西秦岭多哇地区萨日加岩体LA-ICP-MS锆石U-Pb年龄、地球化学特征及其地质意义

西秦岭造山带发育大量的印支期高钾钙碱性花岗岩,它们的成岩时代和岩石成因对认识西秦岭岩浆活动和构造演化具有重要意义。对西秦岭多哇地区萨日加岩体进行了详细的野外地质调查、岩相学观察、LA-ICP-MS锆石U-Pb定年和全岩地球化学研究,旨在查明该岩体的年龄、成因类型以及成岩地球动力学背景。结果表明:萨日加岩体由英安斑岩、花岗斑岩及少量石英闪长岩组成;花岗斑岩LA-ICP-MS锆石U-Pb年龄为(238.2±2.6)Ma(平均标准权重偏差(MSWD)为1.7);萨日加岩体属于过铝质高钾钙碱性岩石系列,富集大离子亲石元素Th、Rb、K和轻稀土元素,亏损高场强元素Nb、Ta、Ti等,指示其岩浆源区具有壳幔混合的特征;岩石的主量、微量元素特征显示,英安斑岩属于I型花岗岩,形成于洋-陆俯冲岛弧环境;花岗斑岩倾向于S型花岗岩,形成于大陆碰撞构造环境。由此认为,萨日加岩体形成于晚三叠世西秦岭由洋-陆俯冲岛弧向陆-陆碰撞转变的构造环境。     

西秦岭大水金矿岩浆岩年代学、地球化学特征

西秦岭大水金矿床与其周围伴生的中酸性小岩体的成因关系,直接影响矿床成因的划分和深部资源的开发。中酸性岩浆岩的成因、源区性质及岩体规模对金矿成矿有重要影响。大水金矿岩浆岩地球化学研究结果显示:岩浆系列属于高钾钙碱性系列;岩体球粒陨石标准化稀土元素配分模式具有轻稀土元素富集、重稀土元素亏损、Eu正异常的特征;岩体洋中脊花岗岩标准化微量元素蛛网图显示其富集大离子亲石元素K、Rb、Ba、Th等,亏损高场强元素Nb、Ta、Hf、Zr、Sm、Y、Yb等,花岗岩的w(Sr)-w(Yb)分类属于高Sr、低Yb"C"型埃达克岩。LA-ICP-MS锆石U-Pb法测年获得大水金矿格尔括合岩体和竖井941岩脉的锆石U-Pb年龄分别为(215.8±1.3)、(202.9±1.5)Ma;成矿热液蚀变叠加在脉岩之上,成矿年龄应晚于202.9 Ma的脉岩年龄。Sr-Nd同位素组成具有高初始N(87Sr)/N(86Sr)值、低εNd的特点,模式年龄为1.29~1.47Ga。εSr(t)-εNd(t)图解表明岩浆源区为下地壳;εNd(t)-初始N(87Sr)/N(86Sr)图解暗示西秦岭存在统一的岩浆源区。因此,西秦岭大水金矿在成因上与高Sr、低Yb"C"型埃达克岩密切相关。     

新疆阿尔泰大喀拉苏花岗岩年代学、地球化学特征及其构造意义

大喀拉苏似斑状黑云母二长花岗岩出露于新疆阿尔泰南缘,是研究阿尔泰二叠纪构造环境的理想对象。采用LA-Q-ICP-MS锆石U-Pb定年获得其加权平均年龄为(261.4±2.1)Ma,属中二叠世。岩石具有高Si(SiO2质量分数为69.03%~70.94%)、富Al(Al2O3为14.18%~14.71%)、富K(Na2O/K2O值为0.70~0.87)的特征,A/CNK值为1.02~1.04,属高钾钙碱性弱过铝质花岗岩,显示I-A过渡型特点。微量元素表现出Rb、Th、Pb、Nd、Sm的相对正异常;Ti、P、Sr和Ba的负异常;稀土元素显示轻稀土元素强富集、重稀土元素平缓及明显的负Eu异常(0.55~0.82)。岩石的εNd(t)值和两阶段模式年龄分别为2.66~3.01和0.79~0.80Ga。综合区域地质资料和岩体地球化学特征,认为大喀拉苏黑云母二长花岗岩形成于后造山伸展环境,岩浆来源于地幔和地壳物质的混合,并在岩浆源区经历了分离结晶作用。     

北秦岭孤山坪地区辉长岩地球化学特征、锆石U-Pb年龄及Lu-Hf同位素组成

北秦岭孤山坪地区辉长岩的研究程度较低,而辉长岩通常是下地壳或上地幔玄武质岩浆结晶的产物,可以在一定程度上反映特定地质时代壳幔演化格局。为了研究其成因和形成机制,对其锆石U-Pb年代学、岩石地球化学及锆石Hf同位素进行了研究。结果表明:辉长岩的侵位结晶年龄为（457.4±1.4）Ma,即形成于晚奥陶世;总体上富集轻稀土元素和大离子亲石元素K、Rb、Ba、Sr,相对亏损高场强元素Nb、P、Ti、Zr,指示其可能形成于活动陆缘弧环境;锆石ε_Hf（t）=6.4~9.1,一阶段模式年龄（t_DM1=822~708 Ma）和二阶段模式年龄（t_DM2=1 268~1 025 Ma）均大于锆石结晶年龄。综合研究认为,孤山坪地区辉长岩原始岩浆应来源于受俯冲流体交代作用改造的富集型地幔,可能形成于二郎坪群早期岛弧与秦岭地块之间的弧陆碰撞所导致的增生造山作用过程,代表了晚奥陶世二郎坪群由岛弧向弧后盆地转化的初始岩浆记录。本研究可以为北秦岭早古生代构造演化的厘定提供进一步的约束资料。      

安徽贵池地区燕山期岩浆岩与铜金钼成矿关系:来自地质-地球化学-地球物理证据

安徽贵池地区是长江中下游成矿带的重要组成部分,区内金、银、铜、钼、硫等矿产资源丰富。系统研究了贵池地区地质、岩浆岩、地球化学-地球物理等特征与金银多金属矿床的成矿关系,对抛刀岭金矿、乌石金及多金属矿、朱家冲金矿、铜山铜矿等多金属矿进行详细分析,总结各岩体的地球化学属性,并对贵池地区斑岩型矿床进行了重点研究,分析其成矿专属性。将贵池地区成岩成矿时间划分为两期:第一期是140 Ma左右的岩浆活动及成矿作用,为早白垩世(燕山早期),主要与铜金矿床有关;第二期是125 Ma左右的岩浆活动及成矿作用,主要与钼(铜)矿床(化)有关。这两期岩浆活动及成矿作用包括高钾钙碱性、碱性两个成岩系列,岩石类型以中酸性—酸性花岗闪长岩、花岗岩为主,与长江中下游地区其他矿集区的成矿作用类似。将地质标志、地球物理标志以及地球化学标志结合,建立了该区找矿标志,从而有助于区内金、银(铅锌)及铜钼等金属矿成矿理论的丰富及成矿规律的认识,为区内找矿突破提供科学依据。     

南秦岭胭脂坝花岗岩成因:锆石U-Pb年龄、地球化学和Sr-Nd-Pb同位素的制约

秦岭造山带广泛发育新元古代、古生代、早中生代和晚中生代岩浆作用,是长期复杂造山作用的结果。胭脂坝花岗岩岩体出露于南秦岭宁陕地区五龙岩体群的最东部,是南秦岭早中生代花岗岩的重要组成部分。5个花岗岩样品的锆石U-Pb定年结果分别为(202.9±3.5)、(201.0±3.0)、(202.1±2.6)、(200.4±5.4)、(~(205).5±3.3)Ma,平均年龄为(201.9±1.5)Ma,属于早中生代五龙岩体群岩浆作用中晚期的产物。岩石地球化学成分显示该岩体的主体为黑云母花岗岩,具有高硅、富碱的地球化学特征,富集大离子亲石元素,亏损高场强元素,属于弱过铝质、高钾钙碱性岩石系列。初始Sr同位素组成为0.704 31~0.706 78,ε_(Nd)_(t)值为-5.2~-2.0,初始Pb同位素组成相对高,(N(~(206) Pb)/N(~(204) Pb))_(t)=17.737~18.191,(N(~(207) Pb)/N(~(204) Pb))_(t)=15.511~15.574,(N(~(208)Pb)/N(~(204)Pb))_(t)=37.439~38.071。较高的放射性成因Pb同位素组成说明胭脂坝岩浆源区具有扬子地块的属性;初始Sr同位素组成和ε_(Nd)_(t)值随着SiO2含量的升高呈现出线性变化趋势,说明胭脂坝花岗质岩浆在上升侵位过程中存在围岩物质的同化作用;结合与新元古代火山沉积岩(如耀岭河群、武当群、碧口群)相似的初始Sr-Nd同位素组成,推测胭脂坝岩体的岩浆源区主要是具有扬子地块属性的新元古代地壳物质。     

胶西北秦姑庵花岗岩体岩石成因及对金成矿的启示：元素地球化学、锆石U—Pb年代学及Lu—Hf同位素制约

本文通过对分布于胶西北地区南部的秦姑庵花岗岩体开展详细的岩石学、岩石地球化学、锆石UPb年代学和锆石LuHf同位素地球化学研究,识别出粗中粒二长花岗岩、斑状中粒二长花岗岩和细粒黑云母二长花岗岩,它们具有相同的地球化学特征和同位素组成,呈连续演化关系,为同源岩浆活动的产物。岩石地球化学研究表明,花岗岩具有高的SiO2（68.73％～75.27％）、全碱（K2O+Na2O=8.39％～8.93％）,低的Al2O3（13.38％～15.84％）、MgO（0.14％～0.98%）、P2O5（0.02％～0.13%）、Sr（118×10-6～520×10-6）、Y（7.03×10-6～12.30×10-6）、Yb（0.78×10-6～1.34×10-6）含量特征,轻稀土（LREE）富集、重稀土（HREE）相对亏损（LREE／HREE=18.39～26.72）,轻、重稀土元素分馏明显［(La/Yb)N＝17.13～42.58］,Eu中等负异常（δEu=0.49～0.76）,富集大离子亲石元素（LILE）,亏损高场强元素（HFSE）。锆石SHRIMP定年结果表明,斑状中粒二长花岗岩形成于（119.9±1.3）Ma,秦姑庵岩体形成于早白垩世晚期,时代上与胶东地区伟德山型花岗岩一致。锆石原位LuHf同位素分析表明,εHf（t）为24.07～19.27,二阶段模式年龄TDM2为2398～2696 Ma,岩浆源区主要来源于古元古代物质的部分熔融,少部分为新太古代基底岩石。岩体形成于加厚下地壳的下部,其残留相可能由斜长石+辉石+角闪石+石榴石组成,相当于麻粒岩相或石榴石麻粒岩相。花岗岩的同位素年龄与胶西北金矿床的成矿时代一致,指示120Ma左右的岩浆活动为金成矿提供了流体和热动力条件。     

库米什地区火山岩岩石地球化学特征及大地构造环境

库米什地区火山岩属该区蛇绿岩套的组成部分,形成于晚泥盆世,以中性和酸性岩石为主,火山碎屑岩较发育,具有钙碱性火山岩套的特征。岩套内的沉积夹层具有远海沉积的性质。火山岩岩石化学特征属钙碱性系列;微量元素地球化学证明岩浆起源于消减板块之上的地幔楔形区;稀有元素地球化学特征与安山岩的特征相符。综合分析这些证据发现,该区火山岩形成于弧后盆地环境。     

阿尔金曼特里克地区亚干布阳花岗质片麻岩地球化学特征及其成因

为了解阿尔金南缘在新元古代早期的构造-岩浆事件,选取曼特里克地区亚干布阳花岗质片麻岩进行详细的岩石学、同位素年代学和地球化学研究。结果表明：亚干布阳花岗质片麻岩形成于新元古代青白口纪,锆石U-Pb年龄为(880.3±3.4)Ma;岩石属过铝质、钙碱性系列的镁质花岗岩,轻、重稀土元素分馏明显,Nb、Ta、Zr、Hf等高场强元素亏损,具有典型的地壳重熔型花岗岩特征,其岩浆来源于下地壳角闪岩相基性岩类的部分熔融,形成于同碰撞花岗岩区;阿尔金南缘新元古代早期的构造-岩浆事件可能对应于新元古代Rodinia超大陆汇聚事件,说明塔里木板块和柴达木板块之间在新元古代早期曾经存在板块的汇聚碰撞。     

内蒙古准和热音苏木地区岩石元素地球化学特征及成矿性分析

内蒙古准和热音苏木地区属古亚洲成矿域内蒙古-大兴安岭成矿省二连-东乌旗晚古生代-中生代成矿带,是我国重要的铜及多金属集中分布区。野外调查采集了地表岩石(打块)样品61件,化验分析Au,Ag,Cu,Pb,Zn,As,Sb,Bi,Hg,W,Sn,Mo,Cd,Co,Cr,Ni共16种元素。通过综合岩石中元素的地球化学分布特征信息,分析岩石元素的含量、各岩石分区元素的含量、岩石元素富集离散等特征,利用因子分析、聚类分析,研究岩石元素的组合特征,对元素组合的物质属性进行判定,分析成矿性,指明了找矿方向,指出了该区具有寻找硫化物型的Pb,Cu,Bi有色金属矿产及与安山岩有关的Cd,Co矿的找矿潜力。     

小秦岭地区太华群锆石U-Pb年龄及华北克拉通南缘地壳演化

以小秦岭地区太华群二长片麻岩为研究对象,分析其地球化学、锆石U-Pb年龄和Hf同位素特征。地球化学分析显示其原岩为高钾钙碱性花岗质岩石,稀土元素总含量较高(229×10-6),轻、重稀土元素分馏明显(w(La)N/w(Yb)N=45.39),有明显的Eu负异常(0.43)。原始地幔标准化微量元素蛛网图显示其富集Rb、Ba、Th、U等大离子亲石元素和亏损Nb、Ta、Sr、P、Ti等高场强元素。锆石U-Pb定年结果显示,其原岩的形成时代为古元古代早期(2.47Ga)。锆石Hf同位素分析结果显示:初始N(176 Hf)/N(177 Hf)值变化范围很小,为0.281 284~0.281 328,εHf(t)值均为正值(0.93~5.18);二阶段Hf模式年龄为2.70~2.89Ga,新生地壳(现代岛弧火山)Hf模式年龄为2.54~2.73Ga,接近于锆石结晶年龄(2.47Ga),指示华北克拉通南缘在这一时期有明显的新生地壳生长。华北克拉通南缘在新太古代早期(2.7~2.9Ga)、新太古代晚期—古元古代早期(2.2~2.5Ga)和古元古代中期(1.8~2.1Ga)有3期重要的构造热事件。新太古代早期及晚期有明显的新生地壳生长(εHf(t)0),新太古代晚期—古元古代早期和古元古代中期的岩浆活动有明显的新生地壳生长,同时还伴随有古老地壳物质的再循环和改造(εHf(t)0或εHf(t)0)。     

Geochemistry and zircon U-Pb chronology of quartz porphyry in Yuejinshan Fe-polymetallic deposit of Heilongjiang

Quartz porphyry in Yuejinshan Fe-polymetallic deposit is one of the rock masses, which formed the granite belt relating to the late Yanshanian skarn-type Fe-polymetallic deposits in the eastern Heilongjiang, and is also closely related to the metallogenic space of the Fe-polymetallic deposits. Quartz porphyry has the zircon U-Pb concordia age of 125.0±1.1 Ma, overall showing high Si(SiO_2=74.48%--75.00%), rich alkaline(Na_2O+K_2O=7.93%--8.17%, K_2O/Na_2O=1.39--1.46), and poor Mg(MgO=0.27%--0.31%), with the A/CNK value being 0.95--0.99, having the characteristics of obvious enrichment of LREE and medium Eu negative anomaly(0.69--0.74), indicating that the rock belongs to quasi-aluminous high potassium calc-alkaline series and has the same characteristics as those of the I-type granite. The rock is also characterized by the enrichment of LILE and active incompatible elements, and depletion of HFSE such as Nb, Ta, P and Ti, with the Mg~# value being 32--37, indicating that the rock originated from partial melting of crustal materials. It can be concluded from the above characteristics or data and from the distribution of contemporary magmatic rocks in the area, that quartz porphyry in Yuejinshan Fe-polymetallic deposit was formed in a tectonic background of the subduction of the paleo-Pacific plate in late Yanshanian.     

鲁西徂徕山地区傲来山序列二长花岗岩锆石LA-ICP-MS U-Pb定年及其地质意义

出露于鲁西徂徕山地区的傲来山序列二长花岗岩是鲁西新太古代岩浆作用的重要记录,在野外地质工作的基础上,通过对其进行锆石LA-ICP-MS U-Pb同位素年代学研究,得到了二长花岗岩的形成时代,并对鲁西地区新太古代的岩浆活动进行了讨论。研究得到,谐和度90%的锆石中存在岩浆锆石~2 520Ma和继承性岩浆锆石2611Ma~2 766Ma两个年龄区间。岩浆锆石的加权平均年龄为(2 525±18)Ma,认为这一年龄代表了二长花岗岩的形成年龄。2 611Ma~2 766Ma继承性岩浆锆石的存在反映了鲁西地区至少经历了2次壳源物质的重熔和加入。     

胶东崮庄闪长岩锆石U-Pb年代学和岩石地球化学研究

对胶东崮庄岩体黑云母闪长岩进行了岩石学、岩石地球化学和年代学研究。研究表明:崮庄岩体黑云母闪长岩为钙碱性系列岩石,岩石富集大离子亲石元素(如K,Ba,Rb)、LREE和活泼的不相容元素(如Th,U),相对亏损高场强元素(如Nb,Ta,Ti,P),崮庄闪长岩属壳幔混合成因,即由交代地幔部分熔融形成的基性岩浆与地壳物质熔融形成的酸性岩浆混合形成的。构造环境判别显示崮庄闪长岩属火山弧花岗岩,暗示伟德山序列花岗岩与古太平洋板块向欧亚板块俯冲密切相关。崮庄闪长岩LA-ICP-MS锆石U-Pb年龄值为(111.7±0.6)Ma,属燕山期早白垩世。     

Petrogenesis of Adakitic Intrusive Rocks in Xu-Huai Area, Eastern China

The research of the petrology and the geochemistry of the Mosozoic intrusive rocks in Xu-Huai area indicated that they are mainly composition of dioritic porphyry and monzodioritic porphyry, and the features of the petrology and geochemistry of the Mosozoic intrusive rocks are extremely similar to those with the typical adakites. Combined with the petrography and the testimated results of the deep-seated xenoliths in the intrusive rocks, it indicates that the petrogenesis of the Mosozoic intrusive rocks could be resulted from the partial melting of amphibole-bearing garnet pyroxenite and garnet amphibolite in lower continental crust in this area.     

Zircon U-Pb age,geochemical and Nd isotopic data of Middle Jurassic high-Mg dioritic dike in Liaodong Peninsula,NE China

Zircon LA-ICP-MS U-Pb age, geochemical and Nd isotopic data are presented for a newly recognized high-Mg dioritic dike from Haicheng, Liaodong Peninsula, NE China, to constrain its petrogenesis. The zircons from the high-Mg diorite exhibit striped absorption and oscillatory growth zoning in the cathodoluminescence （CL） images, and have high Th/U ratios （0. 05-0.9）, indicating a magma origin. Zircon LA-ICP-MS U-Pb dating indicates that 206pb/238U ages of 12 spots of zircons are between 167 Ma and 178 Ma, yielding a weighted mean 206pb/238U age of 172 ＋ 2 Ma （MSWD =4. 1 ）, which represents the forming age of the high-Mg dioritic dike, i. e. Middle Jurassic. Geochemically, the samples have SiO2 =55.4-60. 6 wt. % , Na20 =2. 2-2.76 wt. % , K20 = 1.32-2. 02 wt. % and （Na2O ＋ K2O） =3.82--4. 47 wt. %, belonging to sub-alkaline series and displaying a calc-alkaline evolutionary trend. They are characterized by high MgO （4. 75-6.85 wt. % ）, Mg# （55-61）, Cr（130-262 ppm）, Ni（63-130 ppm）, Sr（568-857 ppm）, and Ba（484-1 130 ppm） contents, with geochemical features analogous to those of high-Mg adakites. They show variable end （t） values （ - 1.3 to - 3.9） , with a weighted value of - 2. 7, which plot intermediately between the field of the ancient continental crust and the depleted mantle source, indicating that both the lower crust and mantle source are necessary for the generation of the parent magma of the Haicheng high-Mg diorites. The Haicheng high-Mg dioritic dike in the Liaodong Peninsula and the Jurassic magmatism in the eastern North China Craton formed under a continental crustal thickening setting that may be related to subduction of the Paleo-Pacific oceanic plate.     

Zircon U-Pb geochronology and geochemistry of syenogranites in western Niubiziliang,northwestern Qaidam,Qinghai

The study presents the results of U-Pb dating of zircons and whole-rock geochemical analyses of a syenogranite located in the western Niubiziliang area,China with the aim of determining its formation time,petrogenesis and the regional tectonic setting. Zircons within the syenogranite are euhedral-subhedral and display rhythmic growth zoning,indicating a magmatic origin. Zircon U-Pb data obtained by LA-ICP-MS indicate the syenogranite formed in the Late Permian (260.7±1.5 Ma). The w(SiO_2) of syenogranites is 70.82%--73.59%,w(Al_2O_3) is 13.49%--14.82%,and w(Na_2O + K_2O) is 7.85%--8.52%,and yield K_2O/Na_2O ratios of 1.06--1.26. Therefore,the syenogranites belong to the high-K calc-alkaline and metaluminous (A/CNK 1,A/NK 1) series which display I-type granites similarly. The syenogranites also show the geochemical characteristics of volcanic arc rocks,being enriched in large-ion lithophile elements (LILEs; K,Rb) and light rare-earth elements (LREEs; La,Ce,Sm,Nd),but depleted in high field strength elements( HFSEs; Ta,Nb,P,Ti). On the whole,trace element ratios are close to the mean of the Earth's crust,indicating a lowercrust magma source. The low Sr (161--214) ×10~(-6) and Yb (1.08--1.80)×10~(-6) concentrations indicate that plagioclase and hornblende are residual mineral phases in the source. The regional geology and whole-rock geochemistry suggest that the formation of the syenogranites was related to subduction of the Zongwulong Ocean crust,and the north margin of Qaidam Block during the Late Permian was in an active continental margin tectonic setting.     

Zircon U-Pb age,geochemical and Nd isotopic data of Middle Jurassic high-Mg dioritic dike in Liaodong Peninsula,NE China

Zircon LA-ICP-MS U-Pb age,geochemical and Nd isotopic data are presented for a newly recognized high-Mg dioritic dike from Haicheng,Liaodong Peninsula,NE China,to constrain its petrogenesis. The zircons from the high-Mg diorite exhibit striped absorption and oscillatory growth zoning in the cathodoluminescence( CL) images,and have high Th/U ratios( 0. 05--0. 9),indicating a magma origin. Zircon LA-ICP-MS U-Pb dating indicates that206 Pb /238 U ages of 12 spots of zircons are between 167 Ma and 178 Ma,yielding a weighted mean206 Pb /238 U age of 172 ± 2 Ma( MSWD = 4. 1),which represents the forming age of the high-Mg dioritic dike,i. e. Middle Jurassic. Geochemically,the samples have SiO2= 55. 4--60. 6 wt. %,Na2 O = 2. 2--2. 76 wt. %,K2 O = 1. 32--2. 02 wt. % and( Na2 O + K2O) = 3. 82--4. 47 wt. %,belonging to sub-alkaline series and displaying a calc-alkaline evolutionary trend. They are characterized by high MgO( 4. 75--6. 85 wt. %),Mg#( 55--61),Cr( 130--262 ppm),Ni( 63--130 ppm),Sr( 568--857 ppm),and Ba( 484--1 130 ppm) contents,with geochemical features analogous to those of high-Mg adakites. They show variable εNd( t) values(-1. 3 to- 3. 9),with a weighted value of- 2. 7,which plot intermediately between the field of the ancient continental crust and the depleted mantle source,indicating that both the lower crust and mantle source are necessary for the generation of the parent magma of the Haicheng high-Mg diorites. The Haicheng high-Mg dioritic dike in the Liaodong Peninsula and the Jurassic magmatism in the eastern North China Craton formed under a continental crustal thickening setting that may be related to subduction of the Paleo-Pacific oceanic plate.