Characteristics of hydrothermal plumes from two vent fields on the Juan de Fuca Ridge, northeast Pacific Ocean

Deep CTD/transmissometer tows and water bottle sampling were used during 1985 to map the regional distribution of the neutrally-buoyant plumes emanating from each of two major vent fields on the Southern Symmetrical Segment (SSS) and Endeavour Segment (ES) of the Juan de Fuca Ridge. At both vent fields, emissions from point and diffuse hydrothermal sources coalesced into a single 200-m-thick plume elongated in the direction of current flow and with characteristic temperature anomalies of 0.02–0.05°C and light-attenuation anomalies of 0.01–0.08 m⁻¹ (10–80 μg/l above background). Temperature anomalies in the core of each plume were uniform as far downcurrent as the plumes were mapped (10–15 km). Downcurrent light-attenuation trends were non-uniform and differed between plumes, apparently because different vent fluid chemistries at each field cause significant differences in the settling characteristics of the hydrothermal precipitates. Vent fluids from the SSS are metal-dominated and mostly precipitate very fine-grained hydrous Fe-oxides that remain suspended in the plume. Vent fluids from the ES are sulfur-dominated and precipitate a high proportion of coarser-grained Fe-sulfides that rapidly settle from the plume. The integrated flux of each vent field was estimated from measurements of the advective transport of each plume. Heat flux was 1700 ± 1100 MW from the ES and 580 ± 351 MW from the SSS. Particle flux varied from 546 ± 312 g/s to 204 ± 116 g/s at the ES depending on distance from the vent field, and was 92 ± 48 g/s from the SSS.     

Water column anomalies associated with hydrothermal activity in the Guaymas Basin,Gulf of California

Sea floor hydrothermal activity in the Guaymas Basin, Gulf of California, is quite different from that associated with ridge crest spreading centers. Injection of hydrothermal fluids occurs in the bottom of a semi-enclosed basin and water column anomalies produced by this activity increase to much higher values than in the open ocean. In the Guaymas Basin the hydrothermal venting generates large clouds of fine suspended particulate matter (SPM) 100–300 m above active mounds and chimneys. These hydrothermal clouds have potential temperature anomalies of about 0.010–0.020°C, are enriched in dissolved silica, particulate manganese, and depleted in dissolved oxygen relative to areas away from the vents. The particulate manganese values increase from about 3 nmol/kg at ～ 1000 m, well above the enclosing topography of the subsill basin, to 100–150 nmol/kg in the clouds of SPM and in the bottom nepheloid layer. The particulate Mn in the hydrothermal clouds appears to originate from both direct precipitation of dissolved Mn²⁺ injected by the vents and entrainment of Mn-rich SPM in the rising hydrothermal plumes. Injection of silica-rich vent fluids into the basin bottom waters produces a silica anomaly of 10–15 μmol relative to the other deep basins of the Gulf of California. Spillover of Guaymas Basin deep water produces a silica plume just above the basin sill depth which is detectable to the mouth of the Gulf. A simple two-endmember mixing model indicates that the deep waters of the Guaymas Basin contain approximately 0.1% hydrothermal fluid. Oxygen anomalies associated with the hydrothermal clouds are on the order of 5 μmol relative to regions away from active vents. The basin as a whole shows a depletion in oxygen of about 13 μmol relative to the other deep basins of the Gulf. The mixing model shows that this oxygen consumption can be explained by the oxidation of dissolved sulfide and methane injected by the hydrothermal vents. Box models of the deep basins of the southern Gulf of California indicate that the Guaymas Basin has a significantly higher source term for dissolved silica and sink term for dissolved oxygen than the other basins. The calculated flux of hydrothermal fluids into the Guaymas Basin is 10–12 m³/s.     

Temperature, density and buoyancy fluxes in “black smoker” plumes, and the criterion for buoyancy reversal

Measurements of the temperature and composition of effluent from vents on the sea floor can be used to deduce the in-situ density of this fluid, which is required for calculations of flow in the chimneys and through their porous walls. This density is, however, not directly relevant when calculating the buoyancy flux in the plume above a smoker. It is the asymptotic buoyancy flux, following extensive dilution with seawater, which is required when estimating the height of rise of plumes in a stably stratified ocean, and when calculating the criterion for reversal of buoyancy due to non-linear mixing effects. The results of mixing calculations show that the effluent from hydrothermal vents on the sea floor will exhibit reversing buoyancy if the ejected fluid has a temperature of 300°C and a salinity greater than 8 wt.% NaCl. If the temperature of the effluent is 200°C the salinity required for reversing buoyancy falls to 5.5 wt.% NaCl. Measurements of temperature and salinities of sea-floor hydrothermal fluid suggest that fluids with the characteristics required to form reversing plumes are ejected at the sea floor. The possibility that reversing plumes may be found has important implications for the formation of massive sulfide deposits.     

洋壳渗透率结构对其内部热液对流的影响研究——基于热力学数值模拟

洋底特殊环境的限制使数值模拟成为研究海底热液对流与成矿机制的有效方法.本文通过数值模拟的方法,研究洋壳渗透率单因素变化对热液对流系统的形态和输出参数(热液喷发温度和热流值)进行研究.模拟结果表明,洋壳平均渗透率分别与热液喷发温度和热量输出呈反相关和正相关关系,符合达西流体热对流的基本解析规律.另外,洋壳渗透率的垂向变化不会使洋壳内部的对流系统产生明显的横向偏移,只使热液羽规模在垂向上产生规律性变化,且渗透率越大,热液羽规模越小.渗透率在水平方向的变化则是引发热液羽和热液喷发位置横向偏移的主要因素,且只有在特定的渗透率水平变化率范围内,上涌热液羽才会发生向高渗区的明显偏移,这也从一定程度上解释了现今拆离断层相关的热液系统均未发育于断层终止线上的事实.以大西洋Trans-Atlantic Geotraverse(TAG)热液区为例,断裂带高渗区必然影响相邻洋壳内部热液的上涌路径,但受区内拆离断裂带周缘的渗透率水平变化规律的影响,上涌热液羽不至于完全偏移至断裂带,从而产生拆离断层上盘的热液活动.     

Manganese geochemistry near high-temperature vents in the Mid-Atlantic Ridge rift valley

In July 1985 the first high-temperature, hydrothermal vents ever discovered on the MAR were found at 26°N (TAG). A transponder-navigated survey of a 4 × 8 km area was begun when on-board measurements of manganese revealed concentrated hydrothermal plumes in the water column comparable in size and intensity to those found over geothermal fields on the EPR. These plumes also possess anomalously high light scattering properties and anomalously warm potential temperatures. Using relay-transponder navigation with a rosette-CTD system, it was possible to sample bottom waters with temperature anomalies of several decidegrees. Samples collected near vent orifices possessed silica anomalies of up to 17 μM and dissolved manganese anomalies as large as 360 nmol/kg. These manganese and silica anomalies are linearly related and predict aMn/Si ratio of 20 mmol/mol for these MAR vent fluids, a value essentially identical to that measured in 350°C fluid from the EPR at 21°N. The distribution of temperature anomalies in the water column over this area requires the presence of more than one active vent site. A rough estimate of the convective heat loss from this section of the MAR based onθ-z profiles is 1.2 × 10⁸ cal/s which is similar to the heat loss estimated for the vent field on the EPR at 21°N.     

Real-time observation of dispersed hydrothermal plumes using nephelometry: examples from the Mid-Atlantic Ridge

As part of the 1984–1985 NOAA VENTS program on the Mid-Atlantic Ridge, nephelometry was used to provide real-time detection and tracking of dispersed hydrothermal plumes. At all nine 1984 study sites, hydrothermal activity was detected by in-situ, real-time nephelometer measurements and later confirmed by dissolved Mn and particulate Fe measurements. These same techniques were employed in a site-specific survey of the Trans-Atlantic Geotraverse (TAG) area in 1985 where large water-column anomalies in turbidity and in dissolved Mn helped lead to the discovery of high-temperature black smokers.The optical response of the nephelometer was to hydrothermally-derived particulate matter. Thus strong correlations existed between the nephelometer readings and total suspended matter (r = 0.98, n = 34), and particulate Fe (r = 0.88, n = 32). In addition, digital nephelometer data correlated well with dissolved Mn (r = 0.88; n = 78) throughout a large concentration range (0.2–31.0 nmol/kg).These data provide good evidence for the utility of in-situ nephelometer measurements for locating and surveying plumes from hydrothermal vents. It also appears possible, within limits, to predict concentrations of in-situ total suspended matter, of particulate Fe and of dissolved Mn.     

Variation of nutrients in response to the highly dynamic suspended particulate matter in the Changjiang (Yangtze River) plume

During four surveys at spring and neap tides in July and November 2005, continuous observations were conducted at four stations adjacent to the Changjiang (Yangtze River) mouth. The observation times lasted for 26 h that covered two consecutive semidiurnal cycles. Resuspension events and subsequently enhancements of suspended particulate matter (SPM) were commonly observed within a tidal cycle. Although nutrients (SiO₃²⁻, NO₃⁻, and PO₄³⁻) were primarily governed by salinity, their statistically significant correlations with SPM could always be extracted after partial correlation analysis. Three parameter (salinity, SPM, nutrients) regressions generally produced better results of simulating nutrient concentrations than two parameter (salinity and nutrients) regressions, although compared to the latter, the former R² values were elevated by no more than 13%. The partial correlation between SPM and a specific nutrient could be either positive or negative in different surveys, suggesting SPM influenced the nutrients in different ways under various conditions. The minor (albeit statistically significant) impacts of highly dynamic SPM on nutrients might be ascribed to the short duration time of resuspension events and estuarine mixing process, together with the complex nature of circulation in the Changjiang plume seawater.     

Reverse time migration using water-bottom-related multiples

Reverse time migration of multiples can be used to construct subsurface structures where primaries cannot illuminate well. However, the images generated using multiples suffer from severe artefacts due to the cross-talks created by interference among unrelated multiples. We developed a migration approach using water-bottom-related multiples to reduce these cross-talk artefacts. This approach first isolates primaries from the original data and predicts water-column primaries. The nth-order water-column multiples can be obtained by auto-convolving the water-column primaries n times, followed by convolving the nth-order water-column multiples with the primaries to extract the (n+1)th-order water-bottom-related multiples. The approach takes the nth-order water-column multiples as the secondary source and regards the (n+1)th-order water-bottom-related multiples as the receiver wavefield, followed by a cross-correlation imaging condition. Numerical examples from synthetic and field data sets reveal that our approach can provide images with substantially fewer cross-talk artefacts than conventional reverse time migration using multiples, as well as greatly improving shallow imaging compared with reverse time migration of primaries.     

The location of deep salinity sources in the Israeli Coastal aquifer

The salinization process of the Israeli Coastal aquifer has led to an average concentration of about 200 mgCl/l with a significant number of discrete salinity plumes in the middle and southern regions. The salinity of these plumes is high (500–1000 mgCl/l) and is increasing rapidly. Geochemical evidence has suggested that the salinity source in the Be'er Tuvia plume (in the south part of the aquifer) is at the bottom of the aquifer. This paper describes a solution of the source inverse problem and its application in the Be'er Tuvia plume. A transient two-dimensional finite element model was solved and the source terms were computed at each node in a 14×14 km² area. An error analysis has shown that when no errors are introduced in the input data the reconstruction is perfect. The results of a sensitivity analysis are presented and the actual reconstruction errors are estimated. Applying the model in the Be'er Tuvia region indicates that a salinity source exists about 1 km to the west and 1.5 km to the north of the center of the salinity plume. This source is believed to be the plume source.     

Flow rates in the axial hot springs of the East Pacific Rise (21°N): Implications for the heat budget and the formation of massive sulfide deposits

The first in-situ measurements of flow rates in submarine hot springs (temperatures between 275° and 350°C) were made in the hot springs of the East Pacific Rise at 21°N during November, 1981. The flow rates ranged between 0.7 and 2.4 m/s. We estimate that the total rates at which heat and mass are transported from the three hot spring areas—OBS, National Geographic, and Southwest Vents—are ca. 2.2×10⁸ W and 150 kg of fluid/s respectively. The very high rate of heat loss precludes the existence of hot springs as steady state features of the East Pacific Rise at 21°N. We estimate that hot springs are active for a maximum of ca. 40,000 years. Chemical and/or mechanical clogging of the vents can drastically reduce the lifetime of the hot springs.Using a simple model of plume development [1], we calculated that less than 3% of the sulfide particles that are entrained in the hydrothermal plumes at 21°N settle from the plumes before dispersal by a lateral submarine current at a height of ca. 250 m above the seafloor [2]. The time that is required to form the sulfide mounds that surround the hot springs by the accumulation of sulfide particles that settle from the plumes is ca. 70–85 years. The current rate at which sulfide particles settle from the hydrothermal plumes and accumulate near the hot springs appears to be too small to lead to the formation of large massive sulfide deposits such as the Mavrouni deposit on Cyprus [3], within the time limits that are suggested by our thermal energy balance calculations.     

Salinity sources of Kefar Uria wells in the Judea group aquifer of Israel. Part 2—quantitative identification model

The Kefar Uria group of wells have experienced an increase of salinity of the pumped water in the last two decades. The source of salinity is not known. Geohydrological and geochemical considerations of Part 1 (Avissar et al., in press) suggest two possible mechanisms and sources. The first source is infiltrating at the top of the aquifer, in contact with the overlaying formation and is close to the wells. The second source is deep and more distant and is attributed to salt leaching. In the present study, a methodology is developed in order to select the most probable source by quantitative modeling of flow and transport. The problem is more difficult than similar ones investigated in the literature, because of the complex three-dimensional flow pattern. However, simplified models can be used for the limited scope of source identification. The aquifer is modeled as a semi-infinite confined one under steady state conditions. The saline water input area and the 13 wells are represented by source distributions and an analytical solution is obtained for the flow field. A best fit between computed and measured well pressure heads leads to reasonable value of the identified permeability. Advective solute transport from salinity sources to wells is modeled numerically by particle tracking and leads to partition of solute flux among wells. Comparison of calculated wells salinity and the measured ones leads to the conclusive selection of one of the sources as the most probable one.     

Development of a hydrodynamic model of the Bay of Biscay. Validation of hydrology

The hydrology of the Bay of Biscay was investigated using the regional ocean model MARS3D (Model for Application at Regional Scale). The simulated hydrology is compared to a set of various data encompassing monthly climatology, remote sensing SST, CTD casts, and coastal salinity measurements. Special focus was put on the validation over the continental shelf. This paper reports that despite some misfits, the climatological hydrology and its seasonal variability are correctly simulated. Various statistics computed over the period from 1999–2004 highlight different aspects of the hydrology. The biases and root mean square errors (RMSE) remain very weak at all depths when comparing salinity (<0.1 and <0.6 psu respectively). The predicted temperature shows a global overestimation of temperature (bias of around 0.8 °C) and the maximum errors are located near the thermocline (rmse of 1 °C at 20–40 m). The model is shown to properly reproduce the annual dynamics of sea surface temperature, as well as the dynamics of large river plumes observed by high frequency time series from coastal salinity gauges. The misfits highlighted by these various comparisons between model and observations are attributed to heat fluxes and mixing parameterisation.     

From streambed temperature measurements to spatial‐temporal flux quantification: using the LPML method to study groundwater–surface water interaction

Knowledge on groundwater–surface water interaction and especially on exchange fluxes between streams and aquifers is an important prerequisite for the study of transport and fate of contaminants and nutrients in the hyporheic zone. One possibility to quantify groundwater–surface water exchange fluxes is by using heat as an environmlental tracer. Modern field equipment including multilevel temperature sticks and the novel open‐source analysis tool LPML make this technique ever more attractive. The recently developed LPML method solves the one‐dimensional fluid flow and heat transport equation by combining a local polynomial method with a maximum likelihood estimator. In this study, we apply the LPML method on field data to quantify the spatial and temporal variability of vertical fluxes and their uncertainties from temperature–time series measured in a Belgian lowland stream. Over several months, temperature data were collected with multilevel temperature sticks at the streambed top and at six depths for a small stream section. Long‐term estimates show a range from gaining fluxes of ?291 mm day^?1 to loosing fluxes of 12 mm day^?1; average seasonal fluxes ranged from ?138 mm day^?1 in winter to ?16 mm day^?1 in summer. With our analyses, we could determine a high spatial and temporal variability of vertical exchange fluxes for the investigated stream section. Such spatial and temporal variability should be taken into account in biogeochemical cycling of carbon, nutrients and metals and in fate analysis of contaminant plumes. In general, the stream section was gaining during most of the observation period. Two short‐term high stream stage events, seemingly caused by blockage of the stream outlet, led to a change in flow direction from gaining to losing conditions. We also found more discharge occurring at the outer stream bank than at the inner one indicating a local flow‐through system. With the conducted analyses, we were able to advance our understanding of the regional groundwater flow system. Copyright © 2015 John Wiley & Sons, Ltd.     

River plume patterns and dynamics within the Southern California Bight

Stormwater river plumes are important vectors of marine contaminants and pathogens in the Southern California Bight. Here we report the results of a multi-institution investigation of the river plumes across eight major river systems of southern California. We use in situ water samples from multi-day cruises in combination with MODIS satellite remote sensing, buoy meteorological observations, drifters, and HF radar current measurements to evaluate the dispersal patterns and dynamics of the freshwater plumes. River discharge was exceptionally episodic, and the majority of storm discharge occurred in a few hours. The combined plume observing techniques revealed that plumes commonly detach from the coast and turn to the left, which is the opposite direction of Coriolis influence. Although initial offshore velocity of the buoyant plumes was ∼50 cm/s and was influenced by river discharge inertia (i.e., the direct momentum of the river flux) and buoyancy, subsequent advection of the plumes was largely observed in an alongshore direction and dominated by local winds. Due to the multiple day upwelling wind conditions that commonly follow discharge events, plumes were observed to flow from their respective river mouths to down-coast waters at rates of 20–40 km/d. Lastly, we note that suspended-sediment concentration and beam-attenuation were poorly correlated with plume salinity across and within the sampled plumes (mean r²=0.12 and 0.25, respectively), while colored dissolved organic matter (CDOM) fluorescence was well correlated (mean r²=0.56), suggesting that CDOM may serve as a good tracer of the discharged freshwater in subsequent remote sensing and monitoring efforts of plumes.     

Excess3He in the deep water over the Mid-Atlantic Ridge at 26°N: evidence of hydrothermal activity

We have observed distinct and significant patterns of excess³He in bottom waters over the Mid-Atlantic Ridge in the “TAG hydrothermal field”. The lateral regional gradients are comparable in magnitude to gradients observed in the Galapagos rift, an area of confirmed hydrothermal activity. Together with this, the³He patterns, magnitudes and vertical gradients all indicate on-going and continuous hydrothermal activity.     

A Tiered Approach to Evaluating Salinity Sources in Water at Oil and Gas Production Sites

A suspected increase in the salinity of fresh water resources can trigger a site investigation to identify the source(s) of salinity and the extent of any impacts. These investigations can be complicated by the presence of naturally elevated total dissolved solids or chlorides concentrations, multiple potential sources of salinity, and incomplete data and information on both naturally occurring conditions and the characteristics of potential sources. As a result, data evaluation techniques that are effective at one site may not be effective at another. In order to match the complexity of the evaluation effort to the complexity of the specific site, this paper presents a strategic tiered approach that utilizes established techniques for evaluating and identifying the source(s) of salinity in an efficient step‐by‐step manner. The tiered approach includes: (1) a simple screening process to evaluate whether an impact has occurred and if the source is readily apparent; (2) basic geochemical characterization of the impacted water resource(s) and potential salinity sources coupled with simple visual and statistical data evaluation methods to determine the source(s); and (3) advanced laboratory analyses (e.g., isotopes) and data evaluation methods to identify the source(s) and the extent of salinity impacts where it was not otherwise conclusive. A case study from the U.S. Gulf Coast is presented to illustrate the application of this tiered approach.     

Spatial and temporal variability of seawater properties,current velocity and SPM concentration off Cassino Beach-Rio Grande-Southern Brazil

Water column profiles and near-bed time series of pressure, current velocity, suspended-particulate matter (SPM) concentration and seawater temperature and salinity were collected during three short cruises carried out in May 2005 in the shoreface and inner shelf area adjacent to Cassino Beach, southern Brazil. The measurements were part of the Cassino Experiment, a project conducted at an open, sandy coastal area known for the occurrence of patches of fairly large amounts of muddy sediments that are sporadically fluidized, transported onshore and eventually stranded on the beach. The study area is close to the Patos Lagoon mouth, being influenced by its water and suspended-sediment discharge. The presence of the Patos Lagoon outflow on the inner shelf was detected in one of the cruises (May 13) through measurements of near-surface salinity: while close to shore salinity was 29.4, a minimum value of 13.8 was measured at ∼10 km from the coast. Four days later, no trace of the plume was detected in the area. Regarding seawater temperature, no large temporal or spatial variability was documented with measured values ranging from 19.3 to 20 °C. Water column currents were prominently to N and NE, except at the outermost station, located ∼42 km from the coast, where NW-directed flows were observed at surface and mid-depth. Maximum near-bed current velocity oscillated between 18 and 42 cm s⁻¹ in the east–west direction and between 14 and 42 cm s⁻¹ in the north–south direction. Near-surface concentration of SPM oscillated between 11 and 99 mg L⁻¹, in general one order of magnitude lower than near-bed values. However, near-bed concentration of SPM showed large spatial variability: the highest value (2200 mg L⁻¹) was yielded by a water sample collected at ∼8 m water depth, at a station located ∼2 km away from the shoreline; two water samples collected 500 m, apart from this station, yielded SPM concentrations of 148 and 205 mg L⁻¹, one order of magnitude lower. Spectral analyses of near-bed current speed and SPM concentration indicate the relevance of oscillations in the low-frequency (<0.05 Hz) range. Detailed sampling of bottom sediment indicated that in May 2005 the mud patch was centered at ∼8.5 m water depth.     

Decadal-scale variations of water mass properties in the deep Weddell Sea

Data from cruises between 1989 and 2003 with FS Polarstern were used to construct section-wide potential temperature and salinity time series of the main water masses in the Weddell Gyre. In tandem with these CTD data, two time series between 1989 and 1995 are presented from moored instruments in the central Weddell Sea. The regional and methodological consistency of the dataset allows us to quantify variations which are not visible in less homogeneous datasets. The data reveal significant temperature and salinity variations of the Warm Deep Water and the Weddell Sea Bottom Water on a decadal time scale. The longest time series were obtained at the prime meridian. Here warming is observed in the Warm Deep Water from 1992 to 1998 followed by cooling. In the Weddell Sea proper, measurements of instruments moored in the Weddell Sea Bottom Water layer recorded a temperature increase over 6 years at a rate of 0.01 °C a^–1. After the mooring period, CTD casts in 1998 point to a weakening of the trend. The warming trend in the bottom water occurs over most of the Weddell Sea, as detected in the additional CTD surveys. The variations are close to the detection level in the voluminous Weddell Sea Deep Water. The initial warming trend of the Warm Deep Water is consistent with warming trends reported in literature of subsurface waters of the Antarctic Circumpolar Current. The reversal of the trend in the Weddell Sea seems to be related to variations of the atmospheric conditions which can affect both the intrusion of Circumpolar Deep Water from the north and the circulation of the Weddell Gyre. Because the Warm Deep Water is the major source water for the formation of deep and bottom water in the Weddell Sea, it is suggested that its increase in temperature and salinity is likely to at least partly cause the variations which were observed in the bottom water.Responsible Editor: Jörg-Olaf Wolff     

High‐temporal resolution fluvial sediment source fingerprinting with uncertainty: a Bayesian approach

This contribution addresses two developing areas of sediment fingerprinting research. Specifically, how to improve the temporal resolution of source apportionment estimates whilst minimizing analytical costs and, secondly, how to consistently quantify all perceived uncertainties associated with the sediment mixing model procedure. This first matter is tackled by using direct X‐ray fluorescence spectroscopy (XRFS) and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) analyses of suspended particulate matter (SPM) covered filter papers in conjunction with automatic water samplers. This method enables SPM geochemistry to be quickly, accurately, inexpensively and non‐destructively monitored at high‐temporal resolution throughout the progression of numerous precipitation events. We then employed a Bayesian mixing model procedure to provide full characterization of spatial geochemical variability, instrument precision and residual error to yield a realistic and coherent assessment of the uncertainties associated with source apportionment estimates. Applying these methods to SPM data from the River Wensum catchment, UK, we have been able to apportion, with uncertainty, sediment contributions from eroding arable topsoils, damaged road verges and combined subsurface channel bank and agricultural field drain sources at 60‐ and 120‐minute resolution for the duration of five precipitation events. The results presented here demonstrate how combining Bayesian mixing models with the direct spectroscopic analysis of SPM‐covered filter papers can produce high‐temporal resolution source apportionment estimates that can assist with the appropriate targeting of sediment pollution mitigation measures at a catchment level. © 2015 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

Isotopic mapping of groundwater perchlorate plumes

Analyses of stable isotope ratios of chlorine and oxygen in perchlorate can, in some cases, be used for mapping and source identification of groundwater perchlorate plumes. This is demonstrated here for large, intersecting perchlorate plumes in groundwater from a region having extensive groundwater perchlorate contamination and a large population dependent on groundwater resources. The region contains both synthetic perchlorate derived from rocket fuel manufacturing and testing activities and agricultural perchlorate derived predominantly from imported Chilean (Atacama) nitrate fertilizer, along with a likely component of indigenous natural background perchlorate from local wet and dry atmospheric deposition. Most samples within each plume reflect either a predominantly synthetic or a predominantly agricultural perchlorate source and there is apparently a minor contribution from the indigenous natural background perchlorate. The existence of isotopically distinct perchlorate plumes in this area is consistent with other lines of evidence, including groundwater levels and flow paths as well as the historical land use and areal distribution of potential perchlorate sources.