Authigenic carbonates from methane seeps of the Congo deep-sea fan

Submersible investigations with the ROV Victor 6000 of some pockmark structures on the seafloor of the Congo deep-sea fan have shown that they are active venting sites of methane-rich fluids, associated with abundant fauna and carbonate crusts. Moreover, methane hydrates have been observed both outcropping and deep in the sediments in the centre of the “Regab” giant pockmark. Authigenic carbonates, mostly calcite sometimes mixed with aragonite, are cementing the sedimentary matrix components and fauna; diatoms are abundant but only as moulds, indicating that biogenic silica dissolution occurred in situ synchronous with carbonate precipitation. The occurrence of diagenetic barite and pyrite in some carbonate crusts demonstrates that they can be formed either within the sulphate/methane transition zone or deeper in sulphate-depleted sediments. The oxygen isotopic compositions of the diagenetic carbonates (3.17–6.01‰ V-PDB) indicate that precipitation occurred with bottom seawater mixed with a variable contribution of water from gas hydrate decomposition. The very low carbon isotopic compositions of the diagenetic carbonates (−57.1 to −27.75‰ V-PDB) demonstrate that carbon derives mostly from the microbial oxidation of methane.     

Cold-seep assemblages on a giant pockmark off West Africa: spatial patterns and environmental control

A giant pockmark colonised by dense cold‐seep assemblages near 3160 m depth along the Congo‐Angola margin has been surveyed by the ROV Victor 6000. The quantitative distribution of chemosynthetic communities was mapped along the dive tracks from a video study using GIS and image mosaicking. Several types of faunal assemblages, either dominated by bivalves of the families Mytilidae (Bathymodiolus sp.) or Vesicomyidae (Calyptogena sp., ‘Vesicomya’ aff. chuni), or by Siboglinidae polychaetes (Escarpia southwardae) were mapped over the 800‐m diameter pockmark area and sampled for fauna, water and sediment. The isotopic analyses (δ¹³C) of tissues from symbiont‐bearing species were within the range typical of nutrition via symbiosis using methane for mussels and sulphide for vesicomyids and siboglinids. The living chemosynthetic communities were distributed on a SW‐NE axis, corresponding to the expression at the sediment surface of a main buried channel providing fluids to the pockmark. The site was characterised by a more active central part in a depression with abundant carbonate concretions where high‐density clusters of siboglinids and mytilids dominate. Large fields of dead and live vesicomyids with a lower mean density were observed in the external areas. The mean coverage of each of the three symbiotic taxa in these two contrasted areas was estimated from mosaic analysis and was up to 30% in the central area dominated by E. southwardae bushes (23%). Symbiont‐bearing species distribution was consistent with methane concentrations in seawater that were generally higher in mytilid beds than in the vicinity of siboglinids and vesicomyids. A Principal Component Analysis performed on environmental factors at the ten sampling sites revealed that 37% of the observed variance in the distribution of symbiont‐bearing species may be explained by variation in both methane and oxygen concentrations, while a Canonical Redundancy Analysis selected methane concentration as the only variable which explains symbiont‐bearing species densities. This spatial distribution of chemosynthetic species at the pockmark scale may reflect temporal patterns of succession of both substrate and fauna, and may be related to different individual pockmarks visible on the microbathymetry mapped using ROV data.     

Monitoring of a methane-seeping pockmark by cabled benthic observatory (Patras Gulf, Greece)

A new seafloor observatory, the gas monitoring module (GMM), has been developed for continuous and long-term measurements of methane and hydrogen sulphide concentrations in seawater, integrated with temperature (T), pressure (P) and conductivity data at the seafloor. GMM was deployed in April 2004 within an active gas-bearing pockmark in the Gulf of Patras (Greece), at a water depth of 42 m. Through a submarine cable linked to an onshore station, it was possible to remotely check, via direct phone connection, GMM functioning and to receive data in near-real time. Recordings were carried out in two consecutive campaigns over the periods April–July 2004, and September 2004–January 2005, amounting to a combined dataset of ca. 6.5 months. This represents the first long-term monitoring ever done on gas leakage from pockmarks by means of CH₄+H₂S+T+P sensors. The results show frequent T and P drops associated with gas peaks, more than 60 events in 6.5 months, likely due to intermittent, pulsation-like seepage. Decreases in temperature in the order of 0.1–1°C (up to 1.7°C) below an ambient T of ca. 17°C (annual average) were associated with short-lived pulses (10–60 min) of increased CH₄+H₂S concentrations. This seepage “pulsation” can either be an active process driven by pressure build-up in the pockmark sediments, or a passive fluid release due to hydrostatic pressure drops induced by bottom currents cascading into the pockmark depression. Redundancy and comparison of data from different sensors were fundamental to interpret subtle proxy signals of temperature and pressure which would not be understood using only one sensor.     

Influence of seep emission on the non-symbiont-bearing fauna and vagrant species at an active giant pockmark in the Gulf of Guinea (Congo–Angola margin)

Detailed surveying with an ROV found that a dense and diverse cold-seep community colonises a giant pockmark located at 3200 m depth, 8 km north from the deep Congo channel. Several types of assemblages, either dominated by Mytilidae and Vesicomyidae bivalves or Siboglinidae polychaetes, are distributed on the 800-m diameter active area. The site is characterised by a most active central zone in a depression with abundant carbonate concretions and high methane fluxes where high-density clusters of mussels and siboglinids dominate. In contrast, the peripheral zones display large fields of dead and live vesicomyids on soft sediment, with a lower mean density and lower methane concentration in seawater. The associated megafauna includes Alvinocarididae shrimps, echinoids, holothurians of the family Synaptidae, several species of gastropods, two species of galatheids, and Zoarcidae and Ophidiidae fishes. Multivariate analyses of video transect data show that the distribution of these major megafauna species at the pockmark scale is influenced by the habitat heterogeneity due to fluid or gas emission, occurrence of hydrates, substratum variability and by the presence of large symbiont-bearing species. Several assemblages dominated either by mytilids, vesicomyids, or siboglinids have been sampled for megafauna densities and biomass estimations and stable isotope measurements (δ¹³C and δ¹⁵N) of dominant species and food sources. The highest estimates of megafauna densities have been obtained in mytilid beds. According to their stable isotopes values, non-symbiont-bearing species mainly rely on chemosynthesis-originated carbon, either as primary consumers of chemoautotrophic microorganisms, or at higher trophic level recycling organic matter, or relying on bivalve and tubeworm production. Most of them likely feed on different sources like shrimps, but differences according to habitat have been evidenced. Carbon and nitrogen isotope ratios of galatheids and benthic or benthopelagic fishes captured by trawls at increasing distances from the pockmark provide evidence of the high variability in the proportion of chemosynthesis-originated carbon in their diet, from 15% to 38%, according to the species captured as far as 4 km to the site.     

Benthic foraminifera from the deep-water Niger delta (Gulf of Guinea): Assessing present-day and past activity of hydrate pockmarks

We present ecological and isotopic (δ¹⁸O and δ¹³C) data on benthic foraminifera sampled from 4 deep-sea stations in a pockmark field from the deep-water Niger delta (Gulf of Guinea, Equatorial Atlantic Ocean). In addition, a series of sedimentological and (bio)geochemical data are shown to back up foraminiferal observations. All stations are located within 1.2 km of each other, so prevailing oceanographic conditions can be assumed to be similar at each site. Two of the sites (GMMC-01 and GMMC-02) are located in a pockmark (named “pockmark A”) where current methane seepages were recorded by ROV observations. A third station (GMMC-03) is located in the topographic depression interpreted as a collapsed pockmark (named “pockmark B”). The fourth site (GMMC-04) is a reference station, without evidence of past or present seepages. Our observations show that degraded organic matter with low bio-availability is present at all stations with a preferential burial of organic compounds in topographic depressions (GMMC-03 station). Authigenic aragonite is abundant in surface sediments at stations GMMC-01 and -02. Its precipitation is likely related to high rates of methane oxidation during past seep events in episodically active pockmark A. In contrast, the absence of anaerobic methanotrophic Archaea (ANME) during the sampling period (November 2011) suggests that only moderate sulphide and methane oxidation take place close to the sediment–water interface. Compared to the reference site GMMC-04, living foraminifera at the collapsed and episodically active pockmarks show minor changes in terms of diversity, standing stocks and faunal composition. However, the δ¹³C signal of living and dead (but well-preserved) foraminiferal species (Ceratobulimina contraria, Melonis barleeanus, Uvigerina peregrina) is depleted in the episodically active pockmark A compared to the other stations. Overgrowth of authigenic carbonate on altered foraminifera generates an important shift to lower δ¹³C values. Dead faunas carry a complex time-averaged message, integrating taphonomic gains and losses related to the temporal variability of gas emission. They reveal major faunal differences that may be useful to detect gas hydrate seepages in different pockmark stages.     

Pockmarks in the inner Oslofjord,Norway

Multibeam bathymetric surveys of the Inner Oslofjord, Norway have revealed a high density of pockmarks in the 179-km² inner fjord area, which contains over 500 pockmarks of varying size, typically 20–50 m in diameter and 2–10 m deep. These pockmarks have been investigated with a variety of techniques, including acoustic subbottom profiling, sedimentological and geochemical analyses of cores, remotely operated vehicle observation, and morphometry. Both the distribution and shapes of the pockmarks suggest that they are related to structures in the bedrock underlying relatively thin (<50 m) unconsolidated glacial and postglacial sediments. The data provide no direct indication of a particular mode of pockmark formation, but release of large amounts of biogenic, shallow methane seems unlikely. Several lines of evidence point to a continuous process of pockmark formation followed by inactivity, with some pockmarks recently active whereas others have been inactive for a considerable time. Some pockmarks are characterised by coarse sediment in their centres. The density, variety and easy access make this pockmark field an ideal model area for pockmark research. John S. Gray is deceased.     

Glacial and deglacial seafloor methane emissions from pockmarks on the northern flank of the Storegga Slide complex

The Storegga Slide complex is a multi-stage slope failure on the Norwegian continental margin where the most recent major event occurred 8.1 ka b.p. (calendar years before present). Its northern flank contains pockmark features that are commonly inferred to be related to the historical and modern venting of methane-bearing fluids. Three jumbo piston cores (JPC), one from a pockmark and two background cores at variable distances from this site (proximal, 5 km, and distal, 15 km) on the northern flank of the slide (806–1,524 m water depths), were sampled at 10 cm resolution to assess the geologic record of methane venting in the Nyegga pockmark field. Six down-core radiocarbon measurements on mixed planktonic foraminifer species reveal ages of 9.4–16.4 ka b.p. Bathymodiolus mussel shell horizons, indicators of methane-rich environments, have been dated at 15.8–17.6 and ~22 ka b.p. in the pockmark core. Stable isotope analyses on planktonic (Neogloboquadrina pachyderma sinistral) and benthic (Islandiella norcrossi, Melonis barleeanum) Foraminifera reveal δ¹⁸O values indicative of a clear glacial/deglacial transition (−1.5‰ shift in planktonic species). Both planktonic and benthic δ¹³C signatures record multiple excursions, interpreted to reflect the influence of methane in the environment; these δ¹³C excursions occur in the pockmark core and also in the distal background core. While authigenic calcite formation on the seafloor may play an important role in producing such excursions, these data together suggest the influence of methane seepage within the pockmark field over the past 25 ka, whereby seepage was particularly active between 13 and 15 ka. This is consistent with previously inferred regional increases in porewater pressure associated with glacial loading and higher sedimentation rates, which can cause gas hydrate and slope instability.     

Ground-truthing 11- to 12-kHz side-scan sonar imagery in the Norwegia–Greenland Sea: Part I: Pockmarks on the Vestnesa Ridge and Storegga slide margin

 Numerous small (50- to 300-m-diameter) strong-backscatter objects were imaged on the 1200- to 1350-m deep crest of Vestnesa Ridge (Fram Strait) and along the 900- to 1000-m deep northeast margin of the Storegga slide valley. Ground-truthing identified most of these objects as 2- to 10-m-deep pockmarks, developed within soft, acoustically stratified silty clays (typical wet bulk density: 1400–1600 kg m^-3; sound speed: 1480– 1505 m s^-1; porosity, 65–75%; shear strength: 5–10 kPa; water content: 80–120%; and thermal conductivity: 0.8–0.9 W m^-1 deg C^-1 in the top 3 m). Gas wipeouts, enhanced reflectors, and reflector discontinuities indicate recent or ongoing activity, but the absence of local heat flow anomalies suggests that any upward fluid flows are modest and/or local.     

More than a century of bathymetric observations and present-day shallow sediment characterization in Belfast Bay, Maine, USA: implications for pockmark field longevity

Mechanisms and timescales responsible for pockmark formation and maintenance remain uncertain, especially in areas lacking extensive thermogenic fluid deposits (e.g., previously glaciated estuaries). This study characterizes seafloor activity in the Belfast Bay, Maine nearshore pockmark field using (1) three swath bathymetry datasets collected between 1999 and 2008, complemented by analyses of shallow box-core samples for radionuclide activity and undrained shear strength, and (2) historical bathymetric data (report and smooth sheets from 1872, 1947, 1948). In addition, because repeat swath bathymetry surveys are an emerging data source, we present a selected literature review of recent studies using such datasets for seafloor change analysis. This study is the first to apply the method to a pockmark field, and characterizes macro-scale (>5 m) evolution of tens of square kilometers of highly irregular seafloor. Presence/absence analysis yielded no change in pockmark frequency or distribution over a 9-year period (1999–2008). In that time pockmarks did not detectably enlarge, truncate, elongate, or combine. Historical data indicate that pockmark chains already existed in the 19th century. Despite the lack of macroscopic changes in the field, near-bed undrained shear-strength values of less than 7 kPa and scattered downcore ¹³⁷Cs signatures indicate a highly disturbed setting. Integrating these findings with independent geophysical and geochemical observations made in the pockmark field, it can be concluded that (1) large-scale sediment resuspension and dispersion related to pockmark formation and failure do not occur frequently within this field, and (2) pockmarks can persevere in a dynamic estuarine setting that exhibits minimal modern fluid venting. Although pockmarks are conventionally thought to be long-lived features maintained by a combination of fluid venting and minimal sediment accumulation, this suggests that other mechanisms may be equally active in maintaining such irregular seafloor morphology. One such mechanism could be upwelling within pockmarks induced by near-bed currents.     

Pockmarks off Big Sur, California

A pockmark field was discovered during EM-300 multi-beam bathymetric surveys on the lower continental slope off the Big Sur coast of California. The field contains ∼1500 pockmarks which are between 130 and 260 m in diameter, and typically are 8-12 m deep located within a 560 km² area. To investigate the origin of these features, piston cores were collected from both the interior and the flanks of the pockmarks, and remotely operated vehicle observation (ROV) video and sampling transects were conducted which passed through 19 of the pockmarks. The water column within and above the pockmarks was sampled for methane concentration. Piston cores and ROV collected push cores show that the pockmark field is composed of monotonous fine silts and clays and the cores within the pockmarks are indistinguishable from those outside the pockmarks. No evidence for either sediment winnowing or diagenetic alteration suggestive of fluid venting was obtained. ¹⁴C measurements of the organic carbon in the sediments indicate continuous sedimentation throughout the time resolution of the radiocarbon technique (∼45?000 yr BP), with a sedimentation rate of ∼10 cm per 1000 yr both within and between the pockmarks. Concentrations of methane, dissolved inorganic carbon, sulfate, chloride, and ammonium in pore water extracted from within the cores are generally similar in composition to seawater and show little change with depth, suggesting low biogeochemical activity. These pore water chemical gradients indicate that neither significant accumulations of gas are likely to exist in the shallow subsurface (∼100 m) nor is active fluid advection occurring within the sampled sediments. Taken together the data indicate that these pockmarks are more than 45?000 yr old, are presently inactive, and contain no indications of earlier fluid or gas venting events.     

Mud transportation on a steep shelf,Rio de La Plata shelf,Puerto Rico

Hurricanes David (August 29–30, 1979) and Frederick (September 2–5, 1979) caused major flooding of the Rio de La Plata in northern Puerto Rico. A thin mud layer was deposited across the narrow insular shelf adjacent to the river mouth. Within 5 months, fair-weather shelf-winnowing processes moved the mud layer entirely from the shelf, 0.5 to 2 km to the shelf break at the 50-m contour and beyond. The process of mud movement is termed “mud hopping.”     

Characteristics of two natural gas seepages in the North Sea

Two occurrences of active gas seepages are described from the North Sea. The southernmost one, situated above a salt diapir in Norwegian block , has been studied and sampled by use of a remotely operated vehicle (ROV). This seepage consists of about 120 single seeps located within a diameter of 100 m. It is estimated to produce 24 m³ of methane gas per day (at ambient pressure, 75 m water depth). Isotope values of the methane gas and higher hydrocarbon gases in the surrounding seafloor sediments, show that their origin is from a deep seated, thermogenic source. No typical gas-induced erosion features are found on the seafloor at this location, probably due to the lack of very fine grained material.The second occurrence is located in U.K. block (Geoteam, 1984), where the seepage is associated with a very large pockmark depression, measuring 17 m in depth and 700×450 m in width. This depression represents an eroded fine grained sediment volume of 7.10⁵ cubic metres. No detailed inspection or sampling of the gas has been performed here. However seismic reflection anomalies are seen on airgun seismic records at various levels down to a depth of at least 1100 m below seafloor. The seeping gas, possibly mixed with liquids, at this location is therefore also expected to be of a thermogenic origin.     

Active seepage in two contrasting pockmark fields in the Patras and Corinth gulfs, Greece

Two pockmark fields, located along the coastal zone of the Patras and Corinth gulfs, Greece were surveyed in detail. The pockmark fields, which are 30 km apart, are formed in shallow waters at depths of 20–40 m and are about 0.5–1 km from the shoreline. The oceanographic data suggest that two different mechanisms were responsible for their formation. The pockmark field in the Patras Gulf appears to have been formed as a result of methane seepage from the seabed, whereas the field in the Corinth Gulf appears to have resulted from groundwater seepage.     

南海礼乐盆地海底麻坑地貌及成因分析

本文基于高分辨率多波束测深和浅地层剖面数据,首次对南海礼乐盆地南部坳陷海底麻坑进行了系统的识别研究。共识别出各类麻坑81个,其中麻坑直径最大约2.4 km,坑深最大约157 m。麻坑种类多样:按平面形态主要分为圆形、椭圆形、拉长形和新月形麻坑;按组合方式分为孤立麻坑、链状麻坑和复合麻坑;按直径分为正常麻坑和大型麻坑。区域内发育多条大型海底峡谷,峡谷侵蚀引起两侧地层稳定性降低,气体储层遭受破坏,泄露的气体沿断层或气烟囱等喷发出海底形成麻坑。而因麻坑生成时剥蚀的沉积物质与周围水体混合并逐渐发展成浊流,在一定程度上促进海底峡谷向下延伸。研究区内单个麻坑的平面形态最初为圆形或椭圆形,之后由于重力流和峡谷侵蚀的影响,逐渐发展成拉长形或新月形,麻坑之间也会发生组合形成复合麻坑。链状麻坑与冲沟的形成联系密切,沿垂直于等深线方向展布的链状麻坑在重力流的冲刷下,发育成底部平坦的麻坑冲沟。对比分析全球其他海域麻坑,发现海底麻坑尺寸与水深关系密切,在深水区域更容易发育大型麻坑。     

A Compilation of Geophysical Data from the Lazarev Sea and the Riiser-Larsen Sea, Antarctica

On the basis of new geophysical data acquired by the Federal Institute of Geosciences and Natural Resources (BGR) and the Polar Marine Geological Research Expedition (PMGRE) as well as existing data new geophysical maps were compiled for the Lazarev Sea and the Riiser-Larsen Sea between 10°W and 25°E. The new results are: – The drastic change in the strike direction of the volcanic Explora Wedge between longitudes 10°W and 5°W is accompanied with a gradual change from one major wedge, i.e. the Explora Wedge, into at least two wedge-shaped volcanic constructions, each manifested by a sequence of seaward-dipping reflectors in the seismic records. – The southern Lazarev Sea is best described as a continental margin affected by multiple rifting episodes accompanied with transient volcanism. – A distinct N80°E striking basement depression separates the volcanic-prone continental margin of the southern Lazarev Sea from oceanic crust upon which the Maud Rise rests. The southern scarp of the narrow depression was presumably aligned with the eastern scarp of the Mozambique Ridge during the Early Cretaceous. – The Astrid Ridge proper occupies the transition from the volcanic-prone continental margin of the Lazarev Sea to old oceanic crust of the Riiser -Larsen Sea, and it rests upon a large volcanic apron which covers the basement of the southwestern Riiser-Larsen Sea. – No evidence was found that prolific volcanism has affected the early opening of the Riiser-Larsen Sea. – The Lazarev Sea is a sediment-starved region.     

The spatial pattern and drainage cell characteristics of a pockmark field,Nile Deep Sea Fan

Over 25,300 seabed pockmarks were mapped from the Rosetta Channel region of the Western Nile Deep Sea Fan (NDSF) using concurrent High Resolution 2D, Chirp profiler and multibeam bathymetry data which spans the Holocene–Pleistocene period. Within the region, a pockmark field containing >13,800 pockmarks was analysed using spatial statistics to determine the distribution of pockmarks within the field. Pockmarks within the field are small (∼16 m diameter), shallow (∼0.5 m deep) circular depressions which formed within the last ∼ 6500 years. The fluid source for the field is identified as an accumulation/generation of gas beneath a hemipelagic seal c. 20–40 ms beneath the seabed. The position of the pockmarks is shown to be unrelated to the depth to the fluid source and an irregular high amplitude acoustic anomaly which is tentatively interpreted as a possible carbonate precipitate of biogenic microbial activity. Statistical spatial analysis of the field confirms the distribution of pockmarks is not random. An exclusion zone surrounding each individual pockmark is identified. The exclusion zone is a unique minimum radius around each pockmark which is not penetrated by any other pockmark. The exclusion zone works in unison with Self-Organised Criticality (SOC) in determining the spatial distribution of pockmarks within the field. The exclusion zone is interpreted as a pockmark “drainage cell”. A conceptual model for a pockmark drainage cell is proposed whereby pockmark formation dissipates a radius/area of fluid and overpressure, thereby preventing the formation of another pockmark within that cell. Consequently, pockmarks are observed to separate or produce anti-clustering tendencies within the field.     

The hydroacoustic method for the quantification of the gas flux from a submersed bubble plume

This article presents an inverse hydroacoustic method for the remote quantification of the total gas flux transported from an underwater bubble plume. The method includes the surveying of the bubble plume by a vertically looking echo sounder and the calculation of the flux using the spatial distribution of the ultrasound backscattering at a fixed depth. A simplified parameterization containing only a few parameters is introduced to describe the empirical bubble size distribution. The linear correlation between the backscattering cross section of the bubble stream and the vertical gas flux is found. The calculation procedure takes into account the occurrence of a gas hydrate film at the bubble’s surface. The influence of different parameters on the accuracy of the method is investigated. The resolution volume of the echo sounder corresponding to the fixed distance is considered as a two-dimensional spatial window. The method was applied to quantify the total convective methane flux at the Haakon-Mosby mud volcano (HMMV) depth 1280 m. The calculated values of the total flux near the bottom (100–400 t/year) are in good agreement with the independently estimated flux for the single bubble jet observed from the ROV (70 t/year). These calculations also show significant temporal variability of the flux at the HMMV. The total flux was found to vary by about a factor of 2–3 within time scales of days.     

Gas seepage, pockmarks and mud volcanoes in the near shore of SW Taiwan

In order to understand gas hydrate related seafloor features in the near shore area off SW Taiwan, a deep-towed sidescan sonar and sub-bottom profiler survey was conducted in 2007. Three profiles of high-resolution sub-bottom profiler reveal the existence of five gas seeps (G96, GS1, GS2, GS3 and GS4) and one pockmark (PM) in the study area. Gas seeps and pockmark PM are shown in lines A and C, while no gas venting feature is observed along line B. This is the first time that a gas-hydrate related pockmark structure has been imaged off SW Taiwan. The relatively high backscatter intensity in our sidescan sonar images indicates the existence of authigenic carbonates or chemosynthetic communities on the seafloor. More than 2,000 seafloor photos obtained by a deep-towed camera (TowCam) system confirm the relatively high backscatter intensity of sidescan sonar images related to bacteria mats and authigenic carbonates formation at gas seep G96 and pockmark PM areas. Water column gas flares are observed in sidescan sonar images along lines A and C. Likewise, EK500 echo sounder images display the gas plumes above gas seep G96, pockmark PM and gas seep GS1; the gas plumes heights reach about 150, 100 and 20 m from seafloor, respectively. Based on multichannel seismic reflection (MCS) profiles, an anticline structure trending NNE-SSW is found beneath gas seep G96, pockmark PM and gas seep GS2. It implies that the gas venting features are related to the anticline structure. A thermal fluid may migrate from the anticline structure to the ridge crest, then rises up to the seafloor along faults or fissures. The seafloor characteristics indicate that the gas seep G96 area may be in a transitional stage from the first to second stage of a gas seep self-sealing process, while the pockmark PM area is from the second to final stage. In the pockmark PM area, gas venting is observed at eastern flank but not at the bottom while authigenic carbonates are present underneath the pockmark. It implies that the fluid migration pathways could have been clogged by carbonates at the bottom and the current pathway has shifted to the eastern flank of the pockmark during the gas seep self-sealing process.     

Structure of the phytoplankton communities and primary production in the Ob River estuary and over the adjacent Kara Sea shelf

The material was collected in the Ob River estuary and over the adjacent shallow Kara Sea shelf between 71°14′0 and 75°33′0N at the end of September 2007. Latitudinal zoning in the phytoplankton distribution was demonstrated; this zoning was determined by the changes in the salinity and concentration of nutrients. Characteristic of the phytocenosis in the southern desalinated zone composed of freshwater species of diatom and green algae were the high population density (1.5 × 10⁶ cells/l), biomass (210 μgC/l), chlorophyll concentration (4.5 μg/l), and uniform distribution in the water column. High primary production (∼40 μgC/l/day) was recorded in the upper 1.5-m layer. The estuarine frontal zone located to the north contained a halocline at a depth of 3–5 m. Freshwater species with low population density (2.5 × 10⁵ cells/l), biomass (24 μgC/l), and chlorophyll concentration (1.5 μg/l) dominated above the halocline. Marine diatom algae, dinoflagellates, and autotrophic flagellates formed a considerable part of the phytocenosis below the halocline; the community characteristics were twofold lower as compared with the upper layer. The maximal values of the primary production (∼10 μgC/l per day) were recorded in the upper 1.5-m layer. The phytocenosis in the seaward zone was formed by marine alga species and was considerably poorer as compared with the frontal zone. The assimilation numbers at the end of the vegetation season in the overall studied area were low, amounting to 0.4–1.0 μgC/μgChl/h in the upper layer and 0.03–0.1 μgC/μgChl/h under the pycnocline.