Regional record of a global oceanic anoxic event: OAE1a on the Apulia Platform margin, Gargano Promontory, southern Italy

The Gargano Promontory of southern Italy, located on the eastern margin of the Apulia Platform, represents a peculiar Tethyan area where the transition between carbonate platform and adjacent basins is exposed on land. The Aptian stratigraphic record, represented in shallow-water, slope and deep-water deposits, provides a good opportunity to investigate the regional response to the worldwide documented climatic, biotic and palaeoceanographic changes related to Oceanic Anoxic Event 1a (OAE1a). A synthesis of data previously published (Ischitella and Coppitella sections), together with original data (Val Carbonara and Coppa della Guardia sections), from four stratigraphic sections from different depositional settings (proximal to distal) is provided, using an integrated, high-resolution micropalaeontological (planktonic foraminifera and calcareous nannofossils) and, for one section, geochemical (stable carbon and oxygen isotopes) approach. Organic matter preservation is confined to the more distal areas and consists of two thin intervals of black shales in the Aptian portion of the Marne a Fucoidi Formation. Biostratigraphic data assign the older black shale (5 cm thick) to the Selli Level equivalent (OAE1a, Lower Aptian); this carbon-rich interval is immediately followed by another black shale (7–10 cm thick) of early Late Aptian age.OAE1a is generally interpreted as a high-productivity event during a warming interval, followed by a cooling trend. In the Gargano Promontory, although the oxygen isotope curve indicates the above-mentioned climatic evolution, the micropalaeontological data do not support high fertility of the surface water, whereas micropalaeontological and geochemical data for the younger black shale do record high productivity (radiolarian increase in overall abundance, low nannofossil and foraminiferal species richness, increase in abudance of nannofossil fertility indices) associated with a cooling trend. The carbon and oxygen isotope record is in line with evidence from the curves documented elsewhere, whereas, among the biotic events, only the “nannoconid crisis” preceding OAE1a is revealed to be globally correlable.Environmental models for the two episodes of organic matter preservation are proposed, taking into account both global and local controlling factors.     

Aragonite cycles: diagenesis caught in the act

Organic biomarker and nannofossil assemblages are used in combination with sedimentary petrology to identify the role of diagenesis for the formation of a rhythmic calcareous succession. A record from the Early Pliocene of the Maldives (Ocean Drilling Program, ODP Leg 115) is presented containing precession and eccentricity cycles expressed as variable aragonite content. Additional sub‐Milankovitch cycles are caused by rhythmic precipitation of calcite cement in the lower part of the interval. Comparison with palaeo‐productivity indicators (nannofossils, chlorin, total organic carbon) suggests that cementation occurs preferentially in intervals characterized by increasing or decreasing productivity. The coupled variability in productivity and carbonate diagenesis is attributed to the effect of organic matter degradation in the sediment. The observed combination of primary and diagenetic factors hampers the interpretation of the cyclicity on Milankovitch and sub‐Milankovitch scales. Diagenetically stable proxies for palaeo‐productivity, such as nannofossil assemblage data, were used to distinguish between palaeoclimate and diagenetic influences.     

Burial of organic carbon and carbonate on inner shelf of the northern South China Sea during the postglacial period

Two vibrocores from the inner shelf off Hong Kong are investigated to compare the contents of organic and inorganic carbon in postglacial sediments. The compositions of organic elements and carbonate are highly variable in the core sediments, but overall drop within the compositional ranges of modern seabed sediments in the Zhujiang estuarine and its shelf area. The Holocene sediments in the inner shelf have never been subject to subaerial exposure and the organic matter and carbonate can be preserved well. The burial of carbon in river-dominated shelf environments is highly dependent on the river flux with time. Nevertheless, it is difficult to establish a simple relationship between carbon burial in sediments in relation to climatic changes of basin-wide scale due to complex controls of production, transport and deposition of organic matter and carbonate. Our study suggests that the organic carbon to nitrogen ratio can not reliably identify the sources of depositional organic matters because of selective decomposition of organic matter components during humification and sedimentation. Caution is therefore needed in using organic elemental compositions as indicators of organic matter sources and paleoenvironmental changes in the East Asian continental shelves where intense river-sea interaction and variable carbon flux in geologic record occur.     

Relationship between Late Pleistocene sea‐level variations,carbonate platform morphology and aragonite production (Maldives,Indian Ocean)

A piston core from the Maldives carbonate platform was investigated for carbonate mineralogy, grain‐size distributions, calcium carbonate content and organic carbon. The sedimentary record was linked to Late Pleistocene sea‐level variations, using an age model based on oxygen isotopes obtained from planktonic foramanifera, nannofossil biostratigraphy and ¹⁴C age determinations. The correlation between the sedimentary record and Late Pleistocene sea‐level showed that variations in aragonite and mud during the past 150 000 years were clearly related to flooding and sea floor exposure of the main lagoons of the atolls of the Maldives carbonate platform. Platform flooding events were characterized by strongly increased deposition of aragonite and mud within the Inner Sea of the Maldives. Exposure events, in contrast, can be recognized by rapid decreases in the values of both proxy records. The results show that sediments on the Maldives carbonate platform contain a continuous record of Pleistocene sea‐level variations. These sediments may, therefore, contribute to a better understanding of regional and even global sea‐level changes, and yield new insights into the interplay between ocean currents and carbonate platform morphology.     

Biostratigraphy of the Garau Formation (Berriasian?–lower Cenomanian) in central part of Lurestan zone,northwest of Zagros,Iran

Deposition of organic rich black shales and dark gray argillaceous limestones in the Berriasian–Turonian interval has been documented in many parts of the world. Northwest of Zagros, Iran (Lurestan zone), thin bedded black shales and marls, dark gray argillaceous limestones and fissile limestone layers, having bitumen, of the Garau Formation are deposited. For biostratigraphic studies two stratigraphic sections including one surface section (Kuzaran) and one subsurface section (Naft well) were selected, respectively. In this study, 61 foraminiferal species belonging to 17 genera have been identified, and 12 biozones were recognized. Based on fossils distribution and biozones identification, the age of the Garau Formation is Berriasian?–early Cenomanian. In addition, the micropalaeontological study demonstrated a variety of widespread morphological changes in planktonic foraminifera assemblages (e.g., the elongation of the final chambers, appearance of twin chambers in the last whorl). These changes coincide with deposition of argillaceous limestones and marls rich in organic matter, indicating oceanic anoxic events. On this basis, three oceanic anoxic events such as OAE1a, OAE1b and OAE1d were recognized in Naft well section and two (OAE1b and OAE1d) in Kuzaran section.     

The Cenomanian—Turonian Anoxic Event in Southern Tibet：A Study of Organic Geochemistry

The Cenomanian-Turonian oceanic anoxic event(C/T OAE) is developed in southern Tibet.Organic geochemical study of the Cenomanian-Turonian sediments from the Gamba and Tingri aress shows that the mid-Cretaceous black shales in southern Tibet are enriched in organic carbon.Te molecular analyses of organic matter indicate marine organic matter was derived from algae and bacteria.In the Gamba area,the organic matter is characterized by abundant tricyclic terpanes and pregane,which are predominant in 191 and 217 mass chromatograms,respectively,Pristane/phytane(Pr/Ph)ratios in the C/T OAE sediments are less than 1, demonstrating the domination of phytane.The presence of carotane can be regarded as a special biomarker indicating oxygen depletion in the C/T OAE sediments in the Tethyan Himalayas.In anoxic sediments,β-carotane and γ－carotane are very abundant.The β-and γ-carotane ratios relative to nC17 in the Cenomanian-Turonian anoxic sediments vary from 32.28-42.87and 5.10-11.01.     

Paleoceanographic evolution and chronostratigraphy of the Aptian Oceanic Anoxic Event 1a (OAE1a) to oceanic red bed 1 (ORB1) in the Gorgo a Cerbara section (central Italy)

We performed a detailed study of the stratigraphic transition of Oceanic Anoxic Event 1a (OAE1a) to oceanic red bed 1 (ORB1) from the classic Gorgo a Cerbara section in the Umbria region of central Italy. We focused on a 25.5-m-thick stratigraphic succession, from which we analyzed 305 samples for total organic carbon (TOC), CaCO₃, magnetic susceptibility, diffuse reflectance spectrophotometry and the stable carbon and oxygen isotopic composition of both bulk samples and organic matter. In the Gorgo a Cerbara section, the Selli Level of OAE1a (∼1.81 m thick) consists of laminated to bioturbated dark gray to black mudstones and shales with medium to dark gray radiolarian-rich silty to sandy layers and a maximum TOC content of 20.22%. The carbon isotopic values show a negative excursion (C3 stage, ∼0.14 m) at the base of the Selli Level, followed by a stepwise positive excursion (C4–C6 stages, ∼1.67 m) in the upper part of the Selli Level. The transition from OAE1a to ORB1 (∼3.19 m thick) is characterized by bioturbated greenish gray cherty limestones and marly limestones with subordinate marls, corresponding to stable carbon isotopic C7 stage and lasts for ∼0.75 Ma. The ORB1 interval (∼13.15 m) consists of reddish marly claystones, dark-red marlstones, red marly limestones and red calcareous shales which indicate a highly oxic environment. Our results reveal a stepwise transition from a predominantly mesotrophic and dysoxic to anoxic environment at the time that the OAE1a black shales were deposited to an oligotrophic and oxic environment during the transitional interval and finally to highly oxic conditions during the ORB1 interval. The nannoconid crisis occurs at the top of the C2 stage, just 0.34 m below the negative excursion in δ¹³C isotopic values. The massive CaCO₃ dissolution phase occurs 0.25 m above the negative excursion; it persisted for 0.85 Ma and probably resulted from excess CO₂, ocean acidification, and carbonate compensation depth (CCD) shoaling. Deposition of massive black shales occurs at the base of the C6 stage and lasted for 0.4 Ma.     

Early Aptian productivity increase as recorded in the Fourcade level of the Ionian zone of GreecePaléoproductivité élevée enregistrée dans le niveau Fourcade de l'Aptien inférieur en zone ionienne (Grèce)

The Mid-Cretaceous ‘upper siliceous zone’ of the Vigla Limestone is studied in detail along the Paliambela section of northwestern Greece. Within it two radiolarite horizons can be identified, the lower being rich in organic matter and named herein as the ‘Fourcade level’. The preserved organic matter is of planktic/bacterial origin and of low thermal maturity. The nannoflora contained within the lower marly argillites consists of a poorly preserved and oligospecific assemblage characterised by the total absence of Nannoconids. Radiolarian assemblages yielded from the Fourcade level are dominated by the family Archaeodictyomitridae. Integrated calcareous nannofossil and radiolarian biostratigraphic results suggest an Early Aptian age for the Fourcade level, which can be thus considered as the local expression of the globally recognised Early Aptian Oceanic Anoxic Event (OAE 1a). To cite this article: T. Danelian et al., C. R. Geoscience 334 (2002) 1087–1093.     

Palaeoecology and biostratigraphy of early Cretaceous (Aptian) calcareous nannofossils and the δCcarb isotope record from NE Iran

Upper Barremian-Lower Aptian sediments of the Sarcheshmeh and Sanganeh formations in the Kopet Dagh area, northeast Iran were studied with regard to their calcareous nannofossil content and their δ¹³C_carb signal. The sediments are composed mainly of marlstones, argillaceous limestones and limestones. Based on the occurrence of biostratigraphic index taxa, the calcareous nannofossil zones NC5, NC6 and the NC7A Subzone were recognised. The calcareous nannofossils and the δ¹³C_carb data enable recognition of the early Aptian Oceanic Anoxic Event 1a (OAE 1a). The deposits of the OAE 1a interval are characterised by the rarity of nannoconids and a sharp negative δ¹³C_carb excursion (1.36‰), followed by an abrupt positive δ¹³C_carb excursion of 4-5‰; both events have been recognised elsewhere in OAE 1a deposits in the Tethys. In the OAE 1a interval, the relative abundance of Watznaueria barnesiae/Watznaueria fossacincta is higher (more than 40%) than that of Biscutum spp., Discorhabdus spp. and Zeugrhabdotus spp., which indicates dissolution. In the upper part of the section, the higher relative abundance of mesotrophic and oligotrophic taxa (Watznaueria spp. and nannoconids respectively) and the enhanced relative abundance of eutrophic taxa (Biscutum spp., Discorhabdus spp., Zeugrhabdotus spp.) is indicative of an environment with slightly increased nutrient content. The presence of warm water taxa (Rhagodiscus asper and nannoconids) and the absence of cool water taxa (Repagulum and Crucibiscutum) suggest warm surface-water conditions.     

南海北部神狐水合物赋存区浅表层沉积物自生矿物特征及其成因探讨

通过对南海北部神狐海域Site5B和Site4B站位岩心柱沉积物中自生矿物的类型、形貌特点、丰度和稳定同位素特征的研究,探讨了自生矿物的成因机制。研究表明,沉积物中主要发育黄铁矿和碳酸盐类自生矿物。两个站位中发育的自生矿物的丰度、分布位置、晶体形貌和个体大小等存在明显差异,可能与不同站位中甲烷通量和深部构造有关。自生黄铁矿可能是硫酸盐与甲烷等烃类气体或有机质的厌氧氧化作用的产物,极低负值的硫同位素值可能与硫酸盐还原菌和单质硫歧化菌共同参与有关。自生碳酸盐矿物的成因则相对复杂,其形成过程受多种因素的综合影响。碳同位素值未表现出极低负值,可能是甲烷、有机质和正常海水等碳源混合的结果。     

Early Aptian oceanic anoxic event (OAE 1a) in Northeastern Arabian Plate setting: an example from Dariyan Formation in Zagros fold–trust belt,SE Iran

The Dariyan Formation (southwestern Iran) records the characteristic features of an oceanic anoxic event with organic- and radiolarian-rich hemipelagic intervals. A biostratigraphic study based on benthic and planktonic foraminifers provides an early Aptian age for the organic-rich succession and an Aptian age for the entire Dariyan Formation in this area. In this study, we report the first stable carbon isotope curve for the Dariyan Formation which is characterized by a pronounced negative spike (reaching ?2?‰) at the base of the section followed by a subsequent positive excursion (4?‰) and a plateau with values fluctuating around 3?‰. The integration of the δ¹³C record with the previously published litho- and biostratigraphy provides the characteristic features of the oceanic anoxic events (OAE) 1a interval. This detailed curve improved the stratigraphic resolution in this area and allowed the establishment of a temporal framework which showed good correlations with other OAE 1a sections worldwide. High production of organic matter and abundance of radiolarians and planktonic foraminifers suggest high-nutrient fluxes and meso- to eutrophic conditions at the time of deposition of the organic-rich interval of the Dariyan Formation. This is in agreement with enhanced greenhouse conditions. The facies distribution (from shallow to deep water environments) and the paleogeography of Arabian Plate during the early Aptian suggest that increasing continental runoff was a primary trigger of high trophic level conditions. Redox conditions, estimated from manganese (Mn) behavior, indicate dysoxic to anoxic conditions within the basin during OAE 1a.     

Evolution of the Cretaceous calcareous nannofossil genus Eiffellithus and its biostratigraphic significance

The calcareous nannofossil genus Eiffellithus is an important taxon of mid- to Upper Cretaceous marine sediments in biostratigraphy and paleoceanography. The definition of species within Eiffellithus have been both broadly interpreted and variably applied by nannofossil workers. This is particularly true for the Eiffellithus eximius plexus. While the taxonomy of mid-Cretaceous Eiffellithus species has recently been well-defined, the remaining 35 m.y. history of the genus has not been closely examined. Our investigation of Cenomanian to Maastrichtian sediments from the Western Interior Seaway, Gulf of Mexico, and Western Atlantic gives rise to six new species of Eiffellithus that can be reliably differentiated. In this paper the hitherto used biostratigraphic markers (E. turriseiffelii and E. eximius) have been redefined in a more restricted sense to increase their utility. These refinements in taxonomy reveal an obvious shift in abundance both within the genus and within the nannofossil assemblage as a whole through the Late Cretaceous. In the Cenomanian and Maastrichtian the genus is composed exclusively of coccoliths bearing an X-shaped central cross, such as E. turriseiffelii, while in the Coniacian through Campanian axial-cross forms such as E. eximius comprise more than 60% of the genus. Within the nannofossil assemblage the genus has low abundances in the Cenomanian but increases to >15% of the assemblage in well-preserved samples in the Santonian. In addition, the pattern of diversification of this genus, whereby a x-shaped, diagonal cross repeatedly gives rise to an axial cross by rotation about the central axis, is an excellent example of iterative evolution that may be related to repetitive shifts in Late Cretaceous climatic and paleoceanographic regimes.     

Matrix protected organic matter in a river dominated margin: A possible mechanism to sequester terrestrial organic matter?

The provenance of organic matter in surface sediments from the northern Gulf of Mexico was investigated by analyzing the compositions of lipid biomarkers (n-alkanes, fatty acids, sterols) liberated after a series of chemical treatments designed to remove different organo-mineral matrix associations (i.e. freely extractable, base-hydrolyzable, unhydrolyzable). Bulk analyses of the organic matter (carbon content, carbon:nitrogen ratios, stable and radiocarbon isotopic analyses) were also performed on the intact sediments and their non-hydrolyzable, demineralized residue. We found recognizable lipids from distinct sources, including terrestrial vascular plants, bacteria and marine algae and zooplankton, within each of the isolated fractions. Based on the lipid signatures and bulk compositions, the organic matter within the unhydrolyzable fractions appeared to be the most diagenetically altered, was the oldest in age, and had the highest abundance of terrigenous lipids. In contrast, the base-hydrolyzable fraction was the most diagentically unaltered, had the youngest ages and was most enriched in N and marine lipids. Our results indicate that fresh, autochthonous organic matter is the most important contributor to base-hydrolyzable lipids, whereas highly altered allochthonous sources appear to be predominant source of unhydrolyzable lipids in the surface sediments from the Atchafalaya River shelf. Overall, the lipid biomarker signatures of intact sediments were biased towards the autochthonous source because many of the organic compounds indicative of degraded, terrigenous sources were protected from extraction and saponification by organo-mineral matrices. It is only after these protective matrices were removed by treatment with HCl and HF that these compounds became evident.     

Allochthonous versus autochthonous naturally occurring organic matter in the Anllóns river bed sediments (Spain)

Despite of the importance of the aquatic ecosystems as organic matter pools within the global carbon cycle, specific studies in river sediments are still insufficient. This study was carried out in an Atlantic basin where nine sites were selected in the lowest middle stretch of the River. The analyses include total organic carbon, C/N ratios, humus composition (humic, fulvic and humin), A2/A4 and A4/A6 ratios, biologically active organic matter (BAOM), water soluble organic matter (WSOC) and coloured water soluble organic carbon (CWSOC). The results suggested a predominance of allochthonous sources to the organic matter, highly influenced by the land uses together with the river hydrodynamics, namely urban and forest at sites 1, 2 and 9, and agricultural at sites 7 and 8. The 38% of the total organic matter was humic and fulvic acids. The biologically active organic matter, which may act as a proxy of microbial activity, showed a mean value of 0.9% of the total organic matter, showing the lowest values at sites with the highest organic matter total, soluble or coloured. This coloured organic matter represented an average of 3.60% of the total organic matter, and showed the highest visible light absorption at those sites more affected by human activities, close to centres of population (1, 2 and 9). This coloured fraction showed also a high degree of photostability. C/N ratios were less effective to discriminate between allochthonous or autochthonous sources, whereas A4/A6 ratios were effective to estimate variations of autochthonous sources, as it measures the variations of phytopigments of the river bed sediments.     

Ocean current intensification during the Cretaceous oceanic anoxic event 2 – evidence from the northern Tethys

Mesozoic Oceanic Anoxic Events (OAEs) are expressions of major physical oceanographic changes at times of perturbation of the global carbon cycle. A northern Tethyan record of OAE2 is preserved in expanded Cenomanian–Turonian pelagic limestone sections (Seewen Formation) in Eastern Switzerland. The new carbonate carbon‐isotope stratigraphy extracted from these limestones demonstrates that the OAE2 is condensed in all the studied successions and only the onset of the δ¹³C excursion (5.0‰) is present. The condensed interval is characterized by dissolution features, which are filled by a glauconite quartz sandstone. This bed is overlain by a well‐sorted sandstone with intercalated limestone pebbles (Götzis Member), which can be compared with palimpsest sands forming today along current‐swept shelves. The wide distribution of this thin sandstone layer within OAE2 indicates that an intense, erosive, east‐west trending shelf current was active during the highest sea level and most extreme carbon‐cycle perturbation of the OAE2.     

Planktonic foraminiferal distribution record productivity cycles: evidence from the Aptian-Albian Piobbico core (central Italy)

The Aptian-Albian 'Scisti a Fucoidi' varicoloured pelagic sediments in central Italy, show a 'couplet' alternation of carbonate-rich/carbonate-poor layers, which are interpreted as the sedimentary expression of precession (frequency 19–23 kyr). Carbonate content, chromatic variation, and planktonic foraminiferal abundance were analysed at a 1-cm spacing for a 10-m interval of the Piobbico core, specifically drilled through this formation. Spectral analysis of these parameters shows a prominent signal equated to the c . 100 kyr cycle of orbital eccentricity at a sedimentation rate of 5 mm kyr⁻¹. The coherency of the spectral response of each parameter suggests that a single mechanism controlled the whole sedimentary record. Detailed study of planktonic foraminiferal distribution of the same section at 1-mm scale resolves the Milankovitch frequencies of 41 kyr and 18 to 23 kyr, equated with the obliquity and precessional cycles. But foraminiferal abundance is not in phase with carbonate content, which was largely controlled by calcareous nannofossils, but peaked at intermediate carbonate values. The proposed model for explaining the discrepancy at the precessional level is that foraminifera thrived at intermediate values of the precession index, when the environment was only moderately fertile but stable, while during highs of the precession index, mixing of the water column increased fertility and caused calcareous nannofossil blooms and restriction of planktonic foraminifera to few and tolerant species. The resulting bimodality of foraminiferal abundance per precessional cycle appears to be recorded in the spectrum by peaks at the 11 and 14 kyr levels. Cross correlation of foraminiferal abundances with the calcium carbonate curve over 1–2 Myr intervals produces discrepant results (apparent phase lags) which we attribute to differences in the response to the fundamental eccentricity cycles.     

Aragonite and calcite preservation in sediments from Lake Iznik related to bottom lake oxygenation and water column depth

This study examines the forcing mechanisms driving long‐term carbonate accumulation and preservation in lacustrine sediments in Lake Iznik (north‐western Turkey) since the last glacial. Currently, carbonates precipitate during summer from the alkaline water column, and the sediments preserve aragonite and calcite. Based on X‐ray diffraction data, carbonate accumulation has changed significantly and striking reversals in the abundance of the two carbonate polymorphs have occurred on a decadal time scale, during the last 31 ka cal bp . Different lines of evidence, such as grain size, organic matter and redox sensitive elements, indicate that reversals in carbonate polymorph abundance arise due to physical changes in the lacustrine setting, for example, water column depth and lake mixing. The aragonite concentrations are remarkably sensitive to climate, and exhibit millennial‐scale oscillations. Extending observations from modern lakes, the Iznik record shows that the aerobic decomposition of organic matter and sulphate reduction are also substantial factors in carbonate preservation over long time periods. Lower lake levels favour aragonite precipitation from supersaturated waters. Prolonged periods of stratification and, consequently, enhanced sulphate reduction favour aragonite preservation. In contrast, prolonged or repeated exposure of the sediment–water interface to oxygen results in in situ aerobic organic matter decomposition, eventually leading to carbonate dissolution. Notably, the Iznik sediment profile raises the hypothesis that different states of lacustrine mixing lead to selective preservation of different carbonate polymorphs. Thus, a change in the entire lake water chemistry is not strictly necessary to favour the preservation of one polymorph over another. Therefore, this investigation is a novel contribution to the carbon cycle in lacustrine systems.     

The role of diagenetic carbonate concretions in the preservation of the original sedimentary record

The Upper Cretaceous organic rich limestones and marls of the Tarfaya basin of southwest Morocco contain numerous calcite concretions, which formed during early diagenesis. Relative textural similarities are observed both in the concretions and in the host sediments. However, the biological content of the concretions is considerably higher than in the host marls and limestones. Evidence for fossil dissolution in the host marls, and the absence of concretions in some fossil-rich zones, suggest that the difference in fossil abundance between the concretions and host rock is a function of dissolution, rather than preferential precipitation in fossil-rich areas. Consequently, the carbonate concretions appear to represent the 'memory' of the sediment and allow quantification of the original biological components and are potential tools for estimating the original biological material deposited in the soft sediments.     

Do paleoclimate proxies agree? A test comparing 19 late Holocene climate and sea‐ice reconstructions from Icelandic marine and lake sediments

Geochemical, mineralogical and biological indicators preserved in sediments are widely used to reconstruct past climate change, but proxies differ in the degree to which their utility as climate indicators has been validated via laboratory experiments, modern spatial calibrations, or down‐core comparisons with instrumental climate data. Multi‐proxy studies provide another means of evaluating interpretations of proxies. This paper presents a multi‐proxy assessment comparing 19 sub‐centennially resolved late Holocene proxy records, covering the period 300–1900 AD, from seven Icelandic marine and lacustrine core sites. We employ simple statistical comparisons between proxy reconstructions to evaluate their correlations over time and, ultimately, their utility as proxies for regional climate. Proxies examined include oxygen isotopic composition of benthic and planktonic foraminifera, abundance of the sea‐ice biomarker IP₂₅, allochthonous quartz in marine sediments (a proxy for drift ice around Iceland), marine carbonate abundance, total organic carbon concentration, chironomid assemblages, lacustrine biogenic silica and carbon/nitrogen ratios in lake sediments. Most of the examined proxy records, including temperature and sea‐ice proxies, correlate strongly with each other over multi‐centennial timescales, and thus do appear to record changes in regional climate. Copyright © 2011 John Wiley & Sons, Ltd.     

Reflectance spectroscopy and geochemical analyses of Lake Hoare sediments, Antarctica: implications for remote sensing of the Earth and Mars

Visible to infrared reflectance spectroscopic analyses (0.3-25 micromoles) have been performed on sediments from the Dry Valleys region of Antarctica. Sample characterization for these sediments includes extensive geochemical analyses and X-ray diffraction (XRD). The reflectance spectra and XRD indicate major amounts of quartz, feldspar, and pyroxene in these samples and lesser amounts of carbonate, mica, chlorite, amphibole, illite, smectite, and organic matter. Calcite is the primary form of carbonate present in these Lake Hoare sediments based on the elemental abundances and spectroscopic features. The particle size distribution of the major and secondary components influences their detection in mixtures and this sensitivity to particle size is manifested differently in the "volume scattering" and "surface scattering" infrared regions. The Christiansen feature lies between these two spectral regimes and is influenced by the spectral properties of both regions. For these mixtures the Christiansen feature was found to be dependent on physical parameters, such as particle size and sample texture, as well as the mineralogy. Semiquantitative spectroscopic detection of calcite and organic material has been tested in these quartz- and feldspar-rich sediments. The relative spectral band depths due to organics and calcite correlate in general with the wt% C from organic matter and carbonate. The amounts of organic matter and carbonate present correlate with high Br and U abundances and high Ca and Sr abundances, respectively. Variation in the elemental abundances was overall minimal, which is consistent with a common sedimentary origin for the forty-two samples studied here from Lake Hoare.