Hydrochemistry of carbonate terrains in alpine glacial settings

Nearly 200 analyses of meltwaters, ice and snow from three alpine glacial sites in carbonate terrain are summarized and discussed in terms of sources of solutes and kinetic controls on the progress of weathering reactions. Most data derive from the Swiss Glacier de Tsanfleuron which is based on Cretaceous and Tertiary pure and impure limestones. Two other sites (Marmolada, Italian Dolomites and the Saskatchewan Glacier, Alberta) are based on a mixed calcitic-dolomitic substrate. Most solutes originate from carbonate dissolution; moreover, where pyrite is present its oxidation supplies significant sulphate and forces more dissolution of carbonate. The ratios Sr²⁺/Ca²⁺ and Mg²⁺/Ca²⁺ are much higher in Tsanfleuron melt-waters than local bedrock, a phenomenon that can be reproduced in the laboratory at small percentages of dissolution. These anomalous ratios are attributed to incongruent dissolution of traces of the metastable carbonates Mg-calcite and aragonite. These phases also provide Na⁺ to solution. K⁺ is argued to originate mainly by ion-exchange on clays with solute Ca²⁺. Quartz and very minor feldspar dissolution are also inferred. Locally enhanced input from atmospheric sources is recognized by high Cl^? and associated Na⁺. The progress of weathering reactions has been evaluated by the trends in the data, computer modelling and some simple laboratory experiments. The most dilute samples show a trend towards removal of CO₂ to low partial pressures (c. 10^?5.5 atmospheres), reflecting initially rapid carbonate dissolution and relatively slow dissolution of gaseous CO₂. Later addition of atmospheric CO₂ or acid from pyrite oxidation allows further carbonate dissolution, but solutions show a wide range of saturations, and CO₂ pressures as high as 10^?2.2 where pyrite oxidation is important. In a carbonate terrain, measurement of electroconductivity (corrected to 25°C) and alkalinity in the field allows the following preliminary deductions (where meq stands for milliequivalents): where S is the minimum meq(Ca²⁺ + Mg²⁺) produced by simple dissolution of carbonate unconnected with pyrite oxidation. As with any proxy method, these deductions do not remove the need for chemical analysis of waters in a given study area.     

Scale effects of Hortonian overland flow and rainfall–runoff dynamics in a West African catena landscape

Hortonian runoff was measured from plots with lengths of 1·25 and 12 m, and at watershed level for rainstorms during the 1996 rainy season in cental Côte d'Ivoire, Africa. A clear reduction in runoff coefficients was found with increasing slope lengths, giving order of magnitude differences between runoff measurements at point level (1 m²: 30–50% of total rain) and watershed level (130 ha: 4% of total rain). Runoff reduction from 1·25 and 12 m slopes was reproduced for each major runoff‐producing rainstorm at two different sets of plots, but the reduction was erratic for rainfall events which produced little runoff. In addition, runoff reduction varied wildly from one rainstorm to the next. In the analysis, we show that the spatial variability of runoff parameters causes the erratic behaviour during rainstorms with little runoff. During the more important, larger runoff‐producing events, which give 78% of total runoff, the temporal dynamics of the rainfall–runoff process determine the reduction of runoff coefficients from longer slopes. A simple infiltration/runoff model was used to simulate the field results, thereby confirming the importance of rainfall dynamics as an explanatory factor for measured reduction of runoff coefficients. Copyright © 2000 John Wiley & Sons, Ltd.