Distribution of REE between clinopyroxene and basaltic melt along a mantle adiabat: effects of major element composition, water, and temperature

The distribution of rare earth elements (REE) between clinopyroxene (cpx) and basaltic melt is important in deciphering the processes of mantle melting. REE and Y partition coefficients from a given cpx-melt partitioning experiment can be quantitatively described by the lattice strain model. We analyzed published REE and Y partitioning data between cpx and basaltic melts using the nonlinear regression method and parameterized key partitioning parameters in the lattice strain model (D ₀, r ₀ and E) as functions of pressure, temperature, and compositions of cpx and melt. D ₀ is found to positively correlate with Al in tetrahedral site (Al ^T ) and Mg in the M2 site (Mg^M2) of cpx and negatively correlate with temperature and water content in the melt. r ₀ is negatively correlated with Al in M1 site (Al^M1) and Mg^M2 in cpx. And E is positively correlated with r ₀. During adiabatic melting of spinel lherzolite, temperature, Al ^T , and Mg^M2 in cpx all decrease systematically as a function of pressure or degree of melting. The competing effects between temperature and cpx composition result in very small variations in REE partition coefficients along a mantle adiabat. A higher potential temperature (1,400°C) gives rise to REE partition coefficients slightly lower than those at a lower potential temperature (1,300°C) because the temperature effect overwhelms the compositional effect. A set of constant REE partition coefficients therefore may be used to accurately model REE fractionation during partial melting of spinel lherzolite along a mantle adiabat. As cpx has low Al and Mg abundances at high temperature during melting in the garnet stability field, REE are more incompatible in cpx. Heavy REE depletion in the melt may imply deep melting of a hydrous garnet lherzolite. Water-dependent cpx partition coefficients need to be considered for modeling low-degree hydrous melting.     

Geochemistry of Neoproterozoic mafic intrusions in the Panzhihua district (Sichuan Province,SW China): Implications for subduction-related metasomatism in the upper mantle

Metasomatism above subduction zones is an important process that produces heterogeneous mantle and thus a diversity of igneous rocks. In the Panzhihua district, on the western margin of the Yangtze Block (SW China), two Neoproterozoic mafic intrusions, one olivine gabbro and one hornblende gabbro, have identical ages of 746 ± 10 and 738 ± 23 Ma. Both of the gabbros are tholeiitic in composition and have arc-like geochemical compositions. The hornblende gabbros have K₂O concentrations ranging from 0.70 to 1.69 wt.% and show enrichment of Rb, Ba, U, Th and Pb and depletion of Nb,Ta and Ti. They have variable ⁸⁷Sr/⁸⁶Sr ratios (0.7045–0.7070) with constant ɛNd(t) values (−0.12 to −0.93). The olivine gabbros have relatively low K₂O (0.19–0.43 wt.%), are depleted in Rb and Th relative to Ba and U, and have obvious negative Nb–Ta and Zr–Hf anomalies on primitive mantle-normalized trace element diagrams. Their ɛNd(t) values range from −0.64 to −1.73 and initial ⁸⁷Sr/⁸⁶Sr ratios from 0.7070 to 0.7075. Both types of gabbro experienced fractional crystallization of clinopyroxene, plagioclase, amphibole and minor Fe–Ti oxide. The parental magmas of the olivine and hornblende gabbros were formed by about 20% partial melting of garnet–spinel lherzolite and spinel lherzolite, respectively. According to trace elemental ratios, the hornblende gabbros were probably derived from a source strongly modified by subducted slab fluids, whereas the olivine gabbros came from a mantle source modified by subducted slab melts. The close association of the olivine gabbros and hornblende gabbros suggests that a steep subduction zone existed along the western margin of the Yangtze Block during Neoproterozoic time. Thus, the giant Neoproterozoic magmatic event in South China was subduction-related.     

Equivocal carbonatite markers in the mantle xenoliths of the Patagonia backarc: the Gobernador Gregores case (Santa Cruz Province,Argentina)

Amphibole ± phlogopite ± apatite-bearing mantle xenoliths at Gobernador Gregores display modal, bulk-rock and phase geochemical characteristics held as indicators of carbonatitic metasomatism. However, part of these xenoliths has high TiO₂/Al₂O₃ and those displaying the most pronounced carbonatitic geochemical markers modally trend towards harzburgite. Bulk-rock, clinopyroxene and amphibole show Zr, Hf and Ti negative anomalies, which increase at decreasing Na₂O and high field strength elements (HFSE) concentrations. Steady variation trends between xenoliths which have and do not have carbonatitic characteristics suggest a control by reactive porous flow of only one agent, inferred to be initially a ne-normative hydrous basalt (because of the presence of wehrlites) evolving towards silica saturation. Variation trends exhibit cusps when amphibole appears in the mode. Appearance of amphibole may explain the Ti anomaly variations, but not those of Zr and Hf. Numerical modelling [Plate Model (Vernières et al. in J Geophys Res 102:24771–24784, 1997)] gives results consistent with the observed geochemical features by assuming the presence of loveringite. Modest HFSE anomalies in the infiltrating melt may be acquired during percolation in the garnet-facies.In memory of Carlo Rivalenti     

Volatile (S,Cl and F) and fluid mobile trace element compositions in melt inclusions: implications for variable fluid sources across the Kamchatka arc

Volatile element, major and trace element compositions were measured in glass inclusions in olivine from samples across the Kamchatka arc. Glasses were analyzed in reheated melt inclusions by electron microprobe for major elements, S and Cl, trace elements and F were determined by SIMS. Volatile element–trace element ratios correlated with fluid-mobile elements (B, Li) suggesting successive changes and three distinct fluid compositions with increasing slab depth. The Eastern Volcanic arc Front (EVF) was dominated by fluid highly enriched in B, Cl and chalcophile elements and also LILE (U, Th, Ba, Pb), F, S and LREE (La, Ce). This arc-front fluid contributed less to magmas from the central volcanic zone and was not involved in back arc magmatism. The Central Kamchatka Depression (CKD) was dominated by a second fluid enriched in S and U, showing the highest S/K₂O and U/Th ratios. Additionally this fluid was unusually enriched in ⁸⁷Sr and ¹⁸O. In the back arc Sredinny Ridge (SR) a third fluid was observed, highly enriched in F, Li, and Be as well as LILE and LREE. We argue from the decoupling of B and Li that dehydration of different water-rich minerals at different depths explains the presence of different fluids across the Kamchatka arc. In the arc front, fluids were derived from amphibole and serpentine dehydration and probably were water-rich, low in silica and high in B, LILE, sulfur and chlorine. Large amounts of water produced high degrees of melting below the EVF and CKD. Fluids below the CKD were released at a depth between 100 and 200 km due to dehydration of lawsonite and phengite and probably were poorer in water and richer in silica. Fluids released at high pressure conditions below the back arc (SR) probably were much denser and dissolved significant amounts of silicate minerals, and potentially carried high amounts of LILE and HFSE. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Hf-Pb isotope and trace element constraints on the origin of the Jacupiranga Complex (Brazil): Insights into carbonatite genesis and multi-stage metasomatism of the lithospheric mantle

The Lower Cretaceous Jacupiranga complex, in the central-southeastern portion of the South American Platform, includes carbonatites in close association with silicate rocks (i.e. strongly and mildly silica-undersaturated series). Here we document the first hafnium isotope data on the Jacupiranga complex, together with new trace element and Pb isotope compositions. Even though liquid immiscibility from a carbonated silicate melt has been proposed for the genesis of several Brazilian carbonatites, isotopic and geochemical (e.g., Ba/La ratios, lack of pronounced Zr-Hf and Nb-Ta decoupling) information argues against a petrogenetic relationship between Jacupiranga carbonatites and their associated silicate rocks. Thus, an origin by direct partial melting of the mantle is considered. The isotopic compositions of the investigated silicate samples are coherent with a heterogeneously enriched subcontinental lithospheric mantle (SCLM) source of rather complex evolution. At least two metasomatic processes are constrained: (1) a first enrichment event, presumably derived from slab-related fluids introduced into the SCLM during Neoproterozoic times, as indicated by consistently old T_DM ages and lamprophyre trace signatures, and (2) a Mesozoic carbonatite metasomatism episode of sub-lithospheric origin, as suggested by εNd-εHf values inside the width of the terrestrial array. The Jacupiranga parental magmas might thus derive by partial melting of distinct generations of metasomatic vein assemblages that were hybridized with garnet peridotite wall-rocks.     

Slab melt and intraplate metasomatism in Kapfenstein mantle xenoliths (Styrian Basin, Austria)

Anhydrous and amphibole-bearing mantle peridotite xenoliths from Kapfenstein (Styrian Basin) have been studied with the aim of understanding both the processes responsible for amphibole formation and the nature of metasomatizing agents which affected this portion of lithosphere. This area of the Pannonian Basin underwent a subduction event which was followed after about 15 Ma, by alkaline intraplate magmatism. Primary clinopyroxene (cpx1) in four-phase lherzolite xenoliths is characterized by LREE-depleted to slightly LREE-enriched patterns. LREE-depleted cpx1 have low Th and U contents and Zr (and Hf) anomalies varying from slightly negative to positive. LREE-enriched cpx have high Th and U contents and remarkable positive anomalies of Zr and Hf. Primary clinopyroxenes in amphibole-bearing lherzolites present a comparable compositional variation from LREE (and Th, U, Zr, Hf)-depleted type to LREE (and Th, U, Zr, Hf)-enriched type. LREE-depleted cpx1, with strong negative Zr and Ti anomalies, are also recognized in the peridotite matrix of a composite sample cut by a large amphibole vein. Textural and geochemical evidence indicates that amphibole disseminated within the matrix grew at the expense of primary spinel and clinopyroxene, mimicking the trace element patterns of the latter. As a consequence, the geochemical features of amphibole vary in relation to those of clinopyroxene, from enriched to depleted. On the other hand, the composition of vein amphibole in the composite xenolith compares well with amphibole megacrysts and microphenocrysts, suggesting that it represents a fractionation product of alkaline melt that passed through the lithosphere. Two kinds of metasomatism, superimposed on a slightly depleted lithospheric mantle, were identified. A slab-derived melt (proto-adakite?) metasomatic agent was responsible for the first enrichment in Th, U, Zr and Hf observed in clinopyroxene, whereas an alkaline within-plate metasomatic agent caused the formation of the Nb (and Ta)- rich disseminated amphibole. The final process was the alkaline magmatism, which was responsible for the formation of the large amphibole vein and megacrysts. It is proposed that the Nb-poor and Nb-rich amphiboles record the transition between the suprasubduction slab melt-related and the intraplate alkaline metasomatism.

These geochemical features are consistent with a lithospheric portion enriched in slab melt components which was subsequently metasomatized by alkaline melt. Alternatively an asthenospheric uprising could have scavenged a previously slab melt-enriched region of the lithosphere.     

Calcio-carbonatite melts and metasomatism in the mantle beneath Mt. Vulture (Southern Italy)

At Mt. Vulture volcano (Basilicata, Italy) calcite globules (5–150 μm) are hosted by silicate glass pools or veins cross-cutting amphibole-bearing, or more common spinel-bearing mantle xenoliths and xenocrysts. The carbonate globules are rounded or elongated and are composed of a mosaic of 2–20 μm crystals, with varying optical orientation. These features are consistent with formation from a quenched calciocarbonatite melt. Where in contact with carbonate amphibole has reacted to form fassaitic pyroxene. Some of these globules contain liquid/gaseous CO₂ bubbles and sulphide inclusions, and are pierced by quench microphenocrysts of silicate phases. The carbonate composition varies from calcite to Mg-calcite (3.8–5.0 wt.% MgO) both within the carbonate globules and from globule to globule. Trace element contents of the carbonate, determined by LAICPMS, are similar to those of carbonatites worldwide including ΣREE up to 123 ppm. The Sr–Nd isotope ratios of the xenolith carbonate are similar to the extrusive carbonatite and silicate rocks of Mt. Vulture testifying to derivation from the same mantle source. Formation of immiscibile silicate–carbonatite liquids within mantle xenoliths occurred via disequilibrium immiscibility during their exhumation.     

Platinum group element enrichment in the upper mantle peridotites of the Monte Maggiore ophiolitic massif (Corsica,France): Mineralogical evidence for ore-fluid metasomatism

Summary Positive platinum and gold anomalies (up to 130 and 54 ppb, respectively)have been identified in ophiolitic mantle peridotites from the Monte Maggiore Massif(MMM), Corsica.Forty-four grains of platinum-group minerals (PGM) were found in seven rock samples with Pt, Pd, Os and Ir contents as low as 20,10, 5 and 1.9 ppb, respectively. PGM are mainly alloys: of native osmium, iridium, platinum, palladium and gold, tetraferroplatinum more or less rich in copper, the Cu-bearing equivalent of rustenburgite, potarite, moncheite and Ni-rich merenskyite. The presence of these low temperature minerals (<650°C) which precipitated after the pentlandite, allows us to rule out the possibility of a magmatic origin for platinum group element (PGE) anomalies. Therefore the model presented here proposes the late precipitation of PGM linked to a hydrothermal system created by the rising of a fluid-enriched magma occurring under a mid-oceanic ridge during the diapiric uprising of asthenospheric mantle at about 0.9 GPa.Compositional evolution of tetraferroplatinum and late stage precipitation of tellurides and intermetallic compounds are evidence of PGE fractionation as the fluid became progressively enriched in Te, Bi, Cu, Sri and Pb, and depleted in S. This occurred during the transport and entrapment of the fluid in cooler parts of the residual peridotite surrounding the melting zone.The proposed mechanism for PGE anomalies in the Monte Maggiore mantle peridotites illustrates a mineralizing process involving concentration and transport of PGE through a fluid-rich medium followed by sudden precipitation of PGM along preferential fractures caused by a thermal gradient.

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Enrichissement en éléments du groupe du platine (EGP) dans les péridotites ophiolitiques du manteau supérieur, massif du Monte Maggiore, Corse: mise en évidence, à partir d'études minéralogiques, d'un métasomatisme lié à un fluide minéralisant

Résumé Dans le Massif du Monte Maggiore (MMM), Corse, des anomalies de platine et d'or (respectivement, jusqu' à 130 et 54 ppb) ont été mises en évidence dans des péridotites du manteau ophiolitique.Quarante quatre grains de minéraux du groupe du platine (MGP) ont été observés dans sept échantillons ayant des teneurs en Pt, Pd, Os et Ir respectivement aussi faibles que 20, 10, 5 et 1,9 ppb. Les MGP sont principalement des alliages: osmium, iridium, platine, palladium et or natifs, téétraferroplatine plus ou moins riche en cuivre, équivalent cuprifère de la rustenburgite, potarite, ainsi que monchéite et merenskyite riche en nickel. Ces minéraux de basses températures (< 650 °C) qui ont précipité après la pentlandite permettent d'écarter une origine magmatique pour les anomalies en éléments du groupe du platine (EGP). A l'opposé, le modèle propose une précipitation tardive des MGP liée à un système hydrothermal créé par la montée d'un magma enrichi en fluides, au sein d'un diapir mantellique ascendant à l'aplomb d'une dorsale médioocéaniq,ue, sous des pressions de l'ordre de 0.9 GPa.L'évolution de la composition des tétraferroplatines et la cristallisation tardive des tellurures et des composés intermétalliques témoignent du fractionnement des EGP, alors que le fluide minéralisant s'enrichit progressivement en Te, Bi, Cu, Sn et Pb et s'appauvrit en S. Ceci s'est produit durant le transport et le piégeage du fluide dans les zones plus froides du massif représentées par les péridotites résiduelles autour de la zone de fusion.Le mécanisme proposé pour les péridotites anomales en EGP du manteau du Monte Maggiore illustre un type de processus minéralisant impliquant la concentration et le transport des EGP dans un milieu enrichi en fluides, suivi de la précipitation rapide des MGP le long de fractures préférentielles sous l'effet d'un gradient thermique.

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With 3 Figures and 2 Plates     

Diamond precipitation and mantle metasomatism – evidence from the trace element chemistry of silicate inclusions in diamonds from Akwatia, Ghana

Trace element concentrations in the four principal peridotitic silicate phases (garnet, olivine, orthopyroxene, clinopyroxene) included in diamonds from Akwatia (Birim Field, Ghana) were determined using SIMS. Incompatible trace elements are hosted in garnet and clinopyroxene except for Sr which is equally distributed between orthopyroxene and garnet in harzburgitic paragenesis diamonds. The separation between lherzolitic and harzburgitic inclusion parageneses, which is commonly made using compositional fields for garnets in a CaO versus Cr₂O₃ diagram, is also apparent from the Ti and Sr contents in both olivine and garnet. Titanium is much higher in the lherzolitic and Sr in the harzburgitic inclusions. Chondrite normalised REE patterns of lherzolitic garnets are enriched (10–20 times chondrite) in HREE (La_N/Yb_N = 0.02–0.06) while harzburgitic garnets have sinusoidal REE_N patterns, with the highest concentrations for Ce and Nd (2–8 times chondritic) and a minimum at Ho (0.2–0.7 times chondritic). Clinopyroxene inclusions show negative slopes with La enrichment 10–100 times chondritic and low Lu (0.1–1 times chondritic). Both a lherzolitic and a harzburgitic garnet with very high knorringite contents (14 and 21 wt% Cr₂O₃ respectively) could be readily distinguished from other garnets of their parageneses by much higher levels of LREE enrichment. The REE patterns for calculated melt compositions from lherzolitic garnet inclusions fall into the compositional field for kimberlitic-lamproitic and carbonatitic melts. Much more strongly fractionated REE patterns calculated from harzburgitic garnets, and low concentrations in Ti, Y, Zr, and Hf, differ significantly from known alkaline and carbonatitic melts and require a different agent. Equilibration temperatures for harzburgitic inclusions are generally below the C-H-O solidus of their paragenesis, those of lherzolitic inclusions are above. Crystallisation of harzburgitic diamonds from CO₂-bearing melts or fluids may thus be excluded. Diamond inclusion chemistry and mineralogy also is inconsistent with known examples of metasomatism by H₂O-rich melts. We therefore favour diamond precipitation by oxidation of CH₄-rich fluids with highly fractionated trace element patterns which are possibly due to “chromatographic” fractionation processes. Received: 27 January 1996 / Accepted: 5 May 1997     

Petrological constraints on seismic properties of the Slave upper mantle (Northern Canada)

Modes and compositions of minerals in Slave mantle xenoliths, together with their pressures and temperatures of equilibrium were used to derive model depth profiles of P- and S-wave velocities (Vp, Vs) for composites equivalent to peridotite, pyroxenite and eclogite. The rocks were modeled as isotropic aggregates with uniform distribution of crystal orientations, based on single-crystal elastic moduli and volume fractions of constituent minerals. Calculated seismic wave velocities are adjusted for in situ pressure and temperature conditions using (1) experimental P- and T- derivatives for bulk rocks' Vp and Vs, and (2) calculated P- and T- derivatives for bulk rocks' elastic moduli and densities. The peridotite seismic profiles match well with the globally averaged IASP91 model and with seismic tomography results for the Slave mantle. In peridotite, an observed increase of seismic wave velocities with depth is controlled by lower degrees of chemical depletion in the deeper upper mantle. In eclogite, seismic velocities increase more rapidly with depth than in peridotite. This follows from contrasting first-order pressure derivatives of bulk isotropic moduli for eclogite and peridotite, and from the lower compressibility of eclogite at high pressures. Our calculations suggest that depletion in cratonic mantle has a distinct seismic signature compared to non-cratonic mantle. Depleted mantle on cratons should have slower Vp, faster Vs and should show lower Poisson's ratios due to an orthopyroxene enrichment. For the modelled Slave craton xenoliths, the predicted effect on seismic wave velocities would be up to 0.05 km/s.     

Time constraints on the tectonic evolution of the Eastern Sierras Pampeanas (Central Argentina)

The application of the SHRIMP U/Pb dating technique to zircon and monazite of different rock types of the Sierras de Córdoba provides an important insight into the metamorphic history of the basement domains. Additional constraints on the Pampean metamorphic episode were gained by Pb/Pb stepwise leaching (PbSL) experiments on two titanite and garnet separates. Results indicate that the metamorphic history recorded by Crd-free gneisses (M2) started in the latest Neoproterozoic/earliest Cambrian (553 and 543 Ma) followed by the M4 metamorphism at ~530 Ma that is documented in the diatexites. Zircon ages of 492 Ma in the San Carlos Massif correlate partly with rather low Th/U ratios (<0.1) suggesting their growth by metamorphic fluids. This age is even younger than the PbSL titanite ages of 506 Ma. It is suggested that the fluid alteration relates to the beginning of the Famatinien metamorphic cycle in the neighbouring Sierra de San Luis and has not affected the titanite ages. The PTt evolution can be correlated with the plate tectonic processes responsible for the formation of the Pampean orogene, i.e., the accretion of the Pampean basement to the Río de La Plata craton (M2) and the later collision of the Western Pampean basement with the Pampean basement.     

Experimental and major element constraints on the evolution of lavas from Lihir Island,Papua New Guinea

The major element chemistry of SiO₂-undersaturated arc lavas from Lihir Island, Papua New Guinea, and 1 atmosphere experiments on an alkali basalt from this island show complex polybaric fractionation affected this suite of lavas. Low Ni and MgO are typical of these arc lavas and result from olivine fractionation, probably at high pressure. Fractionation at low pressure (<5 kb) produces two evolutionary trends. Separation of clinopyroxene, plagioclase and minor olivine from the primitive lavas results in increasing normative nepheline contents and major element trends similar to those of the experiments. In contrast, addition of magnetite and amphibole to the fractionating assemblage in the evolved lavas results in decreasing normative nepheline and major element trends which are markedly different from those of the experiments. The composition of experimental glasses and 1 atmosphere liquid lines of descent, derived from anhydrous melting experiments run at the fayalite-magnetite-quartz (FMQ) buffer and at higher oxygen fugacities, are displaced from the lavas on oxide-oxide plots. HighfO₂ produces high Fe³⁺/Fe²⁺ and the early crystallization of abundant magnetite, and high H₂O contents are responsible for crystallization of amphibole. Crystal fractionation of these phases and the high Fe³⁺/Fe²⁺ are responsible for the displacement of the lavas and experimental glasses in mineral projection schemes from the 1 atmosphere olivine-clinopyroxene-plagioclase saturation boundary of Sack et al. (1987).     

Relation between trace and major element composition of the Chitaldrug metabasalts,Mysore, India,and the Archaean mantle

The ferromagnesium trace-element content of the Chitaldrug metabasalts is not compatable with its normative composition. The major elements resemble quartz-normative tholeiites and some trace-elements like Co are even higher or similar to that of olivine-normative tholeiites or the deep-oceanic tholeiites. The relationship between MgO and ferromagnesium traces is sympathetic but of very low order. The high ferromagnesium trace content in this suite and its poor relation with major elements suggest that probably the Archaean/Early Precambrian upper mantle had higher levels of these elements than the present mantle. Lateral compositional inhomogeneities in the Archaean upper mantle are also indicated from the available trace-element data over the Archaean metabasalts from different shields.     

Os isotopes in mantle xenoliths from the Eifel volcanic field and the Vogelsberg (Germany): age constraints on the lithospheric mantle

The effects of mantle metasomatism on the sulfide phase in mantle xenoliths in general, and on the Os isotopic system in particular, have received increased attention in recent years. Here, we report on Os isotopic systematics of metasomatized mantle xenoliths from the late Quaternary Eifel (Dreiser Weiher and Meerfelder Maar) and neighboring Vogelsberg volcanic fields, which provide insight into the effects of melt extraction and metasomatism on Os isotopes and place constraints on the evolution of the lithospheric mantle component beneath central Europe. Sixteen harzburgite, lherzolite, and pyroxenite xenoliths from the Eifel and two lherzolite xenoliths from the Vogelsberg were analyzed for Os isotopes. Samples from the anhydrous peridotite suite (Ib) are highly variable in their Os isotopes, ranging from subchondritic values (¹⁸⁷Os/¹⁸⁸Os=0.1236) to suprachondritic values (¹⁸⁷Os/¹⁸⁸Os=0.1420), indicating that some of these samples have been overprinted by the addition of radiogenic Os and have lost the primary mantle Os that was presumably present. The suprachondritic values suggest a source for this Os in a reservoir with a time-integrated Re/Os ratio greater than that of the bulk Earth. Eifel samples with Os contents >1.5 ng/g from the hydrous suite (Ia) have relatively unradiogenic Os isotope compositions (¹⁸⁷Os/¹⁸⁸Os=0.1208-0.1237) and Al₂O₃-Os isotopic systematics consistent with ancient melt depletion and isolation from the convecting asthenospheric mantle for time periods similar to the age of the overlying crust (~1.5 Ga) as well with results from peridotite massifs in the European region. The LREE-metasomatism and the enrichment of Os (up to 6.47 ng/g) and As (sulfide metasomatism?) in the hydrous suite is strongly inversely correlated with the Os isotope ratios, demonstrating that mantle processes such as metasomatism can significantly modify the Os isotope chemistry of mantle xenoliths.     

Experimental study of Cl solubility in hydrous alkaline melts: constraints on the theoretical maximum amount of Cl in trachytic and phonolitic melts

. Cl solubility in evolved alkaline melts was investigated at 860-930 °C and pressures of 25 to 250 MPa using natural trachytes and a synthetic phonolite equilibrated with subcritical fluids in the H₂O-(Na,K)Cl system (i.e. silicate melt coexisted with water-rich aqueous fluid and a saline brine). Fluid phase characteristics were identified by examination of fluid inclusions present in the run product glasses and the fluid bulk composition was calculated by mass balance. The Cl contents of trachytic glasses coexisting with subcritical fluids increase linearly with decreasing pressure from 250 to 25 MPa and range from 0.37 to 0.90 wt%; Cl in the phonolitic glass ranges from 0.35 to 0.59 wt%. These values are approximately twice those found in metaluminous rhyolitic melts under similar conditions. Variations from peralkaline to peraluminous composition has little effect on Cl solubility in trachytes, whereas it is a more important factor in phonolites. More generally, melt structure, in particular non-bringing oxygen, appears to strongly influence Cl solubility in silicate melts. The negative correlation between pressure and melt Cl content is governed by the large negative partial volume of NaCl in the vapour phase. No change in Cl solubility is observed between 200 and 250 MPa. Comparison of our experimental results with Cl abundance in glass inclusion and matrix glass from Italian volcanoes can be used to identify those eruptive products preserved in the geologic record which may have been associated with large Cl emissions.     

Platinum-group element abundances in the upper mantle: new constraints from in situ and whole-rock analyses of Massif Central xenoliths (France)

Fourteen peridotite xenoliths collected in the Massif Central neogene volcanic province (France) have been analyzed for platinum-group elements (PGE), Au, Cu, S, and Se. Their total PGE contents range between 3 and 30 ppb and their PGE relative abundances from 0.01 to 0.001 × CI-chondrites, respectively. Positive correlations between total PGE contents and Se suggest that all of the PGE are hosted mainly in base metal sulfides (monosulfide solid solution [Mss], pentlandite, and Cu-rich sulfides [chalcopyrite/isocubanite]). Laser ablation microprobe-inductively coupled plasma mass spectrometry analyses support this conclusion while suggesting that, as observed in experiments on the Cu-Fe-Ni-S system, the Mss preferentially accommodate refractory PGEs (Os, Ir, Ru, and Rh) and Cu-rich sulfides concentrate Pd and Au. Poikiloblastic peridotites pervasively percolated by large silicate melt fractions at high temperature (1200°C) display the lowest Se (<2.3 ppb) and the lowest PGE contents (0.001 × CI-chondrites). In these rocks, the total PGE budget inherited from the primitive mantle was reduced by 80%, probably because intergranular sulfides were completely removed by the silicate melt. In contrast, protogranular peridotites metasomatized by small fractions of volatile-rich melts are enriched in Pt, Pd, and Au and display suprachondritic Pd/Ir ratios (1.9). The palladium-group PGE (PPGE) enrichment is consistent with precipitation of Cu-Ni-rich sulfides from the metasomatic melts. In spite of strong light rare earth element (LREE) enrichments (Ce/Yb_N < 10), the three harzburgites analyzed still display chondrite-normalized PGE patterns typical of partial melting residues, i.e., depleted in Pd and Pt relative to Ir and Ru. Likewise, coarse-granular lherzolites, a common rock type in Massif Central xenoliths, display Pd/Ir, Ru/Ir, Rh/Ir, and Pt/Ir within the 15% uncertainty range of chondritic meteorites. These rocks do not contradict the late-veneer hypothesis that ascribes the PGE budget of the Earth to a late-accreting chondritic component; however, speculations about this component from the Pd/Ir and Pt/Ir ratios of basalt-borne xenoliths may be premature.     

Constraints on metasomatized mantle under Central South America: evidence from Jurassic alkaline lamprophyre dykes from the Eastern Cordillera, NM Argentina

In the Río Grande Valley, NW Argentina, several porphyritic panidiomorphic, ocelli-bearing dykes and sills intrude the Neoproterozoic to lower Paleozoic basement of the Eastern Cordillera. New petrographical and geochemical data permit us to classify these rocks as ocellar-analcime monchiquites, a feldspar-free variety of alkaline lamprophyre composed of Ti-rich-diopside/augite, Ti-rich biotite/phlogopite, forsteritic olivine, titanian-pargasite and analcime, with abundant ocelli filled with analcime/carbonate. In terms of geochemical compositions they are characterized by LILE and LREE enrichment and lack of Nb-Ta and Eu anomalies. The ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd initial ratios range between 0.70377 to 0.70781 and 0.512506 and 0.512716 respectively, and T_DM model ages vary between 0.25–0.64 Ga. A K-Ar age of 163?±?9 Ma suggests that these rocks are related to the pre-rifting stage of the Mesozoic-Cenozoic continental Salta Rift in NW Argentina. Partial melting of a heterogeneous enriched metasomatized lithospheric mantle, magma mixing and fractionation are envisaged to explain the petrographic, geochemical and isotope characteristics of these magmas.     

Impact of the 1960 major subduction earthquake in Northern Patagonia (Chile,Argentina)

The recent sedimentation processes in four contrasting lacustrine and marine basins of Northern Patagonia are documented by high-resolution seismic reflection profiling and short cores at selected sites in deep lacustrine basins. The regional correlation of the cores is provided by the combination of ¹³⁷Cs dating in lakes Puyehue (Chile) and Frías (Argentina), and by the identification of Cordon Caulle 1921–22 and 1960 tephras in lakes Puyehue and Nahuel Huapi (Argentina) and in their catchment areas. This event stratigraphy allows correlation of the formation of striking sedimentary events in these basins with the consequences of the May–June 1960 earthquakes and the induced Cordon Caulle eruption along the Liquiñe-Ofqui Fault Zone (LOFZ) in the Andes. While this catastrophe induced a major hyperpycnal flood deposit of ca. 3×10⁶ m³ in the proximal basin of Lago Puyehue, it only triggered an unusual organic rich layer in the proximal basin of Lago Frías, as well as destructive waves and a large sub-aqueous slide in the distal basin of Lago Nahuel Huapi. A very recent mega-turbidite in the two distal basins of Reloncavi fjord located close to the LOFZ suggests that 1960 co-seismic movements in this area may have triggered the remobilization of ca. 187×10⁶ m³ of marine sediments.