-assemblages in isotopic equilibrium, which have to be defined by analysis of all rock-forming minerals. Conventional two-point ‘mica ages’ for such rocks are a priori geochronologically uninterpretable, and valid multimineral isochron ages a priori do not record cooling but instead date recrystallization-inducing processes like fluid-rock interaction.     

Trace Element Geochemistry of Cenozoic Volcanic Rocks in Shandong Province

The Cenozoic volcanic rock of Shandong Province are mainly alkalic and strongly alkalic basaltic rocks.The Contents of major and trace elements including transitional,incompatible and rare-earth elements were determined.The chemical characterisitics of major and trace elements indicate that these basaltic rocks were derived from a mantle source and probably represent a primary magma,I,e.,unmodifiecd partical melts of mantle peridotite in terms of Mg values,correlatione between P2O5 and Ce,Sr,Ni and Rb concentrations,mantle xenoliths,etc.The abundances of trace elements vary systematically from west to east.The compatible transition elements such as Co,Ni,and Cr show a remarkable depletion,whereas the incompatible and rare-earth elements are abundant as viewed from the chondrite-nor-malized patterns.The chemical composition and correlation are consistent with the tectonic setting.According to the batch and fractional partial melting theory,the trace element contents of Shandong volcanic rocks can be calculated from the two-component mixing model.     

云南腾冲新期火山岩矿物及其熔体包裹体研究

腾冲火山群位于我国云南省西部和缅甸的交界处,由黑空山、大空山、小空山、打鹰山、马鞍山等一系列火山组成,是我国著名的第四纪火山群,从喷发活动时间上可分为老期火山和新期火山.前人研究证实,打鹰山、马鞍山和黑空山为新期火山,它们在全新世都有过喷发活动.这些新期火山岩的主要斑晶矿物为辉石、橄榄石和长石,主要的斑晶矿物中都含有熔体包裹体,它们形态多样,分布不规则,且部分显示后期有变化.探针分析表明,新期火山岩矿物中熔体包裹体成分的变化范围大于其基质玻璃成分的变化范围,它们的化学成分分布范围涵盖了玄武粗安岩、粗面安山岩、粗面岩和流纹岩等岩石类型,与腾冲火山区晚更新世以来火山岩的成分分布范围基本一致.根据对新期火山岩斑晶和微晶矿物中熔体包裹体及基质玻璃成分的测试研究,其中挥发分Cl的含量在包裹体和基质中变化不大,但F、SO3在熔体包裹体中的含量高于基质,总体上腾冲新期火山喷发时岩浆的脱气率较低,喷发时并未向空中喷出大量气体,推测对当时的气候环境影响不大,但未来喷发的灾害效应不容忽视.     

南秦岭耀岭河群裂谷型火山岩锆石U—Pb年代学

南秦岭耀岭河群以变质基性火山岩为主,夹少量酸性火山岩和碎屑岩。基性火山岩和凝灰岩的TIMS法锆石U-Pb同位素年龄分别为808Ma±6Ma和746Ma±2Ma,表明耀岭河群主体形成于南华纪,西峡-淅川一带所谓的“武当岩群”明显年轻于中元古代武当岩群,应该属于耀岭河群。耀岭河群大陆裂谷型火山岩是全球Rodinia超大陆在新元古代晚期南华纪裂解过程中的产物,反映秦岭造山带和Rodinia超大陆的形成演化密切相关。     

西藏冈底斯带措勤地区则弄群火山岩锆石U-Pb年代学格架及构造意义

大规模的则弄群火山岩呈带状近东西向展布于西藏冈底斯带中北部地区.对出露状况较好的措勤地区则弄群火山岩进行了锆石U-Pb定年,以建立其年代学格架便于区域对比.措勤地区则弄群火山岩多数锆石具有生长振荡环带,部分锆石显示核边结构.在措勤达雄北西部上覆于中二叠统下拉组灰岩的1件则弄群英安岩样品的LA-ICP-MS锆石U-Ph年龄为130±1Ma,1件则弄群流纹岩样品的SHRIMP锆石U-Pb年龄为129±3Ma;在措勤达雄北东部与下白垩统多尼组碎屑岩呈断层接触的1件则弄群英安岩样品中的锆石具有两组LA-ICP-MS锆石U-Pb年龄,最年轻的一组(包括增生边)为121±1Ma,较老的一组(包括核部)为131±1Ma;在措勤南西部1件则异群流纹岩样品的LA-ICP-MS锆石U-Pb年龄为111±1Ma,与措勤地区花岗岩类的侵位时代相当.这些高质量的锆石U-Pb年代学数据表明,措勤地区的则弄群火山作用很可能开始于约130Ma,停息于约110Ma,持续时间约20Ma.区域对比表明,东西延伸约1000km的则弄群火山作用同时发生在约130Ma.区域上目前的年代学数据结合同时代岩浆作用的分布特征表明,冈底斯带中北部地区早白垩世岩浆作用不太可能由新特提斯洋壳向北的低角度或平板俯冲产生.     

陆相火山岩区填图方法的实践——以浙江嵊州新生代玄武岩为例

从20世纪90年代以来,中国陆相火山岩区调查工作普遍采用"火山构造-火山岩相-火山岩性"三位一体的思路与工作方法。以浙江嵊州地区1∶5万区域地质调查工作为例,探讨了该方法在大面积新生代玄武岩区中的应用。系统的野外调查及研究显示,在新生代玄武岩区,遥感技术及新的影像图是火山岩区填图的关键,图像解译-野外验证的反复实践,是提高填图效果和质量的有效方法。在野外,特殊的地貌、爆发相的集块角砾岩及火山颈相的玄武玢岩往往指示了火山机构的中心;火山岩相、喷发间断是划分火山旋回的关键。火山机构、火山岩相、火山岩性的时间-空间变化是恢复古火山喷发历史的关键手段。