Constraints on bulk composition,seasonal variation,and global dynamics of Pluto's atmosphere

Cosmic abundance, vapor pressure, and molecular weight considerations restrict the likely gas candidates for Pluto's atmosphere to Ne, N₂, CO, O₂, and Ar, in addition to the already detected CH₄. The vapor pressures and cosmic abundances of these gases indicate that all except Ne should be saturated in Pluto's atmosphere. The vapor pressure of Ne is so high that the existence of solid or liquid Ne on Pluto's surface is very unlikely; cosmic abundance arguments imply that Ne cannot attain saturation in Pluto's atmosphere. At both perihelion, N₂ should dominate the saturated gases. CO₂ should have the next highest mixing ratio, followed by O₂ and Ar. CH₄ should have the smallest mixing ratio. Because vapor pressures of these gases vary with temperature at diverse rates, the bulk and constituent mixing ratios of Pluto's atmosphere should vary with season. Between perihelion and aphelion, the column abundance of CH₄ may change by a factor of 260 while that of N₂ changes by only a factor of 52. The potential seasonal variation of Pluto's atmosphere was investigated by considering the behavior of these gases when individually mixed with CH₄. The effects of diurnal and latitudinal variation of insolation and eclipses on the atmosphere also were investigated. Seasonal effects are shown to dominate. It was shown that the atmospheric bulk may not be a minimum near aphelion but rather at intermediate distances from the Sun during summer/winter inadequate ice deposits may allow the atmosphere to collapse by freezing out over winter latitudes. If the atmosphere does not collapse, its weight is sufficient to keep it distributed uniformly around Pluto's surface. In this case, the atmosphere tends to regulate the surface temperature to a seasonally dependent value which is uniform over the globe.Finally, the likely global circulation regimes for each model atmosphere as a function of temperature were investigated and it was concluded that if CH₄, O₂, or CO dominates the atmosphere, Pluto will exhibit cyclic variations between an axially symmetric circulation system at perihelion and a baroclinic wave regime at aphelion. However, if N₂ dominates, as is likely, the wave regime should hold continuously. If the atmosphere collapses to a thin halo during summer/winter seasons, only a weak, symmetric circulation should occur.     

Large seasonal variations in Triton's atmosphere

Triton's seasons differ materially from those of Pluto owing to four important differences in the governing physics: First, the obliquity of Triton is significantly less than Pluto's obliquity. Second, Triton's inclined orbit precesses rapidly about Neptune so that a complicated seasonal variation in the latitude of the Sun occurs for Triton. Third, Neptune's orbit is much more circular than Pluto's orbit so that the sunlight intercepted by Triton's disk does not vary seasonally. Finally, Triton's atmosphere cannot be saturated at the lower latitudes so that the mass of the atmosphere is controlled by the temperature of the high-latitude ices or liquids (polar caps), as for CO₂ on Mars. The consequences of Triton's entire surface being covered with volatile substances have been examined. It is found that the circularity of Neptune's orbit then implies that Triton would have hardly any seasonal variation at all in surface temperature or atmospheric bulk, in spite of the complicated precessional effects of Triton's orbit. The only seasonal effect would be the migration of surface ices and liquids. This scenario is ruled out because it implies a column CH₄ abundance much higher than that observed and because it quickly depletes the lower latitudes of volatiles. It is concluded that Triton's most volatile surface substances are probably relegated to latitudes higher than 35° and probably form polar caps. The temperature of the polar caps should be nearly equal, even during midwinter/midsummer when the insolation of the summer pole is greatest. If the summer pole completely sublimates during one of the “major” summers, Triton's atmosphere may begin to freeze out over the winter caps. It is therefore expected that Triton's atmosphere undergoes large and complex seasonal variations. Triton is currently approaching a “maximum southern summer”, and over the remainder of this century, a dramatic increase in CH₄ abundance above the current upper limit of 1 m-Am may be witnessed.     

Io's surface composition based on reflectance spectra of sulfur/salt mixtures and proton-irradiation experiments

The available full-disk reflectance spectra of Io in the range 0.3 to 2.5 μm have been interpreted by comparison with new laboratory spectra of a wide variety of natural and synthetic mineral phases in order to determine a surface compositional model for Io that is consistent with Io's other known chemical and physical properties. Our results indicate that the dominant mineral phases are sulfates and free sulfur derived from them, which points toward a low temperature and initially water-rich surface assemblage. Our current preferred mineral phase mixture that best matches the Io data and is simultaneously most consistent with other constraints, consists of a fine-grained particulate mixture of free sulfur (55 vol%), dehydrated bloedite [Na₂Mg(SO₄)₂·xH₂O] (30 vol%) ferric sulfate [Fe₂(SO₄)₃·xH₂O] (15 vol%), and trace amounts of hematite [Fe₂O₃]. Other salts may be present, such as halite and sodium nitrate, as well as clay minerals. Such a model is consistent with a probable pre- and post-accretion thermal history of Io-forming material and Io's observed Na emission and other properties. These results further support the evaporite surface hypothesis of Fanale et al'; while not precluding the presence of certain silicate phases such as montmorillonite.The average surface of Io's leading hemisphere appears to contain less free sulfur and more salts and to be finer grained than that of the trailing hemisphere. Since Io is immersed in Jupiter's magnetosphere, irradiation damage effects from low-energy proton bombardment were studied. Irradiation damage of lattices is estimated to be a relatively minor but operative process on the surface of Io; irradiation darkening by sulfate reduction to free sulfur and by F-center production in salts may be partly responsible for the differences in albedo of leading and trailing hemispheres and equatorial and polar regions of Io, but slight regional differences in relative intrinsic phase concentration on the surface may likewise account for these global variations in albedo.Possible unusual surface properties predicted by this model include: posteclipse darkening in certain wavelenghts, limb brightening in certain wavelengths, and unusual surface electrical properties. Further refinement of Io's surface composition model and better understanding of surface irradiation effects will be possible when observational data in the range 0.20 to 0.30 μm are obtained and when improved spectra in the range 0.30 to 5.0 μm are obtained having increased spectral, spatial, and temporal resolution.     

The evolution of the atmosphere of the earth

Computer simulations of the evolution of the Earth's atmospheric composition and surface temperature have been carried out. The program took into account changes in the solar luminosity, variations in the Earth's albedo, the greenhouse effect, variation in the biomass, and a variety of geochemical processes. Results indicate that prior to two billion years ago the Earth had a partially reduced atmosphere, which included N₂, CO₂, reduced carbon compounds, some NH₃, but no free H₂. Surface temperatures were higher than now, due to a large greenhouse effect. When free O₂ appeared the temperature fell sharply. Had Earth been only slightly further from the Sun, runaway glaciation would have occured at that time. Simulations also indicate that a runaway greenhouse would have occured early in Earth's history had Earth been only a few percent closer to the Sun. It therefore appears that, taking into account the possibilities of either runaway glaciation or a runaway greenhouse effect, the continously habitable zone about a solar-type star is rather narrow, extending only from roughly 0.95 to 1.01 AU.     

Near-infrared spectrophotometry of Titan

Detailed analysis of the R(5) manifold of Titan's 3ν₃ CH₄ band confirms that the column abundance of Titan's spectroscopically visible atmosphere is greater than 1.6 kmamagats. This agrees with the value estimated from the strength of Titan's 3ν₃ CH₄Q branch and is at least 25 times the value for the column abundance of Mars' atmosphere. Moreover, the enhanced strength of the weaker CH₄ lines in Titan's spectrum relative to Saturn's spectrum suggests that CH₄ constitutes a significant fraction of this bulk.Recently discovered strong, unidentified absorptions in Titan's spectrum at 1.05–1.06 μm have been compared with laboratory spectra of a number of gases including CH₄, C₂H₄, C₂H₆, and C₃H₈ with negative results. These comparisons, however, have not excluded the possibility that these features arise from a very large quantity of CH₄ or from an isotope of CH₄. The fundamental transition of the responsible molecule may affect the interpretation of Titan's 8–14 μm spectrum since its wavelength may lie in this window. Comparison with Uranus' spectrum suggests that the visible abundance of this molecule in Titan's atmosphere may be much greater than in Uranus' relatively clear, deep atmosphere.Spectra of features at λ8150.7 and λ8272.7 attributed possibly to H₂ have been obtained at high resolution also during the apparitions of 1971, 1972, and 1973. These are presented for comparison with the results of the 1970 apparition. The existence of the λ8150.7 feature is established definitively but further observations are needed to establish whether the λ8272.7 feature exists beyond doubt.     

Chemistry and evolution of Titan's atmosphere

The chemistry and evolution of Titan's atmosphere is reviewed in the light of the scientific findings from the Voyager mission. It is argued that the present N₂ atmosphere may be Titan's initial atmosphere rather than photochemically derived from an original NH₃ atmosphere. The escape rate of hydrogen from Titan is controlled by photochemical production from hydrocarbons. CH₄ is irreversibly converted to less hydrogen rich hydrocarbons, which over geologic time accumulate on the surface to a layer thickness of ～0.5 km. Magnetospheric electrons interacting with Titan's exosphere may dissociate enough N₂ into hot, escaping N atoms to remove ～0.2 of Titan's present atmosphere over geologic time. The energy dissipation of magnetospheric electrons exceeds solar e.u.v. energy deposition in Titan's atmosphere by an order of magnitude and is the principal driver of nitrogen photochemistry. The environmental conditions in Titan's upper atmosphere are favorable to building up complex molecules, particularly in the north polar cap region.     

The Jovian atmospheric window at 2.7 μm: A search for H2S

The atmospheric transmission window at 2.7 μm in Jupiter's atmosphere was observed at a spectral resolution of 0.1 cm^?1 from the Kuiper Airborne Observatory. From analysis of the CH₄ abundance (～80m-am) and the H₂O abundance (<0.0125cm-am) it was determined that the penetration depth of solar flux at 2.7 μm is near the base of the NH₃ cloud layer. The upper limit to H₂O at 2.7 μm and other recent results suggest that photolytic reactions in Jupiter's lower troposphere may not be as significant as was previously thought. The search for H₂S in Jupiter's atmosphere yielded an upper limit of ～0.1cm-am. The corresponding limit to the elemental abundance ratio [S]/[H] was ～1.7 × 10^?8, about 10^?3 times the solar value. Upon modeling the abundance and distribution of H₂S in Jupiter's atmosphere it was concluded that, contrary to expectations, sulfur-bearing chromophores are not present in significant amounts in Jupiter's visible clouds. Rather, it appears that most of Jupiter's sulfur is locked up as NH₄SH in a lower cloud layer. Alternatively, the global abundance of sulfur in Jupiter may be significantly depleted.     

Axel dust on Saturn and Titan

The scattering and absorption properties of Axel dust were investigated by means of Mie theory. We find that a flat distribution of particle radii between 0 and 0.1 μm, and an imaginary part of the index of refraction which varies as λ^?2.5 produce a good fit to the variation of Titan's geometric albedo with wavelength (λ) provided that τ_ext, the extinction optical depth of Titan's atmosphere at 5000 Å, is about 10. The real part of the complex index is taken to be 2.0. The model assumes that the mixing ratio of Axel dust to gas is uniform above the surface of Titan. The same set of physical properties for Axel dust also produces a good fit to Saturn's albedo if τ_ext = 0.7 at 5000 Å. To match the increase in albedo shortward of 3500 Å, a clear layer (containing about 7 km-am H₂) is required above the Axel dust. Such a layer is also required to explain the limb brightening in the ultraviolet. These models can be used to analyze the observed equivalent widths of the visible methane bands. The analysis yields an abundance of the order of 1000 m-am CH₄ in Titan's atmosphere. The derived CH₄/H₂ mixing ratio for Saturn is about 3.5 × 10^?3 or an enhancement of about 5 over the solar ratio.     

On the origin and initial temperature of Jupiter and Saturn

A two-stage growth of the giant planets, Jupiter and Saturn, is considered, which is different from the model of contraction of large gaseous protoplanets. In the first stage, within a time of ～3 × 10⁷ years in Jupiter's zone and ～2 × 10⁸ years in Saturn's zone, a nucleus forms from condensed (solid) material having the mass, ～10²⁸ g, necessary for the beginning of acceleration. The second stage may gravitating body, and a relatively slow accretion begins until the mass of the planet reaches ～10 m_⊕. Then a rapid accretion begins with the critical radius less than the radius of the Hill lobe, so that the classical formulae for the rate of accretion may be applied. At a mass m > m₁ ≈ 50 m_⊕ accretion proceeds slower than it would according to these formulae. When the planet sweeps out all the gas from its nearest zone of feeding (m = m₂ ≈ 130 m_⊕), the width of the exhausted zone being $\text{～}\text{built1}\text{3}$ of the whole zone of the planet) growth is provided the slow diffusion of gas from the rest of the zone (time scale increases to 10⁵?10⁶ years and more). The process is terminated by the dissipation of the remnants of gas. In Saturn's zone m₁ > m₂ ≈ 30 m_⊕. The initial mass of the gas in Jupiter's zone is estimated. Before the beginning of the rapid accretion about 90% of the gas should have been lost from the solar system, and in the planet's zone less than two Jupiter masses remain. The highest temperature of Jupiter's surface, ≈5000°K, is reached at the stage of rapid accretion, m < 100 m_⊕, when the luminosity of the planet reaches 3 × 10^?3 L_⊙. This favors an effective heating of the inner parts of the accretionary disk and the dissipation of gas from the disk. The accretion of Saturn produced a temperature rise up to 2000?2400° K (at m ≈ 20?25 m_⊕) and a luminosity up to 10^?4 L_⊙.     

Past 100 ky surface salinity-gradient response in the Eastern Arabian Sea to the summer monsoon variation recorded by δO of G. sacculifer

Northward flowing coastal currents along the western margin of India during winter–spring advect low-salinity Bay of Bengal water in to the Eastern Arabian Sea producing a distinct low-salinity tongue, the strength of which is largely governed by the freshwater flux to the bay during summer monsoons. Utilizing the sedimentary records of δ¹⁸O_{G. sacculifer}, we reconstructed the past salinity-gradient within that low-salinity tongue, which serves as a proxy for the variation in freshwater flux to the Bay of Bengal and hence summer monsoon intensity.The north–south contrast in the sea level corrected (residual)-δ¹⁸O_{G. sacculifer} can be interpreted as a measure of surface salinity-contrast between those two locations because the modern sea surface temperature and its past variation in the study region is nearly uniform. The core-top residual-δ¹⁸O_{G. sacculifer} contrast of 0.45‰ between the two cores is assumed to reflect the modern surface salinity difference of 1 psu and serves as a calibration for past variations.The residual-δ¹⁸O_{G. sacculifer} contrast varies between 0.2‰ at 75 ky B.P. (i.e., late-Marine Isotope Stage 5) and 0.7‰ at 20 ky B.P. (i.e., Last Glacial Maximum), suggesting that the overall salinity difference between the northern- and southern-end of the low-salinity tongue has varied between 0.6 and 1.6 psu. Considerably reduced difference during the former period than the modern suggests substantially intensified and northward-extended low-salinity tongue due to intense summer monsoons than today. On the other hand, larger difference (1.6 psu) during the latter period indicates that the low-salinity tongue was significantly weakened or withdrawn due to weaker summer monsoons. Thus, the salinity-gradient in the eastern Arabian Sea low-salinity tongue can be used to understand the past variations in the Indian summer monsoons.     

Io's 4-μm band and the role of adsorbed SO2

The role of adsorbed SO₂ on Io's surface particles in producing the observed spectral absorption band near 4 μm in Io's reflectance spectrum is explored. Calculations show that a modest 50% monolayer coating of adsorbed SO₂ molecules on submicron grains of sulfur of alkali sulfide, assumed to make up Io's uppermost optical surface (“radialith”), will result in a ν₁ + ν₃ absorption band near 4 μm with depth ～30% below the adjacent continuum, consistent with the observed strength of the Io band. The precise wavelength position of the ν₁ + ν₃ band of SO₂ in different phase states such as frost, ice, adsorbate, and gas are summarized from the experimental literature and compared with the available telescopic measurements of the Io band position. The results suggest that the 4-μm band in Io's full disk spectrum can best be explained by the presence on Io's surface of widespread SO₂ in the form of adsorbate rather than ice or frost.     

An interpretation of the rotational temperature of the airglow hydroxyl emissions

The rotational temperature of the airglow hydroxyl emissions arising from various schemes of vibrational transitions was obtained by using spectroscopic data from six observational sources. The rotational temperature was found to depend systematically on the quantum number (ν') of the upper vibrational level from which the relevant band originates. It has a doubly degrading characteristic with respect to ν' taking maximal values at ν' = 6 and 9, which exceed considerably the atmospheric temperature. It drops off quickly as ν' decreases from 9 to 7, and then from 6 to 3 after making an abrupt rise at ν' = 6. This ν'-dependence of the rotational temperature is in favor of the hypothesis that there are two routes of excitation of the hydroxyl airglow: O₃ + H = OH(ν ? 9) + O₂, and HO₂ + O = OH(ν ? 6) + O₂. The present result implies also that the relaxation time of rotation of OH in the upper mesosphere is as long as 0.1 sec; a value an order of magnitude larger than that inferred in earlier laboratory experiments.     

Photochemistry of the Martian atmosphere

A variety of models are explored to study the photochemistry of CO₂ in the Martian atmosphere with emphasis on reactions involving compounds of carbon, hydrogen, and oxygen. Acceptable models are constrained to account for measured concentrations of CO and O above 90 km, with an additional requirement that they should be in accord with observations of CO, O₂, and O₃ in the lower atmosphere. Dynamical mixing must be exceedingly rapid at altitudes above 90 km, with effective eddy diffusion coefficients in excess of 10⁷ cm² sec^?1. If recombination of CO₂ is to occur mainly by gas phase chemistry, catalyzed by trace quantities of H, OH, and HO₂, mixing must be rapid over the altitude interval 30 to 40 km. The value implied for the diffusion coefficient in this region is a function of assumptions made regarding the rates for reaction of OH with HO₂ to form H₂O and of the rate for reaction of HO₂ with itself to form H₂O₂. If rates for these reactions are taken to have values similar to rates used in current models for the Earth's stratosphere, the eddy diffusion coefficient at 40 km on Mars should be about 5 × 10⁷ cm² sec^?1, consistent with Zurek's (1976) estimate for this parameter inferred from tidal theory. Surface chemistry could have an influence on the abundances of atmospheric CO and O₂, but a major effect would imply sluggish mixing at all altitudes below 50 km and in addition would carry implications for the magnitude of the rates for reaction of OH with HO₂ and HO₂ with itself.     

Orbital inclination of Iapetus and the rotation of the Laplacian plane

This paper explores the possibility that the orbit of Iapetus, with its relatively large inclination but small eccentricity, was generated by a rapid dispersal of a gaseous circumplanetary disk, assumed to be the progenitor of the satellite system. The orientation of the local Laplacian plane is shown to be a sensitive function of the disk's structure. Modification of the disk on a time scale comparable to the precesion of the orbit's nodal line, [i.e., $\text{O}$(10²?10³ years)], can produce a large inclination from one that is initially zero, while leaving the eccentricity unchanged. This time is of the same order of magnitude as the viscous evolution time scale for a fully turbulent disk. Hence Iapetus need not be a captured satellite to account for its curious orbital signature.     

Late glacial and Holocene environmental change in the Lake Baikal region documented by oxygen isotopes from diatom silica

We investigate late glacial and Holocene climate change recorded in Lake Baikal using the oxygen isotope composition of diatom silica (δ¹⁸O_DIAT). Evaporation from the lake is minor, and the temperature fractionations of δ¹⁸O are unable to explain variations in the δ¹⁸O_DIAT record alone. Isotopically, low meltwater input from glaciers may have some influence on δ¹⁸O_DIAT, but the assumed periods of climatic warming and wastage do not coincide with large shifts in δ¹⁸O_DIAT. There is a gradual oxygen isotope lowering from 27.0‰ to 20.6‰ over the late glacial, while, during the Holocene, δ¹⁸O_DIAT values return to relatively high values. Previous studies of the modern oxygen and hydrogen isotope composition of Lake Baikal's inputs reveal that fluvial input to the lake's North Basin are isotopically lower than fluvial input from South Basin rivers. This north–south gradient of river δ¹⁸O and δD is mainly due to the greater input from isotopically low winter precipitation in the north and isotopically higher summer precipitation in the south. As a result, the δ¹⁸O_DIAT record from Lake Baikal can at least in part be explained by varying input from these sources related to seasonal changes in precipitation. Changes in atmospheric conditions may have a role in altering seasonality and the distribution of precipitation over Lake Baikal's catchment. A feedback mechanism is well known linking higher Eurasian spring snow cover extent (ESSC) to the development of anticyclonic conditions and low precipitation the following summer in the areas south of Lake Baikal. A simultaneous increase in the importance of depleted water (snowmelt) input from the north and decreased enriched summer precipitation in the south is needed to explain depletions in δ¹⁸O of lake water and subsequently δ¹⁸O_DIAT during colder periods. The opposite of this situation is required to enrich lake water during warmer periods. The analysis of δ¹⁸O from diatom silica is a useful proxy for environmental change, especially in lakes, like Lake Baikal, where carbonates are absent or diluted. However, analysis must be based on near pure diatom samples as even trace amounts of silt can have a dominating effect on δ¹⁸O_DIAT values.     

Models of the cometary coma in which abundances are calculated for various heliocentric distances

One-dimensional radial models of the chemistry in cometary comae have been constructed for heliocentric distances ranging from 2 to 0.125 AU. The coma's opacity to solar radiation is included and photolytic reaction rates are calculated. A parent volatile mixture similar to that found in interstellar molecular clouds is assumed. Profiles through the coma of number density and column density are presented for H₂O, OH, O, CN, C₂, C₃, CH, and NH₂. Whole-coma abundances are presented for NH₂, CH, C₂, C₃, CN, OH, CO⁺, H₂O⁺, CH⁺, N₂⁺, and CO₂⁺.     

Long-term changes in Saturn's troposphere

We report the results of monitoring Saturn's H₂ quadrupole and CH₄ band absorptions outside of the equatorial zone over one-half of Saturn's year. This interval covers most of the perihelion half of Saturn's elliptical orbit, which happens to be approximately bounded by the equinoxes. Marked long-term changes occur in the CH₄ absorption accompanied by weakly opposite changes in the H₂ absorption. Around the 1980 equinox, the H₂ and CH₄ absorptions in the northern hemisphere appear to be discontinuous with those in the southern hemisphere. This discontinuity and the temporal variation of the absorptions are evidence for seasonal changes. The absorption variations can be attributed to a variable haze in Saturn's troposphere, responding to changes in temperature and insolation through the processes of sublimation and freezing. Condensed or frozen CH₄ is very unlikely to contribute any haze. The temporal variation of the absorption in the strong CH₄ bands at south temperate latitudes is consistent with a theoretically expected phase lag of 60° between the tropopause temperature and the seasonally variable insolation. We model the vertical haze distribution of Saturn's south temperature latitudes during 1971–1977 in terms of a distribution having a particle scale height equal to a fraction of the atmospheric scale height. The results are a CH₄/H₂ mixing ratio of (4.2 ± 0.4) × 10^?3, a haze particle albedo of $\text{ω}\text{= 0.995 ± 0.003}$, and a range of variation in the particle to gas scale-height ratio of 0.6 ± 0.2. The haze was lowest near the time of maximum temperature. We also report spatial measurements of the absorption in the 6450 Å NH₃ band made annually since the 1980 equinox. A 20 ± 4% increase in the NH₃ absorption at south temperate latitudes has occurred since 1973–1976 and the NH₃ absorption at high northern latitudes has increased during spring. Increasing insolation, and the resulting net sublimation of NH₃ crystals, is probably the cause. Significant long-term changes apparently extend to the deepest visible parts of Saturn's atmosphere. An apparently anomalous ortho-para H₂ ratio in 1978 suggests that the southern temperate latitudes experienced an unusual upwelling during that time. This may have signaled a rise in the radiative-convective boundary from deep levels following maximum tropospheric temperature and the associated maximum radiative stability. This would be further evidence that the deep, visible atmosphere is governed by processes such as dynamics and the thermodynamics of phase changes, which have response times much shorter than the radiative time constant.     

Petrology,mineralogy, and oxygen isotope compositions of aluminum‐rich chondrules from CV3 chondrites

Bulk major element composition, petrography, mineralogy, and oxygen isotope compositions of twenty Al‐rich chondrules (ARCs) from five CV3 chondrites (Northwest Africa [NWA] 989, NWA 2086, NWA 2140, NWA 2697, NWA 3118) and the Ningqiang carbonaceous chondrite were studied and compared with those of ferromagnesian chondrules and refractory inclusions. Most ARCs are marginally Al‐richer than ferromagnesian chondrules with bulk Al₂O₃ of 10–15 wt%. ARCs are texturally similar to ferromagnesian chondrules, composed primarily of olivine, pyroxene, plagioclase, spinel, Al‐rich glass, and metallic phases. Minerals in ARCs have intermediate compositions. Low‐Ca pyroxene (Fs_0.6–8.8Wo_0.7–9.3) has much higher Al₂O₃ and TiO₂ contents (up to 12.5 and 2.3 wt%, respectively) than that in ferromagnesian chondrules. High‐Ca pyroxene (Fs_0.3–2.0Wo_33–54) contains less Al₂O₃ and TiO₂ than that in Ca,Al‐rich inclusions (CAIs). Plagioclase (An_77–99Ab_1–23) is much more sodic than that in CAIs. Spinel is enriched in moderately volatile element Cr (up to 6.7 wt%) compared to that in CAIs. Al‐rich enstatite coexists with anorthite and spinel in a glass‐free chondrule, implying that the formation of Al‐enstatite was not due to kinetic reasons but is likely due to the high Al₂O₃/CaO ratio (7.4) of the bulk chondrule. Three ARCs contain relict CAIs. Oxygen isotope compositions of ARCs are also intermediate between those of ferromagnesian chondrules and CAIs. They vary from ?39.4‰ to 13.9‰ in δ¹⁸O and yield a best fit line (slope = 0.88) close to the carbonaceous chondrite anhydrous mineral (CCAM) line. Chondrules with 5–10 wt% bulk Al₂O₃ have a slightly more narrow range in δ¹⁸O (?32.5 to 5.9‰) along the CCAM line. Except for the ARCs with relict phases, however, most ARCs have oxygen isotope compositions (>?20‰ in δ¹⁸O) similar to those of typical ferromagnesian chondrules. ARCs are genetically related to both ferromagnesian chondrules and CAIs, but the relationship between ARCs and ferromagnesian chondrules is closer. Most ARCs were formed during flash heating and rapid cooling processes like normal chondrules, only from chemically evolved precursors. ARCs extremely enriched in Al and those with relict phases could have had a hybrid origin (Krot et al. 2002) which incorporated refractory inclusions as part of the precursors in addition to ferromagnesian materials. The occurrence of melilite in ARCs indicates that melilite‐rich CAIs might be present in the precursor materials of ARCs. The absence of melilite in most ARCs is possibly due to high‐temperature interactions between a chondrule melt and the solar nebula.     

The composition and origin of Titan's atmosphere

The discovery that Titan had an atmosphere was made by the identification of methane in the satellite's spectrum in 1944. But the abundance of this gas and the identification of other major constituents required the 1980 encounter by the Voyager 1 spacecraft. In the intervening years, traces of C₂H₂, C₂H₄, C₂H₆ and CH₃D had been posited to interpret emission bands in Titan's i.r. spectrum. The Voyager Infra-red Spectrometer confirmed that these gases were present and added seven more. The atmosphere is now known to be composed primarily of molecular nitrogen. But the derived mean molecular weight suggests the presence of a significant amount of some heavier gas, most probably argon. It is shown that this argon must be primordial, and that one can understand the evolution of Titan's atmosphere in terms of degassing of a mixed hydrate dominated by CH₄, N₂ and ³⁶Ar. This model satisfactorily explains the absence of neon and makes no special requirements on the satellite's surface temperature.     

The effect of upwelling on the distribution and stable isotope composition of Globigerina bulloides and Globigerinoides ruber (planktic foraminifera) in modern surface waters of the NW Arabian Sea

Hydrographic changes in the NW Arabian Sea are mainly controlled by the monsoon system. This results in a strong seasonal and vertical gradient in surface water properties, such as temperature, nutrients, carbonate chemistry and the isotopic composition of dissolved inorganic carbon (δ¹³C_DIC). Living specimens of the planktic foraminifer species Globigerina bulloides and Globigerinoides ruber, were collected using depth stratified plankton tows during the SW monsoon upwelling period in August 1992 and the NE monsoon non-upwelling period in March 1993. We compare their distribution and the stable isotope composition to the seawater properties of the two contrasting monsoon seasons. The oxygen isotope composition of the shells (δ¹⁸O_shell) and vertical shell concentration profiles indicate that the depth habitat for both species is shallower during upwelling (SW monsoon period) than during non-upwelling (NE monsoon period). The calcification temperatures suggest that most of the calcite is precipitated at a depth level just below the deep chlorophyll maximum (DCM), however above the main thermocline. Consequently, the average calcification temperature of G. ruber and G. bulloides is lower than the sea surface temperature by 1.7±0.8 and 1.3±0.9 °C, respectively. The carbon isotope composition of the shells (δ¹³C_shell) of both species differs from the in situ δ¹³C_DIC found at the calcification depths of the specimens. The observed offset between the δ¹³C_shell and the ambient δ¹³C_DIC results from (1) metabolic/ontogenetic effects, (2) the carbonate chemistry of the seawater and, for symbiotic G. ruber, (3) the possible effect of symbionts or symbiont activity. Ontogenetic effects produce size trends in Δδ¹³C_shell–DIC and Δδ¹⁸O_shell–w: large shells of G. bulloides (250–355μm) are 0.33‰ (δ¹³C) and 0.23‰ (δ¹⁸O) higher compared to smaller ones (150–250 μm). For G. ruber, this is 0.39‰ (δ¹³C) and 0.17‰ (δ¹⁸O). Our field study shows that the δ¹³C_shell decreases as a result of lower δ¹³C_DIC values in upwelled waters, while the effects of the carbonate system and/or temperature act in an opposite direction and increase the δ¹³C_shell as a result lower [CO₃²⁻] (or pH) values and/or lower temperature. The Δδ¹³C_shell–DIC [CO₃²⁻] slopes from our field data are close to those reported literature from laboratory culture experiments. Since seawater carbonate chemistry affects the δ¹³C_shell in an opposite sense, and often with a larger magnitude, than the change related to productivity (i.e. δ¹³C_DIC), higher δ¹³C_shell values may be expected during periods of upwelling.