Hydrograph Separation of the Amazon River: A Methodological Study

The hydrograph separation of the Amazon river was performed using three different methodologies. Were applied isotopic, filter-separation, and mixing methods to estimate the contributions of the surface runoff (event water) and baseflow (pre-event water) components to the total river flow, during the 1973–1974 hydrological years. The importance of the baseflow contribution, mainly during the peak discharge, suggesting that the groundwater plays a much more active and important role in the storm dynamics, was verified. Similar results were obtained for all the methods used, and the applicability of each one was discussed in detail. For the Amazon river basin, the average contribution of the baseflow was 56% of the total river flow, at peak discharge. The average surface runoff contribution, which represents the water capable of mechanical erosion in drainage basins, expressed in terms of the surface runoff coefficient (Kr), was 31.9%, while the mean contribution of the baseflow, expressed by the baseflow coefficient (Kb), was 68.1%.     

Relationship between electrical conductivity, <Superscript>18</Superscript>O of water and NO<Subscript>3</Subscript> content in different streamflow stages

The Ballenera Creek has 160 km² being a small catchment in the Pampa Plain in Argentina. This area has been deeply modified by human action through agricultural activities. From 2013 to 2017, electrical conductivity, stable isotopes of water and nitrate concentration monitoring program were conducted. The sampling included weekly and bimonthly samples in two sites along the stream, several groundwater wells and monthly precipitation. Chemical and isotopic tracers are used to discriminate the streamflow components and to evaluate their incidence in the nitrate concentration. The easiest conceptual model for gaining streams contemplates two main elements: direct runoff and groundwater (baseflow and pre-event water). The direct runoff has the lowest electrical conductivity and ¹⁸O_w variable content. The baseflow component is characterized by the highest electrical conductivity and isotope composition quite constant. Finally, pre-event water has an intermediate electrical conductivity and isotopic content close to the rainfall-weighted average composition. The nitrate concentration obtained was in general related to the different stream stages and was a useful indicator to evaluate the fertilization in agricultural zones.     

Deep groundwater flow as the main pathway for chemical outputs in a small headwater watershed (Mule Hole,South India)

This study examined the water and chemical cycles of a small forested head catchment. Application of Cl^? mass balance lead to the identification of a groundwater baseflow located into the active zone of the crystalline aquifer, below the weir. These findings indicate that groundwater contributes to a large part of chemical outputs at the catchment scale. This study shows that groundwater should not be ignored in most small watershed studies because this flow path and associated solutes are strongly significant for chemical balance assessment.     

黄河源区气候对径流的影响分析

根据对降水响应速度的快慢,径流又可分为直接径流和基流。基流一般定义为河川径流中来自于地下蓄水或者其他延迟水源的成分,代表地下水出流;直接径流表示对降水事件的直接响应。从这一思路出发,文中在分析降水到总径流、直接径流和基流的转化率的基础上分析了气候变化对径流的影响。研究发现,黄河源区的径流系数随降水量的增加而增大,随气温升高而降低;径流随着降水的增加而增加。20世纪90年代降水减少和气温的大幅度升高是黄河源区径流减少的重要原因。区间子流域分析表明,不同的子流域气温和降水对径流的影响不同,在吉迈以上区间,年气温比较低,气温是影响径流系数的主要因子,径流随着气温的升高而降低,降水对径流的影响比较小;在吉迈—玛曲区间,直接径流量/降水量主要受降水的影响,总径流量/降水量、基流量/降水量随降水增加而升高,随气温升高而降低。总径流和基流随降水的增加而增大,随气温的升高而减少;在玛曲—唐乃亥区间,径流系数随着降水量的增加而增加,直接径流量/降水量随气温的升高而降低,降水是径流的主要影响因素。     

黑河上游高寒山区降雨-径流形成过程的同位素示踪

为揭示中、低纬度高寒山区降雨-径流的形成过程,指导水资源的合理开发利用,选择黑河上游红泥沟小流域为研究区,基于河道径流量及雨水和河水稳定同位素的观测数据,构建二元混合模型,计算了2013年7月23日及8月21日两次典型降雨-径流事件中事件水（降雨）和事件前水（流域前期储水）对河道径流的贡献及其动态变化.结果显示:两次降雨事件中事件前水的贡献比例分别为68.69%和54.46%;事件前水的贡献比例在涨水阶段减小,在退水阶段增大.结合河水电导率的观测结果,进一步分析了降雨-径流的形成过程:河道径流的形成主要受饱和区蓄满产流、河岸带地下径流和山坡地下径流3种产流机制控制;事件水主要源于蓄满产流,事件前水主要源于河岸带和山坡地下径流;事件初期和末期以河岸带地下水补给为主,涨水阶段后期和退水阶段前期转为以蓄满产流和山坡地下水补给为主,洪峰期间蓄满产流的贡献达到最大.两次事件的对比表明,事件前的湿度条件和降雨强度对降雨-径流的形成过程有着重要影响:前期越湿润,流域储水能力越弱,导水能力越强,事件水的贡献越大,河道径流对降雨的响应越迅速;降雨强度越大,蓄满产流及其中的事件水比例越高,河道径流中事件水的比例也越高.      

Investigating hydrological drivers of nitrate export dynamics in two agricultural catchments in Germany using high-frequency data series

In this study near-continuous time series of nitrate, electrical conductivity, and discharge were used to identify the dominating hydrological mechanisms that control nitrate export dynamics in two agricultural catchments. The main goal was to assess relationships between contrasting event based as well as long-term nitrate transport behaviour and catchment hydrology. Data records were obtained from online probes that allow field based high-frequency analyses over long time periods. The catchments of the Ammer River (southwestern Germany) and the Weida River (eastern Germany) are similar with respect to size (~100 km²), morphology, and climate and are dominated by agricultural use. Main differences are the stronger urbanization and the occurrence of karstic rocks in the Ammer catchment. Nitrate concentrations are high in water of both streams and range mostly between 20 and 50 mg l^?1. Nitrate export in the Ammer catchment is dominated by baseflow and a minor second, diluting runoff component generated in urbanized areas. In contrast, nitrate dynamics of the Weida catchment is governed by the interplay of at least three runoff components, while the largest amount of nitrate is mobilized intermittently by a delayed fast component generated in the catchment’s soils during wet conditions. These interpretations, derived with one online probe at the outlet of each catchment, are well in line with the former modeling results. This study shows that high-resolution data obtained by online techniques offers a large potential to improve the conceptualization of dominating flow and transport processes at catchment scales at relatively low costs and effort.     

Storm runoff processes in a small forested drainage basin

A brief review was made of storm runoff processes and the mechanisms of its generation in relation to subsurface water behaviors in a small forested drainage basin located in the western suburbs of Tokyo, Japan. The results of field investigations showed that the main source of storm runoff was groundwater flow and that the rapid and large amounts of groundwater discharge during a storm event could not be explained solely by the traditional concept of Darcian matrix flow. Several mechanisms such as pipe flow, air pressure effect, and capillary barrier effect were recognized that would induce a rapid response of groundwater to storm events depending on differences in local hydrologic conditions. All of these mechanisms were chiefly attributed to inhomogeneities of the soil deposits. The importance of dynamic behaviors of subsurface water during a storm event was emphasized in considering the mechanism of storm runoff generation.     

Runoff and sediment yield modeling by means of WEPP in the Bautzen dam catchment,Germany

Soil erosion by water is one of the most widespread forms of soil degradation in Europe. There are many undesirable consequences of soil erosion due to water such as loss of water storage capacity in reservoirs and transfer of pollutants from farmland to water bodies. The objectives of this study were to calibrate and validate the Water Erosion Prediction Project watershed model (WEPP 2012.8) in the Bautzen dam catchment area with monthly and daily single events for runoff and sediment yield. This is to our knowledge the first study using WEPP in Germany. The catchment (310 km²) was subdivided into small sub-catchments with an area of <260 ha as recommended in WEPP. A sensitivity analysis revealed that the runoff is highly sensitive to the effective hydraulic conductivity in Bautzen, whereas the sediment yield is highly sensitive to rill erodibility, critical shear stress, and to the effective hydraulic conductivity as well. All these parameters were initially calculated using WEPP’s built-in equations and parameters, which, however, produced very poor results for both runoff and sediment yield. Therefore, the model was calibrated for 2 years (2005–2007) and validated for another 2 years (2008–2009) against monthly measurements, in addition to 14 daily single events from the calibration period and 2010. The monthly results were compared with the monthly measurements on the basis of a continuous simulation. Results of calibration and validation periods show a satisfactory performance of WEPP with a determination coefficient R ² above 0.6 and Nash–Sutcliffe efficiency coefficients above 0.50 for runoff and sediment yield. Thus, the model could be used to simulate runoff and sediment yield, and used in scenario studies in the Bautzen dam catchment area.     

Distribution of stable isotopes in arid storms

 Temporal distributions of the isotopic composition in arid rain storms and in the associated runoff were investigated in a small arid rocky basin in Israel. Customized rain and runoff samplers provided sequential water samples hermetically sealed in high-density PVC bags. In several storms where the runoff was isotopically depleted, compared with the rainfall, the difference could not be explained by fractionation effects occurring during overland flow. A water-balance study relating the runoff discharge to rainfall over a rocky watershed showed that the entire discharge is produced by a very small segment (1–2 mm) of the rain storm. The major objective, therefore, was to provide quantitative relations between segments of rainfall (rain showers and rain spells) and runoff. The time distribution of the composition of stable isotopes (oxygen and hydrogen) was used to quantify the correlation between the rain spell's amount and the consequent runoff. The aim of this work was to (a) utilize the dynamic variations in the isotopic composition in rainfall and runoff and model the magnitude of surface-storage capacity associated with runoff processes of overland flow, and (b) characterize the isotopic composition of the percolating water with respect to the isotopic distribution in rainfall and runoff events. The conceptual model postulates an isotopic mixing of overland flow with water within the depression storage. A transport model was then formulated in order to estimate the physical watershed parameters that control the development of overland flow from a certain rainfall period. Part I (this paper) presents the results and the assessment of the relative depression storage obtained from oxygen-18 and deuterium analyses that lead to the physical and mathematical formulation of a double-component model of kinematic-wave flow and transport, which is presented in Part II (accompanying paper). Received, February 1997 · Revised, September 1997 · Accepted, September 1997     

Indication of hydrogen and oxygen stable isotopes on the characteristics and circulation patterns of medium-low temperature geothermal resources in the Guanzhong Basin,China

Guanzhong Basin is a typical medium-low temperature geothermal field mainly controlled by geo-pressure in the west of China.The characteristics of hydrogen and oxygen isotopes were used to analyze the flow and storage modes of geothermal resources in the basin.In this paper,the basin was divided into six geotectonic units,where a total of 121 samples were collected from geothermal wells and surface water bodies for the analysis of hydrogen-oxygen isotopes.Analytical results show that the isotopic signatures of hydrogen and oxygen throughout Guanzhong Basin reveal a trend of gradual increase from the basin edge areas to the basin center.In terms of recharge systems,the area in the south edge belongs to the geothermal system of Qinling Mountain piedmont,while to the north of Weihe fault is the geothermal system of North mountain piedmont,where the atmospheric temperature is about 0.2℃-1.8℃in the recharge areas.The main factors that affect the geothermal waterδ18O drifting include the depth of geothermal reservoir and temperature of geothermal reservoir,lithological characteristics,water-rock interaction,geothermal reservoir environment and residence time.Theδ18O-δD relation shows that the main source is the meteoric water,together with some sedimentary water,but there are no deep magmatic water and mantle water which recharge the geothermal water in the basin.Through examining the distribution pattern of hydrogen-oxygen isotopic signatures,the groundwater circulation model of this basin can be divided into open circulation type,semi-open type,closed type and sedimentary type.This provides some important information for rational exploitation of the geothermal resources.     

Stable-isotope and solute-chemistry approaches to flow characterization in a forested tropical watershed,Luquillo Mountains,Puerto Rico

The prospect of changing climate has led to uncertainty about the resilience of forested mountain watersheds in the tropics. In watersheds where frequent, high rainfall provides ample runoff, we often lack understanding of how the system will respond under conditions of decreased rainfall or drought. Factors that govern water supply, such as recharge rates and groundwater storage capacity, may be poorly quantified. This paper describes 8-year data sets of water stable isotope composition (δ²H and δ¹⁸O) of precipitation (4 sites) and a stream (1 site), and four contemporaneous stream sample sets of solute chemistry and isotopes, used to investigate watershed response to precipitation inputs in the 1780-ha Río Mameyes basin in the Luquillo Mountains of northeastern Puerto Rico. Extreme δ²H and δ¹⁸O values from low-pressure storm systems and the deuterium excess (d-excess) were useful tracers of watershed response in this tropical system. A hydrograph separation experiment performed in June 2011 yielded different but complementary information from stable isotope and solute chemistry data. The hydrograph separation results indicated that 36% of the storm rain that reached the soil surface left the watershed in a very short time as runoff. Weathering-derived solutes indicated near-stream groundwater was displaced into the stream at the beginning of the event, followed by significant dilution. The more biologically active solutes exhibited a net flushing behavior. The d-excess analysis suggested that streamflow typically has a recent rainfall component (∼25%) with transit time less than the sampling resolution of 7 days, and a more well-mixed groundwater component (∼75%). The contemporaneous stream sample sets showed an overall increase in dissolved solute concentrations with decreasing elevation that may be related to groundwater inputs, different geology, and slope position. A considerable amount of water from rain events runs off as quickflow and bypasses subsurface watershed flowpaths, and better understanding of shallow hillslope and deeper groundwater processes in the watershed will require sub-weekly data and detailed transit time modeling. A combined isotopic and solute chemistry approach can guide further studies to a more comprehensive model of the hydrology, and inform decisions for managing water supply with future changes in climate and land use.     

Coupling a glacier melt model to the Variable Infiltration Capacity (VIC) model for hydrological modeling in north-western China

For the sustainable utilization of rivers in the mid and downstream regions, it is essential that land surface hydrological processes are quantified in high cold mountains regions, as it is in these regions where most of the larger rivers in China acquire their headstreams. Glaciers are one of the most important water resources of north-west China. However, they are seldom explicitly considered within hydrological models, and climate-change effects on glaciers, permafrost and snow cover will have increasingly important consequences for runoff. In this study, an energy-balance ice-melt model was integrated within the Variable Infiltration Capacity (VIC) macroscale hydrological model. The extended VIC model was applied to simulate the hydrological processes in the Aksu River basin, a large mountainous and glaciered catchment in north-west China. The runoff components and their response to climate change were analyzed based on the simulated and observed data. The model showed an acceptable performance, and achieved an efficiency coefficient R ² ≈ 0.8 for the complete simulation period. The results indicate that a large proportion of the catchment runoff is derived from ice meltwater and snowmelt water. In addition, over the last 38 years, rising temperature caused an extension in the snow/ice melting period and a reduction in the seasonality signal of runoff. Due to teh increased precipitation runoff, the Aksu catchment annual runoff had a positive trend, increasing by about 40.00 × 10⁶ m³ per year, or 25.7 %.     

Evaluation of diffuse and preferential flow pathways of infiltrated precipitation and irrigation using oxygen and hydrogen isotopes

Subsurface-water flow pathways in three different land-use areas (non-irrigated grassland, poplar forest, and irrigated arable land) in the central North China Plain were investigated using oxygen (¹⁸O) and hydrogen (²H) isotopes in samples of precipitation, soils, and groundwater. Soil water in the top 10 cm was significantly affected by both evaporation and infiltration. Water at 10–40 cm depth in the grassland and arable land, and 10–60 cm in poplar forest, showed a relatively short residence time, as a substantial proportion of antecedent soil water was mixed with a 92-mm storm infiltration event, whereas below those depths (down to 150 cm), depleted δ¹⁸O spikes suggested that some storm water bypassed the shallow soil layers. Significant differences, in soil-water content and δ¹⁸O values, within a small area, suggested that the proportion of immobile soil water and water flowing in subsurface pathways varies depending on local vegetation cover, soil characteristics and irrigation applications. Soil-water δ¹⁸O values revealed that preferential flow and diffuse flow coexist. Preferential flow was active within the root zone, independent of antecedent soil-water content, in both poplar forest and arable land, whereas diffuse flow was observed in grassland. The depleted δ¹⁸O spikes at 20–50 cm depth in the arable land suggested the infiltration of irrigation water during the dry season. Temporal isotopic variations in precipitation were subdued in the shallow groundwater, suggesting more complete mixing of different input waters in the unsaturated zone before reaching the shallow groundwater.

     

Dynamics and anthropogenic impacts of multiple karst flow systems in a mountainous area of South China

The Xiangxi River basin, South China, is a steep terrane with well-developed karst features and an important Cambrian-Ordovician aquifer. Meteoric water in this mountainous area features a mean δ¹⁸O elevation gradient of –2.4?‰/km. This gradient was used to estimate mean recharge elevations of 760 m for Shuimoxi (SMX) spring, 1,060 m for Xiangshuidong (XSD) spring, and 1,430 m for drill hole ZK03, indicating multiple flow paths in the Cambrian-Ordovician karst aquifer. Mean residence times of 230 and 320 days and ～2 years were estimated for these features, respectively, using the damped running average model that predicts the isotopic variations in groundwater from those in precipitation. Groundwater in the regional karst flow system has the longest residence time, the highest recharge elevation, the longest flow paths, the lowest addition of anthropogenic components, and the greatest amount of water–rock interaction as indicated by its higher dissolved solids, Mg²⁺ concentrations and Mg/Ca ratios than the springs. In contrast, the local and shallow karst flow systems respond rapidly to recharge events. Artificial tracer tests prove that these shallow karst systems can also quickly transmit anthropogenic contaminants, indicating that they are highly vulnerable to human impacts, which include the enrichment of NO₃ ^–. The intensity of water–rock interaction and groundwater vulnerability are mainly determined by the structure and dynamics of the multiple karst flow systems.     

Estimating suspended sediment yield, sedimentation controls and impacts in the Mellah Catchment of Northern Algeria

This paper is an assessment of the suspended sediment yield in the Mellah Catchment of northern Algeria. We use discharge–sediment load relationships to explore the variability of water discharge and sediment load, and to investigate the impact of geomorphic factors disturbance on erosion and sedimentation. Suspended sediment load was analyzed in the Mellah Catchment (550 km²) which was controlled by a gauging station to measure discharge and sediment transport. The relations between daily mean sediment concentration and daily mean water discharge were analyzed to develop sediment rating curves. For storms with no water samples, a sediment rating curve was developed. The technique involves stratification of data into discharge-based classes, the mean of which are used to fit a rating curve according to single flow data and season to provide various rating relationships. The mean annual sediment yield during the 24 years of the study period was 562 T km^?2 in the Mellah Catchment. This drainage basin had high rainfall and runoff, the erosion was high. The high sediment yield in the Mellah basin could be explained by a high percentage of sparse grassland and cultivation developed on shallow marly silty-clayey soils with steep slopes often exceeding 12%. Almost all suspended sediment loads are transported during storm events that mainly occur in the winter and spring heavy and medium downpours. The scarceness of these events leads to a very large interseasonal variability of the wadi sediment fluxes. The negative impacts of this enhanced sediment mobility are directly felt in the western part of the basin which shows many mass movements, bank and gully erosion because cultivated areas are often bared during autumnal brief flash floods and furrowed downslope during the winter season.     

Case study of a giant debris flow in the Wenjia Gully, Sichuan Province, China

The debris flow, which was triggered in the Wenjia Gully on August 13, 2010, is an extreme example of mass movement events, which occurred after the Wenchuan earthquake of May 12, 2008. This Earthquake triggered in the Wenjia Gully the second largest co-seismic landslide, which can be classified as a rockslide-debris avalanche. A lot of loose sediments was deposited in the basin. In the main so called Deposition Area II of this landslide, with a volume of 30?×?10⁶?m³, flash floods can easily trigger debris flows because of the steep bottom slope and the relative small grain sizes of the sediments. The largest debris flow of August 13, 2010 destroyed the most downstream dam in the catchment during a heavy rain storm. The debris flow with a peak discharge of 1,530?m³/s and a total volume of 3.1?×?10⁶?m³ caused the death of 7 persons, 5 persons were missing, 39 persons were injured and 479 houses buried. After three rainy seasons, only 16?% of the landslide-debris deposition was taken away by 5 large-scale debris flow events. Since the threshold for rainfall triggered debris flows in the Wenjia Gully and other catchments drastically decreased after the Wenchuan Earthquake, new catastrophic events are expected in the future during the rainy season.     

Effects of restricted recharge in an urban karst system

Urban karst systems are typically considered more vulnerable to contamination and excess storm discharge because of potential source areas, increased sediment loading, and focusing of water from impervious surfaces. However, urban hydrology can lead to unexpected patterns, such as pirating of recharge into man-made storm systems. Valley Creek Basin in southeastern Pennsylvania, presents such an urban karst system. Four springs were monitored for suspended sediment, water chemistry, and storm response for an 18-month period. The baseflow suspended sediment concentrations were low, less than 4.0 mg/l. Furthermore, trace metal analysis of baseflow water samples and spring mouth sediment showed only low concentrations. The response to storms within the system was rapid, on the order of 1–3 h. The maximum water stage increases at the urban springs were typically less than 15 cm, with springs from more commercialized areas showing <2 cm increase. A nearby retention basin, in contrast, had water level rises of 100 cm, suggesting that pirating of recharge into stormwater systems occurs. Thus, the concept of an urban karst system as a contaminant conduit is not the only one that applies. In Valley Creek Basin, reduced infiltration due to paving led to smaller storm response and less contaminant input, and the smaller capture area due to diversion of stormwater led to short flow paths and rapid storm response. Although contaminant levels have not increased due to urbanization, the springs may be at risk for future contamination. Short flow paths may reduce flushing, which means that the system will not cleanse itself if contamination occurs.     

Hydrogeochemical responses to rainfall inputs in a small rainforest basin: Rio de Janeiro,Brazil

This work provides basic information about hydrogeochemical contributions to different pathways of water in a small tropical rainforest catchment (3.5 km²) in Rio de Janeiro, Brazil. Precipitation and discharge measurements were conducted at the basin outlet, and at five other stream sites that were selected according to their hydrological behaviour and lithology. Precipitation and streamflow samples were collected weekly, over seven months, and continuously during one storm event. These streamflow samples were analyzed for Ca²⁺, Mg²⁺ Na⁺, K⁺ and SiO₂. Precipitation, throughfall and topsoil water samples were also collected after various storm events, over six months, within a small sub-catchment and were analysed for Ca²⁺, Mg²⁺, K⁺, Na⁺ and pH. Results from this research showed that rainfall was acid, with low cation content. Throughfall was neutral and cations enriched. Analysis of topsoil water indicated that litter was an important source of Ca²⁺ and K⁺ by means of saturation overland flow. In relation to throughfall, streamflow output was characterized by lower concentrations of K⁺, Ca²⁺, and Mg²⁺. Biotite gneiss weathering was the main source of Mg2+ to streamflow. During stormflow periods SiO₂ and Na⁺ concentrations decreased due to Hortonian overland flow contributions to the stream channel. The increasing concentrations of Ca²⁺ and K⁺ were due to litter leaching, especially in the zones producing saturation overland flow. Streamflow hydrogeochemistry was not only a product of weathering processes, but also of biotic processes.     

Quantification of karst aquifer discharge components during storm events through end-member mixing analysis using natural chemistry and stable isotopes as tracers

Karst aquifer components that contribute to the discharge of a water supply well in the Classical Karst (Kras) region (Italy/Slovenia) were quantitatively estimated during storm events. Results show that water released from storage within the epikarst may comprise as much as two-thirds of conduit flow in a karst aquifer following rainfall. Principal components analysis (PCA) and end-member mixing analysis (EMMA) were performed using major ion chemistry and the stable isotopes of water (δ¹⁸O, δ²H) and of dissolved inorganic carbon (δ¹³C_DIC) to estimate mixing proportions among three sources: (1) allogenic river recharge, (2) autogenic recharge, and (3) an anthropogenic component stored within the epikarst. The sinking river most influences the chemical composition of the water-supply well under low-flow conditions; however, this proportion changes rapidly during recharge events. Autogenic recharge water, released from shallow storage in the epikarst, displaces the river water and is observed at the well within hours after the onset of precipitation. The autogenic recharge end member is the second largest component of the well chemistry, and its contribution increases with higher flow. An anthropogenic component derived from epikarstic storage also impacts the well under conditions of elevated hydraulic head, accounting for the majority of the chemical response at the well during the wettest conditions.