鲁西莱芜矿山岩浆杂岩体源区及成因：地球化学、Sr-Nd-Pb及锆石Hf同位素约束

为限定鲁西莱芜地区典型矽卡岩矿床成矿岩体的岩浆源区及岩石成因,对矿山岩浆杂岩体开展了锆石U-Pb年代学、全岩地球化学、全岩Sr-Nd-Pb及锆石Hf同位素研究。结果显示,该岩体形成于早白垩世(131±1～129±1 Ma),具高镁埃达克质岩石特征,富集LREE和LILEs(Rb、Ba、K、Sr),亏损HREE和HFSEs(Nb、Ta、Ti、P),Eu负异常不明显或有弱的正异常。岩石具有较高的(⁸⁷Sr/⁸⁶Sr)_i比值(0.706 728～0.707 867)和较低的ε_Nd(t)值(-17.67～-13.84)、ε_Hf(t)值(-19.1～-12.2);(²⁰⁶Pb/²⁰⁴Pb)_i为16.833～16.955、(²⁰⁷Pb/²⁰⁴Pb)_i为15.339～15.346和(²⁰⁸Pb/²⁰⁴Pb)_i...     

Petrogenesis of ore-bearing porphyry of a porphyry Cu deposit at Mujicun in the North China Craton and its geological implicationsSCIEI北大核心CSCD

国内外学者对发育于弧环境和碰撞造山环境的斑岩铜矿成岩机制已取得了深刻的理解,但对产出在克拉通内部的斑岩铜矿成岩机制在认识上还有所欠缺。本文报道了侵位于144Ma木吉村斑岩铜矿内的含矿闪长玢岩的岩石地球化学资料,以揭示木吉村斑岩铜矿的含矿斑岩成因。岩石地球化学资料显示:含矿闪长玢岩具有较低的(^(87)Sr/^(86)Sr)i值(0.70599~70690)和εNd(t)值(-19.4~-14.9),富集轻稀土元素(LREEs)和大离子亲石元素(LILEs),相对亏损元素Y和Yb。木吉村含矿斑岩与王安镇杂岩体镁铁质岩(辉石岩、角闪石岩、辉长岩、辉长闪长岩、安山岩)具有相似的微量元素配分模式、Sr-Nd同位素组成及亲EMⅠ地幔特征,这些岩浆岩呈现持续性的成份演化趋势,反映出它们的同源性。木吉村含矿斑岩及相关的镁铁质岩石具有相对较低的(^(87)Sr/^(86)Sr)i值(0.70564~706897)和εNd(t)值(-19.4~-13.8),显著区别于中上地壳同位素区域。含矿斑岩起源于伸展背景下富集地幔部分熔融形成的玄武质岩浆,其上升过程中遭受了一定程度的下地壳混染。玄武质岩浆在深部岩浆房发生堆晶作用形成具典型堆晶结构的角闪石岩等基性岩,随后在浅部岩浆房经历两阶段辉长岩-辉长闪长岩、安山岩-闪长玢岩系列分离结晶作用形成含矿斑岩。此过程可能是形成华北克拉通木吉村斑岩铜矿含矿斑岩的机制和动力诱因。     

安徽省铜陵桂山铜铅锌矿C-H-O-S-Pb 同位素地球化学特征及其意义

安徽铜陵桂山铜铅锌矿床是铜陵矿集区沙滩脚矿田内近年来新发现的以铜矿为主,伴生铅锌矿的中小型多金属矿床,该矿床的矿体主要赋存于三叠系南陵湖组灰岩与青山花岗闪长斑岩体接触带附近及花岗闪长斑岩体内。本文在对该矿床地质特征的研究基础上,对代表性（岩）矿石进行碳、氢、氧、硫、铅同位素研究分析,据此约束该矿床的成矿流体和成矿物质来源。研究成果显示, 桂山铜铅锌矿床中方解石样品中δ¹³C_V-PDB 值为−3.2‰～2.0‰ 间,δ¹⁸O_V-SMOW 为8.3‰～15.2‰ 间,石英流体包裹体水的δD_V-SMOW 为−112.6‰～−6.8‰,δ¹⁸O_V-SMOW 为10.5‰～14.7‰,矿石中硫化物δ³⁴S值变化范围为−0.9‰～4.1‰,具塔式分布特征,矿石铅中的²⁰⁶Pb /²⁰⁴Pb 比值为18.409～18.585,²⁰⁷Pb /²⁰⁴Pb 比值为15.588～15.703,²⁰⁸Pb /²⁰⁴Pb 比值为38.483～38.843,以上指示了桂山铜铅锌矿床的成矿流体主要来源于岩浆水,并有大气降水的加入。分异成矿流体的岩浆可能来源于地幔,且伴有上地壳物质混入的特点。岩浆-地幔的溶解作用,伴有地层中碳质的混入。     

西北天山莱历斯高尔岩体年代学、地球化学及其成因

西北天山莱历斯高尔岩体主要由花岗闪长斑岩和二长花岗斑岩组成,二者具有相似的地球化学特征,可能为同源岩浆分异演化的产物。锆石SHRIMP U-Pb年龄显示岩体形成于晚泥盆世(374±4 Ma)。莱历斯高尔岩体具有较高的SiO₂(67.75% ～74.71%)含量和K₂O/Na₂O(1.24～2.20)比值,属于高钾钙碱性系列。稀土元素配分曲线为轻稀土富集型(La/Yb)_N(5.25～10.57),具有中等-弱的Eu负异常δEu(0.55～0.92)。微量元素特征显示富集大离子亲石元素(LILE),而亏损高场强元素(HFSE),具有较低的Sr(122×10^-6～356×10^-6)含量、较高的Y(17.19×10^-6～21.82×10^-6)和Yb(1.78×10^-6～2.57×10^-6)含量。岩体的Sr-Nd同位素特征为I_Sr=0.707 867～0.709 654,ε_Nd(t)=-2.79～-1.46。铅同位素特征为²⁰⁶Pb/²⁰⁴ Pb=18.423～19.915,²⁰⁷ Pb/²⁰⁴Pb=15.576～15.685,²⁰⁸ Pb/²⁰⁴Pb=38.344～39.305。元素和同位素地球化学特征表明,莱历斯高尔岩体岩浆源区主要为中元古代下地壳的部分熔融,并有部分地幔物质的加入。岩体形成于晚泥盆世准噶尔洋向伊犁-中天山微板块陡角度俯冲的大陆弧构造环境。     

鄂东南地区程潮大型矽卡岩型铁矿区岩体成因探讨

湖北程潮铁矿是鄂东南矿集区内最大的矽卡岩型铁矿床。为了系统研究矿区内不同侵入体的成因,对程潮矿区内不同时代的侵入体进行了矿物学、地球化学和Sr-Nd-Pb同位素研究。矿区内花岗岩、石英二长斑岩、闪长岩中的黑云母成分特征暗示它们均为壳幔物质混合成因的镁质黑云母;与成矿相关的花岗岩、石英二长斑岩中原生黑云母矿物学成分显示出原始岩浆具有高氧逸度的特征,高氧逸度为磁铁矿的形成提供了有利条件。岩石地球化学特征研究表明,不同类型的岩石都具有富钾和准铝质的特征,富集Rb、Ba、K等大离子亲石元素和轻稀土元素,亏损Nb、Ta、Ti等高场强元素。矿区岩石的(⁸⁷Sr/⁸⁶Sr)_i值为0.705 0~0.709 1,ε_Nd(t)值为-14.16~-6.95,²⁰⁶Pb/²⁰⁴Pb值为17.636~18.919,²⁰⁷Pb/²⁰⁴Pb值为15.451~15.613,²⁰⁸Pb/²⁰⁴Pb值为37.833~39.556。矿物学、地球化学、Sr-Nd-Pb同位素特征暗示矿区岩体为富集地幔发生部分熔融并同化混染了不同比例下地壳物质的产物,早期闪长岩（（140±1） Ma）比晚期花岗岩和石英二长斑岩（（128±1） Ma）的源区有更多的地幔成分,花岗岩和石英二长斑岩与闪长岩具有相近的锆石饱和温度（平均值分别为783、788、765℃）。     

西藏则不吓铅锌矿床硫、铅同位素组成及对成矿物质来源的指示

西藏则不吓铅锌矿床位于冈底斯成矿带北缘西部,矿体主要赋存于古近系林子宗群典中组火山碎屑岩中。在分析成矿地质条件的基础上,系统地研究该矿床矿石硫、铅同位素组成特征,探讨其成矿物质来源。结果表明,则不吓铅锌矿床金属硫化物样品的δ³⁴S值变化于-0.6‰～2.7‰之间,变化范围较窄,具有明显的塔式分布特征,显示硫来源较单一,具有岩浆硫的特征,可能与区内花岗斑岩及深部相关的隐伏岩体有关。矿石铅的²⁰⁶Pb/²⁰⁴Pb、²⁰⁷Pb/²⁰⁴Pb和²⁰⁸Pb/²⁰⁴Pb同位素比值十分稳定,变化范围较小,具正常铅特征;根据铅同位素μ值(9.61～10.0)和构造演化模式图投图结果,反映该矿床矿石铅主要来自于上地壳物质。结合区域成岩成矿事件和矿区地质特征,认为该矿床成矿物质很可能来源于印亚大陆主碰撞时期上地壳部分熔融形成的中酸性岩浆。     

云南中甸红山铜-多金属矿床新生代热泉喷流沉积型矿床

红山铜-多金属矿床位于滇西中甸红山一带,主矿体是一个石榴子石型夕卡岩矿床。野外考察中发现了一个叠加在夕卡岩矿体之上的热泉喷流构造,它保存了具典型热泉喷流特征的喷口。喷口附近产出近水平层状的含铁硅质岩中硫化物的硫同位素δ³⁴S为3.73‰~5.57‰,平均值5.08‰;铅同位素²⁰⁶Pb/²⁰⁴Pb和²⁰⁷Pb/²⁰⁴Pb比值分别为18.670~18.808和15.614~15.784,其硫、铅同位素组成与滇西地区喜马拉雅期斑岩和斑岩矿床的硫、铅同位素组成相似,暗示红山矿区有新生代的岩浆活动和成矿作用。该区新生代热泉喷流成矿作用的发现既丰富了对滇西中甸地区成矿作用的认识,也对红山铜-多金属矿床的成因有了更全面的了解,为该区进一步扩展找矿远景提供了重要依据。     

浙江治岭头钼铅锌金多金属矿床矿质来源的硫、铅同位素示踪及成矿时代

治岭头矿床上部(火山岩盖层)以铅锌矿床、硫矿床为主,中间(变质岩基底)以金银矿、铅锌矿为主,深部(侵入岩体)以斑岩型钼矿床为主的"三层楼"模式。本文在前人研究的基础上,通过辉钼矿Re-Os同位素定年技术对治岭头矿床进行了成矿时代的厘定。6件辉钼矿样品的模式年龄为113.7～114.6 Ma,加权平均年龄为114.03±1.78 Ma,表明治岭头钼多金属矿床成矿作用发生于早白垩世晚期。该矿床辉钼矿样品的Re含量变化于16.05×10^-6～66.29×10^-6,表明其成矿物质具有壳幔混源的特征。矿石硫同位素组成变化范围较窄(-2.1‰～2.6‰),具有相对均一的来源,可能主要来自上地幔或下地壳的深源岩浆,但也可能受到陆壳沉积物的混染。治岭头钼铅锌金多金属矿床矿石铅同位素组成变化范围比较小,²⁰⁸Pb/²⁰⁴Pb、²⁰⁷Pb/²⁰⁴Pb、²⁰⁶Pb/²⁰⁴Pb的范围分别为38.765～39.137、15.523～15....     

浙江常山里山岭斑岩型铜矿床成岩时代及岩浆源区

浙江是非金属矿大省,金属矿特别是斑岩型矿床的研究亟待进行。本文以里山岭斑岩型铜矿床为研究对象,首次采用SHRIMP U-Pb对该岩体侵位时代进行精确限定,利用Sr-Nd同位素示踪含矿岩体的岩浆源区,不仅为浙江斑岩型矿床成因的深入研究增加了新资料,还对浙西下一步找矿勘探具有重要意义。浙江常山里山岭斑岩型铜矿床位于钦杭成矿带东段,受球川-萧山深断裂带控制。该矿床铜矿化主要赋存于花岗斑岩体中。含矿花岗斑岩为高硅、富碱、高分异、过铝质S型花岗岩。岩体的稀土分布型式右倾,整体呈“海鸥型”,有明显负Eu异常。岩石亏损Sr、Ba等大离子亲石元素,富集Nb、Ta、Zr、Hf、Ti、Y、Yb等高场强元素。含矿花岗斑岩锆石SHRIMP U-Pb年龄为（131±2）Ma,为早白垩世构造-岩浆活动的产物,形成于中国东部岩石圈减薄背景。岩浆岩（⁸⁷Sr/⁸⁶Sr）_i值为0.679 95~0.721 08,平均0.701 14。ε_Nd（t）值为-8.4~-5.8,平均-6.7。Sr-Nd同位素特征表明含矿花岗斑岩源区主要为地壳,兼有少量地幔物质的混染。     

湘中龙山Au-Sb矿床成矿物质来源——来自S、Pb和Sr同位素证据

龙山Au-Sb矿床是湘中Au、Sb矿集区的代表性矿床,本文对其不同类型矿石、矿区围岩和区域地层进行了S、Pb、Sr同位素组成对比研究。矿石中硫化物的δ³⁴S值为-3.0‰～5.1‰,平均值2.3‰;矿区围岩的δ³⁴S值为4.0‰～5.9‰,平均值5.2‰;区域地层的δ³⁴S值为9.3‰～13.3‰,平均值11.3‰。矿石与矿区围岩、区域地层的硫同位素组成差别较大,矿石硫具岩浆来源特征。矿石中硫化物的²⁰⁶Pb/²⁰⁴Pb、²⁰⁷Pb/²⁰⁴Pb和²⁰⁸Pb/²⁰⁴Pb比值分别为16.992～18.457、15.392～15.722和37.586～38.960,矿区围岩的²⁰⁶Pb/²⁰⁴Pb、²⁰⁷Pb/²⁰⁴Pb和²⁰⁸Pb/²⁰⁴Pb比值分别为17.630～...     

Geochemical and Sr–Nd–Pb isotopic compositions of the Eocene Dölek and Sariçiçek Plutons, Eastern Turkey: Implications for magma interaction in the genesis of high-K calc-alkaline granitoids in a post-collision extensional setting

The major and trace elements and Sr–Nd–Pb isotopes of the host rocks and the mafic microgranular enclaves (MME) gathered from the Dölek and Sariçiçek plutons, Eastern Turkey, were studied to understand the underlying petrogenesis and geodynamic setting. The plutons were emplaced at  43 Ma at shallow depths ( 5 to 9 km) as estimated from Al-in hornblende geobarometry. The host rocks consist of a variety of rock types ranging from diorite to granite (SiO₂ = 56.98–72.67 wt.%; Mg# = 36.8–50.0) populated by MMEs of gabbroic diorite to monzodiorite in composition (SiO₂ = 53.21–60.94 wt.%; Mg# = 44.4–53.5). All the rocks show a high-K calc-alkaline differentiation trend. Chondrite-normalized REE patterns are moderately fractionated and relatively flat [(La/Yb)_N = 5.11 to 8.51]. They display small negative Eu anomalies (Eu/Eu = 0.62 to 0.88), with enrichment of LILE and depletion of HFSE. Initial Nd–Sr isotopic compositions for the host rocks are ε_Nd(43 Ma) = − 0.6 to 0.8 and mostly I_Sr = 0.70482–0.70548. The Nd model ages (T_DM) vary from 0.84 to 0.99 Ga. The Pb isotopic ratios are (²⁰⁶Pb/²⁰⁴Pb) = 18.60–18.65, (²⁰⁷Pb/²⁰⁴Pb) = 15.61–15.66 and (²⁰⁸Pb/²⁰⁴Pb) = 38.69–38.85. Compared with the host rocks, the MMEs are relatively homogeneous in isotopic composition, with I_Sr ranging from 0.70485 to 0.70517, ε_Nd(43 Ma) − 0.1 to 0.8 and with Pb isotopic ratios of (²⁰⁶Pb/²⁰⁴Pb) = 18.58–18.64, (²⁰⁷Pb/²⁰⁴Pb) = 15.60–15.66 and (²⁰⁸Pb/²⁰⁴Pb) = 38.64–38.77. The MMEs have T_DM ranging from 0.86 to 1.36 Ga. The geochemical and isotopic similarities between the MMEs and their host rocks indicate that the enclaves are of mixed origin and are most probably formed by the interaction between the lower crust- and mantle-derived magmas. All the geochemical data, in conjunction with the geodynamic evidence, suggest that a basic magma derived from an enriched subcontinental lithospheric mantle, probably triggered by the upwelling of the asthenophere, and interacted with a crustal melt that originated from the dehydration melting of the mafic lower crust at deep crustal levels. Modeling based on the Sr–Nd isotope data indicates that  77–83% of the subcontinental lithospheric mantle involved in the genesis. Consequently, the interaction process played an important role in the genesis of the hybrid granitoid bodies, which subsequently underwent a fractional crystallization process along with minor amounts of crustal assimilation, en route to the upper crustal levels generating a wide variety of rock types ranging from diorite to granite in an extensional regime.     

山西梨园金矿黄铁矿微量元素及S-Pb-He-Ar同位素地球化学特征及其地质意义

山西梨园金矿是近年华北克拉通内部金矿找矿的新进展,其矿化样式多,具有较高的研究价值。梨园金矿赋存于太古宙阜平群片麻岩和混合岩化花岗岩中,受区内北北东向断裂控制,主要由爆破角砾岩型的1号矿体和石英脉型的2号矿体组成。矿石矿物主要为黄铁矿、方铅矿和闪锌矿等,脉石矿物主要为石英、绢云母、钾长石等,蚀变类型主要为硅化、钾长石化、绢云母化、绿泥石化等。黄铁矿、黄铜矿和闪锌矿δ³⁴S值为0.9‰~4.3‰,平均值为3.0‰,说明硫源主要来自岩浆;方铅矿δ³⁴S值为-12.8‰~1.4‰,平均值为-4.2‰,pH值升高可能是造成方铅矿高负δ³⁴S值的原因。金属硫化物Pb同位素变化范围较小,²⁰⁶Pb/²⁰⁴Pb为16.697~16.890,²⁰⁷Pb/²⁰⁴Pb为15.239~15.267,²⁰⁸Pb/²⁰⁴Pb为42.186~45.334,均落入下地壳演化线附近,表明成矿流体运移过程中可能淋滤了富Th的下地壳物质。黄铁矿的³He/⁴He为0.27~1.04 R_a,⁴⁰Ar/³⁶Ar为1 194.61~5 488.80,³⁸Ar/³⁶Ar为0.204~0.218,表明成矿流体主要来源于地壳,部分来源于地幔流体,具有壳幔混合的岩浆流体特点。微量元素特征显示黄铁矿具有岩浆热液型黄铁矿的特点,辉绿岩脉和石英斑岩的部分物质可能加入了成矿过程。文章认为梨园金矿为与浅成岩浆侵入作用相关的岩浆热液型金矿床,爆破角砾岩型和石英脉型矿体不同的沉淀机制和矿物结晶过程是导致二者REE含量、S-Pb-He-Ar同位素等方面存在差异的主要原因。梨园金矿深部具有寻找细脉浸染型矿体的可能,其成矿作用是太行山中部地区燕山期构造岩浆活动的又一具体表现。     

Isotopic equilibrium/disequilibrium in granites, metasedimentary rocks and migmatites (Damara orogen, Namibia)—a consequence of polymetamorphism and melting

The overwhelming part of the continental crust in the high-grade part of the Damara orogen of Namibia consists of S-type granites, metasedimentary rocks and migmatites. At Oetmoed (central Damara orogen) two different S-type granites occur. Their negative ε_Nd values (− 3.3 to − 5.9), moderately high initial ⁸⁷Sr/⁸⁶Sr ratios (0.714–0.731), moderately high ²⁰⁶Pb/²⁰⁴Pb (18.21–18.70) and ²⁰⁸Pb/²⁰⁴Pb (37.74–37.89) isotope ratios suggest that they originated by melting of mainly mid-Proterozoic metasedimentary material. Metasedimentary country rocks have initial ε_Nd of − 4.2 to − 5.6, initial ⁸⁷Sr/⁸⁶Sr of 0.718–0.725, ²⁰⁶Pb/²⁰⁴Pb ratios of 18.32–18.69 and ²⁰⁸Pb/²⁰⁴Pb ratios of 37.91–38.45 compatible with their variation in Rb/Sr, U/Pb and Th/Pb ratios. Some migmatites and residual metasedimentary xenoliths tend to have more variable ε_Nd values (initial ε_Nd: − 4.2 to − 7.1), initial Sr isotope ratios (⁸⁷Sr/⁸⁶Sr: 0.708–0.735) and less radiogenic ²⁰⁶Pb/²⁰⁴Pb (18.22–18.53) and ²⁰⁸Pb/²⁰⁴Pb (37.78–38.10) isotope compositions than the metasedimentary rocks. On a Rb–Sr isochron plot the metasedimentary rocks and various migmatites plot on a straight line that corresponds to an age of c. 550 Ma which is interpreted to indicate major fractionation of the Rb–Sr system at that time. However, initial ⁸⁷Sr/⁸⁶Sr ratios of the melanosomes of the stromatic migmatites (calculated for their U–Pb monazite and Sm–Nd garnet ages of c. 510 Ma) are more radiogenic (⁸⁷Sr/⁸⁶Sr: 0.725) than those obtained on their corresponding leucosomes (⁸⁷Sr/⁸⁶Sr: 0.718) implying disequilibrium conditions during migmatization that have not lead to complete homogenization of the Rb–Sr system. However, the leucosomes have similar Nd isotope characteristics than the inferred residues (melanosomes) indicating the robustness of the Sm–Nd isotope system during high-grade metamorphism and melting. On a Rb–Sr isochron plot residual metasedimentary xenoliths show residual slopes of c. 66 Ma (calculated for an U–Pb monazite age of 470 Ma) again indicating major fractionation of Rb/Sr at c. 540 Ma. However, at 540 Ma, these xenoliths have unradiogenic Sr isotope compositions of c. 0.7052, indicating depleted metasedimentary sources at depth. Based on the distinct Pb isotope composition of the metasedimentary rocks and S-type granites, metasedimentary rocks similar to the country rocks are unlikely sources for the S-type granites. Moreover, a combination of Sr, Nd, Pb and O isotopes favours a three-component mixing model (metasedimentary rocks, altered volcanogenic material, meta-igneous crust) that may explain the isotopic variabilty of the granites. The mid-crustal origin of the different types of granite emphasises the importance of recycling and reprocessing of pre-existing differentiated material and precludes a direct mantle contribution during the petrogenesis of the orogenic granites in the central Damara orogen of Namibia.     

云南中甸地苏嘎印支期斑岩地球化学特征及其成矿标识

地苏嘎印支期斑岩体位于中甸岛弧东斑岩带的北端,岩性为石英闪长玢岩,与普朗超大型斑岩铜矿的成矿岩体同属于甘孜—理塘洋壳俯冲作用晚期岩浆活动的产物。全岩地球化学特征显示,地苏嘎石英闪长玢岩具有中等的SiO₂含量,较高的Al₂O₃及全碱(K₂O+Na₂O)含量。全岩亏损高场强元素,富集大离子亲石元素,稀土元素配分曲线呈典型的右倾状,显示出轻稀土富集、重稀土相对亏损的特点。主量元素和微量元素成矿指示方面的研究结果表明:与普朗38个与成矿有关的石英闪长玢岩的全岩数据相比,地苏嘎石英闪长玢岩具有相对较低的SiO₂和Y含量、较高的∑REE和(La/Yb)_N比值,但二者的Al₂O₃/(CaO+Na₂O+K₂O)比值及MnO含量差别不大。在成矿与非成矿斑岩的SiO₂- Al₂O₃/(CaO+Na₂O+K₂O)和Y-MnO图解中,地苏嘎石英闪长玢岩与普朗石英闪长玢岩数据投图结果类似。此外,地苏嘎斑岩体在物探异常、化探异常及遥感影像特征上具有明显的矿化标志,同时岩体的剥蚀深度小于侵位深度,有利于矿床的保存。以上研究结果表明地苏嘎斑岩体具有成为斑岩型铜矿床的潜力。     

Geochemical and isotope data from the Acatlán Volcanic Field, western Trans-Mexican Volcanic Belt: Origin and evolution

The Quaternary Acatlán Volcanic Field (AVF) is located at the western edge of the Trans-Mexican Volcanic Belt (TMVB). This region is related to the subduction of the Pacific Cocos and Rivera plates beneath the North American plate since the late Miocene. AVF rocks are products of Pleistocene volcanic activity and include lava flows, domes, erupted basaltic andesite, trachyandesite, trachydacite, and rhyolite of calc–alkaline affinity. Most rocks show depletion in high field-strength elements and enrichment in large ion lithophile elements and light rare earth elements as is typical for magmas in subduction-related volcanic arcs. ⁸⁷Sr/⁸⁶Sr values range from 0.70361 to 0.70412, while Nd values vary from +2.3 to +5.2. Sr–Nd isotopic data plot along the mantle array. On the other hand, lead isotope compositions (²⁰⁶Pb/²⁰⁴Pb=18.62–18.75, ²⁰⁷Pb/²⁰⁴Pb=15.57–15.64, and ²⁰⁸Pb/²⁰⁴Pb=38.37–38.67) give evidence for combined influences of the upper mantle, fluxes derived from subducted sediments, and the upper continental crust involved in magma genesis at AVF. Additionally δ¹⁸O whole rock analyses range from +6.35‰ in black pumice to +10.9‰ in white pumice of the Acatlán Ignimbrite. A fairly good correlation is displayed between Sr as well as O isotopes and SiO₂ emphasizing the effects of crustal contamination. Compositional and isotopic data suggest that the different AVF series derived from distinct parental magmas, which were generated by partial melting of a heterogeneous mantle source.     

滇西北普朗铜矿床高钾中-酸性侵入岩年代学及其地质意义

普朗铜矿床是格咱岛弧产出的超大型斑岩型铜矿床,以往较多关注于含矿的石英二长斑岩,而对矿区出露的闪长岩、花岗闪长斑岩研究相对薄弱.对普朗矿区的闪长岩和花岗闪长斑岩开展了地球化学和锆石年代学分析,结果显示,闪长岩SiO₂含量为62.46%~62.25%,K₂O含量为5.53%~6.27%,MgO含量为3.58%~3.69%,（Na₂O+K₂O）总碱含量为7.93%~8.72%,K₂O/Na₂O>2,属中性超钾质碱性岩;花岗闪长斑岩SiO₂含量为66.00%~66.98%,K₂O含量为4.06%~4.19%,MgO含量为2.04%~2.17%,（Na₂O+K₂O）总碱含量为7.60%~7.81%,K₂O/Na₂O>1,属酸性钾质碱性岩.花岗闪长斑岩与中甸地区火山岩具有一致的Sr-Nd同位素特征,而闪长岩ε_Nd（t）值变化范围大,二阶段模式年龄分散（369 Ma、913 Ma、1 138 Ma）,指示有富集组分的混入.闪长岩LA-ICPMS锆石U-Pb年龄为227.0±2.9 Ma;花岗闪长斑岩LA-ICPMS锆石U-Pb年龄为211.5±3.7 Ma.结合岩石主量、微量元素、全岩Sr-Nd同位素及锆石U-Pb年龄,提出甘孜-理塘洋在长时期的西向俯冲（约25 Ma）过程中,普朗矿区（局部）可能发生过由挤压向伸展构造体制的转换,激发幔源的岩浆活动,导致钾质碱性小岩体侵位,该过程对该超大型斑岩铜多金属矿的形成具有重要意义.      

Spinel-facies mantle xenoliths from Cerro Redondo, Argentine Patagonia: Petrographic, geochemical, and isotopic evidence of interaction between xenoliths and host basalt

Cerro Redondo is an ancient cinder cone now almost completely eroded, sited over a sill that corresponds to a sub-volcanic magma chamber, in Santa Cruz province, Patagonia, Argentina. It is composed of Pliocene-Pleistocene alkaline basalt containing spinel-facies lherzolite and harzburgite mantle xenoliths. Core compositions of pyroxenes indicate temperatures of 823 °C to 1043 °C and pressures of 12.4 kb to 21.4 kb. Based on P–T estimates, petrographic, geochemical, and isotopic characteristics, we propose that Cerro Redondo xenoliths come from a thick homogeneous mantle column (36 km to 63 km depth), and present different degrees of basalt infiltration. A simple mixing model based on Sr isotopes was used to quantify the host basalt infiltration, and contamination values of 0.0%, 0.2%, 3%, and 12% were obtained for samples X-F, X-D, X-C, and X-B, respectively. For unknown reasons, samples X-G and X-E suffered selective isotopic and trace element modification, respectively, associated with 1% of basalt infiltration. Sample X-F best represents the sub-continental lithospheric mantle column, conserving primary equilibrium textures with sharp grain boundaries, and having TiO₂, CaO, Na₂O, K₂O, and P₂O₅ contents lower than average spinel lherzolite, flat chondrite-normalized REE pattern, and ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd ratios of 0.70519 and 0.51297, respectively. This sample records a decoupling of the Sr–Nd system where Sr ratios increase at constant Nd ratios, possibly caused by chromatographic processes. Its ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb ratios are 17.987, 15.556, and 37.959, respectively. As the interaction with the host basalt increases, xenoliths show a gradual increase of disequilibrium textures such as reaction rims and exsolution lamellae in orthopyroxene and clinopyroxene, and increase of TiO₂, CaO, Al₂O₃, Na₂O, K₂O, P₂O₅, LREE, and incompatible element concentrations. The Sr–Nd system shows an unusual positive trend from the unmodified sample X-F toward the host basalt isotope composition with ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd ratios of 0.70447 and 0.51279, respectively, while ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb ratios tend to increase toward those of the host basalt (18.424, 15.648, and 38.728, respectively) as the xenolith–basalt interaction increases. The basalt–xenolith reaction probably started during the transport of the xenoliths to the surface, and continued during the residence of xenoliths in the sub-volcanic magma chamber of Cerro Redondo.