Hydrogeochemistry and environmental isotopes of ground water in Jeju volcanic island,Korea: implications for nitrate contamination

Ground water from springs and public supply wells was investigated for hydrochemistry and environmental isotopes of ³H, ¹⁸O and D in Jeju volcanic island, Korea. The wells are completed in a basaltic aquifer and the upper part of hydrovolcanic sedimentary formation. Nitrate contamination is conspicuous in the coastal area where most of the samples have nitrate concentrations well above 1 mg NO₃ N/l. Agricultural land use seems to have a strong influence on the distribution of nitrate in ground water. Comparison of stable isotopic compositions of precipitation and ground water show that ground water mostly originates from rainy season precipitation without significant secondary modification and that local recharge is dominant. ³H concentration of ground water ranged from nearly zero to 5 TU and is poorly correlated with vertical location of well screens. The occurrence of the ³H‐free, old ground water is due to the presence of low permeability layers near the boundary of the basaltic aquifer and the hydrovolcanic sedimentary formation, which significantly limits ground water flow from the upper basaltic aquifer. The old ground water exhibited background‐level nitrate concentrations despite high nitrate loadings, whereas young ground water had considerably higher nitrate concentrations. This correlation of ³H and nitrate concentration may be ascribed to the history of fertilizer use that has increased dramatically since the early 1960s in the island. This suggests that ³H can be used as a qualitative indicator for aquifer vulnerability to nitrate contamination. Copyright © 2005 John Wiley & Sons, Ltd.     

Hydrogeochemical and isotopic evidence of groundwater salinization in a coastal aquifer: a case study in Jeju volcanic island, Korea

In order to identify the origin of saline groundwater in the eastern part of Jeju volcanic island, Korea, a hydrogeochemical and isotopic study has been carried out for 18 observation wells located in east and southeast coastal regions. The total dissolved solid contents of groundwaters are highly variable (77–21,782 mg/l). Oxygen, hydrogen, sulfur, and strontium isotopic data clearly show that the saline water results from mixing of groundwater with seawater. Strontium isotopic compositions and Br/Cl and I/Cl ratios strongly suggest that the source of salinity is modern seawater intrusion. Hydrogeochemical characteristics based on bivariate diagrams of major and minor ions show that changes in the chemical composition of groundwater are mainly controlled by the salinization process followed by cation-exchange reactions. The highly permeable aquifers at the east coastal region are characterized by low hydraulic gradient and discharge rate and high hydraulic conductivity as compared with other regions. These properties enhance the salinization of groundwater observed in the study area. Based on the Cl, Br, and δ¹⁸O data, seawater was determined to have intruded inland some 2.5 km from the coastline. Considering the poor correlation of sampling depth and Cl concentrations observed, the position of seawater-freshwater interface is not uniformly distributed in the study area, due to heterogeneities of the basaltic aquifers.     

Tidal effects on variations of fresh–saltwater interface and groundwater flow in a multilayered coastal aquifer on a volcanic island (Jeju Island, Korea)

We conducted various field studies at the seawater intrusion monitoring wells located in the eastern part of Jeju Island, Korea, to observe the tidal effect on groundwater–seawater flow in the coastal aquifer. Studies included monitoring the fluctuations of groundwater and tide levels, electrical and temperature logging, and 2-D heat-pulse flowmeter tests. According to time-series analysis, tidal effects on groundwater level reached up to 3 km inland from the coastline. Water-level variation was more sensitive to tidal fluctuations near the coast, and more related to rainfall toward inland areas. Temporal and spatial variations in the shape and location of the freshwater–saltwater interface were analyzed using data from nine monitoring wells. The results indicated that the interface toe is located at a distance of 6–8 km from the coastline and its location was related to geological layers present. Long-term seasonal variations revealed no major changes in the interface; minor variations were due to moving boundary conditions induced by tidal fluctuations. Using the two-dimensional heat-pulse flowmeter, groundwater flow directions and velocities at four tidal stages were measured on three monitoring wells drilled into the multilayered aquifers. This direct measurement enabled us to relate the differences of flow velocities and directions with geology and tidal fluctuations. Combining the results of EC logging and flowmeter tests, we found a zone where freshwater and saltwater moved alternately in opposite directions, as influenced by the tidal fluctuations. Integrating various physical logging and flowmeter data with water-level fluctuations improved our understanding of the behavior of fresh and seawater flow in the coastal aquifers.