GDX-502树脂富集高效液相色谱法测定地表水中酚类化合物

采用自制GDX-502固相萃取小柱萃取水中苯酚、对硝基酚、间甲酚、2，4-二氯酚、2，4，6-三氯酚、五氯酚等6种酚类化合物，以乙腈作为洗脱剂，选择280nm和290nm双波长紫外高效液相色谱进行检测。结果表明，方法检出限为0．01-0．05mg／L，IL水的平均加标回收率为82．5％-95．0％，精密度（RSD，n=7）为3．6％-9．2％。方法用于实际地表水中痕量酚类化合物的检测，操作简单，有机溶剂用量少，分析效率高；萃取小柱可多次重复使用，分析成本低。     

X射线荧光光谱法同时测定煤中砷硫磷氯

采用人工混配有限煤炭标准样品粉末直接压片制样，X射线荧光光谱仪同时测量煤中的砷、硫、磷、氯。优化了样品粒度、样品量、助磨剂、制样压力和保压时间等实验条件，用可变α系数法进行基体校正。方法测定范围为As0．0015％-0．0051％、S0．21％-1．44％、P0．003％～0．096％、C10．01％-0．11％；检出限为As 1．2μg／g、S22μg／g、P2．1μg／g、C12．0μg／g。与标准方法对照，结果基本一致。方法快速、简便，满足了煤炭检验需要。     

东疆沙泉子铜和铜铁矿床岩（矿）石地球化学研究与地质找矿前景

沙泉子铜铁矿床安山岩类和闪长岩属偏碱性的钙碱性系列。（玄武）安山岩中含SiO2在49．2％．59．97％，多数样品含铝在16．66％以上，具有高铝玄武安山岩特点，含Na2O为2．19％～5．1％，K2O为0．61％．3．2％，（Na2O＋K2O）为5．32％-7．03％，Na2O／K2O值在1．07-8．36。本区安山岩类和闪长斑岩具有明显的Rb、Th-U-K、La-Ce、Pb和P正异常，富集大离子亲石元素（LILE）和轻稀土元素（LREE），具有明显的Ta．Nb、Sr负异常、中等Eu和Ti负异常，地球化学特征表明它们可能形成在活动大陆边缘上的陆缘岛弧构造背景中。这对于形成大型-超大型斑岩-夕卡岩型铜和铜铁矿床十分有利，深部隐伏矿床的找矿勘查是今后主攻方向。     

河北蔡家营铅-锌-银多金属矿床成矿物理化学条件探讨

蔡家营矿床成矿温度为181-387℃，成矿压力为33．9MPa，流体盐度为5．7％-15．0％NaCl．流体密度为0．74-0．97g／cm^3，pH值为4．746-5．668，Eh值为-0．538--0．512V，fo2为2．29×10^-40-3.98×10^-34，fs2为1.23×10^-16-1.70×10^-10,从早到晚，成矿温度、流体盐度、流体fs2和fo2逐渐降低，而成矿溶液碱性逐渐增强，矿床形成于弱酸性、弱还原一还原的物理化学环境。     

氢化物发生-原子荧光光谱法测定面粉中微量砷

样品用硝酸-高氯酸混合酸消解，考察了氢化物发生-原子荧光光谱法测定面粉中微量砷的实验条件，包括混合酸和还原剂硼氢化钾的用量。方法测定砷的线性范围为0．0—30．0μg／L，仪器的检出限为0．26μg／L，加标回收率为94．0％-104．0％，方法的精密度（RSD，n=11）为1．16％。方法操作简便、快速、灵敏度高。     

氯化钠存在下氯化亚锡-十六烷基三甲基氯化铵体系浮选分离复杂金属基体中锇

研究了氯化钠存在下氯化亚锡-十六烷基三甲基氯化铵体系对Os（Ⅳ）-三氯锡酸络阴离子的浮选行为。实验表明，在盐酸介质中，体系可以浮选分离Os（Ⅳ），其浮选率为95．2％。98.0％。方法加标回收率为94．0％-98．5％，精密度为2．1％-7．7％（RSD，n=5）。方法可用于从大量基体金属中分离Os（Ⅳ），对实际样品分离的分析结果与其他方法推荐值相符。     

西藏过铝花岗岩矿物化学特征及其岩石学意义

本文系统地讨论了西藏过铝花岗岩中斜长石、钾长石、黑云母、白云母和电气石的矿物化学特征。结果表明：岩石中的斜长石均以Ab为主，占78．73％。100％，An分子为0．13％～18．93％，而Or分子仅为0．19％-3．74％；在长石的成分分类图解中多分布于更长石区内，少量分布于钠长石区。钾长石的端元组分中Or含量最高，为81％-98．48％，Ab为1.52％～19．00％，基本不含An分子，在成分分类图解中集中分布在Ab-Or线的正长石区内。斜长石中Ab〉An〉Or，主要属更长石，极少量为中长石；钾长石具有高Or含量，显示Or〉〉Ab〉〉An，属钾透长石。白云母在以22爪氧原子计算的分子式中，Si与Al的阳离子数均较高，其中Si为6．0575-6.6412，属多硅白云母；黑云母中Si阳离子数绝大多数小于6，值介于5．3227-6．1265之间，平均为5．5718；Al离子数为1．8735-2．6464，四面体配位为Si、Al^Ⅳ所占据，八面体配位的阳离子中Al^Ⅵ为0．2101-1．7388，大离子位中以K为主。过铝花岗岩中黑云母的Mg／（Mg＋Fe）比全岩的Mg／（Mg＋Fe）比值略高，但二者具有正相关关系，说明了其成因仍以岩浆成因为主。在云母类矿物的成因图解显示，研究区内大多数黑云母均位于C区，属壳源。     

黑龙江黑河三道湾子金矿床地质地球化学研究

通过氢、氧、硫同位素测试和流体包裹体测温，结合三道湾子金矿床的地质、地球化学特征，探讨了三道湾子金矿矿床成因。研究表明三道湾子金矿为与中生代陆相火山岩有关的中一低温浅成热液矿床。矿石矿化类型为石英脉型。流体包裹体均一温度为150～276℃，盐度(NaCleq)为2．89％～5．82％，平均4．2％。黄铁矿δ^34S值为-3．1‰～ 3．8‰，石英δ^18O值为-11．3‰～-8．5‰，δDv-SMOW值为-110‰～-85‰。     

中国大陆科学深钻主孔岩屑中含钠和锌的尖晶石的发现

一种含钠和锌的尖晶石矿物产于中国大陆科学深钻主孔超镁铁岩中，以出溶的方式存在于钛铁矿和磁铁矿中，长5-60μm，宽2-3μm，化学组成（wB％）为MgO17．143％-22．337％，Al2O3 63．646％～66．492％，FeO9．784％～13．924％，ZnO 1．649％-6．386wt％．Na2O 0．029％～0．219wt％。Na2O与ZnO在尖晶石中的含量呈正相关关系。经同步辐射测得其为尖晶石单晶，空间群为Fm3m，晶胞参数为a=0．83781am。根据尖晶石与钛铁矿、石榴石（pyr=56-58mol％）共生和石榴石退变为顽火辉石和镁绿泥石的特点，表明该尖晶石来自超镁铁岩，它们一起经历了至少为角闪岩相的变质作用。广泛的混溶间断现象及其所造成的出溶结构出现在氧化物中，表现为Mt-Usp、Mt-Spl及Mt-Ilm之间的交生。根据前人有关Mt-Usp和Ilm-Gk-Hem固溶体系的实验。表明主孔岩石的氧逸度相对较低，形成温度应在720℃以上。这些早期在岩浆分离结晶过程中形成的铁钛氧化物出溶体，在后来的超高压变质作用下可能发生再次固溶和因降温减压造成的出溶。     

东疆雅西371-西北坡铜金矿化带下石炭统火山岩地球化学特征与成矿背景

新疆东天山雅西371-西北坡铜金化带中下石炭统火山岩属钙碱性系列。流纹岩类中SiO2（73．96％～78．01％）和Al2O3（11．3％～14．63％）含量高，含Na2O为2．04％～4．15％，K2O为2．74％～3．74％，（Na2O＋K2O）为5．34％～7．03％；流纹岩类属过铝质、中钾-高钾火山岩系列。微量和稀土元素分析结果显示：流纹岩类具有Ti、Nb、P和Ta明显负异常、Sr中等负异常，LREE明显富集，La／Nb值为0．4～2．3，La／Th值0．4—1，Th／Ta值高（6～36．5），具有明显δEu（0．17-0．29）负异常，地球化学特征表明流纹岩类可能形成在活动大陆边缘上的陆缘岛弧构造背景中。本区（含矿）酸性火山岩特征对于寻找与长英质火山岩有关的金属硫化物矿床十分有利，因此认为本区具有较大找矿前景。     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Quaternary stresses revealed by calcite twinning inversion: insights from observations in the Savonnières underground quarry (eastern France)

Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ₁ roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).     

HYDROGEOLOGY

正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level     

METAMORPHIC PETROLOGY

正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),     

SERIALS

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GEOPHYSICAL EXPLORATION

正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-     

PETROLEUM GEOLOGY

正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)