Supersaturation and evasion of CO2 and CH4 in surface waters at Mer Bleue peatland,Canada

Carbon dioxide (CO₂) and methane (CH₄) concentrations and evasion rates were measured in surface waters draining Mer Bleue peatland (Ontario, Canada) between spring and autumn 2005. All sites exhibit a consistent pattern of supersaturation throughout the year, which is broadly related to hydrological and temperature changes between spring snowmelt and autumn freezing. Both measurements and estimates of CO₂ and CH₄ evasion from open water to the atmosphere suggest that parts of the catchment (including beaver dams) are significant degassing hot spots. We present data showing how vertical gaseous carbon fluxes compare with lateral carbon fluxes and make an initial estimate of the importance to the overall carbon budget of CO₂ and CH₄ evasion to the atmosphere from water surfaces at Mer Bleue. Copyright © 2007 John Wiley & Sons, Ltd.     

Vertical changes of POC flux and indicators of early degradation of organic matter in the South China Sea

Tie-series sediment trap materials at different water depths and surface sediments in northern and central South China Sea (SCS) were analyzed for organic carbon, amino acids, amino sugars and carbohydrates. Results show that particulate organic carbon (POC) is mainly derived from marine plankton, only 1.4%–1.6% of primary production sinks into deep SCS water column and less than 0.22 % of primary production ultimately reaches the sediments. The ranineralization and dissolution of organic matter as well as the compositional alterations of organic matter mixtures may mainly take place in the upper few hundred meters of water column, deep carbonate (opal) lysocline zones, and interface layers between sediments and water column, rather than in mid-waters. The organic geochemical parameters such as (T ^aa +T ^sug )OC%, AA/AS, Gluam/Galam, Arom. AA/non-prot. AA, ASP/b-ALA, Glu/g-ABA decrease from living marine plankton (or planktonic shells), to settling particulate matter and to sediments suggesting that they appear to be gad early degraded indicators of organic matter. Project supported by the National Natural Science Foundation of China (Grant No. 49776297). Cruises financially supported by State Oceanic Administration and German Federal Ministry of Research and Technology.     

Variability of particulate (SS,POC) and dissolved (DOC,NO3) matter during storm events in the Alegria agricultural watershed

The temporal variability of suspended sediment, nitrates (NO₃) and dissolved (DOC) and particulate organic carbon concentrations was analysed in the Alegria agricultural watershed over a 2‐year period. Nine storm events were studied, including an exhaustive analysis of hydrometeorological conditions, quantification of fluxes, and concentration‐discharge hysteresis loop characterization. The overall aim was to study the variability in these components during storm events and determine the mechanisms (flow paths) affecting the trajectories, from the source to the stream. The forms, rotational patterns and trends of hysteretic loops were investigated, and relationships between hysteresis features and hydrological parameters were studied. The results revealed clear differences between particulate (suspended sediment, particulate organic carbon) and dissolved (DOC, NO₃) matter transport responses. Movement of the particulate matter was attributed to surface water, as reflected in clockwise hysteresis loops, whereas dissolved matter showed, in general, counterclockwise hysteresis loops, indicating a time delay in the arrival of solutes to the stream. This could be related to subsurface flow paths for DOC and a groundwater source for NO₃. Copyright © 2013 John Wiley & Sons, Ltd.     

Organic and inorganic matter in Louisiana coastal waters: Vermilion, Atchafalaya, Terrebonne, Barataria, and Mississippi regions

Chromophoric dissolved organic matter (CDOM) spectral absorption, dissolved organic carbon (DOC) concentration, and the particulate fraction of inorganic (PIM) and organic matter (POM) were measured in Louisiana coastal waters at Vermilion, Atchafalaya, Terrebonne, Barataria, and Mississippi River locations, in 2007-2008. The range of CDOM was 0.092 m⁻¹ at Barataria in June 2008 to 11.225 m⁻¹ at Mississippi in February 2008. An indicator of organic matter quality was predicted by the spectral slope of absorption coefficients from 350 to 412 nm which was between 0.0087 m⁻¹ at Mississippi in May 2008 and 0.0261 m⁻¹ at Barataria in June 2008. CDOM was the dominant component of light attenuation at Terrebonne and Barataria. Detritus and CDOM were the primary components of light attenuation at Vermilion, Atchafalaya, and Mississippi. DOC ranged between 65 and 1235 μM. PIM ranged between 1.1 and 426.3 mg L⁻¹ and POM was between 0.3 and 49.6 mg L⁻¹.     

Distribution and composition of organic matter in surface sediments of coastal Southeast Alaska

Total organic carbon (TOC) and biogenic silica (opal) content, elemental (C/N) and isotopic (δ¹³C, δ¹⁵N) composition of organic matter and the content of lipid biomarkers derived from both marine and terrestrial sources constrain relative contributions from marine productivity and continental erosion to surface sediments throughout coastal SE Alaska (54°N to 61°N). TOC and opal content are very high (up to 8% and 33% by weight, respectively) in fjords and inlets south of Icy Strait (∼58°N) and uniformly low at offshore sites to the south, and at both offshore and inland sites to the north (averaging 0.6±0.3% and 2.3±1.8%, respectively). TOC and opal mass accumulation rates (MARs, based on bulk density and ²¹⁰Pb-derived sediment MAR) suggest dilution with terrigenous, inorganic detrital materials accounts for the low concentrations of both biogenic phases in sediments from the glacial tidewater fjords of Muir and Yakutat Bays but not elsewhere. C/N, δ¹³C, and δ¹⁵N indicate a dominant marine origin for organic matter deposited at most sites. This conclusion implicates elevated primary productivity in inland waters to the south with diatoms, based on opal results, being the dominant contributor. A very significant terrestrial organic fraction (25–50%) is contained in sediments deposited on the continental shelf to the north of 58°N. Hydrocarbon biomarkers indicate the terrestrial fraction in sediments from this region is represented by old organic matter (kerogen) likely contained within riverborne particles eroding from now heavily glaciated adjacent landscapes. In sediment to the south, the terrestrial fraction is traced to modern soil organic matter eroded from the now non-glaciated, heavily forested adjacent landscape. Our study provides a framework to guide future investigations of short- (anthropogenic) to long- (Holocene) term environmental and/or climate change in this region through down-core, stratigraphic analysis.     

Seasonal variability in organic substances in surface and cave waters at Marengo Cave,Indiana

Water samples from forest soils and a shallow cave underlying them were collected for the hydrological year 1996–1997. The soil waters did not display much seasonal variability in concentrations of organic substances in them but the cave waters yielded distinct highest levels in the spring and autumn seasons. The important controls on the amount of organic substances reaching the cave are the seasonal fluctuation in volume of the percolation waters and the soil's ability to provide organic material for these waters. Fluorescence studies of the organic compounds isolated from these waters revealed shorter peak excitation and emission wavelengths for the cave waters than for the soil waters, a result of both differences in concentration and probably also of significant change in the proportional organic assemblages in the waters. Precipitation appears to affect the fluorescence in both waters, with the dry autumn producing the highest yields. Molecular size fractionation revealed how the larger hydrophobic compounds are preferentially removed from the water before it reaches the cave, with the consequence that the smaller hydrophilic compounds become the dominant fluorophore there. Copyright © 2000 John Wiley & Sons, Ltd.     

Minor effect of beaver dams on stream dissolved organic carbon in the catchment of a German drinking water reservoir

Rising concentrations of dissolved organic carbon (DOC) are negatively affecting the water quality in several drinking water reservoirs. The presence of beaver dams can influence surface water quality on a catchment scale. In recent years, beavers have been re-introduced in numerous locations in Central Europe. We investigated whether the presence of beaver dams in the catchment of a German drinking water reservoir impacts DOC quantity and quality in the streams entering the Wehebach reservoir in Germany.By comparing water quality upstream and downstream of beaver dams during three low discharge situations we did not find a significant effect of dams both on DOC quantity and quality. The analysis of long term monitoring data at the gauges showed that beaver dams had a negligible effect on the DOC load to the reservoir. DOC quantity was closely linked to iron concentration in the streams. Co-precipitation with iron minerals was an effective process removing DOC from the stream-water. By analyzing fluorescence excitation emission indices we show that beaver dams did not have a clear effect on DOC quality. We conclude that the presence of beaver dams has only small effects on water quality and is not a problem for water quality in the downstream drinking water reservoir.     

Impact of urbanization on suspended sediment and organic matter fluxes from small catchments in Tahiti

This study provides an initial characterization of pollution associated with storm runoff in Tahiti. A thousand floodwater samples were collected from three representative catchments and subsequently analysed. The main pollution parameters chosen were total suspended sediment (TSS), chemical oxygen demand (COD), biochemical oxygen demand (BOD5), total nitrogen (TN) and Total Phosphorus (TP). First, organic pollution appeared to be related closely to sediment, thus TSS could be used as a global indicator. Next, regression models between an event's TSS load and its hydrological characteristics were used to obtain annual load estimates. Great interannual variability was found to be strongly influenced by the few major floods that occur during the rainy season. Our results also emphasize the importance of the impact of urbanization on solid catchment exportation: from 60 TSS t/km²/year in a natural forested catchment, fluxes reached more than 700 TSS t/km²/year during preparatory urbanization earthworks before stabilizing at 140 TSS t/km²/year in a consolidated urbanized area. Clearly, runoff effects need to be taken into consideration for effective urban planning and for the preservation of the coastal environment in Tahiti. Copyright © 2002 John Wiley & Sons, Ltd.     

Temporal and spatial variations in the discharge and dissolved organic carbon of drip waters in Beijing Shihua Cave,China

To detect the causal relationship between cave drip waters and stalagmite laminae, which have been used as a climate change proxy, three drip sites in Beijing Shihua Cave were monitored for discharge and dissolved organic carbon (DOC). Drip discharges and DOC were determined at 0 to 14‐day intervals over the period 2004–2006. Drip discharges show two types of response to surface precipitation variations: (1) a rapid response; and (2) a time‐lagged response. Intra‐annual variability in drip discharge is significantly higher than inter‐annual variability. The content of DOC in all drip waters varies inter‐ and intra‐annually and has good correlation with drip water discharge at the rapid response sites. High DOC was observed in July and August in the three years observed. The flushing of soil organic matter is dependent upon the intensity of rain events. The DOC content of drip water increases sharply above a threshold rainfall intensity (>50 mm d^?1) and shows several pulses corresponding with intense rain events (>25 mm d^?1). The DOC content was lower and less variable during the dry period than during the rainy period. The shape of DOC peak also varies from year to year as it is influenced by the intensity and frequency of rainfall. The different drip sites show marked differences in DOC response, which are dominated by hydrological behaviour linked to the recharge of the soil and karst micro‐fissure/porosity network. The results explain why not all stalagmite laminae are consistent with climate changes and suggest that the structure of the rainy season events could be preserved in speleothems. Copyright © 2008 John Wiley & Sons, Ltd.     

Emerging organic contaminants in coastal waters: Anthropogenic impact,environmental release and ecological risk

This study provides a first estimate of the sources, distribution, and risk presented by emerging organic contaminants (EOCs) in coastal waters off southwestern Taiwan. Ten illicit drugs, seven nonsteroidal anti-inflammatory drugs (NSAIDs), five antibiotics, two blood lipid regulators, two antiepileptic drugs, two UV filters, caffeine, atenolol, and omeprazole were analyzed by solid-phase extraction and liquid chromatography coupled to tandem mass spectrometry (SPE–LC–MS/MS). Thirteen EOCs were detected in coastal waters, including four NSAIDs (acetaminophen, ibuprofen, ketoprofen, and codeine), three antibiotics (ampicillin, erythromycin, and cefalexin), three illicit drugs (ketamine, pseudoephedrine, and MDMA), caffeine, carbamazepine, and gemfibrozil. The median concentrations for the 13 EOCs ranged from 1.47 ng/L to 156 ng/L. Spatial variation in concentration of the 13 EOCs suggests discharge into coastal waters via ocean outfall pipes and rivers. Codeine and ampicillin have significant pollution risk quotients (RQ > 1), indicating potentially high risk to aquatic organisms in coastal waters.     

Spatial scale impact on daily surface water and sediment fluxes in Thukela river,South Africa

The on- and off-site effects of soil erosion in many environments are well known, but there is still limited understanding of the soil loss fluxes in downstream direction due, among other factors, to scarce and poor quality. A four year study to (i) evaluate water and sediment fluxes at different spatio-temporal scales and (ii) interpret the results in terms of processes involved and the controlling factors, was conducted in Thukela basin, South Africa. Five hierarchically nested catchments; namely microcatchment (0.23 km²), subcatchment (1.20 km²), catchment (9.75 km²), sub-basin (253 km²) and basin (29,038 km²), were used in addition to fifteen (1 m²) microplots and ten (10 m²) plots on five locations within the microcatchment. The results showed 19% decrease of unit-area runoff (q) from 3.1 L m⁻² day⁻¹ at microplot to 2.5 L m⁻² day⁻¹ at plot scale followed by steeper (56%) decrease at microcatchment scale. The q decreased in downstream direction to very low level (q ≤ 0.26 L m⁻² day⁻¹). The changes in q were accompanied by initial 1% increase of soil loss (SL) from 18.8 g m⁻² day⁻¹ at microplot to 19.1 g m⁻² day⁻¹ at plot scale. The SL also decreased sharply (by 39 fold) to 0.50 g m⁻² day⁻¹ at microcatchment scale, followed by further decrease in downstream direction. The decrease of q with spatial scale was attributed to infiltration losses, while initial increase of SL signified greater competence of sheet than splash erosion. The decrease of SL beyond the plot scale was attributed to redistribution of the soil on the hillslope and deposition on the stream channel upstream of the microcatchment outlet. Therefore, erosion control strategies focussing on the recovery of vegetation on the slope and stabilisation of gullies are recommended.     

Landscape influences on aluminium and dissolved organic carbon in streams draining the Hubbard Brook valley,New Hampshire,USA

Concentrations of both aluminium (Al) and dissolved organic carbon (DOC) in stream waters are likely to be regulated by factors that influence water flowpaths and residence times, and by the nature of the soil horizons through which waters flow. In order to investigate landscape‐scale spatial patterns in streamwater Al and DOC, we sampled seven streams draining the Hubbard Brook valley in central New Hampshire. We observed considerable variation in stream chemistry both within and between headwater watersheds. Across the valley, concentrations of total monomeric aluminium (Al_m) ranged from below detection limits (<0·7 µmol l⁻¹) to 22·3 µmol l⁻¹. In general, concentrations of Al_m decreased as pH increased downslope. There was a strong relationship between organic monomeric aluminium (Al_o) and DOC concentrations (R² = 0·92). We observed the highest Al_m concentrations in: (i) a watershed characterized by a steep narrow drainage basin and shallow soils and (ii) a watershed characterized by exceptionally deep forest floor soils and high concentrations of DOC. Forest floor depth and drainage area together explained much of the variation in ln Al_m (R² = 0·79; N = 45) and ln DOC (R² = 0·87; N = 45). Linear regression models were moderately successful in predicting ln Al_m and ln DOC in streams that were not included in model building. However, when back‐transformed, predicted DOC concentrations were as much as 72% adrift from observed DOC concentrations and Al_m concentrations were up to 51% off. This geographic approach to modelling Al and DOC is useful for general prediction, but for more detailed predictions, process‐level biogeochemical models are required. Copyright © 2005 John Wiley & Sons, Ltd.     

Optical properties of chromophoric dissolved organic matter (CDOM) in surface and pore waters adjacent to an oil well in a southern California salt marsh

Chromophoric dissolved organic matter (CDOM) optical properties were measured in surface and pore waters as a function of depth and distance from an oil well in a southern California salt marsh. Higher fluorescence and absorbances in pore vs. surface waters suggest soil pore water is a reservoir of CDOM in the marsh. Protein-like fluorophores in pore waters at distinct depths corresponded to variations in sulfate depletion and Fe(II) concentrations from anaerobic microbial activity. These variations were supported by fluorescence indexes and are consistent with differences in optical molecular weight and aromaticity indicators. Fluorescence indices were consistent with autochthonous material of aquatic origin in surface waters, with more terrestrial, humified allochthonous material in deeper pore waters. CDOM optical properties were consistent with significantly enhanced microbial activity in regions closest to the oil well, along with a three-dimensional excitation/emission matrix fluorescence spectrum peak attributable to oil, suggesting anaerobic microbial degradation of oil.     

Seasonal dynamics of microbial sulfate reduction in temperate intertidal surface sediments: controls by temperature and organic matter

The role of microbial sulfate reduction on organic matter oxidation was studied quantitatively in temperate intertidal surface sediments of the German Wadden Sea (southern North Sea) on a seasonal base in the years 1998–2007. The sampling sites represent the range of sediments found in the back-barrier tidal area of Spiekeroog Island: sands, mixed and muddy flats. The correspondingly different contents in organic matter, metals, and porosities lead to significant differences in the activity of sulfate-reducing bacteria with volumetric sulfate reduction rates (SRR) in the top 15 cm of up to 1.4 μmol cm^?3 day^?1. Depth-integrated areal SRR ranged between 0.9 and 106 mmol m^?2 day^?1, with the highest values found in the mudflat sediments and lower rates measured in sands at the same time, demonstrating the impact of both temperature and organic matter load. According to a modeling approach for a 154-km² large tidal area, about 39, 122, and 285 tons of sulfate are reduced per day, during winter, spring/autumn, and summer, respectively. Hence, the importance of areal benthic organic matter mineralization by microbial sulfate reduction increases during spring/autumn and summer by factors of about 2 and 7, respectively, when compared to winter time. The combined results correspond to an estimated benthic organic carbon mineralization rate via sulfate reduction of 78 g C m^?2 year^?1.     

Controls of interactions between iron hydroxide colloid and water on REE fractionations in surface waters: Experimental study on pH-controlling mechanism

The influence of pH on the partitioning behavior of REE at the water/particulate interface has been studied experimentally. At the beginning of colloid formation the adsorption of REE on iron hydroxide colloids is dominant, followed by REE desorption. Finally adsorption and desorption tend to reach equilibration. The capability of iron hydroxide colloids to adsorb the HREE is greater than that to adsorb the LREE. With increasing pH, LREE/HREE fractionations will take place between iron hydroxide colloids and water, leading to the reduction of their partition coefficient ratio (DLREE/DHREE). The DREE distribution patterns show Y anomalies (DY/DHo <1), with obvious REE tetrad effects appearing under low pH conditions. Experimental results have shown that there do exist REE tetrad effects in nature. In addition to pH, the chemical type of surface water and ion intensity are also the important factors controlling REE tetrad effects and leading to fractionations between particulate-adsorbed REE and dissolved REE.     

Evaluation of snow models in terrestrial biosphere models using ground observation and satellite data: impact on terrestrial ecosystem processes

Snow is important for water management, and an important component of the terrestrial biosphere and climate system. In this study, the snow models included in the Biome‐BGC and Terrestrial Observation and Prediction System (TOPS) terrestrial biosphere models are compared against ground and satellite observations over the Columbia River Basin in the US and Canada and the impacts of differences in snow models on simulated terrestrial ecosystem processes are analysed. First, a point‐based comparison of ground observations against model and satellite estimates of snow dynamics are conducted. Next, model and satellite snow estimates for the entire Columbia River Basin are compared. Then, using two different TOPS simulations, the default TOPS model (TOPS with TOPS snow model) and the TOPS model with the Biome‐BGC snow model, the impacts of snow model selection on runoff and gross primary production (GPP) are investigated. TOPS snow model predictions were consistent with ground and satellite estimates of seasonal and interannual variations in snow cover, snow water equivalent, and snow season length; however, in the Biome‐BGC snow model, the snow pack melted too early, leading to extensive underpredictions of snow season length and snow covered area. These biases led to earlier simulated peak runoff and reductions in summer GPP, underscoring the need for accurate snow models within terrestrial ecosystem models. Copyright © 2007 John Wiley & Sons, Ltd.     

Effects of climate-related variability in storage on streamwater solute concentrations and fluxes in a small forested watershed in the Southeastern United States

Streamwater quality can be affected by climate-related variability in hydrologic state, which controls flow paths and affects biogeochemical processes. Thirty-one years of input/output solute fluxes at Panola Mountain Research Watershed, a small, forested, seasonally water-limited watershed near Atlanta, Georgia, were used to quantify the effects of climatic-related variability in storage on streamwater solute concentrations and fluxes. Streamwater fluxes were estimated for ten solutes from weekly and event sample concentrations using regression-based methods. The most pertinent storage attribute (current or antecedent watershed, shallow, and deep storage) for each solute was determined by fitting separate concentration relationships. The concentration-discharge relationships varied more for reactive solutes such as potassium, sulfate, and DOC and less for weathering products (base cations and dissolved silica) and conservative chloride. Many solutes exhibited higher concentrations when storage levels were lower or wetting up, which was likely the result of the concentrating effects of evapotranspiration and/or the buildup and flushing of weathering products associated with longer residence times. The impacts of storage modeling on annual fluxes varied by solute, ranging from about 5% (magnesium) to 52% (nitrate) as relative standard deviations, and sufficiently removed climate-related patterns observed in streamwater concentrations. Sulfate was particularly mobilized following growing season droughts but only if deep storage was sufficiently recharged, possibly indicating that sulfides in the deep storage pool were oxidized to sulfate during droughts and mobilized when re-wetted. The lack of streamwater sulfate response to 61% declines in atmospheric deposition indicates the importance of watershed biogeochemical processes on controls of streamwater export of sulfate. The approach of explicitly incorporating storage in the streamwater concentration modeling elucidated the effects of climate on streamwater water-quality and may provide insight into the effects of climatic change on future fluxes.     

Diurnal cycle of surface energy fluxes in high mountain terrain: High-resolution fully coupled atmosphere-hydrology modelling and impact of lateral flow

Water and energy fluxes are inextricably interlinked within the interface of the land surface and the atmosphere. In the regional earth system models, the lower boundary parameterization of land surface neglects lateral hydrological processes, which may inadequately depict the surface water and energy fluxes variations, thus affecting the simulated atmospheric system through land-atmosphere feedbacks. Therefore, the main objective of this study is to evaluate the hydrologically enhanced regional climate modelling in order to represent the diurnal cycle of surface energy fluxes in high spatial and temporal resolution. In this study, the Weather Research and Forecasting model (WRF) and coupled WRF Hydrological modelling system (WRF-Hydro) are applied in a high alpine catchment in Northeastern Tibetan Plateau, the headwater area of the Heihe River. By evaluating and intercomparing model results by both models, the role of lateral flow processes on the surface energy fluxes dynamics is investigated. The model evaluations suggest that both WRF and coupled WRF-Hydro reasonably represent the diurnal variations of the near-surface meteorological fields, surface energy fluxes and hourly partitioning of available energy. By incorporating additional lateral flow processes, the coupled WRF-Hydro simulates higher surface soil moisture over the mountainous area, resulting in increased latent heat flux and decreased sensible heat flux of around 20–50 W/m² in their diurnal peak values during summertime, although the net radiation and ground heat fluxes remain almost unchanged. The simulation results show that the diurnal cycle of surface energy fluxes follows the local terrain and vegetation features. This highlights the importance of consideration of lateral flow processes over areas with heterogeneous terrain and land surfaces.