The effect of mining and related activities on the sediment–trace element geochemistry of Lake Coeur d'Alene,Idaho, USA. Part III. Downstream effects: the Spokane River Basin

During 1998/1999, surface and subsurface sediment samples were collected along the entire length of the Spokane River from its outlet at the northern end of Lake Coeur d'Alene (CDA), Idaho, to Lake Roosevelt on the Columbia River, Washington. The study was conducted to determine if the trace element enrichments observed in Lake CDA and on the floodplain and in the CDA River extend through the Spokane River Basin (SRB). As in Lake CDA, surface sediments in the SRB are enriched in Pb, Zn, As, Cd, Sb and Hg relative to local background levels. Pb, Cd and Zn are the most elevated, with maximum enrichment occurring in the upper Spokane River in close proximity to Lake CDA. On average, enrichment decreases downstream, apparently reflecting both increased distance from the inferred source (the CDA River Basin), as well as increased dilution by locally derived but unenriched materials. Only Cd and Zn display marked enrichment throughout the SRB. Pb, Zn and Cd seem to be associated mainly with an operationally defined iron oxide phase, whereas the majority of the As and Sb seem to be matrix‐held. Subsurface sediments also are enriched in Pb, Zn, As, Cd, Sb and Hg relative to background levels. Based on ¹³⁷Cs and excess ²¹⁰Pb dating, trace element enrichment began in the middle part of the SRB (Long Lake) between 1900 and 1920. This is contemporaneous with similar enrichments observed in Lake CDA, as well as the completion of Long Lake Dam (1913). In the most downstream part of the basin (Spokane River Arm of Lake Roosevelt), enrichment began substantially later, between 1930 and 1940. The temporal difference in enrichment between Long Lake and the River Arm may reflect the latter's greater distance from the presumed source of the enrichment (the CDA River Basin); however, the difference is more likely the result of the completion of Grand Coulee Dam (1934–1941), which formed Lake Roosevelt, backed up the Spokane River, and increased water levels in the River Arm by about 30 m.     

Aquatic system response to climatic and human changes: Productivity,bottom water oxygen status,and sapropel formation in Lake Lugano over the last 10 000 years

The Holocene record of Lake Lugano (southern basin: surface area 20.3 km², maximum depth 87 m) comprising organic carbon-rich sediments (sapropels), is divided into eight intervals based on radiocarbon- and varve-dating. The content of organic carbon, inorganic carbon, and biogenic silica, as well as the benthic remains of ostracods and oligochaetes, are converted into accumulation rates and benthic abundances in order to assess past production rates and bottom water oxygen status, respectively. The results suggest three periods of distinct palaeolimnological character: (i) low primary production combined with shifts between aerobic and anaerobic profundal conditions (prior to ca. 3000 BC), (ii) moderate rates of production combined with a relatively high profundal oxygen content (after ca. 1500 BC), and (iii), high production rates (460 g C m^–2 a^–1) combined with anaerobic profundal conditions (present eutrophic state). Corresponding organic carbon contents in the sediments are: up to 5% (i), 4% (ii), and 8% (iii). Until the beginning of this century, the flux of autochthonous sediments to the lake floor correlated with the fluctuations in the allochthonous sediment accumulation rate, indicating that catchment erosion largely controlled lacustrine production during the Holocene history of Lake Lugano. Pollen data show catchment-vegetational transformations at ca. 3500 BC (change from fir to beech forests), at 1400 BC (onset of cereal vegetation) and at ca. A.D. 450 (strong increase in various cultural plants). The first two changes had a relatively large imprint on lacustrine sedimentation. At ca. 3500 BP, erosion increase in the catchment was triggered by vegetation changes in the mountain zone above ca. 1000 m a. s. l., which may have been induced by climatic and human alteration (drop in the treeline altitude). Maximum catchment erosion occurred at ca. 1400 BC which was clearly dominated by human cultivation during the Bronze Age. More oxygenated profundal conditions in the lake after ca. 3000 BC are possibly related to a better mixing of the lake waters during the winter season by increased wind activity.