Eclogitic metamorphism in carbonate rocks: the example of impure marbles from the Sesia-Lanzo Zone,Italian Western Alps1

The impure marbles of the internal Sesia-Lanzo Zone underwent a multi-stage metamorphic evolution of Alpine age and retain early-Alpine eclogitic assemblages, partially recrystallized under blueschist to greenschist facies conditions. These high-P assemblages consist of carbonates, phengite, quartz, omphacite, grossular-rich (locally spessartinic) garnet, zoisite and Al-rich titanite. Retrogressive stages are characterized by the growth of glaucophane, paragonite, phlogopite, tremolite and albite. Halogen-rich biotite and amphibole are also present. P-T estimates of the early-Alpine metamophism have been calculated from these unique high-P assemblages, in order to test the applicability of some calibrations to impure carbonate systems. In particular, some Gt-Cpx calibrations and the phengite geobarometer give results (T= 575 ± 45° C at 15 kbar for the eclogitic climax and T≤ 500° C at PH₂O ≤ 9 kbar for early-Alpine retrogressive stages) which are within the range obtained from the surrounding lithologies. Phase relationships in P-T-XCO₂ space indicate that mineral assemblages in the impure marbles coexisted with H₂O-rich fluids (XCO₂ <0.03) during their entire Alpine evolution.     

Alpine metamorphism in the south-east Tauern Window, Austria: 1. P–T variations in space and time

Abstract The Pennine rocks exposed in the south-east Tauern Window, Austria, contain mineral assemblages which crystallized in the mid-Tertiary ‘late Alpine’regional metamorphism. The pressure and temperature conditions at the thermal peak of this event have been estimated for rocks at four different structural levels using a variety of published and thermochemically derived geobarometers and geothermometers. The results are: (a) In the garnet+chlorite zone, 2–5 km structurally above the staurolite+biotite isograd: T= 490.50°C, P= 7° 1 kbar; (b) Within 0.5 km of the staurolite+biotite isograd: T= 560±300C, P=7.1 kbar; (c) In the staurolite+biotite zone, c. 2.5 km structurally below the staurolite+biotite isograd: T= 610±30°C, P=7.6±1.2 kbar; (d) In the staurolite+biotite zone, 3–4 km structurally below the staurolite+biotite isograd: T= 630±40°C, P= 6.6±1.2 kbar. The pressure estimates imply that the total thickness of overburden above the basement-cover interface in the mid-Tertiary was c. 26.4 km. This overburden can only be accounted for by the Austro-Alpine units currently exposed in the vicinity of the Tauern Window, if the Altkristallin (the ‘Middle Austro-Alpine’nappe) was itself buried beneath an ‘Upper Austro-Alpine’nappe or nappe-pile which was 7.4 km thick at that time. The occurrence of epidote + margarite + quartz pseudomorphs after lawsonite in garnet, indicates that part of the Mesozoic Pennine cover sequence in the south-east Tauern experienced blueschist-facies conditions (T<450°C, P<12 kbar) in early Alpine times. Evidence from the central Tauern is used to argue that the blueschist-facies imprint post-dated the main phase of tectonic thickening (D¹_A) and was thus a direct consequence of continental collision. Combined oxygen-isotope and fluid-inclusion studies on late-stage veins, thought to have been at lithostatic pressure and in thermal equilibrium with their host rocks during formation, suggest that they crystallized from aqueous fluids at 1.1±0.4 kbar and 420.20°C. Early Alpine, late Alpine and vein-formation P–T constraints have been used to construct a P–T path for the base of the Mesozoic cover sequence in the south-east Tauern Window. The prograde part of the P–T path, between early and late Alpine metamorphic imprints, is unlikely to have been a smooth curve and may well have had a low dP/dT overall; the decompression (presumably due to erosion) which occurred immediately before the thermal peak and possibly also earlier in the Tertiary, was probably partly or completely cancelled by the effects of early- to mid-Tertiary (D²_A) tectonic thickening. The thermal peak of metamorphism was followed by a phase of almost isothermal decompression, which implies a period of rapid uplift in the middle Tertiary. The peak metamorphic P–T estimates are compared with the solutions of England's (1978) one-dimensional conductive thermal model of the Eastern Alps, and are shown to be consistent with the idea that the late Alpine metamorphism was caused by tectonic burial of the Pennine Zone beneath the Austro-Alpine nappes in the absence of extraneous heat sources, such as large intrusions, at depth.     

Coupling of oceanic and continental crust during Eocene eclogite-facies metamorphism: evidence from the Monte Rosa nappe,western Alps

High precision U–Pb geochronology of rutile from quartz–carbonate–white mica–rutile veins that are hosted within eclogite and schist of the Monte Rosa nappe, western Alps, Italy, indicate that the Monte Rosa nappe was at eclogite-facies metamorphic conditions at 42.6 ± 0.6 Ma. The sample area [Indren glacier, Furgg zone; Dal Piaz (2001) Geology of the Monte Rosa massif: historical review and personal comments. SMPM] consists of eclogite boudins that are exposed inside a south-plunging overturned synform within micaceous schist. Associated with the eclogite and schist are quartz–carbonate–white mica–rutile veins that formed in tension cracks in the eclogite and along the contact between eclogite and surrounding schist. Intrusion of the veins at about 42.6 Ma occurred at eclogite-facies metamorphic conditions (480–570°C, >1.3–1.4 GPa) based on textural relations, oxygen isotope thermometry, and geothermobarometry. The timing of eclogite-facies metamorphism in the Monte Rosa nappe determined in this study is identical to that of the Gran Paradiso nappe [Meffan-Main et al. (2004) J Metamorphic Geol 22:261–281], confirming that these two units have shared the same Alpine metamorphic history. Furthermore, the Gran Paradiso and Monte Rosa nappes underwent eclogite-facies metamorphism within the same time interval as the structurally overlying Zermatt-Saas ophiolite [∼50–40 Ma; e.g., Amato et al. (1999) Earth Planet Sci Lett 171:425–438; Mayer et al. (1999) Eur Union Geosci 10:809 (abstract); Lapen et al. (2003) Earth Planet Sci Lett 215:57–72]. The nearly identical P–T–t histories of the Gran Paradiso, Monte Rosa, and Zermatt-Saas units suggest that these units shared a common Alpine tectonic and metamorphic history. The close spatial and temporal associations between high pressure (HP) ophiolite and continental crust during Alpine orogeny indicates that the HP internal basement nappes in the western Alps may have played a key role in exhumation and preservation of the ophiolitic rocks through buoyancy-driven uplift. Coupling of oceanic and continental crust may therefore be critical in preventing permanent loss of oceanic crust to the mantle.     

Franciscan eclogite revisited: Reevaluation of the P–T evolution of tectonic blocks from Tiburon Peninsula, California, U.S.A.

Summary High-grade blocks in the Franciscan complex at Tiburon, California, record relatively low temperature eclogite-facies metamorphism and blueschist-facies overprinting. The eclogite-facies mineral assemblage contains prograde-zoned garnet + omphacite + epidote ± hornblende (katophoritic and barroisitic Ca–Na amphibole) ± glaucophane + phengite (∼3.5 Si p.f.u.) ± paragonite + rutile + quartz. The blueschist-facies mineral assemblage contains chlorite + titanite + glaucophane + epidote ± albite ± phengite (∼3.3 Si p.f.u.). Albite is not stable in the eclogite stage. New calculations based on garnet-omphacite-phengite thermobarometry and THERMOCALC average-P–T calculations yield peak eclogite-facies P–T conditions of P = 2.2–2.5 GPa and T = 550–620 °C; porphyroclastic omphacite with inclusions of garnet and paragonite yields an average-P–T of 1.8 ± 0.2 GPa at 490 ± 70 °C for the pre-peak stage. The inferred counterclockwise hairpin P–T trajectory suggests prograde eclogitization of a relatively “cold” subducting slab, and subsequent exhumation and blueschist-facies recrystallization by a decreasing geotherm. Although an epidote-garnet amphibolitic assemblage is ubiquitous in some blocks, P–T pseudosection analyses imply that the epidote-garnet amphibolitic assemblage is stable during prograde eclogite-facies metamorphism. Available geochronologic data combined with our new insight for the maximum pressure suggest an average exhumation rate of ∼5 km/Ma, as rapid as those of some ultrahigh pressure metamorphic terranes.     

全球典型大陆造山带中榴辉岩的折返机制:来自变质岩和地球物理的限制

大陆岩石圈深俯冲作用是地球科学领域的前沿热点,榴辉岩的折返机制是板块构造及动力学的关键科学问题。全球著名的大陆造山带中榴辉岩的p-T轨迹呈现差异性折返特征,为了揭示榴辉岩的折返机制,本文结合变质岩石学和地球物理学研究,选取3个典型大陆造山带——中生代—新生代的阿尔卑斯造山带、中生代的苏鲁—大别造山带和新生代的喜马拉雅造山带中的榴辉岩进行阐述。在阿尔卑斯造山带地区,地球物理研究结果发现,欧洲板块的俯冲造成了Adria地区下方的岩石圈存在明显厚度差异。同时,阿尔卑斯造山带Doria Maria和Pohorje地区以及Pohorje地区内部,榴辉岩折返历史也不尽相同,原因可能是亚德里亚大洋岩石圈断离后不同期次的逆冲推覆作用使其差异性斜向挤出。苏鲁—大别造山带中榴辉岩的快速折返,原因可能是华南板块与华北板块碰撞后岩石圈的拆沉或断离作用。在喜马拉雅造山带,西构造结和中喜马拉雅榴辉岩的折返存在差异性。在西构造结,那让和卡甘榴辉岩呈现不同的p-T轨迹和折返速率,变质岩石学和地球物理研究结果都表明它们的差异性折返很可能与印度-欧亚大陆碰撞过程中的构造挤压作用以及印度大陆岩石圈的断离作用有关。喜马拉雅造山带是年轻的正在进行造山活动的造山带,相较于古老的苏鲁-大别造山带,它更适合变质岩石学和地球物理学的综合研究。因此西构造结高压/超高压榴辉岩的折返机制——构造挤压和俯冲板块断离可应用于全球造山带。     

Integration of natural data within a numerical model of ablative subduction: a possible interpretation for the Alpine dynamics of the Austroalpine crust

A numerical modelling approach is used to validate the physical and geological reliability of the ablative subduction mechanism during Alpine convergence in order to interpret the tectonic and metamorphic evolution of an inner portion of the Alpine belt: the Austroalpine Domain. The model predictions and the natural data for the Austroalpine of the Western Alps agree very well in terms of P–T peak conditions, relative chronology of peak and exhumation events, P–T–t paths, thermal gradients and the tectonic evolution of the continental rocks. These findings suggest that a pre‐collisional evolution of this domain, with the burial of the continental rocks (induced by ablative subduction of the overriding Adria plate) and their exhumation (driven by an upwelling flow generated in a hydrated mantle wedge) could be a valid mechanism that reproduces the actual tectono‐metamorphic configuration of this part of the Alps. There is less agreement between the model predictions and the natural data for the Austroalpine of the Central‐Eastern Alps. Based on the natural data available in the literature, a critical discussion of the other proposed mechanisms is presented, and additional geological factors that should be considered within the numerical model are suggested to improve the fitting to the numerical results; these factors include variations in the continental and/or oceanic thickness, variation of the subduction rate and/or slab dip, the initial thermal state of the passive margin, the occurrence of continental collision and an oblique convergence.     

High-P (P = 1.5–1.8 GPa) blueschist from Elba: Implications for underthrusting and exhumation of continental units in the Northern Apennines

The Acquadolce Subunit on the Island of Elba, Italy, records blueschist facies metamorphism related to the Oligocene–early Miocene stages of continental collision in the Northern Apennines. The blueschist facies metamorphism is represented by glaucophane- and lawsonite-bearing metabasite associated with marble and calcschist. These rock types occur as lenses in a schistose complex representing foredeep deposits of early Oligocene age. Detailed petrological analyses on metabasic and metapelitic protoliths, involving mineral and bulk-rock chemistry coupled with P–T and P–T–X(Fe₂O₃) pseudosection modelling using PERPLE_X, show that the Acquadolce Subunit recorded nearly isothermal exhumation from peak pressure–temperature conditions of 1.5–1.8 GPa and 320–370°C. During exhumation, peak lawsonite- and possibly carpholite- or stilpnomelane-bearing assemblages were overprinted and partially obliterated by epidote-blueschist and, subsequently, albite-greenschist facies metamorphic assemblages. This study sheds new light on the tectonic evolution of Adria-derived metamorphic units in the Northern Apennines, by showing (a) the deep underthrusting of continental crust during continental collision and (b) rapid exhumation along ‘cold’ and nearly isothermal paths, compatible with syn-orogenic extrusion.     

The Meso-Neoarchaean Belomorian eclogite province: Tectonic position and geodynamic evolution

The aim of this paper is to review the main features of the Meso-Neoarchaean Belomorian eclogite province (BEP) in the northeastern Fennoscandian Shield, including regional and local geology, geochemistry, petrology and geochronology and to compare the Belomorian eclogites with Precambrian eclogites elsewhere. Two eclogite associations have been recognized within Belomorian TTG gneisses: (1) the subduction-type Salma association and (2) Gridino eclogitized mafic dykes. Protoliths of the Salma eclogites represent a sequence comprising gabbro, Fe–Ti gabbro and troctolites, formed at ~ 2.9 Ga in a slow-spreading ridge setting (like the Southwest Indian Ridge). The main subduction and eclogite-facies events occurred between ~ 2.87 and ~ 2.82 Ga. Injection of mafic magma into an active continental margin setting, recorded by the Gridino dyke swarm, is attributed to subduction of a mid-ocean ridge, commencing at 2.87 Ga. Crustal delamination of the active margin and subsequent involvement of the lower crust in subduction between 2.87 and 2.82 Ga ago caused high-pressure metamorphism of the Gridino dykes, culminating in eclogite-facies conditions between 2.82 and 2.78 Ga and accompanying amalgamation of the Karelia, Kola and Khetolamba blocks and formation of the Mesoarchaean Belomorian accretionary–collisional orogen. The clockwise P–T paths of the Salma and Gridino associations cross the granulite-facies P–T field. Detailed metamorphic studies indicate a complicated post-eclogite history with thermal events and fluid infiltration, related to plume activity at 2.72–2.70, ~ 2.4 and ~ 1.9 Ga. The eclogite assemblages were exhumed to mid-to-lower crustal depths at ~ 1.7 Ga, while erosion or younger tectonic events were responsible for final exhumation to the surface. Comparison of P–T–t paths and data for peak metamorphic parameters demonstrates the general similarity of the Archaean and Palaeoproterozoic eclogites worldwide and their association with anomalously “hot” environments. The occurrence of high-T conditions during eclogite-facies metamorphism can be attributed to either subduction of a mid-ocean ridge (Archaean, BEP) or to interaction with mantle plumes (Proterozoic).     

A counter-clockwise P–T path for the Voltri Massif eclogites (Ligurian Alps, Italy)

Integrated petrological and structural investigations of eclogites from the eclogite zone of the Voltri Massif (Ligurian Alps) have been used to reconstruct a complete Alpine P–T deformation path from burial by subduction to subsequent exhumation. The early metamorphic evolution of the eclogites has been unravelled by correlating garnet zonation trends with the chemical variations in inclusions found in the different garnet domains. Garnet in massive eclogites displays typical growth zoning, whereas garnet in foliated eclogites shows rim‐ward resorption, likely related to re‐equilibration during retrogressive evolution. Garnet inclusions are distinctly different from core to rim, consisting primarily of Ca‐, Na/Ca‐amphibole, epidote, paragonite and talc in garnet cores and of clinopyroxene ± talc in the outer garnet domains. Quantitative thermobarometry on the inclusion assemblages in the garnet cores defines an initial greenschist‐to‐amphibolite facies metamorphic stage (M1 stage) at c. 450–500 °C and 5–8 kbar. Coexistence of omphacite + talc + katophorite inclusion assemblage in the outer garnet domains indicate c. 550 °C and 20 kbar, conditions which were considered as minimum P–T estimates for the M2 eclogitic stage. The early phase of retrograde reactions is polyphase and equilibrated under epidote–blueschist facies (M3 stage), characterized by the development of composite reaction textures (garnet necklaces and fluid‐assisted Na‐amphibole‐bearing symplectites) produced at the expense of the primary M2 garnet‐clinopyroxene assemblage. The blueschist retrogression is contemporaneous with the development of a penetrative deformation (D3) that resulted in a non‐coaxial fabric, with dominant top‐to‐the‐N sense of shear during rock exhumation. All of that is overprinted by a texturally late amphibolite/greenschist facies assemblages (M4 & M5 stages), which are not associated with a penetrative structural fabric. The combined P–T deformation data are consistent with an overall counter‐clockwise path, from the greenschist/amphibolite, through the eclogite, the blueschist to the greenschist facies. These new results provide insights into the dynamic evolution of the Tertiary oceanic subduction processes leading to the building up of the Alpine orogen and the mechanisms involved in the exhumation of its high‐pressure roots.     

Granulites and related rocks in variscan median Europe: A dualistic interpretation

On the basis of differences in structural, petrological and radiometric features, two main clear-cut groups can be distinguished for the granulites of the Variscan median Europe.Group I comprises lenses of eclogite-granulite scattered in the internal zones of the Hercynian belt, whereas Group II includes granulitic slices related to deep-seated Alpine lineaments and xenoliths scavenged by recent volcanoes.Group I granulites belong to early thrust nappes of the Variscan orogen; they display high-pressure assemblages and are commonly associated with eclogites and garnet-peridotites. From radiometric data, this HP granulitic-eclogitic metamorphism happened around 450-400 Ma throughout median Europe. A subduction context is suggested by the low T/P gradient, the occurrence of eclogites and the contemporaneity with some blueschist-facies rocks.Group II granulites are characterized by massive occurrences, intermediate-pressure granulite-facies parageneses and the absence of eclogites. Granulitic paragneisses often display a pronounced depletion in granitophile elements and may appear as degranitized restites. Numerous basic-ultrabasic complexes occur and are interpreted as deep-seated, layered igneous intrusions emplaced during the granulitic metamorphism. Radiometric dating indicates a late Hercynian (ca. 300 Ma) age. The high T/P gradient, the occurrence of synchronous basic intrusions and the post-collision context suggest a granulitic event due to a major thermal anomaly.The Variscan cycle is thus characterized by two granulite-forming episodes. “Older granulites” of the HP type result from an early compressive stage in a crustal subduction context and “younger granulites”, from a major thermal event which originated in the upper mantle and annealed the deepest parts of the Variscan belt. A broadly similar duality in the genesis of granulitic rocks may be anticipated in other collisional belts.     

High-pressure eclogites in northern Jiangsu – southern Shandong province, eastern China

Abstract Eclogites are distributed for more than 500 km along a major tectonic boundary between the Sino-Korean and Yangtze cratons in central and eastern China. These eclogites usually have high-P assemblages including omphacite + kyanite and/or coesite (or its pseudomorph), and form a high-P eclogite terrane. They occur as isolated lenses or blocks 10 cm to 300 m long in gneisses (Type I), serpentinized garnet peridotites (Type II) and marbles (Type III). Type I eclogites were formed by prograde metamorphism, and their primary metamorphic mineral assemblage consists mainly of garnet [pyrope (Prp) = 15–40 mol%], omphacite [jadeite (Jd) = 34–64 mol%], pargasitic amphibole, kyanite, phengitic muscovite, zoisite, an SiO₂ phase, apatite, rutile and zircon. Type II eclogites characteristically contain no SiO₂ phase, and are divided into prograde eclogites and mantle-derived eclogites. The prograde eclogites of Type II are petrographically similar to Type I eclogites. The mantle-derived eclogites have high MgO/(FeO + Fe₂O₃) and Cr₂O₃ compositions in bulk rock and minerals, and consist mainly of pyrope-rich garnet (Prp = 48–60 mol%), sodic augite (Jd = 10–27 mol%) and rutile. Type III eclogites have an unusual mineral assemblage of grossular-rich (Grs = 57 mol%) garnet + omphacite (Jd = 30–34 mol%) + pargasite + rutile. Pargasitic and taramitic amphiboles, calcic plagioclase (An₆₈), epidote, zoisite, K-feldspar and paragonite occur as inclusions in garnet and omphacite in the prograde eclogites. This suggests that the prograde eclogites were formed by recrystallization of epidote amphibolite and/or amphibolite facies rocks with near-isothermal compression reflecting crustal thickening during continent–continent collision of late Proterozoic age. Equilibrium conditions of the prograde eclogites range from P > 26 kbar and T= 500–750°C in the western part to P > 28 kbar and T= 810–880°C in the eastern part of the high-P eclogite terrane. The prograde eclogites in the eastern part are considered to have been derived from a deeper position than those in the western part. Subsequent reactions, manifested by (1) narrow rims of sodic plagioclase or paragonite on kyanite and (2) symplectites between omphacite and quartz are interpreted as an effect of near-isothermal decompression during the retrograde stage. The conditions at which symplectites re-equilibrated tend to increase from west (P < 10 kbar and T < 580°C) to east (P > 9 kbar and T > 680°C). Equilibrium temperatures of Type II mantle-derived eclogites and Type III eclogite are 730–750°C and 680°C, respectively.     

Modelling phase–assemblage diagrams for magnesian metapelites in the system K2O–FeO–MgO–Al2O3–SiO2–H2O: geodynamic consequences for the Monte Rosa nappe, Western Alps

Magnesian metamorphic rocks with metapelitic mineral assemblage and composition are of great interest in metamorphic petrology for their ability to constrain P–T conditions in terranes where metamorphism is not easily visible. Phase–assemblage diagrams for natural and model magnesian metapelites in the system KFMASH are presented to document how phase relationships respond to water activity, bulk composition, pressure and temperature. The phase assemblages displayed on these phase diagrams are consistent with natural mineral assemblages occurring in magnesian metapelites. It is shown that the equilibrium assemblages at high pressure conditions are very sensitive to a(H₂O). Specifically, the appearance of the characteristic HP assemblage chloritoid–talc–phengite–quartz (with excess H₂O) in the magnesian metapelites of the Monte Rosa nappe (Western Alps) is due to the reduction of a(H₂O). Furthermore, the mineral assemblages are determined by the whole-rock FeO/(FeO+MgO) ratio and effective Al content X _A as well as P and T. The predicted mineral associations for the low- and high-X _A model bulk compositions of magnesian metapelites at high pressure are not dependent on the X _A variations as they show a similar sequence of mineral assemblages. Above 20 kbar, the prograde sequence of assemblages associated with phengite (with excess SiO₂ and H₂O) for low- and high-X _A bulk compositions of magnesian metapelites is: carpholite–chlorite → chlorite–chloritoid → chloritoid–talc → chloritoid–talc–kyanite → talc–garnet–kyanite → garnet–kyanite ± biotite. At low to medium P–T conditions, a low-X _A stabilises the phengite-bearing assemblages associated with chlorite, chlorite + K-feldspar and chlorite + biotite while a high-X _A results in the chlorite–phengite bearing assemblages associated with pyrophyllite, andalusite, kyanite and carpholite. A high-X _A magnesian metapelite with nearly iron-free content stabilises the talc–kyanite–phengite assemblage at moderate to high P–T conditions. Taking into account the effective bulk composition and a(H₂O) involved in the metamorphic history, the phase–assemblage diagrams presented here may be applied to all magnesian metapelites that have compositions within the system KFMASH and therefore may contribute to gaining insights into the metamorphic evolution of terranes. As an example, the magnesian metapelites of the Monte Rosa nappe have been investigated, and an exhumation path with P–T conditions for the western roof of the Monte Rosa nappe has been derived for the first time. The exhumation shows first a near-isothermal decompression from the Alpine eclogite peak conditions around 24 kbar and 505°C down to approximately 8 kbar and 475°C followed by a second decompression with concomitant cooling.M. Frey: deceased     

High-pressure metamorphism in Antarctica from the Proterozoic to the Cenozoic: A review and geodynamic implications

The survey of high-P metamorphic rocks in Antarctica can help clarify the geodynamic evolution of the continent by pointing out palaeo-suture zones and constraining the age of subduction and collision events. There are eclogite-facies rocks along the eastern margin of the ‘Mawson block’ (e.g., in the Nimrod Glacier region and George V Land). Some of these have been long forgotten (George V Land; Eyre Peninsula in Australia). Stillwell (1918) described rocks from George V Land containing glaucophane, lawsonite, garnet coronas and symplectites possibly after omphacite. These high-P rocks were apparently involved in the Nimrod-Kimban orogenic cycle and therefore provide a record of convergence along the eastern margin of the Mawson block at ~ 1700 Ma; they could represent one of the oldest blueschist-facies imprint. Many terranes in East Antarctica underwent a tectonometamorphic evolution during the Grenvillian (1300–900 Ma) and/or the Pan-African (600–500 Ma) orogenies, corresponding to the amalgamation of Rodinia and Gondwana, respectively. High-P relicts have been described or are suspected to occur in these terranes. Garnet-bearing coronitic metagabbros, in some cases possibly containing omphacite, are common in Dronning Maud Land and the Rayner Complex. They formed under high-P granulite-facies or eclogite-facies conditions and recall similar metabasites from the Grenville mobile belt of Canada. Note that some reconstructions of the Rodinia supercontinent consider these two Antarctic regions as an extension of the Grenvillian belt of Canada. Other eclogite-facies metamorphic rocks and ophiolites (Shackleton Range and possibly Sverdrupfjella) belong to the Pan-African mobile belt extending from Tanzania to East Antarctica. Since the Cambrian, the terranes of West Antarctica have been accreted along the palaeo-Pacific margin of Gondwana/Antarctica during several subduction-accretion orogenies. The ultrahigh-P metamorphic rocks of Northern Victoria Land formed through the accretion of an arc-backarc system during the Cambrian-Ordovician Ross orogeny; eclogites of the same orogeny also exist in Tasmania and Australia. Lastly, on the western edge of the Antarctic Peninsula, the Mesozoic–Cenozoic Andean orogeny generated a subduction-accretionary complex containing blueschist-facies rocks.     

Structural evolution of the contact between two Penninic nappes (Zermatt-Saas zone and Combin zone,Western Alps) and implications for the exhumation mechanism and palaeogeography

The boundary zone between two Penninic nappes, the eclogite-facies to ultrahigh-pressure Zermatt-Saas zone in the footwall and the blueschist-facies Combin zone in the hanging wall, has been interpreted previously as a major normal fault reflecting synorogenic crustal extension. Quartz textures of mylonites from this fault were measured using neutron diffraction. Together with structural field observations, the data allow a refined reconstruction of the kinematic evolution of the Pennine nappes. The main results are: (1) the contact is not a normal fault but a major thrust towards northwest which was only later overprinted by southeast-directed normal faulting; (2) exhumation of the footwall rocks did not occur during crustal extension but during crustal shortening; (3) the Sesia-Dent Blanche nappe system originated from a continental fragment (Cervinia) in the Alpine Tethys ocean, and the Combin zone ophiolites from the ocean basin southeast of Cervinia; (4) out-of-sequence thrusting played a major role in the tectonic evolution of the Penninic nappes. An erratum to this article can be found at     

Sm-Nd Isotope Tracer Study of UHP Metamorphic Rocks: Implications for Continental Subduction and Collisional Tectonics

Sm-Nd isotope tracer techniques are powerful tools in identification of the protolith nature of UHP and HP rocks and can be used to constrain modeling of tectonic processes of continental collision. UHP rocks may have diverse origins, and not all of them carry the same significance for subduction of continental blocks. In this paper, Sm-Nd isotopic data are compiled for UHP and HP rocks, mostly represented by eclogites and garnet peridotites, from the Alpine, Hercynian (Variscan), and Caledonian belts of western Europe; the Pan-African belts of northern Africa; and the Ross belt of Antarctica. These data then are compared with the isotopic characteristics of the UHP rocks from the Dabie orogen of central China. Except for the coesite-bearing quartzitic metasediments of Dora-Maira (Western Alps), which are clearly of continental origin, all HP and UHP rocks (eclogites and ultramafic rocks) from the Alpine, Hercynian, and Pan-African belts have oceanic affinities with the characteristic positive ε_Nd(T) values (= metamorphic initial ¹⁴³Nd/¹⁴⁴Nd ratios). They represent segments of oceanic lithosphere that were subducted, underwent eclogite-facies metamorphism, and later were tectonically transported into orogenic zones during continental collisions. By contrast, the majority of UHP rocks from the European Caledonide and the Dabie orogen have negative ε_ND(T) values, indicating continental affinity. This suggests that these mafic and ultramafic rocks have had a long crustal residence time and that their UHP metamorphism is indicative of subduction of ancient and cold continental blocks, as represented by some Precambrian gneiss terranes containing mafic components including greenschists, amphibolites, or basic granulites.

In the Dabie orogen, none of the UHP eclogites analyzed thus far have shown oceanic affinity; thus they do not represent subducted Tethys Ocean crust. The preservation of ultrahigh ε_ND(0) values (+170 to +260) in eclogites of very low Nd concentrations (average 0.5 ppm) from the Weihai region and of the extraordinarily low δ¹⁸O in many eclogites and gneisses, the general absence of syntectonic granites in the Dabie Shan, and the available age data obtained by different techniques all point to a rapid rate of exhumation and the absence of a pervasive aqueous fluid phase during the entire process of subduction and exhumation of the Dabie UHP terrane.     

The metamorphic history of rocks buried,accreted and exhumed in an accretionary prism: an example from the Otago Schist,New Zealand

Although subgreenschist facies metamorphic rocks are widespread in the upper crust, mineralogical processes affecting these rocks are poorly understood. Subgreenschist mineralogical transitions have been invoked as critical controls on the mechanical behaviour of rocks within the crustal seismogenic zone, calling for further study of very low‐grade metamorphic assemblages. In this study a multi‐technique thermobarometric study of the Chrystalls Beach Complex mélange, which is located within the Otago Schist accretion‐collision assemblage of the South Island of New Zealand, is presented. The Chrystalls Beach Complex comprises highly sheared trench‐fill sedimentary rocks and scattered pillow basalts, and is inferred to have formed during Jurassic subduction under the paleo‐Pacific Gondwana margin. Equilibrium mineral assemblages indicate peak P–T conditions in the range 400–550 MPa and 250–300 °C, which is supported by chlorite thermometry. Relatively high pressures of burial and accretion during foliation development are inferred from phengite content and b₀ spacing analyses of white mica. Rare lawsonite occurs in a post‐foliation vein, and illite ‘crystallinity’ measurements indicate a thermal overprint during exhumation. These P–T estimates and their relative chronology indicate that the mineral assemblages developed along a clockwise P–T path. Based on variability in P–T estimates from different techniques, mineral assemblages developed during burial are largely overprinted during exhumation at similar or higher‐T than experienced along the prograde path. Observed subduction‐related subgreenschist assemblages are therefore likely to indicate lower‐P than experienced during subduction, as higher‐P mineral compositions re‐equilibrate during exhumation. The P–T path inferred in this study is similar in shape to P–T paths for higher grade parts of the Otago Schist, and other exhumed accretionary prisms around the world, and is therefore probably common for rocks buried, accreted and exhumed in accretionary prisms.     

Interaction of deformation and metamorphism during subduction and exhumation of hydrated oceanic mantle: Insights from the Western Alps

Petrological investigations supported by multi‐scale structural analysis of eclogitized serpentinite in the Zermatt–Saas Zone of the Western Alps allows for the determination of mineral assemblages related to successive fabrics, upon which the P–T–d–t path of these hydrated mantle rocks can be inferred. Serpentinites of the upper Valtournanche, with lenses and dykes of metagabbro and meta‐rodingite, display an Alpine polyphase metamorphic evolution from eclogite to epidote‐amphibolite facies conditions associated with three successive foliations having different parageneses in these rocks. Serpentinite mainly consists of serpentine with minor magnetite; however, where S1 and S2 foliations are pervasive, metamorphic olivine, together with Ti‐clinohumite and clinopyroxene, are also found. The mineral assemblage associated with D1 includes serpentine1, clinopyroxene1, opaque minerals, titanite ± olivine1, Ti‐clinohumite1 and ilmenite; the D2 assemblage is the same (±chlorite) but minerals have different compositions. The assemblage associated with D3 comprises serpentine3, opaque minerals, ±chlorite3, ilmenite and amphibole3. Ti‐clinohumite is associated with veins that are older than D2 and pre‐date D3. Veins that post‐date D3 are characterized by amphibole + chlorite or by serpentine. P–T conditions for S2 parageneses evaluated using two pseudosections for different bulk compositions suggest that these rocks experienced pressures >2.5 ± 0.3 GPa at temperatures slightly higher than 600 °C. The late epidote–amphibolite facies re‐equilibration associated with D3 and D4 developed during late syn‐exhumation deformation related to folding and testifies to a small temperature decrease. These results, which were integrated in the regional framework, suggest that different portions of the Zermatt–Saas Zone registered different P–T peak conditions and underwent different exhumation paths. In addition, the inferred P–T–d–t path suggests that the Valtournanche serpentinites re‐equilibrated close to the UHP conditions registered by the Cignana meta‐cherts. These results imply that tectonic slices exhumed after UHP metamorphism might be wider than previously reported or that small‐size UHP units, tectonically sampled during the Alpine convergence, are more abundant than those that have been detected to date.     

High pressure metamorphism in the nappes of the Valle dell'Orco traverse (Western Alps collisional belt) *

Abstract A detailed field and petrological study of rocks from nappes cut by the Valle dell'Orco (Italian Western Alps), in particular the Sesia–Lanzo composite unit, has revealed geological and metamorphic histories which started in pre-alpine times and lasted up to the alpine subduction-collisional processes. During these processes the nappes sustained an early high P–low T stage and a later low P greenschist facies stage, but followed partly distinctive P–T–time trajectories. This paper discusses the kinematic evolution and the thermal history of the alpine belt from the early subduction/underthrust to the later exhumation stage. The metamorphic crystallization is often governed by incomplete and/or local equilibrium, and the pervasive syn-metamorphic deformation and the composition of the syn-metamorphic fluid phase (if present) have exerted an effective local control on reaction kinetics.     

Post-collision magmatism and tectonics in northwest Anatolia

A suite of biotite-hornblende granodiorite intrusions has been emplaced into blueschist-facies metasediments in northwest Anatolia, following collision between two continental margins, now represented by the Tavanli and Sakarya zones. The ⁴⁰Ar/³⁹Ar ages of phengites and glaucophanes from the blueschists, metamorphosed under unusually high P-low T conditions (P=20±2 kbar, T=430±30° C), suggest that metamorphism apparently occurred over a period spanning at least 20 Ma from 108 to 88 Ma. Post-tectonic granodiorites were emplaced during the Eocene (53 to 48 Ma) resulting in a cordierite and andalusite-bearing thermal aureole, indicative of pressures of 3 kbar. Trace-element systematics of the granodiorites are consistent with a derivation either from mantle-derived magmas by fractional crystallisation in shallow magma chambers, or from anatexis of crustal lithologies of internediate composition at pressures <10 kbar. The preservation of high P-low T assemblages in the blueschists together with the range of ages determined for blueschist-facies metamorphism are indicative of rapid exhumation of delaminated fragments from a subducted continental margin. However decompression melting of the crust is unlikely to have been a significant cause of magmatism, both because exhumation of the blueschists from deep crustal levels predated magmatism by at least 25 Ma, and because of the small melt fraction (<0.1) that may be generated in crustal lithologies by this process. Melting in the mantle wedge is required either to generate a primary melt for the derivation of magmas of intermediate composition or to provide an advective heat source for crustal melting. The cause of melt formation in the upper mantle may be related to the termination of subduction following collision during the Mid-Eocene.     

Phase equilibria modelling of blueschist and eclogite from the Sanbagawa metamorphic belt of southwest Japan reveals along‐strike consistency in tectonothermal architecture

The Sanbagawa metamorphic belt of southwest Japan is one of the type localities of subduction‐related high‐P metamorphism. However, variable pressure–temperature (P–T) paths and metabasic assemblages have been reported for eclogite units in the region, leading to uncertainty about the subduction zone paleo‐thermal structure and associated tectonometamorphic conditions. To analyse this variation, phase equilibria modelling was applied to the three main high‐P metabasic rock types documented in the region – glaucophane eclogite, barroisite eclogite and garnet blueschist – with modelling performed over a range of P, T, bulk rock H₂O and bulk rock ferric iron conditions using thermocalc . All samples are calculated to share a common steep prograde P–T path to similar peak conditions of ～16–20 kbar and 560–610 °C. The results establish that regional assemblage variation is systematic, with the alternation in peak amphibole phase due to peak conditions overlapping the glaucophane–barroisite solvus, and bulk composition effects stabilizing blueschist v. eclogite facies assemblages at similar P–T conditions. Furthermore, the results reveal that a steep prograde P–T path is common to all eclogite units in the Sanbagawa belt, indicating that metamorphic conditions were consistent along strike. All localities are compatible with predictions made by a ridge approach model, which attributes eclogite facies metamorphism and exhumation of the Sanbagawa belt to the approach of a spreading ridge.