Lithophile elements in Huronian low-Ti continental tholeiites from Canada, and evolution of the Precambrian mantle

Huronian basalts from central Ontario, Canada, dated at about 2450 Ma and associated with an early rifting episode, are classified as siliceous, low-TiNb tholeiites. They display strong enrichment in large-ion lithophile (LILE) and light rare earth (LREE) elements compared to modern oceanic lavas. The tectonic setting and geochemistry resemble Mesozoic rift-related low-Ti flood basalts, including the Ferrar Group of Antarctica, and the Parana and equivalent Etendeka volcanics of south Brazil and Namibia, respectively. High LILE/LREE ratios are also similar to subduction-related island arc tholeiites, and it is suggested that enrichment of the Huronian lithospheric mantle source occurred through ancient subduction of crustal material, probably during formation and consolidation of the Archean continental crust.Melting models suggest that Huronian subcontinental mantle source compositions, derived from least contaminated, aphyric, mafic end-members, had already undergone a complex evolution, including withdrawal of Archean basalts and hydrous enrichment in incompatible components. Despite several subsequent melting episodes and a second, probably magmatic, enrichment event, however, many aspects of the Huronian source signature were preserved, and appeared in later basaltic products of this mantle mass. Keweenawan volcanics, for example, dated at about 1100 Ma, preserve low P, Zr, Ti and HREE abundances.     

The subcontinental versus suboceanic debate,I Lead-neodymium-strontium isotopes in primary alkali basalts from a shield area the Ahaggar volcanic suite

Pb, Nd and Sr isotopic compositions have been determined in lherzolite-xenolith-bearing alkali-basalts from the center of the African shield. The present data are very similar to those reported for ocean-island basalts and do not support the hypothesis of different mantle sources for alkali-basalts from continental and oceanic areas. From these observations and on the basis of data obtained for xenolith in kimberlite and for tholeiitic continental basalts one may infer the following terrestrial mantle structure: whereas oceanic tholeiites would originate in upper oceanic mantle, oceanic and continental alkali basalts would come from the lower mantle and tholeiitic continental basalts from the continental lithosphere.     

Internal stratigraphic relationships in the Etendeka group in the Huab Basin, NW Namibia: understanding the onset of flood volcanism

The Etendeka Igneous Province in NW Namibia forms the eastern most extent of the Paraná–Etendeka Flood Basalt Province and, despite only covering about 5% of the Paraná–Etendeka, has been the focus of much interest, due to its extremely well exposed nature. The Huab Basin in NW Namibia forms the focus of this study, and formed a connected basin with the Paraná throughout Karoo times (late Palaeozoic) into the Lower Cretaceous. It contains a condensed section of the Karoo deposits, which indicate early periods of extension, and Lower Cretaceous aeolian and volcanic Etendeka deposits, which have their correlatives in the Paraná. In the Huab Basin, the volcanic rocks of the Etendeka Group consists of the Awahab and Tafelberg Formations, which are separated by a disconformity. Detailed examination of the Awahab Formation reveals an additional disconformity, which separates olivine-phyric basalts (Tafelkop-type) from basalt/basaltic andesites (Tafelberg-type) marking out a shield volcanic feature which is concentrated in an area to the SE of the Huab River near to the Doros igneous centre. Early volcanism consisted of pahoehoe style flows of limited lateral extent, which spilled out onto aeolian sands of an active aeolian sand sea 133 million years ago. This sand sea is equivalent to the sands making up the Botucatu Formation in the Paraná basin. The early expression of flood volcanism was that of laterally discontinuous, limited volume, pahoehoe flows of Tafelkop-type geochemistry, which interleaved with the aeolian sands forming the Tafelkop–Interdune Member basalts. These basalts are on-lapped by more voluminous, laterally extensive, basalt/basaltic andesite flows indicating a step-up in the volume and rate of flood volcanism, leading to the preservation of the shield volcanic feature. These geochemically distinct basalts/basaltic andesites form the Tsuhasis Member, which are interbeded with the Goboboseb and Sprinkbok quartz latite flows higher in the section. The Tsuhasis Member basalts, which form the upper parts of the Awahab Formation, are of Tafelberg-type geochemistry, but are stratigraphically distinct from the Tafelberg lavas, which are found in the Tafelberg Formation above. Thus, the internal stratigraphy of the flood basalt province contains palaeo-volcanic features, such as shield volcanoes, and other disconformities and is not that of a simple layer-cake model. This complex internal architecture indicates that flood volcanism started sporadically, with low volume pahoehoe flows of limited lateral extent, before establishing the more common large volume flows typical of the main lava pile.     

The Karoo igneous province — A problem area for inferring tectonic setting from basalt geochemistry

Tholeiitic basalts and associated intrusives are the major component of the Karoo igneous province. They are of Mesozoic age and constitute one of the world's classic continental flood basalt (CFB) provinces. It has been argued that most Karoo basalts have not undergone significant contamination with continental crust and that their lithospheric mantle source areas were enriched in incompatible minor and trace elements during the Proterozoic. The only exceptions to this are late-stage MORB-like dolerites near the present-day continental margins which are considered to be of asthenospheric origin.When data for the “southern” Karoo basalts are plotted on many of the geochemical discriminant diagrams which have been used to infer tectonic setting, essentially all of them would be classified as calc-alkali basalts (CAB's) or low-K tholeiites. Virtually none of them plot in the compositional fields designated as characteristic of “within-plate” basalts. There is little likelihood that the compositions of the Karoo basalts can be controlled by active subduction at the time of their eruption and no convincing evidence that a “subduction component” has been added to the subcontinental lithospheric mantle under the entire area in which the basalts crop out. It must be concluded that the mantle source areas for CAB's and the southern Karoo basalts have marked similarities.In contrast, the data for “northern” Karoo basalts largely plot in the “within-plate” field on geochemical discriminant diagrams. Available data suggest that the source composition and/or the restite mineralogy and degree of partial melting are different for southern and northern Karoo basalts. There is no evidence for any difference in tectonic setting between the southern and northern Karoo basalts at the time they were erupted. This appears to be clear evidence that specific mantle source characteristics and/or magmatic processes can vary within a single CFB province to an extent that renders at least some geochemical discriminant diagrams most unreliable for classifying tectonic environment with respect to continental volcanic rocks.     

Age of Seychelles–India break-up

Many continental flood basalt provinces are spatially and temporally linked with continental break-up. Establishing the relative timing of the two events is a key step in determining their causal relationship. Here we investigate the example of the Deccan Traps and the separation of India and the Seychelles. Whilst there has been a growing consensus as to the age of the main phase of the Deccan emplacement (65.5 ± 1 Ma, chron 29r), the age of the rifting has remained unclear. We resolve this issue through detailed seafloor magnetic anomaly modeling (supported by wide-angle and reflection seismic results) of the north Seychelles and conjugate Laxmi Ridge/Gop Rift margins, and geochemistry and ⁴⁰Ar/³⁹Ar geochronology of rocks from the north Seychelles margin. We show that syn-rift volcanics offshore the Seychelles Islands in the form of seaward-dipping reflectors were most likely erupted during chron 28n, and the first organized seafloor spreading at the Carlsberg Ridge also initiated during this chron at 63.4 Ma. The severing of the Seychelles occurred by a south-eastward ridge propagation that was completed by the start of chron 27n (~ 62 Ma). A brief, pre-28r phase of seafloor spreading occurred in the Gop Rift, possibly as early as 31r–32n (~ 71 Ma). Initial extension at the margin therefore preceded or was contemporaneous with the Deccan emplacement, and separation of the Seychelles was achieved less than 3.5 Ma afterwards. This is the shortest time interval between flood basalt emplacement and break-up yet reported for any continental flood basalt-rifted margin pair. A contributing factor to the apparently short interval in the Deccan case may be that rifting occurred by a ridge jump into already thinned continental lithosphere. However, we conclude that external plate-boundary forces, rather than the impact of a mantle plume, were largely responsible for the rifting of the Seychelles from India.     

Plate-plume-accretion tectonics in Proterozoic terrain of northeastern Rajasthan, India: Evidence from mafic volcanic rocks of north Delhi fold belt

Abstract   The northern part of the Aravalli mountain belt of northwestern Indian shield is broadly composed of three Proterozoic volcano-sedimentary domains, i.e. the Bayana, the Alwar and the Khetri basins, comprising collectively the north Delhi fold belt. Major, trace and rare earth element concentrations of mafic volcanic rocks of the three basins exhibit considerable diversity. Bayana and Alwar volcanics are typical tholeiites showing close similarity with low Ti–continental flood basalts (CFB) with the difference that the former shows enriched and the latter flat incompatible trace element and rare earth element (REE) patterns. However, the Khetri volcanics exhibit a transitional composition between tholeiite and calc-alkaline basalts. It appears that the melts of Bayana and Alwar tholeiites were generated by partial melting of a common source within the spinel stability field possibly in the presence of mantle plume. During ascent to the surface the Bayana tholeiites suffered crustal contamination but the Alwar tholeiites erupted unaffected. Geochemically, the Khetri volcanics are arc-like basalts which were generated in a segment of mantle overlying a Proterozoic subduction zone. It is suggested that at about 1800 Ma the continental lithosphere in northeastern Rajasthan stretched, attenuated and fractured in response to a rising plume. The produced rifts have undergone variable degrees of crustal extension. The extension and attenuation of the crust facilitated shallowing of the asthenosphere which suffered variable degree of melting to produce tholeiitic melts – different batches of which underwent different degrees of lithospheric contamination depending upon the thickness of the crust in different rifted basins. The occurrence of subduction-related basaltic rocks of Khetri Belt suggests that a basin on the western margin of the craton developed into a mature oceanic basin.     

Trace element geochemistry of some continental tholeiites

Continental tholeiites from four regions (Late Cretaceous to Early Eocene Deccan Trap lavas of central India, Early Mesozoic tholeiites from the Atlantic margins of Northwest Africa-Morocco, and northeastern North America-Nova Scotia, Canada and Precambrian Coppermine River basalts from Northwest Territories, Canada) differ from MORB by higher concentrations of K, Rb, Ba and Th and to a lesser degree light REE. Their chondrite-normalized trace element patterns show negative Nb anomalies. The distribution and variation of trace elements indicate that the rocks from all the areas studied were affected by interaction with the continental crust. It is suggested that continental tholeiites have been generated from a similar source as oceanic tholeiites and many of their geochemical differences are related to crustal contamination.     

Deccan plume,lithosphere rifting,and volcanism in Kutch,India

Kutch (northwest India) experienced lithospheric thinning due to rifting and tholeiitic and alkalic volcanism related to the Deccan Traps K/T boundary event. Alkalic lavas, containing mantle xenoliths, form plug-like bodies that are aligned along broadly east–west rift faults. The mantle xenoliths are dominantly spinel wehrlite with fewer spinel lherzolite. Wehrlites are inferred to have formed by reaction between transient carbonatite melts and lherzolite forming the lithosphere. The alkalic lavas are primitive (Mg# = 64–72) relative to the tholeiites (Mg# = 38–54), and are enriched in incompatible trace elements. Isotope and trace element compositions of the tholeiites are similar to what are believed to be the crustally contaminated Deccan tholeiites from elsewhere in India. In terms of Hf, Nd, Sr, and Pb isotope ratios, all except two alkalic basalts plot in a tight cluster that largely overlap the Indian Ridge basalts and only slightly overlap the field of Reunion lavas. This suggests that the alkalic magmas came largely from the asthenosphere mixed with Reunion-like source that welled up beneath the rifted lithosphere. The two alkalic outliers have an affinity toward Group I kimberlites and may have come from an old enriched (metasomatized) asthenosphere. We present a new model for the metasomatism and rifting of the Kutch lithosphere, and magma generation from a CO₂-rich lherzolite mantle. In this model the earliest melts are carbonatite, which locally metasomatized the lithosphere. Further partial melting of CO₂-rich lherzolite at about 2–2.5 GPa from a mixed source of asthenosphere and Reunion-like plume material produced the alkalic melts. Such melts ascended along deep lithospheric rift faults, while devolatilizing and exploding their way up through the lithosphere. Tholeiites may have been generated from the main plume head further south of Kutch.     

Continental flood basalt magmatism contemporaneous with Deccan traps in the Mannar basin,offshore Sri Lanka

The Gulf of Mannar and adjoining Cauvery basin to the north between India and Sri Lanka are associated with a failed rift, which initiated during the late Jurassic to early Cretaceous as a precursor to the breakup of East Gondwana. Despite the occurrence of igneous rocks that can be noted in seismic profiles, offshore, and deep seated occurrence of those have lead only to the limited understanding of igneous activity in the Mannar basin. Rock cuttings recovered in the Barracuda exploratory well in the Mannar basin shows approximately 700 m thick basalt rock sequence interlayered with sediments at a depth of 3500–4200 m below mean sea level. Here, we analyzed samples recovered from the Barracuda well for major and trace element composition. Major and trace element data suggest that the basalts were crystallized from two different degrees of partial melts from a similar source. Chondrite normalized rare earth element (REE) patterns indicate that the basalts are similar to continental flood basalt, though they show a distinct Ba positive anomaly. Importantly, supported with previously available K–Ar data, we decipher that these basalts are contemporaneous with the Deccan traps. Rifting between Seychelles and India which had occurred at ~62 Ma approximately 3.5 Ma after the main Deccan eruption is synchronous with the Barracuda volcanism suggesting coeval rifting between Seychelles–India and India–Sri Lanka. Thus, our data suggest simultaneous rifting between Seychelles–India and India–Sri Lanka. Large plate reorganizations that took place during this time period in the Indian Ocean have likely caused consequent passive rifting in the Mannar basin.     

Origin of Deccan Trap lavas: evidence from combined trace element and Sr-, Nd- and Pb-isotope studies

Geochemical and isotope results are presented from a new study of the most southern basalts in the Deccan Trap, India. Three chemical formations are recognised, two of which can be correlated with the established stratigraphy in Mahabaleshwar and imply a regional southerly dip of 0.06° over a distance of 250 km. In detail Sr-isotope variations within the Ambenali and Mahabaleshwar Formations can be shown to reflect three distinct end-members which provide new constraints for petrogenetic models. Pb-isotope data for selected basalts exhibit a wide range with²⁰⁶Pb/²⁰⁴Pb= 16.87–22.45, and a linear correlation on a Pb—Pb diagram. The least contaminated Ambenali basalts plot within the Pb-array, and interaction with mantle lithosphere involves a shift to less radiogenic Pb whereas contamination with crust is characterised by more radiogenic Pb. Unlike the Karoo and Parana continental flood basalt provinces only four flow units within the southern Deccan appear to contain a significant contribution from mantle lithosphere. The Mahabaleshwar and Ambenali Formation basalts exhibit a striking negative Pb—Sr isotope trend which is presently regarded as one of the features of interaction with shallow level lithospheric mantle. It further suggests that basalts from the Walvis Ridge, Kerguelen and Ninetyeast ridge all remobilised such shallow level material, and that the Deccan basalts which were not affected by crustal contamination reflect interaction between asthenospheric material similar to T-type MORB, but related to the Reunion hotspot, and continental mantle lithosphere of the Indian plate.     

The Harrat Al-Birk basalts in southwest Saudi Arabia:characteristic alkali mafic magmatism related to Red Sea rifting

Harrat Al-Birk volcanics are products of the Red Sea rift in southwest Saudi Arabia that started in the Tertiary and reached its climax at ~ 5 Ma.This volcanic field is almost monotonous and is dominated by basalts that include mafic-ultramafic mantle xenoliths(gabbro,websterite,and garnet-clinopyroxenite).The present work presents the first detailed petrographic and geochemical notes about the basalts.They comprise vesicular basalt,porphyritic basalt,and flow-textured basalt,in addition to red and black scoria.Geochemically,the volcanic rock varieties of the Harrat Al-Birk are low- to medium-Ti,sodic-alkaline olivine basalts with an enriched oceanic island signature but extruded in a within-plate environment.There is evidence of formation by partial melting with a sort of crystal fractionation dominated by clinopyroxene and Fe-Ti oxides.The latter have abundant titanomagnetite and lesser ilmenite.There is a remarkable enrichment of light rare earth elements and depletion in Ba,Th and K,Ta,and Ti.The geochemical data in this work suggest Harrat Al-Birk basalts represent products of watersaturated melt that was silica undersaturated.This melt was brought to the surface through partial melting of asthenospheric upper mantle that produced enriched oceanic island basalts.Such partial melting is the result of subducted continental mantle lithosphere with considerable mantle metasomatism of subducted oceanic lithosphere that might contain hydrous phases in its peridotites.The fractional crystallization process was controlled by significant separation of clinopyroxene followed by amphiboles and Fe-Ti oxides,particularly ilmenite.Accordingly,the Harrat Al-Birk alkali basalts underwent crystal fractionation that is completely absent in the exotic mantle xenoliths(e.g.Nemeth et al.in The Pleistocene Jabal Akwa A1 Yamaniah maar/tuff ring-scoria cone complex as an analogy for future phreatomagmatic to magmatic explosive eruption scenarios in the Jizan Region,SW Saudi Arabia 2014).     

Mafic alkalic magmatism in central Kachchh,India: a monogenetic volcanic field in the northwestern Deccan Traps

Magmatism in Kachchh, in the northwestern Deccan continental flood basalt province, is represented not only by typical tholeiitic flows and dikes, but also plug-like bodies, in Mesozoic sandstone, of alkali basalt, basanite, melanephelinite and nephelinite, containing mantle nodules. They form the base of the local Deccan stratigraphy and their volcanological context was poorly understood. Based on new and published field, petrographic and geochemical data, we identify this suite as an eroded monogenetic volcanic field. The plugs are shallow-level intrusions (necks, sills, dikes, sheets, laccoliths); one of them is known to have fed a lava flow. We have found local peperites reflecting mingling between magmas and soft sediment, and the remains of a pyroclastic vent composed of non-bedded lapilli tuff breccia, injected by mafic alkalic dikes. The lapilli tuff matrix contains basaltic fragments, glass shards, and detrital quartz and microcline, with secondary zeolites, and there are abundant lithic blocks of mafic alkalic rocks. We interpret this deposit as a maar-diatreme, formed due to phreatomagmatic explosions and associated wall rock fragmentation and collapse. This is one of few known hydrovolcanic vents in the Deccan Traps. The central Kachchh monogenetic volcanic field has >30 individual structures exposed over an area of ∼1,800 km² and possibly many more if compositionally identical igneous intrusions in northern Kachchh are proven by future dating work to be contemporaneous. The central Kachchh monogenetic volcanic field implies low-degree mantle melting and limited, periodic magma supply. Regional directed extension was absent or at best insignificant during its formation, in contrast to the contemporaneous significant directed extension and vigorous mantle melting under the main area of the Deccan flood basalts. The central Kachchh field demonstrates regional-scale volcanological, compositional, and tectonic variability within flood basalt provinces, and adds the Deccan Traps to the list of such provinces containing monogenetic- and/or hydrovolcanism, namely the Karoo-Ferrar and Emeishan flood basalts, and plateau basalts in Saudi Arabia, Libya, and Patagonia.     

Tectonic setting of basic volcanic rocks determined using trace element analyses

Analyses for Ti, Zr, Y, Nb and Sr in over 200 basaltic rocks from different tectonic settings have been used to construct diagrams in which these settings can usually be identified. Basalts erupted within plates (ocean island and continental basalts) can be identified using a Ti-Zr-Y diagram, ocean-floor basalts, and low-potassium tholeiites and calc-alkali basalts from island arcs can be identified using a Ti-Zr diagram (for altered samples) and a Ti-Zr-Sr diagram (for fresh samples). Y/Nb is suggested as a parameter for indicating whether a basalt is of tholeiitic or alkalic nature. Analyses of dykes and pillow lavas from the Troodos Massif of Cyprus are plotted on these diagrams and appear to the tholeiitic ocean-floor rocks.     

Bundelkhand mafic dykes, Central Indian Shield: Implications for the role of sediment subduction in Proterozoic crustal evolution

Abstract The Archean to Paleo–Proterozoic Bundelkhand massif basement of the central Indian shield has been dissected by numerous mafic dykes of Proterozoic age. These dykes are low‐Ti tholeiites, ranging in composition from subalkaline basalt through basaltic‐andesite to dacite. They are enriched in light rare earth elements (LREE), large ion lithophile elements (LILE) and depleted in high field strength elements (HFSE: Nb, P and Ti). Negative Sr anomaly is conspicuous. Nb/La ratios of the dykes are much lower compared with the primitive mantle, not much different from the average crustal values, but quite similar to those of continental and subduction related basaltic rocks. Bulk contamination of the mantle derived magma by crustal material is inadequate to explain the observed geochemical characteristics; instead contamination of the mantle/lithospheric source(s) via subduction of sediment is a better proposition. Thus, in addition to generating juvenile crust along the former island arcs, subduction processes appear to have influence on the development of enriched mantle/lithospheric source(s). The Bundelkhand massif basement is inferred to represent subduction related juvenile crust, that experienced lithospheric extension and rifting possibly in response to mantle plume activities. The latter probably supplied the required heat, material (fluids) and extensional environment to trigger melting in the refractory lithospheric source(s) and emplacement of the mafic dykes. Proterozoic mafic magmatic rocks from Bundelkhand, Aravalli, Singhbhum and Bastar regions of the Indian shield and those from the Garhwal region of the Lesser Himalaya display remarkably similar enriched incompatible trace elements characteristics, although limited chemical variations are observed in all these rocks. This may indicate the existence of a large magmatic province, different parts of which might have experienced similar petrogenetic processes and were probably derived from mantle/lithospheric source(s) with similar trace element characteristics. The minor, less enriched to depleted components of the Jharol Group of the Aravalli terrane and those from the Singhbhum terrane may represent protracted phases of rifting, that probably caused thinning and mobilization of the lithosphere, facilitating the eruption/emplacement of the asthenospheric melts (with N‐ to T‐types mid‐oceanic ridge basalts signatures) and deposition of deep water facies sediments in the younger developing oceanic basins. In contrast, Bundelkhand region did not experience such protracted rifting, although dyke swarms were emplaced and shallow water Bijawar Group and Vindhyan Supergroup sediments were deposited in continental rift basins. All these discrete Proterozoic terranes appear to have experienced similar petrogenetic processes, tectonomagmatic and possibly temporal evolution involving subduction processes, influencing the lithospheric source characteristics, followed by probably mantle plume induced ensialic rifting through to the development of oceanic basins in the Indian shield regions and their extension in the Lesser Himalaya.     

Platinum-group element geochemistry of Cenozoic basalts from the North China Craton: Implications for mantle heterogeneity

Forty-two Cenozoic(mostly Miocene) basalt samples from Jining, Chifeng, Fansi, Xiyang, and Zuoquan areas of the North China Craton(the NCC basalts hereafter) were analyzed for platinum-group elements(PGE, including Os, Ir, Ru, Rh, Pt, and Pd). Most of them are alkaline basalts and tholeiites and all of them display little crustal contamination. The total PGE contents of the NCC basalts vary from 0.1 to 0.9 ppb, much lower than those of the primitive mantle values of 23.5 ppb. Primitive mantle-normalized PGE patterns of these basalts define positive slopes and Pd/Ir ratios vary from 1.2 to 25. In terms of both PGE contents and Pd/Ir ratios, they are quite similar to the mid-ocean ridge basalts. There are no obvious negative correlations between PGE vs. Mg O, Ni, and Cu in the NCC basalts, indicating that fractional crystallization of olivine, pyroxene, and/or sulfides during magmatic process cannot be the controlling factor for the observed PGE variation. The observed Pd/Ir variations of the NCC basalts require involvement of non-chondritic heterogeneous mantle sources. Based on Sr-Nd-Pb-Hf isotopic systematics and incompatible-element signatures, a mixing of partial melts from both asthenospheric peridotites and enclosed mantle eclogites at the top of asthenosphere was proposed for the origin of these NCC basalts. The lenses of eclogites are derived from upwelling of recycled continental crust during the westward subduction of the Pacific plate from the ~600 km discontinuity zone. The PGE geochemistry of these basalts provides independent evidence to support this conclusion and the observed Pd/Ir variations may reflect variations in proportions of tapped peridotitic and eclogitic melts.     

Sr isotopic composition of Afar volcanics and its implication for mantle evolution

Investigations of Rb-Sr systematics of basalts from the Afar depression (Ethiopia) indicate the presence of a heterogeneous mantle source region. The Sr isotopic compositions of the basalts from the Afar axial and transverse ranges identify source regions which are enriched in LIL elements and radiogenic Sr (axial ranges) and others which are relatively depleted (transverse ranges). Sr isotopic composition of basalts from the Red Sea, Gulf of Aden and Gulf of Tadjoura, which range from 0.70300 to 0.70340 are also reported and compared with the more radiogenic Afar region, which is characterized by⁸⁷Sr/⁸⁶Sr ranging from 0.70328 to 0.70410.Available geochemical and isotopic data suggest that a relation exists between magma composition and the advancement of the rifting process through progressive lithosphere attenuation leading to continental break-up. However, the petrogenetic process is not simple and probably implies a vertically zoned mantle beneath the Afar region. Sr isotopic evidence suggests that the vertically zoned mantle is more radiogenic and enriched in LIL elements in its upper part.     

Compositionally diverse magmas erupted close together in space and time within a Karoo flood basalt crater complex

Geochemical data and mapping from a Karoo flood basalt crater complex reveals new information about the ascent and eruption of magma batches during the earliest phases of flood basalt volcanism. Flood basalt eruptions at Sterkspruit, South Africa began with emplacement of thin lava flows before abruptly switching to explosive phreatomagmatic and magmatic activity that formed a nest of craters, spatter and tuff rings and cones that collectively comprise a crater complex >40 km² filled by 9–18 km³ of volcaniclastic debris. Rising magma flux rates combined with reduced access of magma to external water led to effusion of thick Karoo flood basalts, burying the crater-complex beneath the >1.5 km-thick Lesotho lava pile. Geochemical data is consistent with flood basalt effusion from local dikes, and some lava flows likely shared or re-occupied vent sites active during explosive eruptions at Sterkspruit. Flood basalt magmas involved in Sterkspruit eruptions were chemically heterogenous. This study documents the rapid (perhaps simultaneous) eruption of three chemically distinct basaltic magmas which cannot be simply related to one another from one vent site within the Sterkspruit crater complex. Stratigraphic and map relationships indicate that eruption of the same three magma types took place from closely spaced vents over a short time during formation of the bulk of the crater-complex. Two magma types recognized there have not been recognized in the Karoo province before. The variable composition of flood basalts at Sterkspruit argues that magma batches in flood basalt fields may be small (0.5–1 km³) and not simply related to one another. This implies in turn that heterogeneities in the magma source region may be close to each other in time and space, and that eruptions of chemically distinct magmas may take place over short intervals of space and time without significant hybridisation in flood basalt fields.     

Determination of properties of Proterozoic continental flood basalts of western part from North Qilian Mountains

Proterozoic volcanic rocks of the western part from the North Qilian Mountains are the products of continental rift volcanism, belonging to continental flood basalts, the petrogeochemistry of which apears to suggest that they are derived from sub-lithospheric mantle plume sources, but that they also show evidence of continental lithosphere components involvement. Their formation is the consequences of plume-lithosphere interactions and is precursive to the opening of the North Qilian Early-Paleozoic ocean basin.     

Low- and high-Ti ophiolites in Northern Pindos: Petrological and geological constraints

Ophiolites with different magmatic characteristics are closely associated in space with one another in northern Pindos. Some have affinities with ocean-floor magmas (Group I), and others represent melts which are frequently strongly depleted in «incompatible» elements (Group II). Group I is composed of cumulates, dolerites and lavas, whereas Group II occurs mainly as pillows and dykes, and postdates Group I. The two groups have different geochemical, mineralogical and petrographic features. They exhibit different Ti, Cr, Ni, Y, Zr, P, Si and Mg contents, and clinopyroxenes and spinels of Group I have higher Ti/Al and Ti/Mn ratios, and lower Cr/(Cr + Al) values respectively than those of Group II. Many rocks of Group II are chemically similar to boninites and associated rocks as well as to low-Ti basalts from other areas and ophiolitic complexes. It is concluded that geochemical and mineralogical data alone do not allow a definitive answer about the original tectonic setting of the investigated rocks, although a genesis above a subduction zone seems to be plausible hypothesis.     

Rifting of a tethyan continent — Rare earth evidence of an accreting plate margin

Rifting of a continent in the Tethys ocean was associated with two forms of volcanism initially identified by Hynes (1972). An early light rare earth element (LREE)-enriched magma accompanied rifting of the continental crust and subsidence of a marginal carbonate platform. The early basalts are high K₂O, nepheline-normative basalts, associated with silic igneous rocks, and carrying olivine pseudomorphs. A later or contemporaneous LREE-depleted magma is associated with the active formation of sea floor in a marginal embryo ocean basin. The ophiolite basalts are low K₂O, hypersthene-normative basalts containing feldspar laths and pyroxene subhedra. Similar transitions or changes in extrusives are evident in present-day embryo oceans and at the edges of rifted continental margins which surrounded larger ocean basins. Genesis of the tholeiites can be related to 10–30% partial fusion of foliated mantle lherzolites a sample of which adheres to the base of the Othris ophiolite. The alkalic basalts require either a fractionation model, or a more LREE-enriched source perhaps similar to the Ataq lherzolites, since the “tholeiite source lherzolite” can only produce alkalic basalts at low degrees of melting.