An Environmental Threshold of Soil Test P and Degree of P Saturation of Brazilian Oxisols

To develop P management guidelines for poultry litter application in Oxisols of Brazil, the relationship between water soluble P (WSP), soil test P (STP), and degree of P saturation (DPS) needs to be established. The study examined this relationship in Oxisols of Brazil receiving poultry litter. Soils were analyzed for Mehlich‐1 P (M1‐P), WSP, P fractions, P sorption index (PSI), and P saturation based on Mehlich‐1 extractable P, Al, Fe (DPS_M1), and PSI (DPS_PSI). Surface water bodies in the catchment area were examined for inorganic and total P. All the surface water bodies in the catchment area of the sampled plots were highly enriched in inorganic and organic P. Enrichment of soil P fractions following poultry litter application followed the order HCl‐bound > NaOH‐bound > NaHCO₃‐bound fraction. M1‐P was correlated to labile (NaHCO₃‐P_i), and stable P pools (NaOH‐P and HCl‐P) and reflected the cumulative P accumulation in these soils. P saturation indices increased with cumulative P addition and increasing M1‐P. WSP increased with increasing DPS and a change point was noticed at 23% DPS_PSI (equivalent to DPS_M1 of 16.5%) corresponding to M1‐P of 44.5 mg P kg^?1, which could be regarded as threshold for P loss in these soils.     

Stability of P Saturated Water Treatment Residuals under Different Levels of Dissolved Oxygen

Water treatment residuals (WTRs) are effective phosphorus (P) immobilizers that have been used in constructed wetlands (CWs). In CWs, dissolved oxygen (DO) levels vary from location to location and fluctuate over time. Therefore, this work accessed the stability of P saturated ferric and alum water treatment residuals (FARs) under low (<1 mg/L), medium (2–4 mg/L), and high (5–8 mg/L) DO levels. In the experiments, which had a 40‐day duration, three stages of P release from the P saturated FARs were observed: an initial rapid P desorption stage, followed by a P re‐adsorption stage, and a P desorption balance stage. The strongest bonding between P and FARs occurred at the low DO level. A limited amount of Fe and Al was released from the P saturated FARs. Interestingly, the P in the FARs tended to transform from the Al bound P to the Fe bound P, and this transformation was stronger at lower DO levels. However, no more than 1.12% of the total P in the P saturated FARs was desorbed under any of these DO levels. Therefore, FARs can be considered as a safe P adsorption medium for CWs.     

Comparison of the response of the Landsat 7 Enhanced Thematic Mapper Plus and the Earth Observing-1 Advanced Land Imager over active lava flows

Using near simultaneously acquired Landsat 7 Enhanced Thematic Mapper Plus (ETM+) and Earth Observing-1 Advanced Land Imager (ALI) data we assess the relative radiant responses over active lava flows from the Mt. Etna July/August 2001 flank eruption. By assessing the extent of saturation between the two instruments and using the dual-band method of extracting sub pixel thermal information, we show that the ALI represents an improvement over the ETM+ in the present ability to assess temperatures of hot active lava flows for a number of reasons. (1) The extra spectral channels provided by ALI compliment the current SWIR channels on ETM+ by providing a greater number of paired channel combinations for input into the dual-band method. Thus, dual-band temperature solutions can be determined for a greater range of lava flow types than previously possible using the two paired channel combinations available with the ETM+. (2) The ALI instrument is less susceptible than ETM+ to saturation within the SWIR, especially when using channels 5, 5p and 4p at wavelengths of 1.65, 1.25 and 0.87 μm respectively. (3) The greater radiometric sensitivity of the ALI 12 bit electronics coupled with a significantly higher signal to noise ratio aid in obtaining successful dual-band solutions.     

Volcanic-sedimentary features in the Serra Geral Fm., Paraná Basin,southern Brazil: Examples of dynamic lava-sediment interactions in an arid setting

The formation of volcanic–sedimentary interaction features in extreme arid environments is not a commonly described process. Specifically the occurrence of dynamically mixed sediments and juvenile igneous clasts as peperites, for water has been considered one major important factor in the processes of magma dismantling and mingling with unconsolidated sediment to form such deposits. The study area, located in south Brazil, shows a sequence of lava flows and intertrapic sandstone layers from the Paraná Basin, associated with the formation of clastic dykes, flow striations, peperite and ‘peperite-like’ breccias. Four processes are suggested for the genesis of the peperites: (a) fragmentation of the flow front and base; (b) sand injection; (c) dune collapse; (d) magma cascade downhill. The continued flow of a lava, while its outer crust is already cooling, causes it to break, especially in the front and base, fragments falling in the sand and getting mixed with it, generating the flow front ‘peperite-like’ breccia. The weight of the lava flow associated to shear stress at the base cause sand to be injected inwards the flow, forming injection clastic dykes in the cooled parts and injection peperite in the more plastic portions. The lava flow may partially erode the dune, causing the dune to collapse and forming the collapse ‘peperite-like’ breccia. The shear stress at the base of a flowing lava striates the unconsolidated sand, forming the flow striations. The sand that migrates over a cooled, jointed lava flow may get caught in the cavities and joints, forming the filling clastic dykes. These deposits are analogous to those found in the Etendeka, NW Namibia, and show that sediment–lava interactions in arid settings are widespread throughout the Paraná-Etendeka province during the onset of flood volcanism.     

Mass Balance Study on Phosphorus Removal in Constructed Wetland Microcosms Treating Polluted River Water

A number of studies have showed that the mass removal rates of phosphorus (P) in different constructed wetlands (CWs) varied significantly, and it is essential to quantify the contributions of major P removal processes in order to improve system design. The objective of this study was to investigate the effects of vegetation, hydraulic retention time (HRT), and water temperature on P removal from polluted river water and to quantify the contributions of different P removal pathways in surface CWs. Results showed that the average total P removal rates ranged between 2.69 and 20.84 mg/(m² day) in different seasons and were influenced significantly by vegetation, HRT, and water temperature. According to the mass balance approach, plant uptake removed 4.81–22.33% of P input, while media storage contributed 36.16–49.66%. Other P removal processes such as microbiota uptake removed around 0.26–4.13%. Media storage and plant uptake were identified as the main P removal processes in surface CWs treating polluted river water. This illustrated the importance of selecting media and plants in CWs for future practical application.     

Seasonal variations in the cycling of aluminium,cadmium and manganese in a Scottish sea loch: biogeochemical processes involving suspended particles

Concentrations of Al, Cd and Mn were determined in water and particles collected from water bottles over one year during 19 surveys of a silled fjord. Nutrient and hydrographic data were also collected. Particle fluxes were determined at one site using a sediment trap array. Concentrations of dissolved Al showed the strongest (negative) relationship to salinity (r=0.91). This correlation decreased with the onset of the diatom bloom and was insignificant immediately post bloom. Removal of dissolved Al was coincident with an increase in particulate Al concentrations. The degree of removal could be predicted from previously reported Al/Si uptake ratios. Concentrations of leachable P in particulate material from the sediment traps increase at the onset of the bloom and decrease coincident with rapid regeneration as the bloom crashed. Particulate leachable Cd showed a lag in apparent uptake and regeneration relative to particulate leachable P. A substantial amount (ca. 53%) of the annual particle flux of Mn to the deepest trap is material recycled at the sediment surface and is not accumulated in the bottom sediment. Dissolved and particulate Mn levels in the loch have a strong seasonal pattern with low values prior to the spring phytoplankton bloom and increased values after the bloom crash. Maximum concentrations were observed in late autumn. Levels decreased to near pre-bloom values early the following year. This suggests bacterial decay of deposited organic carbon associated with the spring bloom-maintained suboxic conditions at or near the seawater-sediment interface throughout the majority of the year. After exhaustion of this organic matter pool recycling ceased for a brief (2–3 months) winter period.     

五大连池火山群最新喷发时间的热释光(TL)年代学证据

首次利用ＴＬ测年技术,测定了五大连池火山群中两座最新喷发的火山熔岩中的烘烤捕虏体的年代。测定结果（（２６４±１９）ａＢ．Ｐ．,（２７３±１９）ａＢ．Ｐ．）在误差范围内与喷发的历史记载（１７１９～１７２１年）一致,表明这两座火山是同期喷发的产物,同时也表明利用ＴＬ测年技术能比较准确地测定年轻火山活动的年代,它为恢复火山最新喷发历史的研究提供了一种比较可靠的年代测定途径     

Volcanic sands of Iceland ‐ Diverse origins of aeolian sand deposits revealed at Dyngjusandur and Lambahraun

The origin, formation and evolution of volcanic sands are less well known than the formation of the much more common quartz‐rich sand sheets. Combining active volcanism and a cold climate, Iceland is covered for about 21% of its surface by sandy areas. The sands were analyzed in detail at two sites and results reveal their diverse origins. The first site is Dyngjusandur, located north of Vatnajökull, and the second site is the Lambahraun area, located south of Langjökull. At both sites, the sand origin is determined from field observations (wind directions from ventifacts), chemical and mineralogical analyses of rocks and sands. At Dyngjusandur, the sand is dominated by glass grains, a situation typical of sand plains in Iceland. Hyaloclastite ridges presently buried beneath Vatnajökull are the dominant source of the sand, and only large size plagioclase crystals (0.5 cm) in sands seem to be derived from the lava flows. Hyaloclastite ridges were crushed by glaciers and mechanically eroded sediments were washed out by melt‐water onto flood plains. The sand chemical composition is spatially homogeneous and similar to the average composition of neighboring sub‐aerial lava flows, reflecting efficient mixing of distinct sources below the glacier. The presence of sand north of Dyngjujökull can be taken as a way to explore the average chemical composition of non‐exposed volcanic material beneath the glacier. In the case of Lambahraun, prevailing winds indicate several potential sources of sand at the north of the sand sheet. Comparison of chemical and mineralogical analyses of sands and rock samples helped to refine the exact origin. In contrast with the first site, the sand is dominated by crystals and is chemically consistent with a mixture of material derived from the lava flows of Eldborgir and Skersli shield volcanoes. Analysis of the contact between the lava flows and the glacier reveals that basaltic sand grains formed as the result of recent advances of the glacier abrading the rocks. The direct interaction of glacial and fluvio‐glacial activity with basaltic plains appears to be necessary to produce a large amount of sands in a relatively short period of time (<4000 years). This site appears to be an excellent natural laboratory for further studies concerning the sand evolution and physical sorting processes in basaltic material, which have important implications for understanding aeolian processes on Mars. Copyright © 2011 John Wiley & Sons, Ltd.     

Regional scale nutrient modelling: exports to the Great Barrier Reef World Heritage Area

Clearing of native vegetation and replacement with cropping and grazing systems has increased nutrient exports to the Great Barrier Reef (GBR) to a level many times the natural rate. We present a technique for modelling nutrient transport, based on material budgets of river systems, and use it to identify the patterns and sources of nutrients exported. The outputs of the model can then be used to help prioritise catchment areas and land uses for management and assess various management options. Hillslope erosion is the largest source of particulate nutrients because of its dominance as a sediment source and the higher nutrient concentrations on surface soils. Dissolved nutrient fractions contribute 30% of total nitrogen and 15% of total phosphorus inputs. Spatial patterns show the elevated dissolved inorganic nitrogen export in the wetter catchments, and the dominance of particulate N and P from soil erosion in coastal areas. This study has identified catchments with high levels of contribution to exports and targeting these should be a priority.     

Spectral and petrologic analyses of basaltic sands in Ka'u Desert (Hawaii) – implications for the dark dunes on Mars

Dark aeolian deposits on Mars are thought to consist of volcanic materials due to their mineral assemblages, which are common to basalts. However, the sediment source is still debated. Basaltic dunes on Earth are promising analogs for providing further insights into the assumed basaltic sand dunes on Mars. In our study we characterize basaltic dunes from the Ka'u Desert in Hawaii using optical microscopes, electron microprobe, and spectral analyses. We compare the spectra of terrestrial and Martian dune sands to determine possible origins of the Martian dark sediments. Our results show that the terrestrial sands consist primarily of medium to coarse sand‐sized volcanic glass and rock fragments as well as olivine, pyroxene, and plagioclase minerals. Grain shapes range from angular to subrounded. The sample composition indicates that the material was derived from phreatomagmatic eruptions partially with additional proportions of rock fragments from local lava flows. Grain shape and size indicate the materials were transported by aeolian processes rather than by fluvial processes. Spectral analyses reveal an initial hydration of all terrestrial samples. A spectral mineralogical correlation between the terrestrial and Martian aeolian sands shows a similarity consistent with an origin from volcanic ash and lava. We suggest that the Martian deposits may contain similar abundances of volcanic glass, which has not yet been distinguished in Martian spectral data. Copyright © 2011 John Wiley & Sons, Ltd.     

DNAPL Flow Behavior in a Contaminated Aquifer: Evaluation of Field Data

A pool of dense nonaqueous phase liquid (DNAPI.) containing TCE and other chlorinated solvents has been removed from the subsurface at Hill Air Force Base, Uthah. as part of an interim remedial action. The removal of the DNAPI. pool means that future off-site migration of dissolved contaminants in the ground water is minimized, and costs for final remedial actions are reduced. A pump-and-treat system recovered more than 23.000) gallons of DNAPI. and one million gallons of contaminated ground water from the aquifer. The efficiency of this remedial action was evaluated on the basis of extensive field and laboratory data. The behavior of DNAPI. flow in the aquifer sands was characterized by collecting core samples from two borings in the DNAPL pool and measuring relative permeabilities and DMAPI. saturation. Core Hooding results show that approximately one-third of the DNAPI. originally in the pool is not recovered by water displacement, but remains as a residual saturation held in place by capillary pressure. However, subsequent Hooding with two pore volumes of surfactant solution reduced the residual DNAPI. saturation in the sand by one order of magnitude. Analytical and numerical models for the DNAPI flow behavior at the site were developed. This is the first time that such models have been developed and applied to an actual DNAPI. pumping lest conducted in the field. Because measured permeabilities and residual saturations were used lo calibrate the models. the model predictions could be used lo provide valuable insights into the controlling mechanisms for DNAPL recovery. The data collection and modeling procedures outlined in this paper can be used lo enhance the efficiency and minimize the cost 10 clean up this and other DNAPI.-contaminated sites.     

The distribution of solute processes on an acid hillslope and the delivery of solutes to a stream: II. Exchangeable Al3+

In order to identify the distribution of aluminium (Al) within an acid hillslope and its release to a stream, the spatial distribution of acid ammonium oxalate extractable Al (Al_o) and exchangeable Al³⁺ have been investigated on a podzolized hillslope in Bicknoller Combe, Somerset, UK. The eluviated Al from topsoils is mainly deposited in the lower soil horizons forming podzolic B horizons, but some Al flows downslope carried by lateral throughflow. Al oxides may provide the main source of exchangeable Al³⁺ on the study slope due to high soil acidity. Examination of the spatial distribution of exchangeable Al³⁺ suggests that the slope hollow, where active convergent throughflow occurs, and the saturation wedge at the base of the slope are the main delivery routes of dissolved Al³⁺ to the stream. Divalent base cations (Ca²⁺ and Mg²⁺), supplied from atmospheric input and organic decomposition and carried by throughflow, exchange Al³⁺ via cation exchange reactions under high water content. Laterally illuviated Al oxides in the lower hollow adjacent to the saturation wedge probably provide a pool for continuous delivery of Al either as soluble or complexed forms to the stream via the saturated wedge. Copyright © 1999 John Wiley & Sons, Ltd.     

Three-phase measurements of oil and gas trapping in sand packs

We measure the trapped saturations of oil and gas as a function of initial saturation in water-wet sand packs. We start with a water-saturated column and inject octane (oil), while water and oil are produced from the bottom. Once water production has ceased, air (gas) then enters from the top, allowing oil and gas to drain under gravity for different times. Finally water is then injected from the bottom to trap both oil and gas. The columns are sliced and the fluids analyzed using gas chromatography. We find that for high initial gas saturations more gas can be trapped in the presence of oil than in a two-phase (gas/water) system. The residual gas saturation can be over 20% compared to 14% in two-phase flow [Al Mansoori SK, Iglauer S, Pentland CH, Bijeljic B, Blunt MJ. Measurements of non-wetting phase trapping applied to carbon dioxide storage. Energy Procedia 2009;1(1):3173–80]. This is unlike previous measurements on consolidated media, where the trapped gas saturation is either similar or lower to that reached in an equivalent two-phase experiment. For lower initial gas saturation, the amount of trapping follows the initial-residual trend seen in two-phase experiments. The amount of oil trapped is insensitive to initial gas saturation or the amount of gas that is trapped, again in contrast to measurements on consolidated media. More oil is trapped than would be predicted from an equivalent two-phase (oil/water) system, although the trapped saturation is never larger than the maximum reached in two-phase flow (around 11%) [Pentland CH, Al Mansoori SK, Iglauer S, Bijeljic B, Blunt MJ. Measurement of non-wetting phase trapping in sand packs. In: SPE 115697, proceedings of the SPE annual technical conference and exhibition, Denver, Colorado, USA; 21–24 September 2008]. These initially surprising results are explained in the context of oil layer stability and the competition between snap-off and piston-like advance. In two-phase systems, displacement is principally by cooperative piston-like advance with relatively little trapping, whereas in consolidated media snap-off is generally more significant. However, oil layer collapse events during three-phase waterflooding rapidly trap the oil which acts as a barrier to direct water/gas displacement, except by snap-off, leading to enhanced gas trapping.     

Enhanced attenuation of septic system phosphate in noncalcareous sediments

Review of phosphate behavior in four mature septic system plumes on similar textured sand has revealed a strong correlation between carbonate mineral content and phosphate concentrations. A plume on calcareous sand (Cambridge site, 27 wt % CaCO3 equiv.) has proximal zone PO4 concentrations (4.8 mg/L P average) that are about 75% of the septic tank effluent value, whereas three plumes on noncalcareous sand (Muskoka, L. Joseph, and Nobel sites, <1 wt % CaCO3 equiv.) have proximal zone phosphate concentrations (<0.1 mg/L P) that are consistently less than 2% of the effluent values. Phosphate attenuation at the noncalcareous sites appears to be an indirect result of the development of acidic conditions (site average pH 3.5 to 5.9) and elevated Al concentrations (up to 24 mg/L), which subsequently causes the precipitation of Al-P minerals such as variscite (AlPO4 x 2H2O). This is supported by scanning electron microscope analyses, which show the widespread occurrence of (Al+P)--rich secondary mineral coatings on sand grains below the infiltration beds. All of these septic systems are more than 10 years old, indicating that these attenuation reactions have substantial longevity. A field lysimeter experiment demonstrated that this reaction sequence can be readily incorporated into engineered waste water treatment systems. We feel this important P removal mechanism has not been adequately recognized, particularly for its potential significance in reducing P loading from septic systems in lakeshore environments.     

Dating lava flows of tropical volcanoes by means of spatial modeling of vegetation recovery

The age of past lava flows is crucial information for evaluating the hazards and risks posed by effusive volcanoes, but traditional dating methods are expensive and time‐consuming. This study proposes an alternative statistical dating method based on remote sensing observations of tropical volcanoes by exploiting the relationship between lava flow age and vegetation cover. First, the factors controlling vegetation density on lava flows, represented by the normalized difference vegetation index (NDVI), were investigated. These factors were then integrated into pixel‐based multi‐variable regression models of lava flow age to derive lava flow age maps. The method was tested at a pixel scale on three tropical African volcanoes with considerable recent effusive activity: Nyamuragira (Democratic Republic of Congo), Mt Cameroon (Cameroon) and Karthala (the Comoros). Due to different climatic and topographic conditions, the parameters of the spatial modeling are volcano‐specific. Validation suggests that the obtained statistical models are robust and can thus be applied for estimating the age of unmodified undated lava flow surfaces for these volcanoes. When the models are applied to fully vegetated lava flows, the results should be interpreted with caution due to the saturation of NDVI. In order to improve the accuracy of the models, when available, spatial data on temperature and precipitation should be included to directly represent climatic variation. Copyright © 2017 John Wiley & Sons, Ltd.     

Phosphorus removal from secondary effluents through integrated constructed treatment system

The treatment capacity of an integrated constructed treatment system (CTS) was explored which was designed to reduce phosphorus (P) from secondary effluents. The integrated CTS was combined with vertical-flow constructed wetland, floating bed and sand filter. The vertical wetland was filled from the bottom to the top with gravels, steel slag and peat. Vetiverzizanioides (L.) Nash was selected to grow in the vertical constructed wetland while Coixlacrymajobi L. was grown in floating bed. The results suggested that integrated CTS displayed excellent removal efficiency for chemical oxygen demand (COD), dissolved phosphorus (DP), and total phosphorus (TP). The average COD removal efficiency of the integrated CTS was 90.45% after 40 days of operation, the average DP and TP removal efficiencies of the integrated CTS were 97.43% and 96.40%, respectively. The integrated CTS has good potential in removing COD as well as P from secondary effluents.     

The influence of palaeoenvironment and lava flux on the emplacement of submarine, near-shore Late Permian basalt lavas, Sydney Basin (Australia)

Lava flux and a low palaeoslope were the critical factors in determining the development of different facies in the Late Permian Blow Hole flow, which comprises a series of shoshonitic basalt lavas and associated volcaniclastic detritus in the southern Sydney Basin of eastern Australia. The unit consists of a lower lobe and sheet facies, a middle tube and breccia facies, and an upper columnar-jointed facies. Close similarities in petrography and geochemistry between the basalt lavas from the three facies suggest similar viscosities at similar temperatures. Sedimentological and palaeontological evidence from the sedimentary units immediately below the Blow Hole flow suggests that the lower part of the volcanic unit was emplaced in a cold water, shallow submarine environment, but at least the top of the uppermost lava was subaerial with some palaeosol development. The lower lobe and sheet facies was emplaced on a low slope (<2°) in a lower to middle shoreface environment with water depths of 20–25 m. Lava may have transgressed from subaerial to subaqueous and was emplaced relatively passively with lava flux sufficiently high and uniform to form lobes and sheets rather than pillows. The middle unit probably originated from a subaerial vent and flowed into a shallow (10–15 m) submarine environment, and wave action probably interacted with the advancing lava front to form a lava delta. Lava flux was sufficiently high to produce well-developed, subcircular lava tubes, which lack evidence for thermal erosion. In some areas, lava ‘burrowed’ into the unconsolidated, water-saturated lava delta and sand pile to produce intrusive contacts. The upper columnar-jointed unit represents a ponded facies probably emplaced initially in water depths <5 m but whose top was subaerial.     

Laboratory and Numerical Investigations of Air Sparging Using MTBE as a Tracer

Air sparging experiments were conducted in a laboratory column to investigate air flow and mass transfer behavior in different types of sand at different air injection rates. Methyl tertiary butyl ether (MTBE) was applied as a tracer, and by measuring the volatilization and the mean air content during the experiments, the air flow pattern and its influence on mass transfer were assessed. The experimental results showed large differences among the sand types. In fine sand, the mean air content was high and the volatilization of MTBE was rapid with total recovery after a few hours. In coarse sand, the mean air content was low and the volatilization of MTBE was limited. The results indicate two different air flow distributions. In fine-grained materials, a uniform air distribution can be expected compared to coarse-grained materials where isolated air channels will limit the mass transfer. Afterwards, the experiments were simulated using the numerical multiphase flow code T2VOC, and the results compared to those obtained in the laboratory. The experiments with fine sand were simulated well, while for coarser sand types the volatilization was highly overestimated. The differences between model and laboratory results were mainly attributed to the nonuniformity of the air saturation and the neglection of kinetics in the mass transfer formulation.     

Carbon and nutrients transfer from primary producers to lake sediments – A stoichiometric approach

We aimed to demonstrate different input of organic and inorganic carbon, nitrogen and phosphorus from three main groups of primary producers (phytoplankton, charophytes and vascular submerged macrophytes) to respective lake sediments. Studies were carried out in one eutrophic and two mesotrophic lakes. Samples of sediments were taken from profundal and from littoral zones, the latter divided into such overgrown by charophytes and others covered by vascular submerged macrophytes. We applied a stoichiometric approach to illustrate variable functional carbon to nutrients relationships. Among profundal sediments, the lowest organic to inorganic carbon ratio was found in sediments from the eutrophic lake due to precipitation of calcium carbonate during algal blooms. Extremely low inorganic carbon input to profundal sediment of one of the mesotrophic lakes may be explained by low phytoplankton production but also by dissolution of once deposited calcium carbonates. Charophyte-dominated littoral sediments contained significantly more inorganic carbon than other littoral and profundal sediments. Comparison of stoichiometric ratios between plant standing crop and underlying littoral sediments showed significant enrichment of sediments in nitrogen manifested by reduction of organic carbon to total nitrogen ratio during plant decomposition taking place both in charophyte and in vascular plant stands. We also attempted to divide phosphorus pool in sediments into organic P and calcium-bound P present in charophyte stands and in profundal sediments of eutrophic lake. In the former, calcium-bound P was estimated at 17–19 % of the total P pool while in profundal sediments it amounted 42 % of the total P. This difference suggests that calcium carbonate settling during algal blooms in a eutrophic lake may be more effective in P trapping than calcite encrustations covering charophyte plants in littoral sites. In conclusions, we underline the need of considering often neglected inorganic fractions of carbon and phosphorus to get better insight into carbon and nutrient burial in lake sediments.     

Designing Iron‐Amended Biosand Filters for Decentralized Safe Drinking Water Provision

There are ongoing efforts to render conventional biosand filters (BSF) more efficient for safe drinking water provision. One promising option is to amend BSF with a reactive layer containing metallic iron (Fe⁰). The present communication presents some conceptual options for efficient Fe⁰‐amended BSF in its fourth generation. It is shown that a second fine‐sand layer should be placed downwards from the Fe⁰‐reactive layer to capture dissolved iron. This second fine‐sand layer could advantageously contain adsorbing materials (e.g. activated carbons, wooden charcoals). An approach for sizing the Fe⁰‐reactive layer is suggested based on 3 kg Fe⁰ per filter. Working with the same Fe⁰ load will ease comparison of results with different materials and the scaling up of household BSF to large scale community slow sand filters (SSF).