Dislocations and voids in pyroxene from a low-temperature eclogite: Mechanism of eclogite formation

New occurrences of the phosphates sarcopside/graftonite (Fe, Mn)₃(PO₄)₂, farringtonite (Mg, Fe)₃(PO₄)₂, and brianite Na₂CaMg(PO₄)₂ in iron meteorites are reported. The sarcopside in Duel Hill (1854) (IVA-Anom) contains less than 0.1 mole % Mn₃(PO₄)₂ and more nearly approaches the Fe-rich end member than does any previously reported natural occurrence. This identification of farringtonite in Barranca Bianca (IIE) is the first report of this mineral in a meteorite group other than the pallasites.     

A re-evaluation of eclogite facies metamorphism in SW Japan: proposal for an eclogite nappe

Known eclogite occurrences in the Sanbagawa metamorphic belt of SW Japan are dominantly in metagabbro bodies which have complex polyphase metamorphic histories. These bodies are generally described as tectonic blocks and their relationship to the Sanbagawa metamorphism is unclear. New findings of foliated eclogite in the Seba and Kotsu areas show that eclogite facies metamorphism is much more widespread than generally thought. Evidence that the foliated eclogite units originated as lavas or sediments implies that these units can be treated as a high-grade part of the subduction-related Sanbagawa metamorphism. Although separated by an along-strike distance of 80 km, the Seba and Kotsu eclogites have very similar garnet and omphacite compositions, suggesting that they were formed under similar metamorphic conditions. However, differences in the associated retrograde assemblages (epidote–amphibolite in the Seba unit and epidote–blueschist in the Kotsu unit) suggest contrasting P – T  paths. In both units, the eclogite rocks occupy the highest structural level of the Sanbagawa belt and overlie rocks metamorphosed at lower pressure. The lower boundary to the eclogite units is therefore a major tectonic discontinuity locally decorated with lenses of exotic material. These features can help trace the boundary into other areas. The previously known outcrops of eclogite show enough similarities with the newly found areas to suggest that all the eclogite facies rocks in the Sanbagawa belt constitute a single nappe that lies at the highest structural levels of the orogen.     

榴辉岩部分熔融过程中的同位素分馏

本文对榴辉岩部分熔融过程中不同同位素体系是否存在分馏这一当前研究热点进行了综述.榴辉岩作为研究洋陆俯冲、超高压变质以及壳幔相互作用的主要岩石类型,其部分熔融与地壳增生、板片折返过程以及俯冲隧道中元素的迁移分配等具有紧密的联系.作为典型的高压-超高压变质岩石,榴辉岩可通过俯冲带将壳源信息携带至地幔深部,影响地慢的化学组成...     

On the occurrence of eclogite in Western Norway

Recent experimental data show that eclogites may form in the crust under conditions where total pressure exceeds water pressure. The regional distribution of eclogites in Western Norway and their association with crustal rocks makes their formation in the crust the most attractive hypothesis. Before a mantle origin should be assigned to any rock within this eclogite and garnet peridotite area it should be demonstrated that their country rocks are in a metamorphic state incompatible with the load pressures required for eclogite stability. Criteria for ascertaining eclogite formation in the crust are discussed.Publication no. 8 in the Norwegian geotraverse project.     

Minor element zonation in an eclogite garnet

A zoned garnet from eclogite at Almenningen, Nordfjord, Norway, shows a decrease of Ti, V and possibly also Zr concomitant with its decreasing Alm, Gross and Spess contents from core towards rim. Co, Cr and Ni increase with increasing Py contents towards the rim.Core compositions are related to the absolute size of the garnet crystals, indicative of garnet growth and nucleation over a time interval during which the adjacent domain was progressively depleted in certain elements.     

Nature and origin of eclogite xenoliths from kimberlites

Eclogites from the Earth's mantle found in kimberlites provide important information on craton formation and ancient geodynamic processes because such eclogites are mostly Archean in age. They have equilibrated over a range of temperatures and pressures throughout the subcratonic mantle and some are diamond-bearing. Most mantle eclogites are bimineralic (omphacite and garnet) rarely with accessory rutiles. Contrary to their overall mineralogical simplicity, their broadly basaltic-picritic bulk compositions cover a large range and overlap with (but are not identical to) much younger lower grade eclogites from orogenic massifs. The majority of mantle eclogites have trace element geochemical features that require an origin from plagioclase-bearing protoliths and oxygen isotopic characteristics consistent with seawater alteration of oceanic crust. Therefore, most suites of eclogite xenoliths from kimberlites can be satisfactorily explained as samples of subducted oceanic crust. In contrast, eclogite xenoliths from Kuruman, South Africa and Koidu, Sierra Leone stem from protoliths that were picritic cumulates from intermediate pressures (1–2 Ga) and were subsequently transposed to higher pressures within the subcratonic mantle, consistent with craton growth via island arc collisions. None of the eclogite suites can be satisfactorily explained by an origin as high pressure cumulates from primary melts from garnet peridotite.     

橄榄岩与榴辉岩中的一种金属合金

对江苏东海橄榄岩与榴辉岩中部分矿物的初步测试分析 ,发现其中存在一种金属矿物。其矿物结构与镍纹石近似。推测该矿物为具地幔特征的铁镁质残留物。     

Tale of the Kulet eclogite from the Kokchetav Massive,Kazakhstan: Initial tectonic setting and transition from amphibolite to eclogite

The Kulet eclogite in the Kokchetav Massif, northern Kazakhstan, is identified as recording a prograde transformation from the amphibolite facies through transitional coronal eclogite to fully recrystallized eclogite (normal eclogite). In addition to minor bodies of normal eclogite with an assemblage of Grt + Omp + Qz + Rt ± Ph and fine‐grained granoblastic texture (type A), most are pale greyish green bodies consisting of both coronal and normal eclogites (type B). The coronal eclogite is characterized by coarse‐grained amphibole and zoisite of amphibolite facies, and the growth of garnet corona along phase boundaries between amphibole and other minerals as well as the presence of eclogitic domains. The Kulet eclogites experienced a four‐stage metamorphic evolution: (I) pre‐eclogite stage, (II) transition from amphibolite to eclogite, (III) a peak eclogite stage with prograde transformation from coronal eclogite to UHP eclogite and (IV) retrograde metamorphism. Previous studies made no mention of the presence of amphibole or zoisite in either the pre‐eclogite stage or coronal eclogite, and so did not identify the four‐stage evolution recognized here. P–T estimates using thermobarometry and Xprp and Xgrs isopleths of eclogitic garnet yield a clockwise P–T path and peak conditions of 27–33 kbar and 610–720 °C, and 27–35 kbar and 560–720 °C, respectively. P–T pseudosection calculations indicate that the coexistence of coronal and normal eclogites in a single body is chiefly due to different bulk compositions of eclogite. All eclogites have tholeiitic composition, and show flat or slightly LREE‐enriched patterns [(La/Lu)_N = 1.1–9.6] and negative Ba, Sr and Sc and positive Th, U and Ti anomalies. However, normal eclogite has higher TiO₂ (1.35–2.65 wt%) and FeO (12.11–16.72 wt%) and REE contents than those of coronal eclogite (TiO₂ < 0.9 wt% and FeO < 12.11 wt%) with one exception. Most Kulet eclogites plot in the MORB and IAB fields in the 2Nb–Zr/4–Y and TiO₂–FeO/MgO diagrams, although displacement from the MORB–OIB array indicates some degree of crustal involvement. All available data suggest that the protoliths of the Kulet eclogites were formed at a passive continent marginal basin setting. A schematic model involving subduction to 180–200 km at 537–527 Ma, followed by slab breakoff at 526–507 Ma, exhumation and recrystallization at crustal depths is applied to explain the four‐stage evolution of the Kulet eclogite.     

On the survival of intergranular coesite in UHP eclogite

Coesite is typically found as inclusions in rock‐forming or accessory minerals in ultrahigh‐pressure (UHP) metamorphic rocks. Thus, the survival of intergranular coesite in UHP eclogite at Yangkou Bay (Sulu belt, eastern China) is surprising and implies locally “dry” conditions throughout exhumation. The dominant structures in the eclogites at Yangkou are a strong D₂ foliation associated with tight‐to‐isoclinal F₂ folds that are overprinted by close‐to‐tight F₃ folds. The coesite‐bearing eclogites occur as rootless intrafolial isoclinal F₁ fold noses wrapped by a composite S₁–S₂ foliation in interlayered phengite‐bearing quartz‐rich schists. To evaluate controls on the survival of intergranular coesite, we determined the number density of intergranular coesite grains per cm² in thin section in two samples of coesite eclogite (phengite absent) and three samples of phengite‐bearing coesite eclogite (2–3 vol.% phengite), and measured the amount of water in garnet and omphacite in these samples, and also in two samples of phengite‐bearing quartz eclogite (6–7 vol.% phengite, coesite absent). As coesite decreases in the mode, the amount of primary structural water stored in the whole rock, based on the nominally anhydrous minerals (NAMs), increases from 107/197 ppm H₂O in the coesite eclogite to 157–253 ppm H₂O in the phengite‐bearing coesite eclogite to 391/444 ppm H₂O in the quartz eclogite. In addition, there is molecular water in the NAMs and modal water in phengite. If the primary concentrations reflect differences in water sequestered during the late prograde evolution, the amount of fluid stored in the NAMs at the metamorphic peak was higher outside of the F₁ fold noses. During exhumation from UHP conditions, where NAMs became H₂O saturated, dehydroxylation would have generated a free fluid phase. Interstitial fluid in a garnet–clinopyroxene matrix at UHP conditions has dihedral angles >60°, so at equilibrium fluid will be trapped in isolated pores. However, outside the F₁ fold noses strong D₂ deformation likely promoted interconnection of fluid and migration along the developing S₂ foliation, enabling conversion of some or all of the intergranular coesite into quartz. By contrast, the eclogite forming the F₁ fold noses behaved as independent rigid bodies within the composite S₁–S₂ foliation of the surrounding phengite‐bearing quartz‐rich schists. Primary structural water concentrations in the coesite eclogite are so low that H₂O saturation of the NAMs is unlikely to have occurred. This inherited drier environment in the F₁ fold noses was maintained during exhumation by deformation partitioning and strain localization in the schists, and the fold noses remained immune to grain‐scale fluid infiltration from outside allowing coesite to survive. The amount of inherited primary structural water and the effects of strain partitioning are important variables in the survival of coesite during exhumation of deeply subducted continental crust. Evidence of UHP metamorphism may be preserved in similar isolated structural settings in other collisional orogens.     

Hydration of eclogite, Pam Peninsula, New Caledonia

Garnet glaucophanite and greenschist facies assemblages were formed by the recrystallization of barroisite-bearing eclogite facies metabasites in northern New Caledonia. The mineralogical evolution can be modelled by calculated P–T and P–X _H2O diagrams for appropriate bulk rock compositions in the model system CaO–Na₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O. The eclogites, having developed in a clockwise P–T path that reached P ≈19 kbar and T  ≈590 °C, underwent decompression with the consumption of free H₂O as the volume of hydrous minerals increased. Eclogite is preserved in domains that experienced no fluid influx following the loss of this fluid. Garnet glaucophanite formed at P ≈16 kbar during semi-pervasive fluid influx. Fluid influx, after further isothermal decompression, was focused in shear zones, and resulted in chlorite–albite-bearing greenschist facies mineral assemblages that reflect P ≈9 kbar.     

Diamond formation during metasomatism of mantle eclogite by chloride-carbonate melt

A xenolith of bimineralic eclogite from the Udachnaya kimberlite pipe provides a snapshot of interaction between mantle rocks and diamond-forming fluids/melts. The major-element composition of the eclogite is similar to that of N-MORB and/or oceanic gabbros, but its trace-element pattern shows the effects of mantle metasomatism, which resulted in diamond formation. The diamonds are clustered in alteration veins that crosscut primary garnet and clinopyroxene. The diamonds contain microinclusions of a fluid/melt dominated by carbonate and KCl. Compared to the worldwide dataset, the microinclusions in these diamonds fall in middle of the range between saline fluids and low-Mg carbonatitic melts. The fluid/melt acted as a metasomatic agent that percolated through ancient eclogitic rocks stored in the mantle. This interaction is consistent with calculated partition coefficients between the rock-forming minerals and diamond-forming fluid/melt, which are similar to experimentally-determined values. Some differences between the calculated and experimental values may be due to the low contents of water and silicates in the chloride-carbonate melt observed in this study, and in particular its high contents of K and LILE. The lack of nitrogen aggregation in the diamonds implies that the diamond-forming metasomatism took place shortly before the eruption of the kimberlite, and that the microinclusions thus represent saline carbonate-rich fluids circulating in the basement of lithospheric mantle (150–170 km depth).     

Zoning in eclogite garnets from Nordfjord,West Norway

Some of the garnets in eclogites within the quartzo-feldspathic gneisses of Nordfjord, West Norway, are zoned with higher calcium, iron and manganese in the cores and more magnesium at the rims. The zoning is discussed in terms of the apparent distribution coefficients of Fe²⁺/Mg between garnet and clinopyroxene (which will be aberrantly high for the garnet cores) and in terms of the metamorphic evolution of the eclogites.Publication nr. 32 in The Norwegian geotraverse project.     

Sulfide-oxide minerals in eclogite from Stockdale Kimberlite,Kansas

The opaque minerals in eclogite xenoliths from Stockdale Kimberlite are rutile, ilmenite, and a complex polysulfide assemblage. Rutile shows exsolutions of ilmenite and spinel. Discrete ilmenite contains up to 10 wt % MgO in solid solution and is a primary mineral, but not of kimberlitic origin. Pyrrhotite containing exsolved pentlandite is the major sulfide mineral, and is usually rimmed by chalcopyrite which may display exsolution of cubanite. A veneer of monosulfide solid solution (12 wt % Ni and 5 wt % Cu) forms a rim on the chalcopyrite-pyrrhotite masses. The simple model of sulfide liquid immiscibility within a silicate melt may account for the origin of the pyrrhotite-pentlandite-chalcopyrite assemblage, but it fails to explain the occurrence within one and the same sulfide globule of a monosulfide_ss rim, separated from an exsolved pyrrhotite core by chalcopyrite. The monosulfide_ss is probably a metastable phase produced by the partial melting of a preexisting sulfide assemblage of similar bulk chemical composition to that existing at present. The melting possibly took place instantaneously when the eclogite was incorporated into the rising hot kimberlitic magma. Fast cooling during the explosive ascent of the kimberlite could have led to the quenching of the monosulfide solid solution. Rutile in the eclogite xenolith was unaffected by the heating, but secondary amphibole and biotite may have possibly formed during this event.     

Five clinopyroxenes in the Hareidland eclogite,Western Norway

Five clinopyroxenes can be distinguished on petrographic and chemical grounds in the Hareidland eclogite. Of these, three are omphacites. It is suggested that all three were originally of the same composition and that their present chemical differences are due to differences in their immediate chemical environments during retrograde metamorphism of the eclogite. The other two clinopyroxenes are symplectitic, and chemically vary from sodic augite to jadeite-poor omphacite. They were formed by exsolution of a sodic component (sodic plagioclase) from a parental omphacite.Publication no. 49 in the Norwegian Geotraverse Project.     

榴辉岩组构运动学与大陆深俯冲——中国大陆科学钻探主孔榴辉岩的EBSD研究

中国大陆科学钻探主孔位于苏鲁超高压带南部的东海县毛北榴辉岩体之上。主孔0-600米深度的榴辉岩的塑性变形以具中等倾角的东倾面理,近南北向的水平拉伸线理、“A”型剪切褶皱和一系列平行面理的微型韧性剪切带为特征。使用电子背散射（EBSD）技术测量的主孔7个榴辉岩样品的石榴石和绿辉石的晶格优选定向（LPO）表明：石榴石基本上无序排列,而绿辉石表现出强烈的LPO。绿辉石的[001]轴近平行于拉伸线理方向,（010）面的法线和[100]轴垂直面理分布,{110}的法线形成垂直面理的环带,反映绿辉石的位错蠕变由[001]（100）和1／2〈^-110〉滑移系控制,其不对称的LPO指示了由北向南的剪切指向。根据单斜辉石的高温实验结果,毛北榴辉岩经历了800-900℃的超高压变质作用。通过构造重塑,揭示毛北榴辉岩体为剪切流变褶皱,形成于扬子板块深俯冲时的超高压变质过程。因此榴辉岩中保留的早期岩石组构特征可以为板块的深俯冲运动学和俯冲极性提供重要信息。