Rates of North Atlantic Deep Water formation calculated from chlorofluorocarbon inventories

Chlorofluorocarbon (CFC) inventories provide an independent method for calculating the rate of North Atlantic Deep Water (NADW) formation. From data collected between 1986 and 1992, the CFC-11 inventories for the major components of NADW are: 4.2 million moles for Upper Labrador Sea Water (ULSW), 14.7 million moles for Classical Labrador Sea Water (CLSW), 5.0 million moles for Iceland–Scotland Overflow Water (ISOW), and 5.9 million moles for Denmark Strait Overflow Water (DSOW). The inventories directly reflect the input of newly formed water into the deep Atlantic Ocean from the Greenland, Iceland and Norwegian Seas and from the surface of the subpolar North Atlantic during the time of the CFC-11 transient. Since about 90% of CFC-11 in the ocean as of 1990 entered the ocean between 1970 and 1990, the formation rates estimated by this method represent an average over this time period. Formation rates based on best estimates of source water CFC-11 saturations are: 2.2 Sv for ULSW, 7.4 Sv for CLSW, 5.2 Sv for ISOW (2.4 Sv pure ISOW, 1.8 Sv entrained CLSW, and 1.0 Sv entrained northeast Atlantic water) and 2.4 Sv for DSOW. To our knowledge, this is the first calculation for the rate of ULSW formation. The formation rate of CLSW was calculated for an assumed variable formation rate scaled to the thickness of CLSW in the central Labrador Sea with a 10 : 1 ratio of high to low rates. The best estimate of these rates are 12.5 and 1.3 Sv, which average to 7.4 Sv for the 1970–1990 time period. The average formation rate for the sum of CLSW, ISOW and DSOW is 15.0 Sv, which is similar to (within our error) previous estimates (which do not include ULSW) using other techniques. Including ULSW, the total NADW formation rate is about 17.2 Sv. Although ULSW has not been considered as part of the North Atlantic thermohaline circulation in the past, it is clearly an important component that is exported out of the North Atlantic with other NADW components.     

Total organic and inorganic carbon exchange through the Strait of Gibraltar in September 1997

The total organic carbon (TOC) and total inorganic carbon (C_T) exchange between the Atlantic Ocean and the Mediterranean Sea was studied in the Strait of Gibraltar in September 1997. Samples were taken at eight stations from western and eastern entrances of the Strait and at the middle of the Strait (Tarifa Narrows). TOC was analyzed by a high-temperature catalytic oxidation method, and C_T was calculated from alkalinity–pH_T pairs and appropriate thermodynamic relationships. The results are used in a two-layer model of water mass exchange through the Strait, which includes the Atlantic inflow, the Mediterranean outflow and the interface layer in between. Our observations show a decrease of TOC and an increase of C_T concentrations from the surface to the bottom: 71–132 μM C and 2068–2150 μmol kg⁻¹ in the Surface Atlantic Water, 74–95 μM C and 2119–2148 μmol kg⁻¹ in the North Atlantic Central Water, 63–116 μM C and 2123–2312 μmol kg⁻¹ in the interface layer, and 61–78 μM C and 2307–2325 μmol kg⁻¹ in the Mediterranean waters. However, within the Mediterranean outflow, we found that the concentrations of carbon were higher at the western side of the Strait (75–78 μM C, 2068–2318 μmol kg⁻¹) than at the eastern side (61–69 μM C, 2082–2324 μmol kg⁻¹). This difference is due to the mixing between the Atlantic inflow and the Mediterranean outflow on the west of the Strait, which results in a flux of organic carbon from the inflow to the outflow and an opposite flux of inorganic carbon. We estimate that the TOC input from the Atlantic Ocean to the Mediterranean Sea through the Strait of Gibraltar varies from (0.97±0.8)10⁴ to (1.81±0.90)10⁴ mol C s⁻¹ (0.3×10¹² to 0.56×10¹² mol C yr⁻¹), while outflow of inorganic carbon ranges from (12.5±0.4)10⁴ to (15.6±0.4)10⁴ mol C s⁻¹ (3.99–4.90×10¹² mol C yr⁻¹). The high variability of carbon exchange within the Strait is due to the variability of vertical mixing between inflow and outflow along the Strait. The prevalence of organic carbon inflow and inorganic carbon outflow shows the Mediterranean Sea to be a basin of active remineralization of organic material.     

Water mass properties and fluxes in the Rockall Trough, 1975–1998

A time series of a standard hydrographic section in the northern Rockall Trough spanning 23 yr is examined for changes in water mass properties and transport levels. The Rockall Trough is situated west of the British Isles and separated from the Iceland Basin by the Hatton and Rockall Banks and from the Nordic Seas by the shallow (500 m) Wyville–Thompson ridge. It is one pathway by which warm North Atlantic upper water reaches the Norwegian Sea and is converted into cold dense overflow water as part of the thermohaline overturning in the northern North Atlantic and Nordic Seas. The upper water column is characterised by poleward moving Eastern North Atlantic Water (ENAW), which is warmer and saltier than the subpolar mode waters of the Iceland Basin, which also contribute to the Nordic Sea inflow. Below 1200 m the deep Labrador Sea Water (LSW) is trapped by the shallowing topography to the north, which prevents through flow but allows recirculation within the basin. The Rockall Trough experiences a strong seasonal signal in temperature and salinity with deep convective winter mixing to typically 600 m or more and the formation of a warm fresh summer surface layer. The time series reveals interannual changes in salinity of ±0.05 in the ENAW and ±0.04 in the LSW. The deep water freshening events are of a magnitude greater than that expected from changes in source characteristics of the LSW, and are shown to represent periodic pulses of newer LSW into a recirculating reservior. The mean poleward transport of ENAW is 3.7 Sv above 1200 dbar (of which 3.0 Sv is carried by the shelf edge current) but shows a high-level interannual variability, ranging from 0 to 8 Sv over the 23 yr period. The shelf edge current is shown to have a changing thermohaline structure and a baroclinic transport that varies from 0 to 8 Sv. The interannual signal in the total transport dominates the observations, and no evidence is found of a seasonal signal.     

Increase in anthropogenic CO2 in the Atlantic Ocean in the last two decades

Data from the first systematic survey of inorganic carbon parameters on a global scale, the GEOSECS program, are compared with those collected during WOCE/JGOFS to study the changes in carbon and other geochemical properties, and anthropogenic CO₂ increase in the Atlantic Ocean from the 1970s to the early 1990s. This first data-based estimate of CO₂ increase over this period was accomplished by adjusting the GEOSECS data set to be consistent with recent high-quality carbon data. Multiple Linear Regression (MLR) and extended Multiple Linear Regression (eMLR) analyses to these carbon data are applied by regressing DIC with potential temperature, salinity, AOU, silica, and PO₄ in three latitudinal regions for the western and eastern basins in the Atlantic Ocean. The results from MLR (and eMLR provided in parentheses) indicate that the mean anthropogenic CO₂ uptake rate in the western basin is 0.70 (0.53) mol m^?2 yr^?1 for the region north of 15°N; 0.53 (0.36) mol m^?2 yr^?1 for the equatorial region between 15°N and 15°S; and 0.83 (0.35) mol m^?2 yr^?1 in the South Atlantic south of 15°S. For the eastern basin an estimate of 0.57 (0.45) mol m^?2 yr^?1 is obtained for the equatorial region, and 0.28 (0.34) mol m^?2 yr^?1 for the South Atlantic south of 15°S. The results of using eMLR are systematically lower than those from MLR method in the western basin. The anthropogenic CO₂ increase is also estimated in the upper thermocline from salinity normalized DIC after correction for AOU along the isopycnal surfaces. For these depths the results are consistent with the CO₂ uptake rates derived from both MLR and eMLR methods.     

Mesoscale physical variability affects zooplankton production in the Labrador Sea

Surface distribution (0–100 m) of zooplankton biomass and specific aminoacyl-tRNA synthetases (AARS) activity, as a proxy of structural growth, were assessed during winter 2002 and spring 2004 in the Labrador Sea. Two fronts formed by strong boundary currents, several anticyclonic eddies and a cyclonic eddy were studied. The spatial contrasts observed in seawater temperature, salinity and fluorescence, associated with those mesoscale structures, affected the distributions of both zooplankton biomass and specific AARS activity, particularly those of the smaller individuals. Production rates of large organisms (200–1000 μm) were significantly related to microzooplankton biomass (63–200 μm), suggesting a cascade effect from hydrography through microzooplankton to large zooplankton. Water masses defined the biomass distribution of the three dominant species: Calanus glacialis was restricted to cold waters on the shelves while Calanus hyperboreus and Calanus finmarchicus were widespread from Canada to Greenland. Zooplankton production was up to ten-fold higher inside anticyclonic eddies than in the surrounding waters. The recent warming tendency observed in the Labrador Sea will likely generate weaker convection and less energetic mesoscale eddies. This may lead to a decrease in zooplankton growth and production in the Labrador basin.     

Year-long float trajectories in the Labrador Sea Water of the eastern North Atlantic Ocean

Year-long Lagrangian trajectories within the Labrador Sea Water of the eastern North Atlantic Ocean are analysed for basic flow statistics. Root-mean-square velocities at 1750 m depth are about 2 cm/s, except within the North Atlantic Current, where they are twice as large. These values are consistent with previous Eulerian measurements and extend those results to a much larger domain of the eastern basin. Mean flow estimates in boxes large enough to contain about 1 float-year of data indicate that Labrador Sea Water, having crossed the Mid- Atlantic Ridge (not resolved) near 50–55^°N, presumably with the North Atlantic Current, partially recirculates to the north in the subpolar gyre, as well as entering the subtropical gyre and continuing south and west. The circulation of this water mass, as defined by the 1 yr average velocities, is stronger than traditional models of deep circulation would suggest, with an interior flow of roughly 1 cm/s. Mean speeds up to 3 cm/s were observed, with the highest values near the Azores Plateau. North of 45°N–55°N, mean eastward speeds closer to 0.2 cm/s were observed. Wind-generated barotropic fluctuations may be responsible for some part of the transport at this depth.     

Arctic ocean shelf–basin interaction: An active continental shelf CO2 pump and its impact on the degree of calcium carbonate solubility

The Arctic Ocean has wide shelf areas with extensive biological activity including a high primary productivity and an active microbial loop within the surface sediment. This in combination with brine production during sea ice formation result in the decay products exiting from the shelf into the deep basin typically at a depth of about 150 m and over a wide salinity range centered around S ～33. We present data from the Beringia cruise in 2005 along a section in the Canada Basin from the continental margin north of Alaska towards the north and from the International Siberian Shelf Study in 2008 (ISSS-08) to illustrate the impact of these processes. The water rich in decay products, nutrients and dissolved inorganic carbon (DIC), exits the shelf not only from the Chukchi Sea, as has been shown earlier, but also from the East Siberian Sea. The excess of DIC found in the Canada Basin in a depth range of about 50–250 m amounts to 90±40 g C m^?2. If this excess is integrated over the whole Canadian Basin the excess equals 320±140×10¹² g C. The high DIC concentration layer also has low pH and consequently a low degree of calcium carbonate saturation, with minimum aragonite values of 60% saturation and calcite values just below saturation. The mean age of the waters in the top 300 m was calculated using the transit time distribution method. By applying a future exponential increase of atmospheric CO₂ the invasion of anthropogenic carbon into these waters will result in an under-saturated surface water with respect to aragonite by the year 2050, even without any freshening caused by melting sea ice or increased river discharge.     

The hydrography of the mid-latitude Northeast Atlantic Ocean: II: The intermediate water masses

The intermediate water masses in the eastern Atlantic Ocean between 31°N and 53°N were studied by analysis of the distributions of potential temperature, salinity, dissolved nutrients and oxygen. Sub-surface salinity minima are encountered everywhere in the area. At the northern and southern boundary they are connected with the presence of Sub-Arctic Intermediate Water and Antarctic Intermediate Water, respectively, but towards the European ocean margin the sub-surface salinity minima shift to shallower density levels. The sub-surface salinity minima observed west of the Iberian Peninsula represent a water mass formed by winter convection in the Porcupine Sea Bight and the northern Bay of Biscay. These minima gain salt by diapycnal mixing with the underlying Mediterranean Sea Outflow water and with the overlying permanent thermocline. The core of Antarctic Intermediate Water appears to contribute to the formation of Mediterranean Sea Outflow Water since it becomes entrained into the overflow near Gibraltar. This entrainment gives rise to an enhanced concentration of the nutrients in the Mediterranean water in the North Atlantic. The deep salinity minimum, due to the presence of Labrador Sea Water, is restricted mainly to the Porcupine Abyssal Plain. In the Bay of Biscay this water type is strongly modified by enhanced diapycnal mixing near the continental slope. At all intermediate levels the continental slope in the Bay of Biscay seems to be a focal point for water mass modification by diapycnal mixing. Below the core of the Mediterranean Sea Outflow Water the Labrador Sea Water is also strongly modified. Its salinity is strongly enhanced by diapycnal mixing with the overlying core of Mediterranean Sea Outflow Water. An analysis of the oxygen and nutrient data indicates that the large spatial concentration differences at the level of the Labrador Sea Water are caused mainly by ageing of the water. The youngest water is observed at 52°N, and, especially in the Bay of Biscay and off south-west Portugal, the water at levels of about 1700 dbar are strongly enriched in nutrients and depleted in oxygen.     

An autonomous instrument for time series analysis of TCO2 from oceanographic moorings

The design and testing of a robotic analyzer for autonomous TCO₂ measurement from oceanographic moorings is described. The analyzer employs a conductimetric method of TCO₂ measurement wherein CO₂ from an acidified sample diffuses across a semi-permeable membrane into a NaOH solution decreasing the conductivity of the base. The instrument is capable of ～850 analyses over a period of at least six months. It is designed to operate to depths of at least 1000 m. TCO₂ calibration is based on in situ standardization throughout a deployment.We report both laboratory and in situ tests of the analyzer. In the laboratory automated analyses over a period of 38 days at temperatures ranging from 8° to 25 °C yielded a TCO₂ accuracy and precision of ±2.7 μmol/kg. In situ tests were conducted at the WHOI dock with a deployment of 8 weeks at in situ temperatures of 5°–13 °C. The accuracy and precision of TCO₂ analyses over the deployment period, based on in situ calibration, was ±3.6 μmol/kg.Laboratory tests of reagent and standard solution stability are also reported. Standards, based on Certified Reference Material were followed for periods of up to 2 years. In all cases TCO₂ increased. Drift of the standards was the equivalent of ～1 to 3 μmol/kg per 6 months. The conductivity indicator solution was found to be stable for at least 2 months.     

Uncoupled transport of chlorofluorocarbons and anthropogenic carbon in the subpolar North Atlantic

Chlorofluorocarbon (CFC) 11 and 12 transports across the transoceanic World Ocean Circulation Experiment (WOCE) A25 section in the subpolar North Atlantic are derived from an inverse model using hydrographic and ADCP data (Lherminier et al., 2007). CFC and anthropogenic carbon (C_ANT) advective transports contrary to expected are uncoupled: C_ANT is transported northeastwards (82±39 kmol s^?1) mainly within the overturning circulation, while CFC-11 and CFC-12 are transported southwestwards (?24±4 and ?11±2 mol s^?1, respectively) as part of the large-scale horizontal circulation. The main reason for this uncoupled behaviour is the complex CFC vs. C_ANT relation in the ocean, which stems from the contrasting temperature relation for both tracers: more C_ANT dissolves in warmer waters with a low Revelle factor, while CFC’s solubility is higher in cold waters. These results point to C_ANT and CFC having different routes of uptake, accumulation and transport within the ocean, and hence: C_ANT transport would be more sensitive to changes in the overturning circulation strength, while CFC to changes in the East Greenland Current and Labrador Sea Water formation in the Irminger Sea. Additionally, C_ANT and CFCs would have different sensitivities to circulation and climate changes derived from global warming as the slowdown of the overturning circulation, increase stratification due to warming and changes in wind stress.     

A carbon budget for the Barents Sea

The first carbon budget constructed for the Barents Sea to study the fluxes of carbon into, out of, and within the region is presented. The budget is based on modelled volume flows, measured dissolved inorganic carbon (DIC) concentration, and literature values for dissolved organic carbon (DOC) and particulate organic carbon (POC) concentrations. The results of the budget show that ～5600±660×10⁶ t C yr^?1 is exchanged through the boundaries of the Barents Sea. If a 40% uncertainty in the volume flows is included in the error calculation it resulted in a total uncertainty of ±1600×10⁶ t C yr^?1. The largest part of the total budget flux consists of DIC advection (～95% of the inflow and ～97% of the outflow). The other sources and sinks are, in order of importance, advection of organic carbon (DOC+POC; ～3% of both in- and outflow), total uptake of atmospheric CO₂ (～1% of the inflow), river and land sources (～0.2% of the inflow), and burial of organic carbon in the sediments (～0.2% of the outflow). The Barents Sea is a net exporter of carbon to the Arctic Ocean; the net DIC export is ～2500±660×10⁶ t C yr^?1 of which ～1700±650×10⁶ t C yr^?1 (～70%) is in subsurface water masses and thus sequestered from the atmosphere. The net total organic carbon export to the Arctic Ocean is ～80±20×10⁶ t C yr^?1. Shelf pumping in the Barents Sea results in an uptake of ～22±11×10⁶ t C yr^?1 from the atmosphere which is exported out of the area in the dense modified Atlantic Waters. The main part of this carbon was channelled through export production (～16±10×10⁶ t C yr^?1).     

Microbial respiration in the Levantine Sea: evolution of the oxidative processes in relation to the main Mediterranean water masses

First data on microbial respiration in the Levantine Sea are reported with the aim of assessing the distribution of oxidative processes in association with the main Mediterranean water masses and the changing physical structure determined by the Eastern Mediterranean Transient. Respiratory rates, in terms of metabolic carbon dioxide production, were estimated from measured electron transport system activities in the polygonal area of the Levantine Sea (32.5–36.5 N Latitude, 26.0–30.25 E Longitude) and at Station Geo’95, in the Ionian Sea (35°34.88 N; 17°14.99 E). At the Levantine Sea, the mean carbon dioxide production rate decreased from the upper to the deeper layers and varied from 22.0±12.4 μg C h⁻¹ m⁻³ in the euphotic layer to 1.30±0.5 μg C h⁻¹ m⁻³ in the depth range between 1600 and 3000 m. Significant differences were found among upper, intermediate and bottom layers. The euphotic zone supported a daily carbon dioxide production of 96.6 mg C d⁻¹ m⁻² while the aphotic zone (between 200 and 3000 m) sustained a 177.1 mg C d⁻¹ m⁻² carbon dioxide production. In Station Geo’95, the carbon dioxide production rates amounted to 170.4 and 102.2 mg C d⁻¹ m⁻² in the euphotic and aphotic zones, respectively. The rates determined in the identified water masses showed a tight coupling of respiratory processes and Mediterranean circulation patterns. The increasing respiratory rates in the deep layers of the Levantine Sea are explained by the introduction of younger waters recently formed in the Aegean Sea.     

An inverse modeling study in Fram Strait. Part II: Water mass distribution and transports

A water-mass analysis is carried out in Fram Strait, between 77.15 and 81.15°N, based on three-dimensional large-scale potential temperature and salinity distributions reconstructed from the MIZEX 84 hydrographic data collected in summer 1984. Combining these distributions with the geostrophic flow field derived from the same data in a companion paper (Schlichtholz and Houssais, 1999), the heat, fresh water and volume transports are estimated for each of the water masses identified in the strait. Twelve water masses are selected based on their different origins. Among them, the Polar Water (PW) enters Fram Strait from the Arctic Ocean both over the Greenland Slope and over the western slope of the Yermak Plateau. In the Atlantic Water (AW) range, four modes with distinct geographical distributions are indentified. In the Deep Water range, the Eurasian Basin Deep Water (EBDW) is confined to the Lena Trough and to the Molloy Deep area where it is involved in a cyclonic circulation. The warm and shallower mode of the Norwegian Sea Deep Water (NSDW), concentrated to the west, is mainly seen as an outflow from the Arctic Ocean while the cold and deeper mode, essentially observed to the east, enters the strait from the Greenland Sea. Apart from the EBDW, there is a tendency for all water masses of polar origin to flow along the Greenland Slope. The two most abundant water masses, the AW and the NSDW, occupy as much as 67% of the total water volume. The southward net transport of PW through Fram Strait is about 1 Sv at 78.9°N. At the same latitude, the net transport of AW is southward and equal to about 1.7 Sv. Only the transport of the warm mode (AWw) is northward, amounting to 0.2 Sv. The overall net outflow of the Deep Waters to the Greenland Sea is about 2.6 Sv. Two upper water masses, the fresh (AWf) and the cold (AWc) mode of the AW, and one deep-water mass, the NSDW, appear to be produced in the strait, with production rates, between 77.6 and 79.9°N, of about 0.2, 1.0 and 1.7 Sv, respectively. A southward net fresh-water transport through the strait of about 2000 km³ yr⁻¹ (relative to a salinity of 34.93) is mainly due to the PW. The net heat transport relative to −0.1°C is northward, but undergoes a rapid northward decrease, suggesting an area-averaged surface heat loss of 50–100 W m⁻² in the strait.     

Hydrography of chromophoric dissolved organic matter in the North Atlantic

The distribution and optical absorption characteristics of chromophoric dissolved organic matter (CDOM) were systematically investigated along three meridional transects in the North Atlantic Ocean and Caribbean Sea conducted as part of the 2003 US CLIVAR/CO₂ Repeat Hydrography survey. Hydrographic transects covered in aggregate a latitudinal range of 5° to 62° north along longitudes 20°W (line A16N, Leg 1), 52°W (A20), and 66°W (A22). Absorption spectra of filtered seawater samples were collected and analyzed for depths ranging from the surface to ∼6000 m, sampling all the ocean water masses in the western basin of the subtropical North Atlantic and several stations on the North and South American continental slopes. The lowest surface abundances of CDOM (< 0.1 m⁻¹ absorption coefficient at 325 nm) were found in the central subtropical gyres while the highest surface abundances (∼0.7 m⁻¹) were found along the continental shelves and within the subpolar gyre, confirming recent satellite-based assessments of surface CDOM distribution. Within the ocean interior, CDOM abundances were relatively high (0.1–0.2 m⁻¹ absorption coefficient at 325 nm) except in the subtropical mode water, where a local minimum exists due to the subduction of low CDOM surface waters during mode water formation. In the subthermocline water masses of the western basin, changes in CDOM abundance are not correlated with increasing ventilation age as assessed using chlorofluorocarbon (CFC) concentrations and the atmospheric CFC history. But dissolved organic carbon (DOC) mass-specific absorption coefficients of CDOM increase with increasing ventilation age in the deep sea, indicating that CDOM is a refractory component of the DOC pool. The overall CDOM distribution in the North Atlantic reflects the rapid advection and mixing processes of the basin and demonstrates that remineralization in the ocean interior is not a significant sink for CDOM. This supports the potential of CDOM as a tracer of ocean circulation processes for subducted water masses.     

The carbonate system in the East China Sea in winter

Measurements of dissolved inorganic carbon (DIC), pH, total alkalinity (TA), and partial pressure of CO₂ (pCO₂) were conducted at a total of 25 stations along four cross shelf transects in the East China Sea (ECS) in January 2008. Results showed that their distributions in the surface water corresponded well to the general circulation pattern in the ECS. Low DIC and pCO₂ and high pH were found in the warm and saline Kuroshio Current water flowing northeastward along the shelf break, whereas high DIC and pCO₂ and low pH were mainly observed in the cold and less saline China Coastal Current water flowing southward along the coast of Mainland China. Difference between surface water and atmospheric pCO₂ (ΔpCO₂), ranging from ~ 0 to ? 111 μatm, indicated that the entire ECS shelf acted as a CO₂ sink during winter with an average flux of CO₂ of ?13.7 ± 5.7 (mmol C m^? 2 day^? 1), and is consistent with previous studies. However, pCO₂ was negatively correlated with temperature for surface waters lower than 20 °C, in contrast to the positive correlation found in the 1990s. Moreover, the wintertime ΔpCO₂ in the inner shelf near the Changjiang River estuary has appreciably decreased since the early 1990s, suggesting a decline of CO₂ sequestration capacity in this region. However, the actual causes for the observed relationship between these decadal changes and the increased eutrophication over recent decades are worth further study.     

Smectite composition as a tracer of deep circulation: the case of the Northern North Atlantic

The link between smectite composition in sediments from the northern North Atlantic and Labrador Sea, and deep circulation is being further investigated through detailed studies of the X-ray pattern of smectites and cation saturations. This allows clear distinction of dominant terrigenous sources associated to the main components of the modern Western Boundary Undercurrent. Time variations of smectite characteristics in two piston cores from the inlet and outlet of the Western Boundary Undercurrent gyre in the Labrador Sea indicate: (1) a more southern circulation of North East Atlantic Deep Water during the Late Glacial; (2) a step by step transition to the modern pattern of deep circulation during the Late Glacial/Holocene transition, with intensification of North East Atlantic Deep Water and Davis Strait Overflow; (3) an expansion of Davis Strait Overflow and Labrador Sea Water circulation in relation to ice surges and deposition of detrital layers; (4) an intensified circulation of North East Atlantic Deep Water during the Younger Dryas; and (5) a very recent increased influence of Denmark Strait Overflow Water beginning between 4.4 and <1 kyr.     

Long-term hydrographic changes at 52 and 66°W in the North Atlantic Subtropical Gyre & Caribbean

In July–September 1997 two hydrographic lines were done in the western N. Atlantic along longitudes of 52 and 66°W as part of the WOCE one-time hydrographic survey of the oceans. Each of these two lines approximately repeated earlier ones done during the International Geophysical Year(s) (IGY) and the mid-1980s. Because of this repeated sampling, long-term hydrographic changes in the water masses can be examined. In this report, we focus on temperature and salinity changes within the subtropical gyre mainly between latitudes of 20 and 35°N and compare our results to those presented by Bryden et al. (1996), who examined changes along a zonal line at 24°N, most recently occupied in 1992. Since this most recent 24°N section in 1992, substantial changes have occurred in the western part of the subtropical gyre at the depths of the Labrador Sea Water (LSW). In particular, we see clear evidence for colder, fresher Labrador Sea Water throughout the gyre on our two recent sections that was not yet present in 1992 at similar longitudes along 24°N. At shallower depths inhabited by waters that are an admixture of Mediterranean (MW) and Antarctic Intermediate Waters (AAIW), our recent survey shows an increase in salinity, which can only be attributed to changes in water masses on potential temperature or neutral density surfaces. Furthermore, waters above the MW/AAIW layer and into the deeper part of the main pycnocline have continued to become saltier and warmer throughout the 40-year period spanned by our sections. These latter changes have been dominantly due to a vertical sinking of density surfaces as T/S changes in density surfaces are small, but depths of individual T/S horizons have increased with time. The net change since the IGY shows a mean temperature increase between 800 and 2500 m depth at a rate of 0.57°C/century with a corresponding steric sea level rise of 1 mm/yr, and a net downward heave with small values near the top and bottom, and a maximum rate of −2.7 m/yr at 1800 m depth. Changes in the deep Caribbean indicate a warming since the IGY due to temperature increases of the inflowing source waters in the subtropical gyre at 1800m depth, but no significant change in the deep salinity.     

Regional variations in the fluxes of foraminifera carbonate,coccolithophorid carbonate and biogenic opal in the northern Indian Ocean

Mass fluxes of diatom opal, planktonic foraminifera carbonate and coccolithophorid carbonate were measured with time-series sediment traps at six sites in the Arabian Sea, Bay of Bengal and Equatorial Indian Ocean (EIOT). The above fluxes were related to regional variations in salinity, temperature and nutrient distribution. Annual fluxes of diatom opal range between 3 and 28 g m⁻² yr⁻¹, while planktonic foraminifera carbonate fluxes range between 6 and 23 g m⁻² yr⁻¹ and coccolithophorid carbonate fluxes range between 4 and 24 g m⁻² yr⁻¹. Annual planktonic foraminifera carbonate to coccolithophorid carbonate ratios range between 0.8 and 2.2 and coccolithophorid carbonate to diatom opal ratios range between 0.5 and 3.3.In the western Arabian Sea, coccolithophorids are the major contributors to biogenic flux during periods of low nutrient concentrations. Coccolithophorid carbonate fluxes decrease and planktonic foraminiferal carbonate and diatom opal fluxes increase when nutrient-rich upwelled waters are advected over the trap site. In the oligotropic eastern Arabian Sea, coccolithophorid carbonate fluxes are high throughout the year. Planktonic foraminiferal carbonate fluxes are the major contributors to biogenic flux in the EIOT. In the northern and central Bay of Bengal, when surface salinity values drop sharply during the SW monsoon, there is a drastic reduction in planktonic foraminiferal carbonate fluxes, but coccolithophorid carbonate and diatom opal fluxes remain steady or continue to increase. Distinctly higher annual molar Si_bio/C_inorg (>1) and C_org/C_inorg (>1.5) ratios are observed in the northern and central Bay of Bengal mainly due to lower foraminiferal carbonate production as a result of sharp salinity variations. We can thus infer that the enhanced freshwater supply from rivers should increase oceanic CO₂ uptake. Its silicate supply favours the production of diatoms while the salinity drop produces conditions unfavourable for most planktonic foraminifera species.     

Tracing the North Atlantic Deep Water through the Romanche and Chain fracture zones with chlorofluoromethanes

Chlorofluoromethanes (CFMs) F-11 and F-12 were measured during August 1991 and November 1992 in the Romanche and Chain Fracture Zones in the equatorial Atlantic. The CFM distributions showed the two familiar signatures of the more recently ventilated North Atlantic Deep Water (NADW) seen in the Deep Western Boundary Current (DWBC). The upper maximum is centered around 1600 m at the level of the Upper North Atlantic Deep water (UNADW) and the deeper maximum around 3800 m at level of the Lower North Atlantic Deep Water (LNADW). These observations suggest a bifurcation at the western boundary, some of the NADW spreading eastward with the LNADW entering the Romanche and the Chain Fracture Zones. The upper core (σ_1.5=34.70 kg m^-3) was observed eastward as far as 5°W. The deep CFM maximum (σ₄=45.87 kg m^-3), associated with an oxygen maximum, decreased dramatically at the sills of the Romanche Fracture Zone: east of the sills, the shape of the CFM profiles reflects mixing and deepening of isopycnals. Mean apparent water “ages” computed from the F-11/F-12 ratio are estimated. Near the bottom, no enrichment in CFMs is detected at the entrance of the fracture zones in the cold water mass originating from the Antarctic Bottom Water flow.