Excitation of O(1S) and emission of 5577 Å radiation in aurora

The results of recent laboratory experiments suggest that the reaction N⁺ + O₂ → NO⁺ + O(¹S) is the principal source of O(¹S) in aurora. A negligible time delay between auroral ionization and O(¹S) production is associated with this indirect process, which is a necessary condition for a viable mechanism. The $\text{5577}\text{A}\text{?}\text{3914}\text{A}\text{?}$ volume emission rate ratio associated with this production source remains constant with altitude. The problems encountered by the currently accepted source of O(¹S), the reaction of N₂(A³Σ) molecules with atomic oxygen are explored, and the contributions of this and other reactions to the auroral green line emission are reevaluated.     

Energy transfer of O(1S) atoms in collision with O(3P) atoms

Elastic scattering and excitation transfer collision cross-sections in O(¹S)-O(³P) collisions are calculated. These cross-sections are needed in determining the degree of thermalization of the O(¹S) atoms in the nighttime thermosphere. A formula is given for the rate coefficient for the production of an O(¹S) atom with a specific energy in collisions involving an O(¹S) atom of a given initial energy and the ground state O(³P) atoms of a thermal gas. Effective elastic scattering and excitation transfer cross-sections are defined and calculated to be 1.71 × 10^?15 cm² and 6.67 × 10^?16 cm² respectively at a relative collision energy of 0.41 eV.     

O(1S) quenching profile between 75 and 115 km

The rate at which O(¹S) is quenched in the atmosphere has been calculated as a function of altitude in the 75–115 km region. Recent measurements of the temperature-dependent O ₂ quenching rate coefficient have been used, while for quenching by O(³P), an expression combining new theoretical and experimental results is employed. For the O(³P) altitude profile, the Jacchia (1971) model is chosen. The quenching profile shows a pronounced minimum quenching rate at about 87 km. It is concluded that different studies carried out on pulsating Type-B red aurorae, which extract an O(¹S) quenching rate from the time lag between N ₂⁺(B?X) emission and 5577-Åemission, can now be interpreted as indicating an altitude range for these aurorae of 84–89 km. This conclusion is in accord with observations made on artificial aurorae.     

Linewidth studies on the NI(4S−4P) resonance multiplet

We have measured the linewidths of the NI multiplets $\text{[2p}{}^2\text{3p}{}^4\text{D}{}^0\text{?2p}{}^2\text{3s}{}^4\text{P, λ8691}\text{A}\text{?}\text{; 2p}{}^2\text{3p}{}^4\text{P}{}^0\text{?2p}{}^2\text{3s}{}^4\text{P, λ8212}\text{A}\text{?}\text{; 2p}{}^2\text{3s}{}^4\text{P?2p}{}^3{}^4\text{S}{}^0\text{, λ1200}\text{A}\text{?}\text{]}$ produced in the dissociative excitation of N₂ by energy electrons. The infrared transitions excite the N(⁴P) resonance state by cascade and they account for > 50% of the total N(⁴P) cross section at 100 eV. Both the i.r. and v.u.v. lines are found to be highly Doppler broadened ( ～ 25 times the thermal Doppler line width). These results indicate that dissociative excitation of N₂ produces N (⁴P) atoms with sufficient kinetic energy so that the $\text{λ1200}\text{A}\text{?}$ resonance radiation $\text{[2p}{}^2\text{3s}{}^4\text{P ?2p}{}^3{}^4\text{S}{}^0\text{]}$ emitted by these excited atoms would be optically thin in the Earth's upper atmosphere. We also found that the line strength ratios for the resolved components of the $\text{λ1200}\text{A}\text{?}$ triplet excited by dissociative excitation differ from those predicted by the multiplicities of the states involved and used in current entrapment models; the intensity ratios also vary with the energy of the incident electron. These developments introduce new complications into the analysis of the terrestrial ultraviolet dayglow.     

Energy transfer from excited N2 and O2 as a source of O(1S) in the Aurora

It is proposed that energy transfer from excited O₂ contributes to the production of O(¹S) in aurora. An analysis is presented of the OI5577 Å emission in an IBC II⁺ aurora between 90 and 130 km. The volume emission rate of the emission at these altitudes is consistent with the production rate of O(¹S) by energy transfer to O(³P) from N₂ in the A³Σ₂⁺ state and O₂ in the A³Σ_u⁺, C³Δc¹Σ_u^? states, the N₂A state being populated by direct electron impact excitation and B → A cascade and the excited O₂ states by direct excitation. Above the peak emission altitude (~105 km), energy transfer from N₂A is the predominant production mechanism for O(¹S). Below it, the contribution from quenching of the O₂ states becomes significant.     

Line shape of the non-thermal 6300 Å O(1D) emission

The line shape of the non-thermal O(¹D) 6300 Å emission is calculated using the two population model of Schmitt, Abreu and Hays (Planet. Space Sci.29, 1095, 1981). The calculated line shapes simulate observations made from a space platform at different zenith angles and altitudes. The non-thermal line shapes observed at zenith angles other than the local vertical have been obtained by using the Addition theorem for spherical harmonics of a Legendre polynomial expansion of the non-thermal population distribution function.     

The height,spectrum and mechanism of type-B red aurora and its bearing on the excitation of O(1S) in aurora

The height of the lower red border of type-B aurora has been determined by triangulation using TV cameras at two ground stations. A mean height of 91.4 ± 1.1 km was determined from a set of 12 measurements made under ideal conditions. A TV spectrograph was used simultaneously to seek possible spectral changes between 6400 and 6900 Å which would be indicative of changes in the vibrational distribution in the N₂ First Positive bands. No significant difference was found in this distribution between the spectra from 93 and 122 km. The height distribution of contributions to the OI 5577 Å emission relative to the N⁺₂ First Negative emission was modelled from 80 to 160 km. Contributions from electron impact on atomic O, O⁺₂ dissociative recombination and N₂(A)O energy transfer were included. Account was taken of recent laboratory data on O(¹S) quenching. It was concluded that these processes could explain the excitation of O(¹S) in normal aurora and the height distribution of OI 5577 Å in type-B red aurora. It was confirmed that the lifetime ofO(¹S) in type-B red auroral rapid time variations is about 0.5 s and it was found from the model that the observed time variation can be reproduced by the mechanisms considered, provided the concentration of NO in the auroral atmosphere is about 1 × 10⁹ at 95 km. Before reasonable certainty can be attained in the correctness of the interpretation it will however be necessary to have reliable simultaneous observations of neutral atmospheric composition particularly for O and NO as well as unchallengeable measurements of the yields of O(¹S) for the processes considered and for several other processes which have been suggested recently.     

Observations of horizontal transport effects on high latitude metastable O(1D), N(2D) auroral emissions

An analysis is presented of photometric measurements of the NI (λ = 520nm),OI(λ = 630nm)and other emissions made at Nord, where the invariant latitude is Λ = 80°4. The time variations of the intensities are interpreted in the following way by comparison with simultaneous ground based or satellite measurements.The N(²D) atoms formed in the dayside cleft are carried by the neutral wind in a plume across the polar cap, so that the ratio of λ(630 nm) to λ(520 nm) intensities decreases along the plume with increasing distance from the source region.In the polar cap, but outside the plume region, 630 nm emission is produced by electron impact of polar rain and by substorms that reach high latitudes. Ionization produced at the same time, especially by the substorms, will produce further 630 nm emission through dissociative recombination. In any case, the region outside the plume may be regarded as a source region, with a high value of the ratio $\text{I(630)}\text{I(520)}$. This explains in part the diurnal variations, since this ratio is depressed as Nord crosses the dayside plume.The electron energy along the oval increases progressively from the dayside to the nightside. The intensity ratio increases with increasing electron energy because N(²D) is quenched more rapidly than O(¹D). Thus the ratio rises progressively from noon to midnight.An effect of the interplanetary magnetic field is superimposed on this pattern : as its North-South component B_z increases, the oval contracts so that Nord becomes nearer from the cleft source and the intensity ratio increases on the dayside. The inverse effect is also observed. On the nightside, negative B_z is associated with substorms that produce poleward expansions of the poleward oval boundary, that brings more energetic precipitation to Nord. This causes the intensity ratio to increase with decreasing B_z in a way that is opposite to that for the dayside.     

Associative ionization of N(2D) and O

Recent laboratory measurements have shown that N(²P) atoms, and thus probably hot N(²D) atoms, will recombine with atomic oxygen via an associative ionization process at the gas kinetic rate. While the reaction is endothermic, it has been suggested that this has interesting implications for the upper atmosphere in that N(²D) atoms in the tail of the velocity distribution could provide an additional source of NO⁺ through the reverse of the dissociative recombination reaction

$\text{NO}{}^{\mathrm{+}}\text{+ e ?}\text{N}\text{(}{}^2\text{D}\text{) +}\text{O}$

. It has also been suggested that this process might account for the difference between a laboratory determination of the rate coefficient and that determined from the Atmospheric Explorer Satellite data. In this paper we investigate further the likelihood of the associative ionization of N(²D) and O playing a significant role in the normal ionosphere, in the light of several recent relevant studies. We conclude that the associative ionization process is not an important factor and that a more probable cause for disagreements in the various determinations of the recombination coefficient, is the difference in excited states of the ions in the various experiments.     

A comment on proposed mechanisms for the excitation of O(1S) in the aurora

A recent assessment by Rees (1984) of the contribution made to the excitation of O(¹S) in the aurora by the reaction of N₂(A³Σ⁺) with O(³P) is re-examined. It is demonstrated that the contribution attributed to this reaction may have been seriously under-estimated and it is shown that the results of recent laboratory investigations do not preclude this reaction as a major source of O(¹s) in the aurora.     

Energy distribution function of translationally hot O(3P) atoms in the atmosphere of Earth

Translationally hot O(³P) atoms are produced in the atmosphere of Earth by photolysis of O₂ and O₃ and quenching of O(¹D). A rigorous kinetic theory analysis of this problem is developed and compared with the approach previously employed by Logan and McElroy [Planet. Space Sci.25, 117 (1977)]. It is shown that the kinetic theory employed by the previous workers is somewhat deficient. With the line-of-centers cross-section, the rates of reactions of the translationally hot O(³P) atoms with other atmospheric gases are calculated and found to be in some instances many orders of magnitude larger than the equilibrium rates. Though the non-equilibrium reaction rates with O(³P) are substantially increased, they are still not competitive with the corresponding reaction rates with O(¹D).     

Spectral synthesis of the O2+ 1NG bands observed in aurora

Synthetic spectral band profiles of the O₂⁺ 1NG system are presented for use in the analysis of auroral observations. Observed profiles are used to check the accuracy of the simulation.     

Quenching of O+(2D) by electrons in the thermosphere

A major loss process for the metastable species, O⁺(²D), in the thermosphere is quenching by electrons

$\text{O}{}^{\mathrm{+}}\text{(}{}^2\text{D) + e → O}{}^{\mathrm{+}}\text{(}{}^4\text{S) + e}$

.To date no laboratory measurement exists for the rate coefficient of this reaction. Thermospheric models involving this process have thus depended on a theoretically calculated value for the rate coefficient and its variation with electron temperature. Earlier studies of the O⁺(²D) ion based on the Atmosphere Explorer data gathered near solar minimum, could not quantify this process. However, Atmosphere Explorer measurements made during 1978 exhibit electron densities that are significantly enhanced over those occurring in 1974, due to the large increases that have occurred in the solar extreme ultraviolet flux. Under such conditions, for altitudes ? 280 km, the electron quenching process becomes the major loss mechanism for O⁺(²D), and the chemistry of the N⁺₂ ion, from which the O⁺(²D) density is deduced, simplifies to well determined processes. We are thus able to use the in situ satellite measurements made during 1978 to derive the electron quenching rate coefficient. The results confirm the absolute magnitude of the theoretical calculation of the rate coefficient, given by the analytical expression k(T_e) = 7.8 × 10^?8 (T_e/300)^?0.5cm³s^?1. There is an indication of a stronger temperature dependence, but the agreement is within the error of measurement.     

A discussion of the energy transfer from N2(A3Σu+) to O(1S) in pulsating aurora

In a recent paper, Brekke and Pettersen (1972) have introduced a method for estimating any indirect process in the production of the $\text{O}\text{(}{}^1\text{S}$) atoms in pulsating aurora; for 38 per cent of their data they found that the decay time for the indirect mechanism was shorter than the effective lifetime of the ${}^1\text{S}$ state. These data are related to the energy transfer from the N₂(A³Σ) molecules to the $\text{O}\text{(}{}^1\text{S)}$ state, and evidence is found for this process to contribute in the altitude range below 125 km.     

The excitation of atomic oxygen to the O(1S) level by energy transfer from N2(A3∑u+) molecules in aurora

The part that the energy transfer reaction $\text{N}{}_2\text{(A}{}^3\text{∑}{}_{\mathrm{u}}{}^{\mathrm{+}}\text{) + O(}{}^3\text{P) → N}{}_2\text{(X}{}^1\text{∑}{}_{\mathrm{g}}{}^{\mathrm{+}}\text{) + O(}{}^1\text{S)}$ plays in the excitation of the auroral green line has been investigated. The contribution is estimated to be 40 per cent in this case, containing pulsating aurora in class IBC 1. Due to greater quenching of the A³∑_u⁺ state, the centroid of the VK emission is displaced 10 km upwards of the green line height, which is centred at 110 km.     

The 12C/13C ratio in jupiter from the Voyager infrared investigation

The ¹²C/¹³C ratio in Jupiter has been derived from the analysis of the ν₄ band of CH₄ in the spectra recorded by the Voyager 1 IRIS experiment. It is found to be 160_?55⁺⁴⁰, i.e., 1.8_?0.6^+0.4 times the terrestrial value. Instrumental noise as well as systematic sources of error were taken into account for the estimate of the uncertainty. No plausible theory predicts such a difference between the values of the ¹²C/¹³C ratio in the inner solar system and in Jupiter. However, values of this ratio in the solar neighborhood 4.5 by ago inferred—through the use of models of chemical evolution of the Galaxy —from recent interstellar medium measurements are compatible with the present determination in Jupiter. The Jovian value, rather than the terrestrial one, could then be representative of the ratio in the primitive solar nebula.     

Changes in thermospheric composition inferred from twilight O+(2P) emission

Measurements of the twilight enhancement of airglow emission from O⁺(²P) near 7325 Å reveal major changes which accompany geomagnetic activity, no significant distance between evening and morning and an increase in brightness paralleling the approach to solar maximum. The principal source for O⁺(²P) is direct photoionization from O(³P) but at low solar activity there appears to be a contribution from another source in early twilight which may be local photoelectron ionization into O⁺(²P). The geomagnetic and solar effects appear to reflect changes in the O and N₂ density in the thermosphere; ground based twilight measurements of O⁺ emissions thus provide a simple means for monitoring thermospheric structure from 300 km to ～ 500 km at solar minimum and to ～600 km at solar maximum.     

Ir Observations Of An Outburst In Comet Hale-Bopp (C/1995 O1)

The comet Hale-Bopp (C/1995 O1) has been observed in the infrared (1–2.5 μm) with the Nordic Optical Telescope (NOT) equipped with the Arcetri NICMOS3 camera (ARNICA). Two observational campaigns, each one lasting about one week, were made when the comet heliocentric distance was about 3 AU. The first campaign was at the end of August and the second at the end of September 1996. During both runs two major outbursts were observed, the more intense of them started the day before the beginning of the second run. In the images recorded during the first three nights (24.8–26.8 Sept.) of the second run a dust shell expanding in the northern quadrant with a projected velocity of 0.14–0.28 km/s is clearly evident. The dust production rate increased by at least a factor ≈3 at the time of the outburst. Also evident on the first night is a change in the IR color that is well correlated with the dust shell. This is an indication that the material released by the outburst has a different composition and/or size distribution than that in the “quiescent” dust coma. In this paper we present preliminary results about the evolution and the photometric characteristics of the dust shell. This revised version was published online in July 2006 with corrections to the Cover Date.     

Transport of aurorally produced N(2D) by winds in the high latitude thermosphere

A time-dependent two-dimensional numerical model of the minor neutral constituents of the thermosphere NO, N(²D), and N(⁴S) is used to examine the effects of winds in transporting these constituents from their production region in auroral arcs. The calculations show that thermospheric winds flowing through regions of enhanced local auroral production produce downwind plumes of enhanced minor neutral constituent densities and that the densities depend upon the wind velocity. Below about 200 km N(²D) is in photochemical equilibrium and is not transported. Above 200 km N(²D) is transported by the wind and since quenching of N(²D) by O is small and the radiational lifetime is long, a downwind plume of emission at 5200 Å develops from the particle source region. We present data from a rocket flight in the vicinity of the magnetospheric cusp and data from the Atmosphere Explorer-D (AE-D) satellite that both show enhanced 5200 Å emission rates in a general downwind direction from a region of direct particle precipitation. The general wind speed and direction are obtained from predictions made by the NCAR thermospheric general circulation model. The results suggest that transport of N(²D) by the wind system is more important than the convection of O⁺ ions by electric fields in causing the enhanced 5200 Å emission rate in regions outside but in the vicinity of direct particle precipitation.     

Observations of the inner coma of C/1995O1 (Hale-Bopp)—gas and dust production

Hale-Bopp (C/1995 O1) was the most productive recent comet observed in terms of gas and dust output. Since its discovery in 1995 at a distance of 7.14 AU from the Sun, the comet has been well observed, revealing the dynamics of a rare and large comet. Hale-Bopp showed strong emissions of the principle cometary gases CN, C₃, and C₂, as well as an abundance of dust. The production rates of these gases were found to be 1.45×10²⁸, 1.71×10²⁸, and , respectively, with dust production, in terms of Afρ, , as measured in the green continuum (5260 Å). The observations for this paper are presented in two groups spanning 10 days each, one group centered near 32 days prior to and the other 21 days after perihelion. The averages of dust and gas production rates show a slightly higher value for each prior to perihelion than after perihelion, consistent with a possible peak in production a few weeks prior to perihelion passage.