西成地区铅-锌矿、金矿硫铅同位素特征及成矿关系的研究

甘肃省西成地区分布有多种类型的铅-锌矿和金矿,已探明海底喷流型（SEDEX）铅-锌矿资源量超过1300×10^4t（金属量）。金矿主要分布于盆地中西部泥盆系厚层碎屑岩中．受控于韧性剪切带。对矿床中硫化物硫、铅同位素研究结果表明,西成铅-锌矿田北矿带的后期改造是在相对封闭的环境下实现的、而南矿带铅-锌矿则有部分外来物质的参与,但并未发生明显的分异,同时,两个矿带喷流（气）-沉积过程的不同,这也是导致硫同位素存在差异的重要原因。在印支期的成矿过程中金矿具有明显独立于铅-锌矿的地质特点与硫、铅同位素演化过程,硫主要源自区内的围岩,而铅同位素中则有较多放射性成因铅的加入。     

Ore Genesis for Stratiform Ore Bodies of the Dongfengnanshan Copper Polymetallic Deposit in the Yanbian Area, NE China：Constraints from LA-ICP-MS in situ Trace Elements and Sulfide S–Pb Isotopes

The Dongfengnanshan Cu polymetallic deposit is one representative deposit of the Tianbaoshan ore district in the Yanbian area, northeast(NE) China. There occur two types of ore bodies in this deposit, the stratiform ore bodies and veintype ones, controlled by the Early Permian strata and the Late Hercynian diorite intrusion, respectively. Due to the ambiguous genetic type of the stratiform ore bodies, there has been controversy on the relationship between them and veintype ore bodies. To determine the genetic type of stratiform ore bodies, laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS) in situ trace elements and S–Pb isotope analysis have been carried on the sulfides in the stratiform ore bodies. Compared with that in skarn, Mississippi Valley-type(MVT), and epithermal deposits, sphalerite samples in the stratiform ore bodies of the Dongfengnanshan deposit are significantly enriched in Fe, Mn, and In, while depleted in Ga, Ge, and Cd, which is similar to the sphalerite in volcanic-associated massive sulfide(VMS) deposits. Co/Ni ratio of pyrrhotites in the stratiform ore bodies is similar to that in VMS-type deposits. The concentrations of Zn and Cd of chalcopyrites are similar to those of recrystallized VMS-type deposits. These characteristics also reflect the intermediate ore-forming temperature of the stratiform ore bodies in this deposit. Sulfur isotope compositions of sulfides are similar to those of VMS-type deposits, reflecting that sulfur originated from the Permian Miaoling Formation. Lead isotope compositions indicate mixed-source for lead. Moreover, the comparison of the Dongfengnanshan stratiform ore bodies with some VMStype deposits in China and abroad, on the trace elements and S–Pb isotope characteristics of the sulfides reveals that the stratiform ore bodies of the Dongfengnanshan deposit belong to the VMS-type, and have closely genetic relationship with the early Permian marine volcanic sedimentary rocks.     

青藏高原及邻区层控型铅锌矿时空分布特征

青藏高原古生代—中生代复杂的多岛弧盆系演化和新生代高原急剧隆升的构造格局造就了层控型铅锌矿特定的时空分布和成矿作用的分带性。在不同类型的构造单元内具有特征的成矿专属性和矿床类型。青藏高原及周缘层控型铅锌矿有多时代成矿的特点,寒武系和泥盆系是主要赋矿层位。古生代—中生代铅锌矿含矿层岩相古地理具有多样性,以台地相作为控矿优势相,尤其以白云岩作为容矿岩石的矿床居多。另外新生代地层作为主要容矿层之一,发育有大型甚至特大型的层控铅锌矿体,为低温热卤水运移充填矿床。推测青藏高原在新生代快速隆升是该类矿床富集成矿的重要控矿因素。随着研究的深入和勘查的进展,这种新生代矿床将在该区显示出巨大的找矿潜力。     

甘肃省迭部刀扎—舟曲憨班一带金矿找矿新认识

迭部刀扎—舟曲憨班一带已发现金矿床(点)与桑坝推覆体构造前缘的采古逆冲断裂具有密切的关系。该断裂不仅控制了含矿地层、岩浆岩的分布,而且是区内重要的控矿、容矿断裂。有规模的金矿体一般产在岩体的接触带上。金矿化与硅化、黄(褐)铁矿化、黄铜矿化关系密切。由此而提出了在该区带进一步找矿的主要地质标志。     

黑龙江省羊鼻山铁钨矿床中钨矿成因及物质来源

黑龙江省双鸭山市羊鼻山铁钨矿床处于中亚造山带东段的佳木斯地块中部。兴东群大盘道组变质岩系为矿区主要赋矿地层,铁矿矿体呈层状、似层状赋存于大盘道组第一岩段,白钨矿矿体呈透镜状和脉状产于铁矿矿体底板围岩中,受片麻状花岗岩与大盘道组大理岩的接触带控制;主要含矿岩石为石榴石矽卡岩和透辉石矽卡岩,钨矿石中主要金属矿物为磁黄铁矿和白钨矿,并含少量磁铁矿、黄铁矿、黄铜矿、闪锌矿、锡石、毒砂和辉钼矿。含钨石英脉中δ¹⁸O_水值为3.6‰~7.5‰,δD值为-120.9‰~-66.2‰,表明其成矿流体以岩浆水为主。矽卡岩中与白钨矿共生的金属硫化物δ³⁴S值为16.1‰~18.1‰,²⁰⁶Pb/²⁰⁴Pb值为17.879~18.863,²⁰⁷Pb/²⁰⁴Pb值为15.537~15.603,²⁰⁸Pb/²⁰⁴Pb值为38.202~38.544,表明金属硫化物中的硫和铅主要来源于地层与地壳重熔型岩浆。结合钨矿成矿地质特征,认为羊鼻山铁钨矿床中钨矿的成因类型应属矽卡岩型。     

辽东林家三道沟-小佟家堡子地区金（银）矿成矿特征及成因

以林家三道沟、小佟家堡子金（银）矿床为例,系统总结了区内金（银）矿床的成矿条件及地质特征,对矿床的相关岩体、围岩及矿石进行了流体包裹体、稳定同位素测试分析。结果表明：矿床赋存于古元古界辽河群大石桥亚群杨树沟岩组第6岩段碎屑岩-碳酸盐岩建造和盖县亚群汤家沟岩组碎屑岩建造中;主要容矿岩石为硅化大理岩、变粒岩、片岩;近矿围岩蚀变主要为硅化、绢云母化、黄铁矿化和碳酸盐化;自然金的粒度以显微不可见金为主;均一温度（100～200 ℃）、成矿流体盐度（w（NaCl）（1.91 % ～9.73%）均较低;矿石石英中成矿流体δD值为-48.0‰～-93.0‰,δ¹⁸O_H2O计算值为-8.63‰～+1.31‰,表明成矿流体主要来自于地热水和原生地层水;矿石硫同位素δ³⁴S值平均为+8.61‰,赋矿围岩、岩体δ³⁴S为＋0.50‰～＋7.6‰,表明矿石中硫主要来自古元古代地层和印支晚期岩体;金（银）矿石中²⁰⁶Pb/²⁰⁴Pb为17.664～19.186 7,²⁰⁷Pb/²⁰⁴Pb为15.044～15.883,²⁰⁸Pb/²⁰⁴Pb为37.693～38.784,铅源具有壳幔混合源特点。矿床成因类型为沉积变质-岩浆热液叠加型。     

秦岭凤太矿田层控铅锌(铜)矿床的主要成矿特征及成矿模式

以较详细的资料论述了秦岭凤太矿田层控铅锌(铜)矿床的主要成矿特征。包括反映成矿地质环境、成矿方式、成矿物质来源和成矿物理化学条件等方面的特征,据上述综合特征提出了海底喷气-沉积成矿模式。     

微细浸染型金矿深源成矿流体的硅同位素地球化学示踪

对黔西南和桂西北微细浸染型金矿床围岩,矿石和热液硅化石英的硅同位素组成及硅质阴极发光特征的研究发现,原生硅化石英不发光,而围岩中的石英和次生硅化石英明显发光、与对对应,围岩中石英的硅同位素组成与矿石的热液硅化石英的硅同位素组成也可以明显分开。     

贵州普定五指山地区铅锌矿床成矿模式

黔西北五指山铅锌矿集区是川滇黔接壤铅锌成矿域的重要组成部分之一,近年已探明多个大中型铅锌矿床,提交铅锌金属资源储量超250万t,实现了地质找矿的重大突破。文章对区内典型矿床的地质、地球化学等资料进行综合分析,并与邻区及MVT矿床进行比较。研究结果显示,本区矿体主要赋存于上震旦统灯影组和下寒武统清虚洞组白云岩中,呈层状、似层状和陡倾斜脉状产出,断控和层控特征明显。矿石自然类型为原生硫化矿型,主要金属矿物由闪锌矿和方铅矿组成。矿床形成受构造、层位及岩性、沉积岩相等因素的约束,构造是必要条件和主要控矿因素,灯影组和清虚洞组鲕状白云岩是有利赋矿层位和容矿岩性,局限-半局限的台地-泻湖相沉积为有利沉积岩相条件。成矿物质具有混合特征,其中成矿金属Pb、Zn等主要来源于基底岩石,而矿化剂C和S则分别来自赋矿海相碳酸盐岩及其内的蒸发膏岩。成矿流体属于与右江盆地演化有关的低温中低盐度盆地卤水,矿体是富金属流体在早燕山期区域挤压向伸展转换的动力学背景下卸载,与富硫流体混合的产物,成矿过程与MVT矿床相似。五指山地区铅锌矿床成矿模式的建立,有望推动区内找矿新突破,并为邻区铅锌成矿预测提供理论指导。     

贵州赫章铜厂沟铜矿地质地球化学特征

通过野外地质观察和对已揭露工程地段进行取样,采用显微镜观察、岩石化学分析、微量元素分析、X射线衍射、扫描电镜及微区能谱分析等手段,研究了铜厂沟铜矿矿石矿物组成及地质地球化学特征。结果表明,铜厂沟铜矿矿石类型为含铜砂岩型和含铜蚀变构造角砾岩型:砂岩型铜矿具有层控特征,矿体产出明显受三叠系飞仙关组等赋矿层位的控制;蚀变构造角砾岩型铜矿矿体沿SW向次级控矿断裂具一定规模展布并受其控制,矿石含铜品位达3.26%～3.88%。2类型铜矿石的主要矿物组成为斑铜矿、黄铜矿、辉铜矿、孔雀石,见少量蓝铜矿、自然铜、方解石、石英;主要围岩蚀变为沸石化、重晶石化、沥青化、硅化、绿泥石化、高岭石化及碳酸盐化等。砂岩型铜矿控矿及赋矿围岩岩石化学成分中SiO₂含量、SiO₂/Al₂O₃值、Na₂O、 K₂O含量特征和CaO+MgO含量分布特点,表明岩石为海相碎屑沉积成因。蚀变构造角砾岩型铜矿石为构造运动改造形成。     

Late Mesozoic Ore‐forming Events in the Ningwu Ore District,Middle‐Lower Yangtze River Polymetallic Ore Belt,East China: Evidence from Zircon U‐Pb Geochronology and Hf Isotopic Compositions of the Granodioritic Stocks

Late Mesozoic volcanic-subvolcanic rocks and related iron deposits, known as porphyry iron deposits in China, are widespread in the Ningwu ore district (Cretaceous basin) of the middle–lower Yangtze River polymetallic ore belt, East China. Two types of Late Mesozoic magmatic rocks are exposed: one is dioritic rocks closely related to iron mineralization as the hosted rock, and the other one is granodioritic (-granitic) rocks that cut the ore bodies. To understand the age of the iron mineralization and the ore-forming event, detailed zircon U-Pb dating and Hf isotope measurement were performed on granodioritic stocks in the Washan, Gaocun-Nanshan, Dongshan and Heshangqiao iron deposits in the basin. Four emplacement and crystallization (typically for zircons) ages of granodioritic rocks were measured as 126.1±0.5 Ma, 126.8±0.5 Ma, 127.3±0.5 Ma and 126.3±0.4 Ma, respectively in these four deposits, with the LA-MC-ICP-MS zircon U-Pb method. Based on the above results combined with previous dating, it is inferred that the iron deposits in the Ningwu Cretaceous basin occurred in a very short period of 131–127 Ma. In situ zircon Hf compositions of εHf(t) of the granodiorite are mainly from ?3 to ?8 and their corresponding 176Hf/177Hf ratio are from 0.28245 to 0.28265, indicating similar characteristics of dioritic rocks in the basin. We infer that granodioritic rocks occurring in the Ningwu ore district have an original relationship with dioritic rocks. These new results provide significant evidence for further study of this ore district so as to understand the ore-forming event in the study area.     

New insights into the origin of early Cambrian carbonate-hosted Pb-Zn deposits in South China: A case study of the Maliping Pb-Zn deposit

The western margin of the Yangtze Block hosts the giant Upper Yangtze Pb-Zn metallogenic province, with the occurrence of >400 carbonate-hosted Pb-Zn deposits. More than 50% of these deposits are hosted in carbonate rocks of late Ediacaran to early Cambrian age. Although they have attracted great attention over the past two decades, it is still unclear why such carbonate sequences host so many Pb-Zn deposits and the role that the country rocks played during mineralization. The newly-discovered Maliping Pb-Zn deposit (~6 Mt @ 4.18 wt% Pb and 9.18 wt% Zn) is hosted in early Cambrian strata composed of carbonate and phosphate rocks, black shales, as well as evaporite sulfates, of which the carbonate rocks are the direct ore-hosting rocks. Evidence from mineralogy and the concentrations of ore-forming metals indicate that the phosphate rocks played an important role in providing geochemical barriers during Pb-Zn ore formation. Homogenization temperatures of the primary fluid inclusions in sphalerite and quartz range from 185 to 282 °C, and their salinities vary from 3.39 to 17.17 wt% NaCl equiv. The REE and C-O isotopes imply that the hydrothermal carbonates were formed under relatively oxidizing conditions and that the wall rocks were involved in the Pb-Zn mineralization through dissolution. Sulfur isotopic compositions (δ³⁴S = +7.60–+31.79‰) of sulfides reveal that S²⁻ originated from evaporite sulfates within the ore-hosting strata, and that the black shales acted as an important reducing agent during thermo-chemical reduction (TSR). Pb isotopic ratios of galena (²⁰⁶Pb/²⁰⁴Pb = 17.856–17.973, ²⁰⁷Pb/²⁰⁴Pb = 15.668–15.689 and ²⁰⁸Pb/²⁰⁴Pb = 37.953–38.101) are similar to those of Proterozoic basement rocks in the region. This implies that the basement could be the key source of mineralizing metals. Hence, we propose that: (i) The favorable lithological combination of early Cambrian phosphate rocks, black shales, carbonates and evaporites, as well as Proterozoic basement in the area, were responsible for controlling the majority of Pb-Zn deposits in the late Ediacaran-early Cambrian carbonate sequences in the western Yangtze Block; and (ii) the Maliping Pb-Zn deposit resulted from a combination of mineralized fluids, various trap structures and favorable lithologies, of which the fluids were epigenetic with low to moderate temperatures and salinities.     

东坪式金矿床铅同位素组成特征及其化探评价

东坪式金矿床产于华北克拉通化缘深大断裂－－尚义－赤城断裂的南侧,海西期水泉沟正长岩杂岩体内外接触带。矿体具有明显的分层笥,自上而下矿石类型由石英脉型向钾、硅化蚀变岩型过渡。矿床形成于燕山早期,成矿物质主要来源于正长岩杂岩体。矿石铅同位素组成与正长岩杂岩体相似,在＾２０７Ｐｂ／＾２０６Ｐｂ－＾２０８Ｐｂ／＾２０６Ｐｂ图解上,矿石、正长岩、矿石中的钾长石脉石及太古宇桑干群变质岩呈线性分布,矿石与正长岩     

西昆仑库科西力克一带多金属矿地质及地球化学特征的初步研究

新疆阿克陶县恰尔隆一带1：5万区调工作中曾在库科西力克一带发现数个具有一定工业价值的矿点,这些矿点位于西昆仑铜钼多金属元素富集带,其矿种齐全,涉及Au、Ag、Cu、Pb—Zn、M0、W和Fe等,分布较为集中,资源前景较好,找矿潜力巨大。本文从矿床地质及元素地球化学的角度对一些典型矿点进行了系统调查、采样、分析及研究,发现库尔尕斯金铜矿点主成矿元素中Ag、Cu和Pb具有一致的成矿阶段,而Au受后期构造作用可能滞后富集成矿。同时各矿点间REE含量及分布模式存在较大的差异。除库尔尕斯金铜矿点外,各矿点中矿石和围岩REE总量和分布模式差别也较为明显。认为库科西力克一带各矿点在成矿地质条件上具有一定的联系,成矿物质可能主要来源于深部,主要受区域性断裂（库科西力克断裂）及岩浆活动的影响,但各矿点之间具有各自的成矿特点,这与各矿点不同的矿床类型相关。     

右江褶皱带有色金属矿床成矿系列初步研究

右江褶皱带位于华南褶皱系的南西端，地质构造复杂，有色金属矿产丰富。本文对该区有色金属矿床的两个主要成矿系列进行了研究，一是与重熔型花岗岩类有关的锡－铜－银多金属矿床成矿系列，其中又可将其分为锡－铜与银多金属两个亚系列；二是沉积－改造型层控锑矿床成矿系列。本文以个旧、都龙、白牛厂、德保、凤凰山和木利、马雄等矿床为实例，分别讨论了两个成矿系列的主要特征、控矿因素和矿床成因。     

Isotopes and Geochronology of the Meixian-type Pb-Zn-(Ag)Deposits,Central Fujian Rift,South China:Implications for Geological Events

Central Fujian Rift is another new and important volcanogenic massive sulfide Pb-Zn polymetallic metallogenetic belt. In order to find out the material genesis and mineralization period of Meixian-type Pb-Zn-Ag deposits, S and Pb isotope analysis and isotope geochronology of ores and wall rocks for five major deposits are discussed. It is concluded that the composition of sulfur isotope from sulfide ore vary slightly in different deposits and the mean value is close to zero with the 834S ranging from -3.5‰ to ＋5.6‰ averaging at ＋2.0‰, which indicates that the sulfur might originate from magma or possibly erupted directly from volcano or was leached from ore-hosted volcanic rock. The lead from ores in most deposits displays radioactive genesis character （206pb/204pb〉18.140, 207Pb/204pb〉15.584, 208pb/204pb〉38.569） and lead isotope values of ores are higher than those of wall rocks, which indicates that the lead was likely leached from the ore-hosted volcanic rocks. Based on isotope data, two significant Pb-Zn metallogenesis are delineated, which are Mid- and Late-Proterozoic sedimentary exhalative metailogenesis （The single zircon U-Pb, Sm-Nd isochronal and Ar-Ar dating ages of ore- hosted wall rocks are calculated to be among 933-1788 Ma.） and Yanshanian magmatic hydrothermal superimposed and alternated metallogenesis （intrusive SHRIMP zircon U-Pb and Rb-Sr isochronal ages between 127-154 Ma）.     

右江褶皱带有金属矿床成矿系列初步研究

右江褶皱带位于华南褶皱系的南西端，地质构造复杂，有色金属矿产丰富，本文对该区有色金属矿床的两个主要成矿系列进行了研究，一是与重熔型花岗岩类有关的锡－铜－银多金属矿床成矿系列，其中又可将其分为锡－铜与银多金属两个亚系列，二是沉积－改造型层控锑矿床成矿系列，本文以上旧，都龙，白占厂，德保，凤凰山和木利，马雄等矿床为实例，分别讨论了两个成矿系列的主要特征，控矿因素和矿床成因。     

关于黔西南微细浸染型金矿床成因的一些初步认识

以黔西南金矿床与莫霍面隆起、深大断裂、岩浆岩体、航磁异常、重力异常、环形构造及地热场的时空对应关系为线索，讨论了深源流体参与金矿成矿的可能性。铅、硫、氢、氧同位素地球化学研究表明，成矿物质来源于深源流体及地层岩石。金矿床是上升热流体改造地层岩石的产物。     

Some aspects of the problem of geochemical methods of prospecting for concealed mineralization

This paper describes a number of different geochemical approaches to the search for concealed ore deposits.The first approach discussed is a broad one that relates mineralization to the types of rock that may occur in a region. Attention is focussed on hydrothermal deposits and their association with specific types of igneous rocks and their differentiation trends.A second considers the control of the structure and physico-chemical properties of the host rocks on the localization of ore bodies. A number of factors, such as effective and total porosity and the brittleness of rocks also plays an important role in determining the nature and extent of dispersion haloes of the elements around ore deposits.In some instances it is possible to predict the presence of ore bodies at depth from the type of composition of metasomatized rocks that occur at the surface.The use of mercury and fluorine in the search for concealed deposits has been given detailed consideration. Methods based on fluorine may be effective in the discovery of skarn, greisen, hydrothermal and rare metal deposits. When using the fluorine content of waters from a taiga-permafrost terrain, it is important to consider the effect of the organic content of the water.In searching for Cu-Ni deposits of the Noril'sk type it is suggested that intrusive complexes characterized by high degrees of differentiation and containing picritic and taxitic facies enriched in Mg, Ni and Co and depleted in alkalis are the most prospective. Ore deposits of this type may have dispersion haloes of Ag, Bi, Zn and Pb which are associated with ore-controlling faults. Magnesian and calcareous skarns, feldspathic and serpentine-chlorite-prehnite rocks may form broad contact haloes with ore-bearing intrusions.The use of gases in prospecting for Cu-Mo deposits in Central Kazakhstan have been investigated with positive results. Gas surveys carried out in conjunction with geophysical methods makes it possible to distinguish zones of Cu-Mo mineralization from zones containing pyrite and carbonaceous material, all of which give similar geophysical responses.The occurrences of uranium in aquifers on the flanks of artesian basins within arid regions is used as an example of the use of geochemical zonation in prospecting. The same approach may be used in prospecting for copper-bearing sandstones.     

Geology, Mineralization, Fluid Inclusion and Stable Isotope of the Early Cretaceous Sn and Associated Metal Deposits in the Southern Great Xing’an Range, NE China: A Review

The Southern Great Xing'an Range(SGXR) hosts a number of Early Cretaceous Sn and associated metal deposits, which can be divided into three principal types according to their geological characteristics: skarn type deposits, porphyry type deposits and hydrothermal vein type deposits. Fluid inclusion assemblages of different types of deposits are quite different, which represent the complexities of metallogenic process and formation mechanism. CH_4 and CO_2 have been detected in fluid inclusions from some of deposits, indicating that the ore-forming fluids are affected by materials of Permian strata. Hydrogen and oxygen isotope data from ore minerals and associated gangue minerals indicate that the initial ore fluids were dominated by magmatic waters, some of which had clearly exchanged oxygen with wall rocks during their passage through the strata. The narrow range for the δ~(34)S values presumably reflects the corresponding uniformity of the ore forming fluids, and these δ~(34)S values have been interpreted to reflect magmatic sources for the sulfur. The comparation between lead isotope ratios of ore minerals and different geological units' also reveals that deeply seated magma has been a significant source of lead in the ores.