The influence of physicochemical parameters on bioavailability and bioaccessibility of heavy metals in sediments of the intertidal zone of Asaluyeh region,Persian Gulf,Iran

In this research, we have worked on the evaluation of heavy metal contamination in the sediments taken from the intertidal zone of Asaluyeh region using Modified Community Bureau of Reference sequential extraction method (mBCR), the simplified bioaccessibility extraction test (SBET), and calculated enrichment factor (EF). Also, potential influencing factors including sediment characteristics that may affect the heavy metals bioavailability and bioaccessibility were investigated. mBCR extraction analysis indicated that among the metals, Mn, Zn, V, Cu, and Cd exhibit relatively higher mobility, while Ti, Pb, Cr, and Ni occur mainly in the residual fractions. Based on the mean values, the bioaccessibility of metals decreased in the order: Mn (50.01%)>Cd (46.26%)>Zn (14.61%)>V (13.97%)>Pb (10.88%)>Ni (9.2%)>Ti (8.43%)>Cr (6.66%)>Cu (6.23%). The obtained results from the principal component analysis (PCA), EF and mBCR extraction showed that most anthropogenic-derived metals with higher solubility are more bioaccessible compared to those of natural origin. Multiple linear regression analysis demonstrated that the main physicochemical variables of the sediment influencing the bioaccessibility of metals include cation exchange capacity (CEC), pH, and particle size fraction.     

The role of organominerals in the lithification of calcareous lumps within the intertidal sediments of Bubiyan Island,Kuwait, Arabian Gulf

Calcareous lumps of varying sizes and shapes are scattered on the landward part of the muddy intertidal flat along the southern coast of Bubiyan Island, northeast Kuwait. Two main lithotypes are recognized, namely, hard sandy crust fragments which are mostly formed of porous calcareous grainstone (bio-oosparite) and lithified muddy lumps that consist of calcareous wackestone (bio-micrite). They were originally eroded from the soft tidal flat sediments then lithified. Petrographic, mineralogical, and SEM/EDS examinations revealed that lithification of these calcareous lumps is attributed to cementation by biologically influenced organominerals, mainly high magnesium calcite and aragonite. The conditions responsible for the precipitation of these organominerals as well as variation in their mineralogy within each type of these calcareous lumps were discussed.     

Grain size analysis and characterization of sedimentary environment along Thiruchendur coast, Tamilnadu, India

Thiruchendur coast of southern Tamilnadu, India has been studied for grain-size spectrum and textural parameters namely mean, sorting, skewness and kurtosis. The grain-size spectrum shows a marked variation in the berm, high tide line (HTL) and low tide line (LTL) stretches. Variation in energy condition is controlled by geomorphology of the sedimentary beach. Textural pattern shows complicated profile as a result of the fluctuation in the physicochemical conditions due to the sediments and the marine interactions. Abundance of the medium sand to fine sand shows the prevalence of comparatively moderate- to low-energy condition in the Thiruchendur area. Linear discriminate function of the samples indicates an aeolian, shallow marine deposition environment and less influence of fluvial (7 %) process. CM diagram (C = one percentile in microns M = medium in microns) of Thiruchendur coast sediments suggests that deposition takes place by (1) rolling, (2) bottom suspension, (3) graded suspension. This is also supported by the wave energy in different stretches in beach line and also tractive current figure implies the sediments disturbed by the tractive and turbidity currents. The heavy minerals are concentrated in the berm (average, 11.8 %) and high tide line (average, 11.2 %) because of high-energy condition and aeolian action. Quartz microtextures show the mechanical action due to high-energy condition in Manapad and Kuduthalai areas, the chemical action because of to low-energy condition along the Thiruchendur, Kallamozhi areas.     

Late Holocene coseismic uplift on the Hua-tung coast, eastern Taiwan: Evidence from mass mortality of intertidal organisms

The evidence of coseismic uplift on the dynamic, wave-dominated Hua-tung coast fringing the active Coastal Range (eastern Taiwan) has been equivocal, due to complex controls by wave and terrestrial sediment over morphological and ecological systems of the coast. This study, by applying radiocarbon dating methods, demonstrates coseismic-uplift nature of the coast by finding synchronously killed intertidal organisms (mostly boring shell Jouannetia sp.) stranded at different sites of the coast with distinct physiographic characters. Based on these data, together with evidence from wave-cut notch sequences, two coseismic-uplift systems are recognized. One centers around the northern-middle part of the coast and yields events with uplift amounts of maximal 3–6 m and an average recurrence interval of at least several hundred years. The most recent activity of this system, influencing at least 70 km of coast, occurred at ~ 0.9 ka. The earthquake generating this event also triggered extensive landslides/debris flows in the region. Another system, exemplified by the uplift associated with the 2003 Cheng-kung earthquake, centers on the southern part of the coast and yields uplift of likely < 1 m every < 0.2 ky. Two pre-historic events of this system are identified as occurring at ~ 0.7 ka and ~ 1.1 ka. These two coseismic-uplift systems are consistent in position with two anticlinal structures defined by long-term uplift of the coast. However, the areas subjected to maximal coseismic uplift are located off where the climaxes of long-term uplift occur, implying that the latter areas have been uplifted mainly by aseismic and/or relatively frequent/small-magnitude coseismic motion.     

Geomorphology, deformation, and chronology of marine terraces along the pacific coast of central Baja California, Mexico

Three emergent marine terraces are prominent between Playa El Marron and Arroyo El Salinito and comprise the most extensive Pleistocene planation surfaces in central Baja California, Mexico. The deposits of the lowest terrace, the Tomatal, are 120,000 ± 20,000 yr old (Sangamonian?) while the absolute ages of the two higher and older terraces, the Andrés and Aeropuerto, are unknown. The Tomatal terrace is particularly well developed and comprises degraded sea cliffs, paleodunes, and lagoonal sequences. Shingle paleobeach ridges also occur locally and reflect shore progradation and tombolo formation. The Tomatal shoreline is nearly horizontal at 7 ± 1 m above present mean sea level, whereas the older Aeropuerto terrace has been tilted so that it decreases in elevation toward the southeast. Nonetheless, coastal tilting is not nearly as great as at many other localities in California and Baja California. This is despite the fact that the entire Baja California peninsula has been assumed to be tectonically unstable during the Pleistocene, primarily because of the forces generated by plate motion.     

Variations in shoreface progradation and ravinement along the Texas coast, Gulf of Mexico

Shoreface architecture, evolution (mid-Holocene to present) and depths of transgressive ravinement were examined from Sabine Pass, at the Texas–Louisiana border, to South Padre Island, near the Texas–Mexico border, using 30 shoreface transects. Shoreface transects extend out to 16-m water depth, each created from an echo-sounding profile and, on average, seven sediment cores. The shoreface is composed of three broad sedimentological facies: the upper shoreface, composed almost entirely of sand; the proximal lower shoreface, composed of sand with thickly to medium-bedded (50–10 cm) mud; and the distal lower shoreface, composed dominantly of mud with medium- to thinly bedded (20–3 cm) sand. Shoreface architecture and evolution is extremely variable along the Texas coast. Shoreface gradients increase from 2·25 m km^–1 in east Texas to 3·50 m km^–1 in south Texas. Shoreface sands coarsen towards south Texas. East and south Texas shoreface deposits are thin and retrograding whereas central Texas shoreface deposits are thicker and prograding. Central Texas is characterized by stacked shoreface successions, whereas in east Texas, lower shoreface sands are preserved only in offshore banks. Preservation of shoreface deposits is low in south Texas. Although eustatic fluctuations and accommodation space have a strong impact on overall mid-Holocene to present shoreface evolution and preservation potential, along-strike variations in sediment supply and wave energy are the main factors controlling shoreface architecture. The transgressive ravinement surface varies from –6 to –15 m along the Texas coast.     

Sediments in the estuarine environment of the tigris/euphrates delta; Iraq; Arabian Gulf

Studies on surface water characters of the estuarine environment of Iraq, northwestern Arabian Gulf, define three subdivisions of salinity: oligohaline, polyhaline, and euhaline. Textural analysis reveals that surface sediments covering the bottom are composed of six distinct classes: silty clay, clayey silt, sand-silt-clays, clayey sand, silty sand and sand. Five physiographic subdivisions are identified and described fluvial-estuarine, tidal mud flats (subtidal flat, lower intertidal flat, upper intertidal flat, supratidal flat), sand bars, Abdallah-Shetana channel and submerged estuarine distributary channel and bar systems. The content of organic matter in the sediments ranges from 0.24-3.69 per cent by weight. High values were recorded from the Abdallah-Shetana channel while lower values are confined to sand bars and submerged estuarine distributary channel and bar systems. Carbonates, quartz, feldspar, and halite are the main mineral constituents of the non-clay grade sediments; carbonates are present mainly as low-magnesium calcite followed by dolomite and high-magnesium calcite. Aragonite is present only in trace amounts. Both detrital and biogenic sources are suggested for low-magnesium calcite. A detrital source for dolomite and a biogenic source for high-magnesium calcite and aragonite are proposed.     

The stratigraphy and origin of the Tofts ridge in north-western Fenland,eastern England

The Tofts located in north-western Fenland is a low ridge composed of sandy silt, elevated several metres above the surrounding land. Stratigraphically, the feature is the landward edge of an intertidal-subtidal sand body that stretches east into The Wash. It was the location of a Medieval salt-making industry. The ridge seems to have been initiated after 2100?cal?years BP by storm waves and/or wind transporting sediment landward from adjacent intertidal flats. Differential consolidation of peat on its landward side and dumping of sediment onto the surface during salt-making enhanced its morphological expression.     

Geochemistry and mineralogy of a recent sabkha along the coast of Sinai, Gulf of Suez

Most efforts in the study of sea-marginal sabkhas have concentrated on the Persian Gulf, but little is known about the sediments and mineralogy of sabkhas marginal to other seas. The purpose of this paper was to present some geochemical and mineralogical observations in a recent sabkha on the coast of Sinai along the Gulf of Suez. The sabkha is composed of coarse clastic sediments with marine-derived groundwater at depth of about 1 m. The general morphology, climate and water salinity of the Gulf of Suez resemble those of the Persian Gulf, despite the fact that the content of authigenic evaporites in this sabkha is more sparse. The evaporite minerals accumulated only in the upper 30–40 cm of the sabkha, below that and down to the groundwater table, there is no accumulation of evaporites. Laterally, the salinity of the groundwater in the sabkha and the concentration of evaporites in the sediments above it increase constantly with distance from the shore. In contrast to the Persian Gulf where anhydrite is a major evaporite mineral, in Belayim gypsum is the only calcium sulphate mineral in the recent sabkha. Anhydrite is found only in an old elevated sabkha where it recrystallized from gypsum. The gypsum occurs as interstitial crystal concentrations or lithified horizons almost exclusively at the depth of 20–40 cm below the sabkha surface. Above that, in the uppermost horizons, there is in situ accumulation of interstitial halite crystals. The total concentrations of gypsum and halite are almost equal in this sabkha. The sea water recharge in El Belayim is almost exclusively by seepage through the sabkha sediments and not by flooding. The groundwater under this sabkha is only slightly more saline than the Gulf water, thus, not heavy enough for extensive downward refluxing. The major hydrodynamic process must be upward migration of the brines from the groundwater, precipitating on the way gypsum and later halite with some magnesite. Since the sediments of the sabkha are too coarse to support extensive capillary movement, the brines must, therefore, migrate upwards due to ‘evaporative pumping’.     

Structural analysis of a newly emerged accretionary prism along the Jinlun-Taimali coast,southeastern Taiwan: From subduction to arc-continent collision

In southern Taiwan the initial collision of the Luzon volcanic arc with the passive continental margin of China results in the emergence of an accretionary prism of, predominantly, turbidites in composition, thus providing an appropriate place to study the temporal and spatial variation of deformation during the transition of subduction to arc-continent collision. Field surveys have recently been carried out in slightly metamorphosed rocks along the well-exposed Jinlun-Taimali coast in southeastern Taiwan. Three folding phases are identified in the area. The first phase is characterized by gently dipping but widely distributed phyllitic cleavage (S₁). The second phase is represented by sparsely distributed crenulation cleavage (S₂) that folded the phyllitic cleavage. The third phase is characterized by E–W trending antiforms (F₃) that involved both types of pre-existing cleavages. Restoration of such an antiform in the north using a method proposed in this paper reveals that phyllitic cleavage in the overturned beds dips gently towards the southeast or east-southeast before the antiform, in relation to the first-phase thrusting or folding under regional ESE-WNW compression. From the first to third phase, the maximum horizontal compression underwent an about 90° anticlockwise rotation from ESE-WNW to E–W or NE–SW to N–S, and the deformation depth seems to decrease drastically, in terms of the decreasing proportion of pervasive deformation. All these variations are attributed to the oblique arc-continent collision that exhumed the whole accretionary prism and induced a local stress perturbation in southeastern Taiwan.     

昆中断裂带南北陆块基底、盖层沉积、岩浆岩对比研究——昆中断裂带构造意义的讨论

本文依据1∶25万区域地质调查成果资料,从昆中断裂带对南北两侧的基底变质岩系(包括变基性火山岩、变泥质岩)、表壳盖层沉积岩系、前寒武纪长英质火成侵入岩以及镁铁-超镁铁质侵入岩的沉积建造、岩石类型组合、岩石地球化学及所反映的源岩物性的控制,系统对比讨论了昆中断裂带南北两侧基底陆块特征及昆中断裂带的构造属性。得出以昆中断裂带为界,南北两侧陆块的大陆岩石圈,无论在表壳沉积岩系、中-下地壳和地幔的层性和物性结构及地球化学成分都存在显著差异。从而提出昆仑造山带实际上是个两陆块碰撞复合陆缘造山带。在元古宇以前南北陆块并非属同一古陆块,或者说昆中断裂带为欧亚大陆和冈瓦纳大陆的真正分界或二者的拼合带。     

Palaeoecological,sedimentological and stratigraphical insights into microbially induced sedimentary structures of the lower Cambrian successions of Iran

Micro-organisms producing microbially induced sedimentary structures, particularly epibenthic cyanobacteria, are not facies-dependent and could flourish in any environment if appropriate ecological conditions were provided. Hence, the changes in environmental parameters are the controlling factors on ecological tolerance of the producers. This study on the lower Cambrian successions of the Lalun Formation in Central Iran shows that paralic environments reacted differently to changes in parameters such as river and tide energy, palaeo-topography, the rate of sediment supply and fluctuations in sea-level, even though all were characterized by sandy substrates suitable for the development of microbially induced sedimentary structures. Therefore, the abundance and preservation of microbially induced sedimentary structures varied in the different paralic environments. From a sequence stratigraphic viewpoint, this study demonstrates that erosional discontinuities lacked the conditions required for the substrate stabilization by microbial communities. The distribution, size and type of microbially induced sedimentary structures within high frequency cycles generally follow the trends of changes in vertical facies stacking patterns. Within systems tracts, the pattern, morphological diversity and size of microbially induced sedimentary structures are not dependent on the type of systems tract, but on the type of depositional system developed such as delta, incised valley, coastal plain, estuaries and shoreline to shelf systems. Generally, estuarine and peritidal carbonates record an increase in the development of mat colonization during the transgressive systems tract, owing to decreased sedimentation rate as well as extended shallow water habitats. In contrast, the existence of microbially induced sedimentary structures depends on the pattern of shoreline shift in depositional systems developed during the highstand systems tract, such as open coast tidal flat and delta environments. If a shoreline regression was continuous (depositional trend and stacking pattern are a set of high frequency cycles), a greater increase in the aggradational component than the progradational component would cause intensified destructive processes hindering the development of microbial communities.     

辽西海岸带第四系全新统六股河组、大凌河组的建立及其沉积环境

通过对位于辽西海岸带第四系地层的剖面测制、14C及OSL测年、地质环境综合样分析研究,将辽西海岸带分布的一套黄色—桔红色松散沉积物及其上部的一套灰白色含砾粉砂-粉砂-粘土质沉积物,按形成时代归入全新统中—上部,建立第四系全新统六股河组和大凌河组。     

Nature and geochemistry of surface sediments of the mangrove environment along the Egyptian Red Sea coast

Grain size and geochemical analyses have been carried out on 58 samples collected from different areas of mangrove environment of the Egyptian Red Sea coast. The texture characteristics of mangrove sediments show that the mean size decreases in sediments of coastal areas while increase in island sediments and the sediment type generally changes from sand to slightly gravelly muddy sand. The sediments are composed mainly of poorly sorted, negatively nearly symmetrical and leptokurtic fine sands. Cluster analysis showed that, distribution of gravel, sand and mud fractions is related to bottom facies and type of sediment source. Generally, sand fraction is the main category among the three constituents. Geochemically the factor controlling the carbonate content of studied sediments includes material supply of biogenic and terrigenous components. Therefore, sediments of Hamata area, km 17 south Safaga, Wadi El-Gemal Island and Abu-Minqar Island are terrigenous sediments, while sediments of km 37 north Quseir are highly carbonates. In general organic matter is higher in the mangrove sediments relative to adjacent areas. The high organic matter in the mangrove sediments is primarily due to the high supply from primary productivity, terrestrial and reworked sediments. Texture is the main controlling factor for the organic matter enrichment. Spatial variations in the phosphorus content in the different studied localities are related to the sources of phosphorus to the area. In comparison, cluster analysis indicates that phosphorus might be transported from terrestrial source to the sea through wadis draining the excavated Upper Cretaceous phosphate rocks. Also, the abundance of phosphorus content may be attributed to phosphatization of calcareous skeletons. Our observations provide knowledge on the physico-chemical effects and will be useful in the management and suitable development of the areas under study. In addition it represent database in the future.     

渤海湾西北岸中更新世中期以来的气候环境和沉积环境演变

渤海湾西北岸是渤海湾沿岸砂坝-澙湖沉积体系组成部分,其沉积物蕴含着丰富的地质环境演变信息,是认识该地区气候环境和新构造活动的关键.通过对渤海湾西北岸QEJ01孔80 m以上地层沉积环境、孢粉分析及微体古生物研究,结合测年数据,根据定量古气候重建数据,探讨了本区中更新世中期以来特征时期的植被演替及环境演变,并对MIS6～...     

关于蓟县型中、上元古界沉积环境及内蒙地轴的性质

内蒙地轴和燕辽坳都是华北地台北缘的二级大地构单元,本文在对蓟县型中、上元古界沉积环境和对内蒙地轴演化历史的初步研究基础上,认为蓟县型中、上元古界沉积盆地于长城－蓟县期,在北部与广海相连,属于陆表海发展,在青白口期,由于北部逐渐抬升,该沉积盆地才具有陆内盆地性质,内蒙地轴在长城－蓟县期总体处于水下环境,青白口爰开始抬升为古陆,其大规模抬升可能是在古生代或更晚。     

Loading fractures and Liesegang laminae: new sedimentary structures found in the north-western North Alpine Foreland Basin (Oligocene–Miocene, south-west Germany)

Abstract Spectacular sedimentary structures recently found in the Molasse Basin (Oligocene–Miocene) in southern Germany were produced by soft‐sediment deformation under highly unusual conditions. These large, apparently wedge‐like structures –‘loading fractures’– cut down into beds of marl and are filled with coarse sand and intraclasts of shale. Wrapping the sides of the structures is a thin, continuous bed of layered dark claystone – the ‘DCB’. The upper and lower layers of this bed are an organic‐rich clay; the middle layer is a laminated quartzite. The precursor of the DCB was a lacustrine gyttja rich in diatom frustules. It was supersaturated in silica as it was buried. Subsequent diffusion of oxygen into this gyttja at a burial depth of only a few metres resulted in the formation of Liesegang laminae of quartz. These laminae grew and amalgamated, forming the layer of laminated quartzite. The sediments overlying the DCB were eventually removed by erosion, probably in a high‐energy marine environment. This erosion cut down to the DCB but was unable to penetrate it. The DCB remained exposed on the sea floor until a sudden depositional event occurred – the deposition of a 2·5 metre thick bed of coarse sand with shale intraclasts. Although the DCB had been able to resist the submarine erosion, it could not support the load of this new bed. The quartzite layer in it therefore fractured, transferring that load down onto the underlying, still‐unconsolidated marl. The intraclast‐rich sands were forced down into this marl, carrying ahead of them the partly broken remains of the DCB.     

The geochemistry of gossans associated with Sarcheshmeh porphyry copper deposit,Rafsanjan, Kerman,Iran: Implications for exploration and the environment

The Sarcheshmeh copper deposit is one of the world's largest Oligo-Miocene porphyry copper deposits in a continental arc setting with a well developed supergene sulfide zone, covered mainly by a hematitic gossan. Supergene oxidation and leaching, have developed a chalcocite enrichment blanket averaging 1.99% Cu, more than twice that of hypogene zone (0.89% Cu). The mature gossans overlying the Sarcheshmeh porphyry copper ores contain abundant hematite with variable amounts of goethite and jarosite, whereas immature gossans consist of iron-oxides, malachite, azurite and chrysocolla. In mature gossans, Au, Mo and Ag give significant anomalies much higher than the background concentrations. However, Cu has been leached in mature gossans and gives values close or even less than the normal or crustal content (< 36.7 ppm). Immature gossans are enriched in Cu (160.3 ppm), Zn (826.7 ppm), and Pb (88.6 ppm). Jarosite- and goethite-bearing gossans may have developed over the pyritic shell of most Iranian porphyry copper deposits with pyrite–chalcopyrite ratios greater than 10 and therefore, do not necessarily indicate a promising sulfide-enriched ore (Kader and Ijo). Hematite-bearing gossans overlying nonreactive alteration halos with pyrite–chalcopyrite ratios about 1.5 and quartz stringers have significant supergene sulfide ores (Sarcheshmeh and Miduk). The copper grade in supergene sulfide zone of Sarcheshmeh copper deposit ranges from 0.78% in propylitized rocks to 3.4% in sericitized volcanic rocks, corresponding to the increasing chalcopyrite–pyrite or chalcocite–pyrite ratios from 0.3 to 3, respectively. Immature gossans with dominant malachite and chrysocolla associated with jarosite and goethite give the most weakly developed enrichment zone, as at God-e-Kolvari. The average anomalous values of Au (59.6 ppb), Mo (42.5 ppm) and Ag (2.6 ppm) in mature gossans associated with the Sarcheshmeh copper mine may be a criterion that provides a significant exploration target for regional metallogenic blind porphyry ore districts in central Iranian volcano–plutonic continental arc settings. Drilling for new porphyry ores should be targeted where hematitic gossans are well developed. The ongoing gossan formation may result in natural acidic rock drainage (ARD).     

四川蒲江地区上三叠统须家河组地层古生物特征及沉积环境

对蒲江县熊坡背斜一带出露的上三叠统须家河组进行了实测和系统采样分析。根据古生物化石组合的特征将其划分为2个生物组合带：即Weiyuanella rhomboidallis-Permophorus emeiensis双壳组合带和Zamites jiangxieensis-Clathropteris植物组合带,结合岩性特征及层位对比, 认为该区仅出露有须家河组五段和六段。沉积相分析表明,须家河组的沉积环境为辫状河三角洲,并细分为三角洲平原亚相和三角洲前缘亚相。证实须家河组与上覆中侏罗统新田沟组为平行不整合接触,缺失下侏罗统