The impact of ditch blocking on the hydrological functioning of blanket peatlands

Ditch blocking in blanket peatlands is common as part of peatland restoration. The effects of ditch blocking on flow regimes and nearby water tables were examined in a field trial. After an initial 6‐month monitoring period, eight ditches had peat dams installed 10 m apart along their entire length (dammed), four of these ditches were also partially infilled through bank reprofiling (reprofiled). Four ditches were left open with no dams or reprofiling (open). These 12 ditches and the surrounding peat were monitored for 4 more years. An initial five‐fold reduction in discharge occurred in the dammed and the reprofiled ditches with the displaced water being diverted to overland flow and pathways away from the ditches. However, there was a gradual change over time in ditch flow regime in subsequent years, with the overall volume of water leaving the dammed and the reprofiled ditches increasing per unit of rainfall to around twice that which occurred in the first year after blocking. Hence, monitoring for greater than one year is important for understanding hydrological impacts of peatland restoration. Overland flow and flow in the upper ~4 cm of peat was common and occurred in the inter‐ditch areas for over half of the time after ditch blocking. There was strong evidence that topographic boundaries of small ditch catchments, despite being defined using a high‐resolution Light Detection And Ranging‐based terrain model, were not always equivalent to actual catchment areas. Hence, caution is needed when upscaling area‐based fluxes, such as aquatic carbon fluxes, from smaller scale studies including those using ditches and small streams. The effect of ditch blocking on local water tables was spatially highly variable but small overall (time‐weighted mean effect <2 cm). Practitioners seeking to raise water tables through peatland restoration should first be informed either by prior measurement of water tables or by spatial modelling to show whether the peatland already has shallow water tables or whether there are locations that could potentially undergo large water‐table recoveries.     

Erosion mechanisms and sediment sources in a peatland forest after ditch cleaning

Ditch cleaning in drained peatland forests increases sediment loads and degrades water quality in headwater streams and lakes. A better understanding of the processes controlling ditch erosion and sediment transport in such systems is a prerequisite for proper peatland management. In order to relate hydrological observations to key erosion processes in headwater peatlands drained for forestry, a two‐year study was conducted in a nested sub‐catchment system (treated with ditch cleaning) and at two reference sites. The treated catchment was instrumented for continuous discharge and turbidity monitoring, erosion pin measurements of changes in ditch bed and banks and time‐integrated sampling of suspended sediment (SS) composition. The results showed that ditch cleaning clearly increased transient suspended sediment concentrations (SSCs) and suspended sediment yields (SSYs), and resulted in temporary storage of loosely deposited organic sediment in the ditch network. After exhaustion of this sediment storage, subaerial processes and erosion from ditch banks became dominant in producing sediment for transport. Recorded SSCs were higher on the rising limbs of event hydrographs throughout the study period, indicating that SS transport was limited by availability of erosion‐prone sediment. A strong positive correlation (R² = 0.84, p < 0.001) between rainfall intensity (above a threshold of 1 mm h^?1) and average SSC obtained on the rising limb of hydrographs for the sub‐catchment showed that soil detachment from ditch banks by raindrop impact can directly increase SSC in runoff. At the main catchment outlet, variation in SSC was best explained (R² = 0.67, p < 0.05) by the linear combination of initial discharge (?), peak discharge (+) and the lag time from initial to peak discharge (?). Based on these factors, ditch cleaning slightly increased peak discharges and decreased transit times in the study catchment. The implications of the results for water pollution management in peatland forests are discussed. Copyright © 2016 John Wiley & Sons, Ltd.     

The impact of ditch blocking on fluvial carbon export from a UK blanket bog

We investigated the effects of ditch blocking on fluvial carbon concentrations and fluxes at a 5‐year, replicated, control‐intervention field experiment on a blanket peatland in North Wales, UK. The site was hydrologically instrumented, and run‐off via open and blocked ditches was analysed for dissolved organic carbon (DOC), particulate organic carbon, dissolved carbon dioxide, and dissolved methane. DOC was also analysed in peat porewater and overland flow. The hillslope experiment was embedded within a paired control‐intervention catchment study, with 3 years of preblocking and 6 years of postblocking data. Results from the hillslope showed large reductions in discharge via blocked ditches, with water partly redirected into hillslope surface and subsurface flows, and partly into remaining open ditches. We observed no impacts of ditch blocking on DOC, particulate organic carbon, dissolved carbon dioxide or methane in ditch waters, DOC in porewaters or overland flow, or stream water DOC at the paired catchment scale. Similar DOC concentrations in ditch water, overland flow, and porewater suggest that diverting flow from the ditch network to surface or subsurface flow had a limited impact on concentrations or fluxes of DOC entering the stream network. The subdued response of fluvial carbon to ditch blocking in our study may be attributable to the relatively low susceptibility of blanket peatlands to drainage, or to physical alterations of the peat since drainage. We conclude that ditch blocking cannot be always be expected to deliver reductions in fluvial carbon loss, or improvements in the quality of drinking water supplies.     

Seasonal variation in albedo and radiation exchange between a burned and unburned forested peatland: implications for peatland evaporation

Forested boreal peatlands represent a precipitation‐dependent ecosystem that is prone to wildfire disturbance. Solar radiation exchange in forested peatlands is modified by the growth of a heterogeneous, open‐crown tree canopy, as well as by likely disturbance from wildfire. Radiation exchange at the peat surface is important in peatlands, as evaporation from the peat surface is the dominant pathway of water loss in peatlands of continental western North America. We examined shortwave and longwave radiation exchange in two forested ombrotrophic peatlands of central Alberta, Canada: one with (>75 years since wildfire; unburned) and another without a living spruce canopy (1–4 years since wildfire; burned) between the autumn of 2007 and 2010. Above‐canopy winter albedo was nearly two times greater in the recently burned peatland than the unburned peatland. Incoming shortwave radiation at the peat surface was much higher at the burned peatland, which increases the amount of energy available for evaporation. This is especially true for hollow microforms that are generally shaded by the tree canopy in unburned peatlands. Snow‐free albedo was similar between peatlands, although an increase in longwave losses at the burned site resulted in slightly greater net radiation at the unburned site. Copyright © 2015 John Wiley & Sons, Ltd.     

Dynamics in land cover and its effect on stream flow in the Chemoga watershed,Blue Nile basin,Ethiopia

The objective of this study was to analyse changes in stream flow patterns with reference to dynamics in land cover/use in a typical watershed, the Chemoga, in northwestern highland Ethiopia. The results show that, between 1960 and 1999, total annual stream flow decreased at a rate of 1 · 7 mm year⁻¹, whereas the annual rainfall decreased only at a rate of 0 · 29 mm year⁻¹. The decrease in the stream flow was more pronounced during the dry season (October to May), for which a statistically significant decline (0 · 6 mm year⁻¹) was observed while the corresponding rainfall showed no discernible trend. The wet season (June to September) rainfall and stream flow did not show any trends. Extreme low flows analysed at monthly and daily time steps reconfirmed that low flows declined with time, the changes being highly significant statistically. Between 1960 and 1999, the monthly rainfall and stream flow amounts of February (month of lowest long‐term mean flow) declined by 55% and 94% respectively. Similarly, minimum daily flows recorded during the three driest months (December to February) showed statistically highly significant declines over the same period. It declined from 0 · 6 m³ s⁻¹ to 0 · 2 m³ s⁻¹ in December, from 0 · 4 m³ s⁻¹ to 0 · 1 m³ s⁻¹ in January and from 0 · 4 m³ s⁻¹ to 0 · 02 m³ s⁻¹ in February (1 · 0 m³ s⁻¹ = 0 · 24 mm day⁻¹ in the Chemoga watershed). In contrast, extreme high flows analysed at monthly (for August) and daily (July to September) time steps did not reveal discernible trends. The observed adverse changes in the stream flow have partly resulted from changes in land cover/use and/or degradation of the watershed that involved destruction of natural vegetative covers, expansion of croplands, overgrazing and increased area under eucalypt plantations. The other contributory factor has been the increased dry‐season water abstraction to be expected from the increased human and livestock populations in the area. Given the significance of the stream flow as the only source of water to the local people, a set of measures aimed at reducing magnitudes of surface runoff generation and increasing groundwater recharge are required to sustain the water resource and maintain a balanced dry‐season flow in the watershed. Generally, an integrated watershed management approach, whereby the whole of the watershed can be holistically viewed and managed, would be desirable. Copyright © 2004 John Wiley & Sons, Ltd.     

Seasonal and spatial variation in suspended matter,organic carbon,nitrogen, and nutrient concentrations of the Senegal River in West Africa

The Senegal River is of intermediate size accommodating at present about 3.5 million inhabitants in its catchment. Its upstream tributaries flow through different climatic zones from the wet tropics in the source area in Guinea to the dry Sahel region at the border between Senegal and Mauritania. Total suspended matter, particulate and dissolved organic carbon and nitrogen as well as nutrient concentrations were determined during the dry and wet seasons at 19 locations from the up- to downstream river basin. The aims of the study were to evaluate the degree of human interference, to determine the dissolved and particulate river discharges into the coastal sea and to supply data to validate model results. Statistical analyses showed that samples from the wet and dry season are significantly different in composition and that the upstream tributaries differ mainly in their silicate and suspended matter contents. Nutrient concentrations are relatively low in the river basin, indicating low human impact. Increasing nitrate concentrations, however, show the growing agriculture in the irrigated downstream areas. Particulate organic matter is dominated by C4 plants during the wet season and by aquatic plankton during the dry season. The total suspended matter (TSM) discharge at the main gauging station Bakel was about 1.93 Tg yr⁻¹ which is in the range of the only available literature data from the 1980s. The calculated annual discharges of particulate organic carbon (POC), dissolved organic carbon (DOC) and dissolved organic nitrogen (DON) are 55.8 Gg yr⁻¹, 54.1 Gg yr⁻¹, and 5.3 Gg yr⁻¹, respectively. These first estimates from the Senegal River need to be verified by further studies.     

FLOW REVERSALS IN PEATLANDS INFLUENCED BY LOCAL GROUNDWATER SYSTEMS

Piezometric head data from various depths were examined at two peatlands in Ontario, Canada and one peatland in Sweden influenced by small-scale, shallow groundwater systems. Data from different hydrogeological settings show reversals in groundwater flow leading to discharge in topographically high regions of peatlands in isolation from large-scale groundwater flow. It is suggested that subsurface flow within peat can reverse in direction in response to water deficit and water-table drawdown. The data presented here refute the assumption that local groundwater flow in peatlands is unidirectional and further illustrate the fact that measurable subsurface water flow can occur at depth in peat isolated from large-scale groundwater flow systems. In the light of implicit assumptions made by many workers on water movement in peatlands, especially when connected to small-scale groundwater systems, the consequences of such reversals are paramount in understanding the hydrology and biogeochemistry of peatlands. © 1997 by John Wiley & Sons, Ltd.     

The high hydraulic conductivity of three wooded tropical peat swamps in northeast Peru: measurements and implications for hydrological function

The form and functioning of peatlands depend strongly on their hydrological status, but there are few data available on the hydraulic properties of tropical peatlands. In particular, the saturated hydraulic conductivity (K) has not previously been measured in neotropical peatlands. Piezometer slug tests were used to measure K at two depths (50 and 90 cm) in three contrasting forested peatlands in the Peruvian Amazon: Quistococha, San Jorge and Buena Vista. Measured K at 50 cm depth varies between 0.00032 and 0.11 cm s^?1, and at 90 cm, it varies between 0.00027 and 0.057 cm s^?1. Measurements of K taken from different areas of Quistococha showed that spatial heterogeneity accounts for ~20% of the within‐site variance and that depth is a good predictor of K. However, K did not vary significantly with depth at Buena Vista and San Jorge. Statistical analysis showed that ~18% of the variance in the K data can be explained by between‐site differences. Simulations using a simple hydrological model suggest that the relatively high K values could lead to lowering of the water table by >10 cm within ~48 m of the peatland edge for domed peatlands, if subjected to a drought lasting 30 days. However, under current climatic conditions, even with high K, peatlands would be unable to shed the large amount of water entering the system via rainfall through subsurface flow alone. We conclude that most of the water leaves these peatlands via overland flow and/or evapotranspiration. Copyright © 2013 John Wiley & Sons, Ltd.     

Oscillating peat surface levels in a restiad peatland,New Zealand—magnitude and spatiotemporal variability

Hydrology, particularly the water table position below the surface (relative water level, RWL), is an important control on biogeochemical and ecological processes in peatlands. The surface elevation (SE) in a peatland oscillates in response to changes in effective stress on the peat matrix mainly caused by water level fluctuations. This phenomenon is called peatland surface oscillation (PSO). To investigate the spatiotemporal variability of PSO, surface elevation and the water level above sea level (AWL) were measured monthly (23 sites) over one year in a warm‐temperate restiad peatland, New Zealand. At one site peat surface elevation was measured indirectly by monitoring AWL and RWL continuously with pressure transducers. Annual PSO (the difference between maximum and minimum surface elevation) ranged from 3·2 to 28 cm (mean = 14·9 cm). Surface elevation changes were caused by AWL fluctuations. Spatially homogenous AWL fluctuations (mean 40 cm among sites) translated into RWL fluctuations reduced 27–56% by PSO except for three sites with shallow and dense peat at the peatland margin (7–17%). The SE‐AWL relationship was linear for 15 sites. However, eight sites showed significantly higher rates of surface elevation changes during the wet season and thus a non‐linear behaviour. We suggest flotation of upper peat layers during the wet season causing this non‐linear behaviour. Surprisingly, PSO was subjected to hysteresis: the positive SE‐AWL relationship reversed after rainfall when the surface slowly rose despite rapidly receding AWL. Hysteresis was more prominent during the dry season than during the wet season. Total peat thickness and bulk density together could only explain 50% of the spatial variability of PSO based on manual measurements. However, we found three broad types of SE‐AWL relationships differing in shape and slope of SE‐AWL curves. These oscillation types reflected patterns in vegetation and flooding. Copyright © 2007 John Wiley & Sons, Ltd.     

Water‐level dynamics in natural and artificial pools in blanket peatlands

Perennial pools are common natural features of peatlands, and their hydrological functioning and turnover may be important for carbon fluxes, aquatic ecology, and downstream water quality. Peatland restoration methods such as ditch blocking result in many new pools. However, little is known about the hydrological function of either pool type. We monitored six natural and six artificial pools on a Scottish blanket peatland. Pool water levels were more variable in all seasons in artificial pools having greater water level increases and faster recession responses to storms than natural pools. Pools overflowed by a median of 9 and 54 times pool volume per year for natural and artificial pools, respectively, but this varied widely because some large pools had small upslope catchments and vice versa. Mean peat water‐table depths were similar between natural and artificial pool sites but much more variable over time at the artificial pool site, possibly due to a lower bulk specific yield across this site. Pool levels and pool‐level fluctuations were not the same as those of local water tables in the adjacent peat. Pool‐level time series were much smoother, with more damped rainfall or recession responses than those for peat water tables. There were strong hydraulic gradients between the peat and pools, with absolute water tables often being 20–30 cm higher or lower than water levels in pools only 1–4 m away. However, as peat hydraulic conductivity was very low (median of 1.5 × 10^?5 and 1.4 × 10^?6 cm s^?1 at 30 and 50 cm depths at the natural pool site), there was little deep subsurface flow interaction. We conclude that (a) for peat restoration projects, a larger total pool surface area is likely to result in smaller flood peaks downstream, at least during summer months, because peatland bulk specific yield will be greater; and (b) surface and near‐surface connectivity during storm events and topographic context, rather than pool size alone, must be taken into account in future peatland pool and stream chemistry studies.     

Impacts of hydraulic redistribution on eco-hydrological cycles: A case study over the Amazon basin

Hydraulic redistribution(HR)refers to the process of soil water transport through the low-resistance pathway provided by plant roots.It has been observed in field studies and proposed to be one of the processes that enable plants to resist water limitations.However,most land-surface models(LSMs)currently do not include this underground root process.In this study,a HR scheme was incorporated into the Community Land Model version 4.5(CLM4.5)to investigate the effect of HR on the eco-hydrological cycle.Two paired numerical simulations(with and without the new HR scheme)were conducted for the Tapajos National Forest km83(BRSa3)site and the Amazon.Simulations for the BRSa3 site in the Amazon showed that HR during the wet season was small,0.1 mm day~(–1),transferring water from shallow wet layers to deep dry layers at night;however,HR in the dry season was more obvious,up to 0.3 mm day~(–1),transferring water from deep wet layers to shallow dry layers at night.By incorporating HR into CLM4.5,the new model increased gross primary production(GPP)and evapotranspiration(ET)by 10%and 15%,respectively,at the BRSa3 site,partly overcoming the underestimation.For the Amazon,regional analysis also revealed that vegetation responses(including GPP and ET)to seasonal drought and the severe drought of 2005 were better captured with the HR scheme incorporated.     

Simultaneous water and vapour transfer in an unsaturated mudstone in badlands terrain,southwestern Taiwan

The simultaneous transfer of pore fluid and vapour was studied in the unsaturated shallow subsurface of a Plio-Pleistocene marine mudstone badland slope in southwestern Taiwan during the dry season using field monitoring data and numerical simulations. Data from field monitoring show mass-basis water contents of ~0.05 to ~0.10 that decrease towards the unsaturated ground surface and were invariant during the middle part of the dry season, except for daily fluctuations. In addition, the observed daily fluctuations in water content correlate with fluctuations in bedrock temperature, especially at depths of 2.5–5.0 cm. Periodic increases in water content occurred most notably during the day, when the bedrock temperature showed the greatest increase. Water contents then decreased to the previous state as bedrock temperature decreased during the night. Calculated vapour fluxes within the mudstone during the day increased up to 6 × 10⁻⁶–1 × 10⁻⁵ kg m⁻² s⁻¹, deriving a 0.01–0.02 increase in mass-basis water content at 2.5 cm depth for a 12-h period. This agrees with field monitoring data, suggesting that increases in water content occurred due to vapour intrusions into the bedrock. Pore water electrical conductivity (EC) showed periodic variations due to vapour intrusion, and gradually increased between the ground surface and depths of 2.5–5.0 cm. In contrast, pore water EC gradually decreased between 15 and 40 cm depth. Calculated water fluxes at depths of 2.5–40.0 cm varied from −4 × 10⁻⁶ to −2 × 10⁻⁹ kg m⁻² s⁻¹. These fluxes generated an increase in solute concentrations at the ground surface, with negative values of water flux indicating an upwards movement of water towards the surface. We show that the increase in solute content due to solute transfer from depth is highly dependent on variations in water flux with depth. © 2020 John Wiley & Sons, Ltd.     

A graphical approach for documenting peatland hydrodiversity and orienting land management strategies

This study focuses on the development of an approach to document the hydrological characteristics of peatlands and understand their potential influence on runoff processes and groundwater flow dynamics. Spatial calculations were performed using geographic information systems data in order to evaluate the distribution of peatlands according to (a) neighbouring hydrogeological units and (b) their position within the hydrographic network. The data obtained from these calculations were plotted in a multiple trilinear diagram (two ternary plots projected into a diamond‐shaped diagram) that illustrates the position of a given peatland within the hydrogeological environment. The data allow for the segregation of peatlands according to groups sharing similarities as well as the identification of peatlands that are most likely to have similar hydrological functions. The approach was tested in a 19,549 km² region of the southern portion of the Barlow‐Ojibway Clay Belt (in Abitibi‐Témiscamingue, Canada) and lead to a conceptual model representing the hydrological interactions between peatlands, aquifers, and surface waters. This approach allows for a geographic information systems‐based differentiation of headwater peatland complexes that are likely to interact with aquifers and to supply continuous baseflow to small streams from lowland peatland complexes of the clay plain that are isolated from surrounding aquifers but that can act as storage reservoirs within the hydrographic network. The typology is further used to discuss land management strategies aimed at preserving peatland hydrodiversity within the study region. The proposed approach relies on widely applicable hydrogeological and hydrographic criteria and provides a tool that could be used for assessing peatland hydrodiversity in other regions of the planet.     

Prediction of subsurface water level change from satellite data

This study explores the potential for predicting the spatial variation in subsurface water level change with crop growth stage from satellite data in Thabua Irrigation Project, situated in the northern central region of Thailand. The relationship between subsurface water level change from pumping water to irrigate rice in the dry season and the age of the rice was analysed. The spatial model of subsurface water level change was developed from the classification using greenness or (normalized difference vegetation index NDVI) derived from Landsat 5 Thematic Mapper data. The NDVI of 52 rice fields was employed to assess its relationship to the age of the rice. It was found that NDVI and rice age have a good correlation (R² = 0·73). The low NDVI values (−0·059 to 0·082) in these fields were related to the young rice stage (0–30 days). NDVI and subsurface water level change were also correlated in this study and found to have a high correlation (Water level change (m day⁻¹) = 0·3442 × NDVI − 0·0372; R² = 0·96). From this model, the water level change caused by rice at different growth stages was derived. This was used to show the spatial variation of water level change in the project during the 1998–99 dry‐season cropping. This simple method of using NDVI relationships with water level change and crop growth stages proves to be useful in determining the areas prone to excessive lowering of the subsurface water level during the dry season. This could assist in the appropriate planning of the use of subsurface water resources in dry‐season cropping. Copyright © 2004 John Wiley & Sons, Ltd.     

Hydraulic redistribution and hydrological controls on aspen transpiration and establishment in peatlands following wildfire

In the sub‐humid Western Boreal Plains of Alberta, where evapotranspiration often exceeds precipitation, trembling aspen (Populus tremuloides Michx.) uplands often depend on adjacent peatlands for water supply through hydraulic redistribution. Wildfire is common in the Boreal Plains, so the resilience of the transfer of water from peatlands to uplands through roots immediately following wildfire may have implications for aspen succession. The objective of this research was to characterize post‐fire peatland‐upland hydraulic connectivity and assess controls on aspen transpiration (as a measure of stress and productivity) among landscape topographic positions. In May 2011, a wildfire affected 90,000 ha of north central Alberta, including the Utikuma Region Study Area (URSA). Portions of an URSA glacio‐fluval outwash lake catchment were burned, which included forests and a small peatland. Within 1 year after the fire, aspen were found to be growing in both the interior and margins of this peatland. Across recovering land units, transpiration varied along a topographic gradient of upland midslope (0.42 mm hr^?1) > upland hilltop (0.29 mm hr^?1) > margin (0.23 mm hr^?1) > peatland (0.10 mm hr^?1); similar trends were observed with leaf area and stem heights. Although volumetric water content was below field capacity, P. tremuloides were sustained through roots present, likely before fire, in peatland margins through hydraulic redistribution. Evidence for this was observed through the analysis of oxygen (δ¹⁸O) and hydrogen (δ²H) isotopes where upland xylem and peat core signatures were ?10.0‰ and ?117.8‰ and ?9.2‰ and ?114.0‰, respectively. This research highlights the potential importance of hydraulic redistribution to forest sustainability and recovery, in which the continued delivery of water may result in the encroachment of aspen into peatlands. As such, we suggest that through altering ecosystem services, peatland margins following fire may be at risk to aspen colonization during succession.     

珠江流域西江支流贺江浮游藻类群落特征及水质分析

为了解珠江流域西江支流贺江浮游藻类的分布并评价其水质情况,于2013年丰水期和枯水期对贺江的浮游藻类群落结构进行调查和分析,结果表明:调查期间共检出浮游藻类7门130种,其中丰水期7门63种,枯水期5门103种,浮游藻类群落组成以绿藻门、硅藻门和蓝藻门为主,丰水期绿藻门居多,硅藻门次之,藻细胞丰度平均值为2.13×106cells/L;枯水期硅藻门最多,藻细胞丰度平均值为3.71×106cells/L;优势种主要有水华微囊藻、卷曲鱼腥藻、小颤藻、啮蚀隐藻、短小舟形藻、变异直链藻、颗粒直链藻、四尾栅藻、集星藻、小球衣藻和小球藻.RDA分析表明,影响贺江浮游藻类群落分布的主要环境因子是氮、磷营养盐,综合营养状态指数显示贺江处于中营养水平.     

Effects of antecedent moisture and macroporosity on infiltration and water flow in frozen soil

Infiltration into frozen soil plays an important role in soil freeze–thaw and snowmelt-driven hydrological processes. To better understand the complex thermal energy and water transport mechanisms involved, the influence of antecedent moisture content and macroporosity on infiltration into frozen soil was investigated. Ponded infiltration experiments on frozen macroporous and non-macroporous soil columns revealed that dry macroporous soil produced infiltration rates reaching 10³ to 10⁴ mm day⁻¹, two to three orders of magnitude larger than dry non-macroporous soil. Results suggest that rapid infiltration and drainage were a result of preferential flow through initially air-filled macropores. Using recorded flow rates and measured macropore characteristics, calculations indicated that a combination of both saturated flow and unsaturated film flow likely occurred within macropores. Under wet conditions, regardless of the presence of macropores, infiltration was restricted by the slow thawing rate of pore ice, producing infiltration rates of 2.8 to 5.0 mm day⁻¹. Reduced preferential flow under wet conditions was attributed to a combination of soil swelling, due to smectite-rich clay (that reduced macropore volume), and pore ice blockage within macropores. In comparison, dry soil column experiments demonstrated that macropores provided conduits for water and thermal energy to bypass the frozen matrix during infiltration, reducing thaw rates compared with non-macroporous soils. Overall, results showed the dominant control of antecedent moisture content on the initiation, timing, and magnitude of infiltration and flow in frozen macroporous soils, as well as the important role of macropore connectivity. The study provides an important data set that can aid the development of hydrological models that consider the interacting effects of soil freeze–thaw and preferential flow on snowmelt partitioning in cold regions.     

Spatiotemporal variations of dissolved inorganic carbon and controlling factors in a small karstic catchment,Southwestern China

Dissolved inorganic carbon (DIC) is the most important carbon component in karst aquatic system where fluid is highly transmissive, but has rarely been examined in the subtropical karst critical zone (K-CZ). In this study, concentrations of dissolved solutes and isotopic compositions of DIC (δ¹³C_DIC) at 11 sites of a 73.4 km² karstic catchment in Southwestern China were analysed monthly in order to uncover the spatiotemporal variations of both DIC and its dominant sources, and to identify relevant controlling factors. Both DIC concentrations and δ¹³C_DIC were highly variable, ranging from 2.52 to 5.85 mmol l⁻¹ and from −15.7 to −4.5‰, respectively. DIC in underground water (UGW) was higher in concentration and more depleted in ¹³C compared to surface water (SFS). DIC concentrations showed an inconsistent seasonal trend with other solutes, with higher values in the wet season at some sites. δ¹³C_DIC values were lower in the wet season than in the dry season. The results of mixing model IsoSource revealed spatiotemporal patterns of DIC sources. During the dry season, carbonate weathering was the primary contributor to DIC in UGW (excluding in the middle reaches). However, during the wet season, soil CO₂ was the dominant source of DIC in both UGW and SFS, and it was higher than in the dry season. Overall, there are significant spatiotemporal disparities and highly transmissive characteristics of both DIC and its sources in the K-CZ, which are controlled by multiple factors. This study also highlights that rainfall may play a crucial role in accelerating carbon dynamics in the K-CZ. High-frequency sampling campaigns in high-flow periods and deep analyses are needed in future work to elucidate the related processes and mechanisms. © 2019 John Wiley & Sons, Ltd.     

Alkalinity and dissolved inorganic carbon exports from tropical and subtropical river catchments discharging to the Great Barrier Reef,Australia

Dissolved inorganic carbon (DIC) transport by rivers is an important control on the pH and carbonate chemistry of the coastal ocean. Here, we combine DIC and total alkalinity (TAlk) concentrations from four tropical rivers of the Great Barrier Reef region in Australia with daily river discharge to quantify annual river loads and export rates. DIC in the four rivers ranged from 284 to 2,639 μmol kg⁻¹ and TAlk ranged from 220 to 2,612 μmol kg⁻¹. DIC:TAlk ratios were mostly greater than one suggesting elevated exports of free [CO₂*]. This was pronounced in the Johnstone and Herbert rivers of the tropical wet north. The largest annual loads were transported in the two large river catchments of the southern Great Barrier Reef region, the Fitzroy and Burdekin rivers. The carbon stable isotopic composition of DIC suggests that carbonate weathering was the dominant source of DIC in the southern rivers, and silicate weathering was likely a source of DIC in the northern Wet Tropics rivers. Annual loads and export rates were strongly driven by precipitation and discharge patterns, the occurrence of tropical cyclones, and associated flooding events, as well as distinct seasonal dry and wet periods. As such, short-lived hydrological events and long-term (seasonal and inter-annual) variation of DIC and TAlk that are pronounced in rivers of the tropical and subtropical wet and dry climate zone should be accounted for when assessing inorganic carbon loads to the coastal ocean and the potential to buffer against or accelerate ocean acidification.     

Alkalinization and acidification of stream water with changes in atmospheric deposition in a tropical dry evergreen forest of northeastern Thailand

Field surveys on atmospheric deposition and stream water chemistry were conducted in an evergreen forest in northeastern Thailand characterized by a tropical savanna climate with distinct dry and wet seasons. Atmospheric deposition of ion constituents by throughfall and stemflow was shown to increase in the beginning and end of the wet season, reflecting the precipitation pattern. The pH and electrical conductivity of stream water increased with alkalinity and base cation concentrations due to mineralization of organic matter by the first rain and retention of anions in soil during the start of the wet season. After initial alkalinization, the pH and alkalinity declined rapidly with the highest SO₄^2? concentration displayed in the middle towards the end of the wet season. The magnitude of peaks in SO₄^2? concentration (13.5–60.6 μmol_c/L) reflects deposition during the first 2 months of the wet season (March and April) in respective years (60.8–170 mol_c/ha). Release of SO₄^2? with H⁺, which is retained in soil during the early wet season, may cause acidification later in the season. The deposition and concentration of SO₄^2? declined over 6 years. However, the pH of stream water declined with increasing concentrations of SO₄^2? and other major ions. The release of materials accumulated in the ecosystem was facilitated by the decrease in SO₄^2? concentration/deposition and increased precipitation in the middle–late wet season. The retention‐release cycle of SO₄^2? largely contributed to both seasonal and interannual variations in stream water chemistry in the tropical savanna climate studied.