共查询到20条相似文献,搜索用时 15 毫秒
1.
Kiranmai Samudrala K A Kamesh Raju P Rama Rao 《Journal of Earth System Science》2016,125(8):1523-1542
High-resolution shipboard geophysical investigations along the Indian Ocean ridge system are sparse especially over the Carlsberg and Central Indian ridges. In the present study, the shipboard gravity and multibeam bathymetry data acquired over a 750 km long section of the Central Indian Ridge between 3 °S and 11 °S have been analysed to understand the crustal structure and the ridge segmentation pattern. The mantle Bouguer anomalies (MBA) and the residual mantle Bouguer anomalies (RMBA) computed in the study area have shown significant variations along the ridge segments that are separated by transform and non-transform discontinuities. The MBA lows observed over the linear ridge segments bounded by well-defined transform faults are attributed to the thickening of the crust at the middle portions of the ridge segments. The estimates of crustal thickness from the RMBA shows an average of 5.2 km thick crust in the axial part of the ridge segments. The MBA and relative RMBA highs along the two non-transform discontinuities suggests a thinner crust of up to 4.0 km. The most significant MBA and RMBA highs were observed over the Vema transform fault suggesting thin crust of 4 km in the deepest part of the transform fault where bathymetry is more than 6000 m. The identified megamullion structures have relative MBA highs suggesting thinner crust. Besides MBA lows along the ridge axis, significant off-axis MBA lows have been noticed, suggesting off-axis mantle upwelling zones indicative of thickening of the crust. The rift valley morphology varies from the typical V-shaped valley to the shallow valley floor with undulations on the inner valley floor. Segments with shallow rift valley floor have depicted well-defined circular MBA lows with persistent RMBA low, suggesting modulation of the valley floor morphology due to the variations in crustal thickness and the mantle temperature. These are supported by thicker crust and weaker lithospheric mantle. 相似文献
2.
I. M. Gorokhov A. B. Kuznetsov G. V. Konstantinova G. V. Lipenkov E. O. Dubinina I. V. Bigun 《Doklady Earth Sciences》2018,482(2):1306-1310
New 87Sr/86Sr, δ13C, and δ18О chemostratigraphic data were obtained for carbonate rocks of the Lower Riphean Yusmastakh and the Vendian Starorechenskaya formations. The δ13С values in dolomites of the Yusmastakh Formation varies from–0.6 to–0.1‰ and in dolomites and dolomitic limestones of the Starorechenskaya Formation, from–1.2 to–0.4‰ PDB, and δ18О values, from 24.4 to 26.4‰ and from 25.3 to 27.6‰ SMOW, respectively. The Rb–Sr systematics of carbonate rocks was studied using the refined method of stepwise dissolution of samples in acetic acid, including chemical removal of up to one-third of the ground sample by preliminary acid leaching and subsequent partial dissolution of the rest of the sample. Owing to this procedure, secondary carbonate material is removed, which enables one to improve the quality of the Sr-chemostratigraphic data obtained. The initial 87Sr/86Sr ratios in carbonate rocks of the Yusmastakh (0.70468–0.70519) and Starorechenskaya (0.70832–0.70883) formations evidence the Riphean–Vendian boundary in the Precambrian sequence of the Anabar Uplift. 相似文献
3.
Chemistry of major and minor elements, 87Sr/86Sr, δD, δ18O and δ34S of brines were measured from Tertiary strata and Quaternary salt lakes in the western Qaidam Basin. The water chemistry
data show that all oilfield brines are CaCl2 type. They were enriched in Ca2+, B3+, Li+, Sr2+, Br−, and were depleted in Mg2+, SO4
2−, which indicated that these brines had the characteristics of deeply circulated water. The relationship between δD and δ18O shows that all data of these brines decline towards the Global Meteoric Water Line (GWL) and Qaidam Meteoric Water Line
(QWL), and that the intersection between oilfield brines and Meteoric Water Lines was close to the local spring and fresh
water in the piedmont in the western Qaidam Basin. The results suggest that oilfield brines has initially originated from
meteoric water, and then might be affected by water-rock metamorphose, because most oilfield brines distribute in the range
of metamorphosing water. The 87Sr/86Sr values of most oilfield brines range from 0.71121 to 0.71194, and was less than that in salt lake water (>0.712), but close
to that of halite in the study area. These imply that salt dissolution occurred in the process of migration. In addition,
all oilfield brines have obviously much positive δ34S values (ranging from 26.46‰ to 54.57‰) than that of salt lake brines, which was caused by bacterial sulfate reduction resulting
in positive shift of δ34S value and depleteed SO4
2− in oilfield brines. Combined with water chemical data and δD, δ18O, 87Sr/86Sr, δ34S values, we concluded that oilfield brines mainly originate from the deeply circulated meteoric waters, and then are affected
by salt dissolution, water-rock metamorphose, sulfate reduction and dolomitization during the process of migration. These
processes alter the chemical compositions of oilfield brines and accumulate rich elements (such as B, Li, Sr, Br, K and so
on) for sustainable utilization of salt lake resources in the Qaidam Basin. 相似文献
4.
5.
M. Deiana F. Cervi M. Pennisi M. Mussi C. Bertrand A. Tazioli A. Corsini F. Ronchetti 《Hydrogeology Journal》2018,26(8):2669-2691
Deep-seated landslides are complex systems. In many cases, multidisciplinary studies are necessary to unravel the key hydrological features that can influence their evolution in space and time. The deep-seated Berceto landslide, in the northern Apennines of Italy, has been investigated in order to define the origin and geochemical evolution of groundwater (GW), to identify the slope system hydrological boundary, and to highlight the GW flow paths, transit time and transfer modalities inside the landslide body. This research is based on a multidisciplinary approach that involves monitoring GW levels, obtaining analyses of water chemistry and stable and unstable isotopes (δ18O-δ2H, 3H, 87Sr/86Sr), performing soil leaching tests, geochemical modelling (PHREEQC), and principal component analysis (PCA). The results of δ18O-δ2H and 87Sr/86Sr analyses show that the source of GW recharge in the Berceto landslide is local rainwater, and external contributions from a local stream can be excluded. In the landslide body, two GW hydrotypes (Ca-HCO3 and Na-HCO3) are identified, and the results of PHREEQC and PCA confirm that the chemical features of the GW depend on water–rock interaction processes occurring inside the landslide. The 3H content suggests a recent origin for GW and appears to highlight mixing between shallow and deep GW aliquots. The 3H content and GW levels data confirm that shallow GW is mainly controlled by a mass transfer mechanism. The 3H analyses with GW levels also indicate that only deep GW is controlled by a pressure transfer mechanism, and this mechanism is likely the main influence on the landslide kinematics. 相似文献
6.
V. N. Golubev E. O. Dubinina I. V. Chernyshev T. A. Ikonnikova 《Doklady Earth Sciences》2016,466(1):28-31
The uneven character of the distribution of 18O/16O and 234U/238U values was established in the vertical cross section of the productive sequence of the Dybryn uranium deposit (Vitim uranium-ore region, Buryatia). Both a deficiency and an excess of 234U in relation to the equilibrium 234U/238U ratio in the vertical sequence may provide evidence for the extremely low rate of the infiltration water flow. The behavior of oxygen isotope characteristics for different size fractions of terrigenous rocks provides evidence for active uranium redistribution and openness of the isotope system of this element during interaction of terrigenous–sedimentary rocks with infiltration waters. 相似文献
7.
Ya. V. Pavlenko 《Astronomy Reports》2008,52(9):749-759
We have modeled absorption lines of the 12CO and 13CO (Δυ = 2) molecular bands at λλ 2.29–2.45 µm in the spectrum of Arcturus (K2III). A grid of model atmospheres and synthetic spectra were computed for the red giant using T eff = 4300, log g = 1.5, and the elemental abundances of Peterson et al. (1993), with the exception of the abundances of carbon, log N(C), and oxygen, log N(O) and the carbon isotopic ratio, 12C/13C, which were varied in our computations. The computed spectra were compared to the observed spectrum of Arcturus from the atlas of Hinkle et al. (1976). The best fit between the synthetic and observed spectra is achieved for log N(C) = ?3.78, 12C/13C = 8 ± 0.5. We discuss the dependence of 12C/13C on log N(C) and log N(O) in the atmosphere of the red giant. 相似文献
8.
Isotopic compositions of carbon (δ13C from −51.4 to −10.8
PDB) and oxygen (δ18O from 14.4 to 21.4
SMOW) were studied in rhodochrosite and calcite from manganese ores in the South Faizuly and Kyzyltash deposits of the southern Urals. The geological, petrographic, and isotopic data indicate that the studied carbonates are diagenetic formations. It is suggested that the main ore element (Mn) was delivered to the marine basin with hydrothermal solutions percolating in the oceanic crust. Manganese precipitated on the oceanic bottom as oxides near solution discharge zones. Manganese carbonates formed in sediments as a result of the oxidation of organic matter by manganese oxides. High biological productivity of the environment was caused by proximity to the hydrothermal vent that provided favorable biogeochemical conditions for the development of biocoenosis. Anomalously low 13C values in the South Faizuly deposit testify to the large-scale oxidation of methane in the course of manganese carbonate formation.__________Translated from Litologiya i Poleznye Iskopaemye, No. 4, 2005, pp. 416–429.Original Russian Text Copyright © 2005 by Kuleshov, Brusnitsyn. 相似文献
9.
Geographical information system (GIS) technology was used to investigate NO3
− concentration of groundwater in the Zhangye Basin, Northwest China. Thematic information and NO3
− data of groundwater from the Zhangye Basin were analyzed in a GIS environment to study the extent and variation of NO3
− concentration and to establish spatial relationships with corresponding land use types. About 38.8% of groundwater samples
showed NO3
− concentration above the human affected value (13 mg/l NO3
−), while more than 10.2% exceeded the maximum acceptable level (50 mg/l NO3
−) according to WHO regulations. The spatial distribution of NO3
− of groundwater in the Zhangye Basin showed an obvious character of zonation; the high NO3
− concentration was mainly located in the city seat areas, and Zhangye City was the high-value center. The probability of over
90% for NO3
− concentration exceeding 13 mg/l was found in urban seat areas. The spatial analyses indicated that groundwater contamination
by NO3
− was closely related to one specific land use class, the urban. The NO3
− concentration of groundwater under urban was significantly higher than that under irrigation land or sand dune. Most of the
unacceptable NO3
− levels were found in groundwater samples assigned to urban area, but a few were also found allotted to irrigation land class.
Therefore, urban source was considered the principal source of NO3
− contamination of groundwater in the Zhangye Basin, while irrigation land source was still a possible source of NO3
− contamination. 相似文献
10.
Shen Qu Guangcai Wang Zheming Shi Qingyu Xu Yuying Guo Luan Ma Yizhi Sheng 《Hydrogeology Journal》2018,26(5):1443-1453
With depleted coal resources or deteriorating mining geological conditions, some coal mines have been abandoned in the Fengfeng mining district, China. Water that accumulates in an abandoned underground mine (goaf water) may be a hazard to neighboring mines and impact the groundwater environment. Groundwater samples at three abandoned mines (Yi, Er and Quantou mines) in the Fengfeng mining district and the underlying Ordovician limestone aquifer were collected to characterize their chemical and isotopic compositions and identify the sources of the mine water. The water was HCO3·SO4-Ca·Mg type in Er mine and the auxiliary shaft of Yi mine, and HCO3·SO4-Na type in the main shaft of Quantou mine. The isotopic compositions (δD and δ18O) of water in the three abandoned mines were close to that of Ordovician limestone groundwater. Faults in the abandoned mines were developmental, possibly facilitating inflows of groundwater from the underlying Ordovician limestone aquifers into the coal mines. Although the Sr2+ concentrations differed considerably, the ratios of Sr2+/Ca2+ and 87Sr/86Sr and the 34S content of SO42? were similar for all three mine waters and Ordovician limestone groundwater, indicating that a close hydraulic connection may exist. Geochemical and isotopic indicators suggest that (1) the mine waters may originate mainly from the Ordovician limestone groundwater inflows, and (2) the upward hydraulic gradient in the limestone aquifer may prevent its contamination by the overlying abandoned mine water. The results of this study could be useful for water resources management in this area and other similar mining areas. 相似文献
11.
The O2 3?-Y3+ center in fluorite-type structures (CaF2 and SrF2) has been investigated at the density functional theory (DFT) level using the CRYSTAL06 code. Our calculations were performed by means of the hybrid B3PW method in which the Hartree–Fock exchange is mixed with the DFT exchange functional, using Becke’s three parameter method, combined with the non-local correlation functionals by Perdew and Wang. Our calculations confirm the stability and the molecular character of the O2 3?-Y3+ center. The unpaired electron is shown to be almost exclusively localized on and equally distributed between the two oxygen atoms that are separated by a bond distance of 2.47 Å in CaF2 and 2.57 Å in SrF2. The calculated 17O and 19F hyperfine constants for of the O2 3?-Y3+ center are in good agreement with their corresponding experimental values reported by previous electron paramagnetic resonance and electron nuclear double resonance studies, while discrepancies are notable for the 89Y hyperfine constants. 相似文献
12.
Pia Söderlund Tobias Hermansson Laurence M. Page Michael B. Stephens 《International Journal of Earth Sciences》2009,98(8):1835-1851
In order to characterize the post-Svecofennian tectonothermal evolution of the Fennoscandian Shield, 40Ar–39Ar biotite and some 40Ar–39Ar muscovite geochronological data are reported from a total of 30 surface outcrop and 1,000 m long borehole samples at Forsmark,
central Sweden. The 13 surface samples were collected across 3 branches of a major WNW to NW trending system of deformation
zones, whereas the boreholes were drilled within a tectonic lens, in between two of these zones. The 40Ar–39Ar biotite ages indicate that the present erosion surface, in central Sweden, cooled below c. 300°C at 1.73–1.66 Ga, and that
the rocks could have accommodated strain in a brittle manner between 1.8 and 1.7 Ga. The variation in surface ages is suggested
to be due to fault along the large WNW to NW trending deformation zones, following the establishment of a sub-Cambrian peneplain.
The minor variation of ages within a single crustal block may be due to disturbance along ENE to NNE trending fracture zones.
Possible cooling paths, derived from 40Ar–39Ar hornblende, muscovite and biotite ages, were calculated for the time interval from 1.80 to 1.67 Ga, when the area cooled
from c. 500 to 300°C. Cooling rates of 1.9–4°C/m.y. have been attained. Between 1.68 and 1.64 Ga, uplift rates of c. 22 m/m.y.
were calculated from borehole 40Ar–39Ar biotite data. Tectonothermal histories, inferred from the combined cooling and uplift rates, are related to simple cooling
after the Svecofennian orogeny, to crustal movement in response to far-field effects of c. 1.7 Ga orogenic activities further
to the west or to a combination of these possibilities. 相似文献
13.
14.
The results of isotope-geochemical studies of carbonates of different mineral types from manganese and host rocks of the Famennian manganiferous formation of Pai-Khoi are reported. Kutnahorite ores are characterized by δ13C values from–6.6 to 1.3‰ and δ18O from 20.0 to 27.4‰. Rhodonite–rhodochrosite rocks of the Silovayakha ore occurrence have δ13C from–5.2 to–2.9 and δ18O from 25.4 to 24.3‰. Mineralogically similar rocks of the Nadeiyakha ore occurrence show the lighter carbon and oxygen isotopic compositions: δ13C from–16.4 to–13.1 and δ18O from 24.8 to 22.5‰. Similar isotopic compositions were also obtained for rhodochrosite–kutnahorite rocks of this ore occurrence: δ13C from–13.0 to–10.4‰ and δ18O from 24.6 to 21.7‰. Siderorodochrosite ores differ in the lighter oxygen and carbon isotopic compositions: δ18O from 18.7 to 17.6‰ and δ13C from–10.2 to–9.3‰, respectively. In terms of the carbon and oxygen isotopic compositions, host rocks in general correspond to marine sedimentary carbonates. Geological-mineralogical and isotope data indicate that the formation of the manganese carbonates was related to the hydrothermal ore-bearing fluids with the light isotopic composition of oxygen and carbon dissolved in CO2. The isotopic features indicate an authigenic formation of manganese carbonates under different isotopegeochemical conditions. 相似文献
15.
A new mineral, droninoite, was found in a fragment of a weathered Dronino iron meteorite (which fell near the village of Dronino, Kasimov district, Ryazan oblast, Russia) as dark green to brown fine-grained (the size of single grains is not larger than 1 μm) segregations up to 0.15 × 1 × 1 mm in size associated with taenite, violarite, troilite, chromite, goethite, lepidocrocite, nickelbischofite, and amorphous Fe3+ hydroxides. The mineral was named after its type locality. Aggregates of droninoite are earthy and soft; the Mohs hardness is 1–1.5. The calculated density is 2.857 g/cm3. Under a microscope, droninoite is dark gray-green and nonpleochroic. The mean (cooperative for fine-grained aggregate) refractive index is 1.72(1). The IR spectrum indicates the absence of S O 4 2? and C O 3 2? anions. Chemical composition (electron microprobe, partition of total iron into Fe2+ and Fe3+ made on the basis of the ratio (Ni + Fe2+): Fe3+ = 3: 1; water is calculated from the difference) is as follows, wt %: 36.45 NiO, 12.15 FeO, 17.55 Fe2O3, 23.78 H2O, 13.01 Cl, ?O=Cl2 ?2.94, total is 100.00. The empirical formula (Z = 6) is Ni2.16Fe 0.75 2+ Fe 0.97 3+ Cl1.62(OH)7.10 · 2.28H2O. The simplified formula is Ni3Fe3+Cl(OH)8 · 2H2O. Droninoite is trigonal, space group R \(\bar 3\) m, R3m, or R32; a = 6.206(2), c = 46.184(18) Å; V = 1540.4(8) Å3. The strong reflections in the X-ray powder diffraction pattern [d, Å (I, %) (hkl)] are 7.76(100)(006), 3.88(40)(0.0.12), 2.64(25)(202, 024), 2.32(20)(0.2.10), 1.965(0.2.16). The holotype specimen is deposited at the Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, registration number 3676/1. 相似文献
16.
The paper presents the results of study of the Sr, C, and O isotope compositions in Upper Jurassic carbonate rocks of the Baidar Valley and Demerdzhi Plateau in the Crimean Mountains represented by different facies of the carbonate platform at the northern active margin of the Tethys. The 87Sr/86Sr value in them varies from 0.70699 to 0.70728. Based on the Sr chemostratigraphic correlation, the age of massive and layered limestones in the western part of the Ai-Petri and Baidar yailas (pastures) is estimated as late Kimmeridgian–early Tithonian, whereas the age of flyschoids of the Baidar Valley are estimated as late Tithonian–early Berriasian. The nearly synchronous formation of carbonate breccias of the Baidar Valley and Demerdzhi Plateau in late Tithonian–early Berriasian is substantiated. A summary section of Upper Jurassic rocks is compiled based on the Sr chemostratigraphic data. It has been established that δ18O values in the studied carbonate sediments vary from–2.9 to 1.3‰ (V-PDB). At the same time, shallow-water sediments in the internal part and the edge of the Crimean carbonate platform are depleted in 18O (–2.9 to +0.1‰) relative to sediments on the slope and foothill (–0.5 to +1.3‰). It is demonstrated that δ13C values do not depend on the facies properties and decrease in younger carbonate sediments from 3–3.5‰ to 1–1.5‰ in line with the Late Jurassic general trend. The δ13C values obtained for the Crimean carbonate platform turned out to be 0.5–1‰ higher than the values typical of the deep-water marine setting at the western margin of the Tethys. These discrepancies are likely related to peculiarities of water circulation and high bioproductivity in marine waters of the northern Peri-Tethys. 相似文献
17.
Lorena N. Dias Maurício V. B. Pinheiro Klaus Krambrock 《Physics and Chemistry of Minerals》2009,36(9):519-525
Irradiation techniques are often applied to gem minerals for color enhancement purposes. Natural green, blue and colorless
specimens of rare gemological quality euclase, BeAlSiO4(OH), from Brazil were irradiated with gamma rays in the dose range from 10 to 500 kGy. Although the colors of the different
specimens were not strongly influenced, two different irradiation-induced paramagnetic defect centers were found by electron
paramagnetic resonance (EPR). The first one is an O− hole center interacting with one Al neighbor and the second is a Ti3+ electron center. The EPR angular rotation patterns of both irradiation-induced defects were measured and analyzed. The results
suggest that O− hole centers are formed by dissociation of the hydroxyl ions, similar as in topaz crystals. In euclase the OH− ions interconnect distorted Al octahedra and Be tetrahedra in O5 positions. During irradiation, the electrons are captured by titanium ions (Ti4+ + e−), leading to the formation of paramagnetic Ti3+ ions. From the EPR rotation patterns it is clear that these ions substitute for Al ions. The spin Hamiltonian parameters
of the irradiation-induced defects are analyzed and compared to similar defect centers in other mineral specimens. Thermal
annealing experiments show that the O− hole centers and Ti3+ electron centers are directly connected through the radiation process. 相似文献
18.
D. E. Martínez E. Fourré O. M. Quiroz Londoño P. Jean-Baptiste M. Glok Galli A. Dapoigny S. I. Grondona 《Hydrogeology Journal》2016,24(5):1107-1120
The Pampa region in Argentina includes vast unconfined–semiconfined aquifers that local economies depend upon, but detailed knowledge of the associated water resources is still lacking. The Pampeano aquifer in the Pampa plain of Argentina covers around 1.5 million km2. In order to achieve a better understanding of the hydrogeological system through the estimation of mean residence times (MRT), water samples were taken from 12 monitoring wells, drilled at different depths in four locations, and analyzed for environmental tracers. The concentrations of 3H, tritiogenic 3He and chlorofluorocarbons (CFCs) can be explained by mixtures of young waters adjusted to exponential piston flow models (EPM) or dispersion models (DM), and different proportions of tracer-free waters (dead water). The sampling site located very close to the water divide shows a dominance of young waters: 85 % of water best represented by a DM model with a MRT of 3 years. For the shallow wells at other sites, best-fitting models result in a DM with MRT between 20 and 35 years, and proportions of dead water between 40 and 60 %. These results lead to important updates in the conceptual model of the Pampeano aquifer. Large proportions of dead water at a few meters depth can be the consequence of upward flows in a multilayered aquifer or diffusive retardation in the inter-bedded clay layers. 相似文献
19.
Gaston Giuliani Anthony E. Fallick Julien Feneyrol Daniel Ohnenstetter Vincent Pardieu Mark Saul 《Mineralium Deposita》2011,46(7):671-676
The combination of oxygen isotope composition with V–Cr–Mn trace element concentrations of V-bearing garnets (tsavorites)
originating from the main deposits of the Neoproterozoic Mozambique Metamorphic Belt is reported for the first time. The database
enables the identification of the geological and geographical sources of the main productive areas from northern and southern
Tanzania, Kenya, and Madagascar. Three consistent sets of δ18O values between 9.5‰ and 11.0‰, 11.6‰ and 14.5‰, and 15.5‰ and 21.1‰ have been recognized for primary deposits hosted in
graphitic gneisses related to the Neoproterozic metasedimentary series. The δ18O value of tsavorite is a good tracer of the environment of its formation; the δ18O of the fluid in equilibrium with tsavorite was buffered by the host rock during metamorphism and fluid-rock interaction.
This study is a first step in characterizing the geochemistry of gem tsavorite from most of the deposits and occurrences worldwide. 相似文献
20.
The Warburton Basin of central Australia has experienced a complex tectonic and fluid-flow history, resulting in the formation of various authigenic minerals. Geochemical and geochronological analyses were undertaken on vein carbonates from core samples of clastic sediments. Results were then integrated with zircon U–Pb dating and uraninite U–Th–total Pb dating from the underlying granite. Stable and radiogenic isotopes (δ18O, Sr and εNd), as well as trace element data of carbonate veins indicate that >200 °C basinal fluids of evolved meteoric origin circulated through the Warburton Basin. Almost coincidental ages of these carbonates (Sm–Nd; 432 ± 12 Ma) with primary zircon (421 ± 3.8 Ma) and uraninite (407 ± 16 Ma) ages from the granitic intrusion point towards a substantial period of active tectonism and an elevated thermal regime during the mid Silurian. We hypothesise that such a thermal regime may have resulted from extensional tectonism and concomitant magmatic activity following regional orogenesis. This study shows that the combined application of geochemical and geochronological analyses of both primary and secondary species may constrain the timing of tectonomagmatic events and associated fluid flow in intraplate sedimentary basins. Furthermore, this work suggests that the Sm–Nd-isotopic system is surprisingly robust and can record geologically meaningful age data from hydrothermal mineral species. 相似文献