Changes in the fatty acid composition of the gill phospholipids in Gammarus duebeni with degree of gill contamination

The fatty acid composition of the gill lipids from Gammarus duebeni have been compared in relation to the degree of contamination of the gills by lipophilic materials. The results indicate that at higher levels of gill contamination a greater proportion of polyunsaturated 20:5 fatty acid occurs in the gill phospholipids. We suggest this may be a response to a change in the physical state of the gill membranes resulting from the contamination.     

Regional distribution and temporal trends of some contaminants in the water of the Baltic Sea

During a cruise on board RV Gauss in May/June 1988, joint investigations into organochlorine compounds, dissolved trace metals, petroleum hydrocarbons and basic hydrography were carried out at representative stations of the Baltic Monitoring Programme (BMP). The aim of the cruise was to study distribution patterns and — using previous data — to establish temporal trends if at all discernible.Each group of contaminants investigated showed specific characteristics, with differences even between compounds within the same group. The differences are due to:

Modelling the fate of oxidisable organic contaminants in groundwater

Subsurface contamination by organic chemicals is a pervasive environmental problem, susceptible to remediation by natural or enhanced attenuation approaches or more highly engineered methods such as pump-and-treat, amongst others. Such remediation approaches, along with risk assessment or the pressing need to address complex scientific questions, have driven the development of integrated modelling tools that incorporate physical, biological and geochemical processes.We provide a comprehensive modelling framework, including geochemical reactions and interphase mass transfer processes such as sorption/desorption, non-aqueous phase liquid dissolution and mineral precipitatation/dissolution, all of which can be in equilibrium or kinetically controlled. This framework is used to simulate microbially mediated transformation/degradation processes and the attendant microbial population growth and decay. Solution algorithms, particularly the split-operator (SO) approach, are described, along with a brief résumé of numerical solution methods. Some of the available numerical models are described, mainly those constructed using available flow, transport and geochemical reaction packages. The general modelling framework is illustrated by pertinent examples, showing the degradation of dissolved organics by microbial activity limited by the availability of nutrients or electron acceptors (i.e., changing redox states), as well as concomitant secondary reactions. Two field-scale modelling examples are discussed, the Vejen landfill (Denmark) and an example where metal contamination is remediated by redox changes wrought by injection of a dissolved organic compound. A summary is provided of current and likely future challenges to modelling of oxidisable organics in the subsurface.     

The role of vegetation in the retention of fine sediment and associated metal contaminants in London's rivers

Many urban rivers receive significant inputs of metal‐contaminated sediments from their catchments. Restoration of urban rivers often creates increased slack water areas and in‐channel vegetation growth where these metal‐contaminated sediments may accumulate. Quantifying the accumulation and retention of these sediments by in‐channel vegetation in urban rivers is of importance in terms of the planning and management of urban river restoration schemes and compliance with the Water Framework Directive. This paper investigates sediment properties at four sites across three rivers within Greater London to assess the degree to which contaminated sediments are being retained. Within paired restored and unrestored reaches at each site, four different bed sediment patch types (exposed unvegetated gravel, sand, and silt/clay (termed ‘fine’) sediments, and in‐channel vegetated sediments) were sampled and analysed for a range of metals and sediment characteristics. Many samples were found to exceed Environment Agency guidelines for copper (Cu), lead (Pb) and zinc (Zn) and Dutch Intervention Values for Cu and Zn. At all sites, sediments accumulating around in‐channel vegetation were similar in calibre and composition to exposed unvegetated fine sediments. Both bed sediment types contained high concentrations of pseudo‐total and acetic acid extractable metal concentrations, potentially due to elevated organic matter and silt/clay content, as these are important sorbtion phases for metals. This implies that the changed sediment supply and hydraulic conditions associated with river restoration may lead to enhanced retention of contaminated fine sediments, particularly around emergent plants, frequently leading to the development of submerged and emergent landforms and potential river channel adjustments. High pseudo‐total metal concentrations were also found in gravel bed sediments, probably associated with iron (Fe) and manganese (Mn) oxyhydroxides and discrete anthropogenic metal‐rich particles. These results highlight the importance of understanding the potential effects of urban river restoration upon sediment availability and channel hydraulics and consequent impacts upon sediment contaminant dynamics and storage. Copyright © 2014 John Wiley & Sons, Ltd.     

Transfer of organic contaminants to the Baltic in the Odra Estuary

This paper describes the transfer of organic contaminants to the sea, using PAHs (12 compounds) and PCBs (11 congeners) as examples, through a eutrophicated coastal lagoon (Szczecin Lagoon, on the Polish-German border). The transfer of contaminants study was based on their concentration in recent sediments (0-10 cm), in relation to different environmental conditions such as temperature, salinity, turbidity, oxygen and nutrients in water, hydrological conditions, organic carbon and biomarkers (pigments and their derivatives) in sediments. Results include the data obtained between 1994 and 2000, also those on before and afterwards the great flood in July 1997, at different stations in the Lagoon and the adjacent Pomeranian Bay. The results indicated that the eutrophic estuary of the shape of lagoon acts as an effective trap for the hydrophobic organic pollutants. The abundance and taxonomy of plankton as well as detritus derived from it play an important role in bonding the studied compounds. The salinity gradient in the lagoon has a significant influence upon deposition of the pollutants from the water column to the sediments and the residence time of the compounds there depends strongly on oxic-anoxic status of the sediments and the strength of interaction with sediments resulting from polarity, the type and stability of associates formed, as well as on hydrological conditions. We conclude that eutrophication in this area prevents pollution of the sea to some extent.     

Organochlorine contaminants in sea turtles from the Eastern Pacific

We measured organochlorine residues in three species of sea turtles from the Baja California peninsula, Mexico. Seventeen of 21 organochlorine pesticides analyzed were detected, with heptachlor epoxide and gamma-hexachlorocyclohexane the most prevalent (14 (40%) and 11 (31%) of the 35 tissue samples, respectively). PCBs were detected in all but one of the 9 turtles studied, with congener 18 the most commonly detected (8 (23%) of the samples). The dioxin-like congeners 118 and 180 were detected in 4 (11%) and 3 (9%) of the samples, respectively. Percent contribution of congeners was negatively correlated to their octanol-water partition coefficients, with kidney and muscle containing more lower-chlorinated congeners than liver or adipose samples. Levels of organochlorines detected in the present study were low, potentially attributable to the feeding habits of the predominant species collected in this study (herbivorous) and/or the samples obtained in an unindustrialized region.     

Observations of neutral hydrogen in the corona

Measurements of the linear polarization degree (p) of the emission in the inner corona (<1.5 R _⊙) in the green and red continuum ranges are discussed. “Excess p” (Δp = pgreen — pred), which reaches its maximum at 1.2–1.3 R _⊙ (<5%) in the polar regions and 20% within large-scale streamers, is present everywhere in the corona. It has been mentioned that excess p can be explained by the presence of neutral hydrogen in the corona.     

The Elbe flood 2002--toxic effects of transported contaminants in flatfish and mussels of the Wadden Sea

Cellular changes in livers from flounder (Platichthys flesus L.) and digestive glands of blue mussels (Mytilus edulis) were studied to analyze whether the Elbe flood catastrophe in August 2002 had any deleterious effects on animal health. Flatfish and mussels were sampled at different locations in the Elbe estuary and the Wadden Sea after the flood wave had reached the German Bight. Internationally used core biomarkers (lysosomal membrane stability, biotransformation enzymes) were applied to assess the toxic effects of putatively increased pollution levels. In comparison to earlier data from long-term studies at the same stations, we found a significant impairment in the function of cell organelles (lysosomes) involved in the detoxification and elimination of pollutants in fish liver. Concentrations of relevant contaminants (organochlorines, polychlorinated biphenyls) were analyzed in parallel with cellular biomarkers, and conspicuously raised concentrations of insecticides metabolites were detected. Cell recovery and a clear reduction in contaminant concentrations were observed in fish livers five months after the flood at all sampling sites except the Helgolander Tiefe Rinne.     

Microplastics as contaminants in the marine environment: a review

Since the mass production of plastics began in the 1940s, microplastic contamination of the marine environment has been a growing problem. Here, a review of the literature has been conducted with the following objectives: (1) to summarise the properties, nomenclature and sources of microplastics; (2) to discuss the routes by which microplastics enter the marine environment; (3) to evaluate the methods by which microplastics are detected in the marine environment; (4) to assess spatial and temporal trends of microplastic abundance; and (5) to discuss the environmental impact of microplastics. Microplastics are both abundant and widespread within the marine environment, found in their highest concentrations along coastlines and within mid-ocean gyres. Ingestion of microplastics has been demonstrated in a range of marine organisms, a process which may facilitate the transfer of chemical additives or hydrophobic waterborne pollutants to biota. We conclude by highlighting key future research areas for scientists and policymakers.     

Retardation of organic contaminants in natural fractures in chalk

Transport of a conservative compound and two sorbing compounds through fractured chalk was studied using flow-through columns consisting of chalk cores with a single subvertical fracture. Two types of chalk matrix were compared, an oxidized white chalk with low organic carbon content (0.2%), and a gray chalk with a higher organic carbon content (1.3%). Initial rapid breakthrough followed by a delayed approach to a relative concentration of unity for the conservative compound (2,6–difluorobenzoic acid [DFBA]) was clear evidence for diffusion into the porous chalk matrix. Matrix diffusion of DFBA was apparently much greater in the gray chalk columns than in the white chalk columns. Breakthrough curves (BTCs) of the sorbing compounds (2,4,6–tri-bromophenol [TBP] and ametryn [AME]) were retarded in all cases as compared to the conservative compound. Sorption retardation was far greater in the gray chalk as compared with the white chalk, in good agreement with results from batch sorption experiments. BTCs for the conservative compound were relatively nonhysteretic for both white and gray chalk columns. In contrast, BTCs for the sorbing compounds were hysteretic in all cases, demonstrating that sorption was not at equilibrium before desorp-tion began. These experiments suggest that on a field scale, transport of contaminants through fractures in chalk and other fractured porous media will be attenuated by diffusion and sorption into the matrix.     

The identification of magnetite in limestones using the low-temperature transition

The low-temperature (K₁) transition has been measured in prepared samples with a low concentration of magnetite to test the validity of the technique for identifying magnetite in weakly magnetized rocks. Using an astatic magnetometer, magnetite concentrations as low as 1 part in 100,000 can be satisfactorily detected.Measurements on natural samples show the presence of magnetite in a variety of limestones which are known to have a stable natural remanent magnetization.     

The shapes of some mountain peaks in the Canadian Rockies

Different mountain shapes in sedimentary sequences in the Canadian Rockies were enhanced by glacial erosion and have been modified postglacially by gravity-driven slope processes. Slope modification by both glacial erosion and postglaciation landslides is related to rock structure, particularly bedding dip, rock mass strength and slope geometry. Five mountain peak shapes in monoclinal sequences each fall into different ranges of bedding dips. Castellate (1) and matterhorn (2) mountains occur in sub-horizontal beds and their slopes on all sides follow combinations of bedding planes and joints. The overall slopes are generally 37 to 65° and oblique to both bedding and joints. Slopes in sub-horizontal beds may be controlled by their rock mass strength. Cuestas (3) develop in gently to moderately dipping beds. Dip slopes and steeper, normal escarpments form their cataclinal and anaclinal sides respectively, with the dihedral angle between them about 90°. Hogbacks (4) in moderately to steeply dipping beds have similar slope angles on both cataclinal and anaclinal slopes. Cataclinal slopes are either dip slopes or underdip slopes but anaclinal slopes are often steepened escarpments; the dihedral angle between the slopes is usually less than 90°. Dogtooth (5) mountains occur in steeply dipping to sub-vertical beds and the dihedral angle can be as low as 60°. Slope gradients in inclined beds are closely related to landslides, whose modes are controlled by bedding dips. Copyright © 1999 John Wiley & Sons, Ltd.     

Surveillance for previously unmonitored organic contaminants in the San Francisco Estuary

The San Francisco Estuary Regional Monitoring Program initiated surveillance monitoring to identify previously unmonitored synthetic organic contaminants in the San Francisco Estuary. Organic extracts of water samples were analyzed using gas chromatography-mass spectrometry in full scan mode. The major contaminant classes identified in the samples were fire retardants, pesticides, personal care product ingredients, and plasticizers. Evidence from the literature suggests that some of these contaminants can persist in the environment, induce toxicity, and accumulate in marine biota and in higher food chain consumers. The major sources of these contaminants into the marine environment are the discharge of municipal and industrial wastewater effluents, urban stormwater, and agricultural runoff. As a proactive effort, it is suggested that surveillance studies be used routinely in monitoring programs to identify and prevent potential problem contaminants from harming the marine environment.     

The Nature of sediments in some wetlands

Five wetlands of temporary-shallow, temporary-deep and permanent-deep types, falling in the inland, channel or stream and riverine drainage basins were studied for their sediment, chemical and textural composition. The content of clay was maximum in the inland type as against the higher content of silt and sand at the channel and riverine sites, respectively. Among the various sediment fractions only the silt particles were distributed along depth gradients. Clay particles were positively correlated with the phosphorus content only, while the organic carbon content was correlated with the levels of calcium and nitrogen in the sediments. Calcium was also positively related to phosphorus, while correlations between all other elements were insignificant. It is concluded that the hydrolytic regime is the major factor determining the nature of wetland sediments.     

The magnetic fabric in some folds

Five folds are described, differing in terms of the relation of the magnetic fabric to the fold curve. The magnetic fabric study enables the time relationship between the magnetic fabric generation and the folding to be determined. In some cases the origin of folds can be studied.     

Sorption of radioactive contaminants by sediment from the Kara Sea

The purpose of this study is to quantify some of the parameters needed to perform near-field modelling of sites in the Kara Sea that were impacted by the disposal of radioactive waste. The parameters of interest are: the distribution coefficients (Kd) for several important radionuclides, the mineralogy of the sediment, and the relationship of Kd to liquid-to-solid ratio. Sediment from the Kara Sea (location: 73 degrees 00'N, 58 degrees 00'E) was sampled from a depth of 287 m on August 23/24, 1992. Analysis of the material included mineralogy, grain size and total organic carbon (TOC). Uptake kinetics were determined for 85Sr, 137Cs, 241Am, 99Tc, 1251, 232U and 210Pb and distribution coefficients (Kd) were determined for these radionuclides using batch type experiments. Sorption isotherms, developed for 137Cs, 85Sr and 99Tc, were linear in each case. Increasing the liquid-to-solid ratio strongly increased uptake of 137Cs and moderately increased uptake of 99Tc. Analysis for anthropogenic radionuclides indicated the presence only of 239/240Pu in the sediment with the highest activity (at the top section of the core) being 0.420 Bq kg(-1). Other anthropogenic radionuclides were below detection limits.     

Geometric properties of the coronal neutral surface

The interrelation between the density inhomogeneity and the magnetic field configuration in the solar corona has been studied. The situation of consistency with the regular cellular magnetic field organization, established by the authors based on polarization data, and helmet-shaped coronal structures has been analyzed. Consistency was found when coronal helmets appeared as projections on the plane of the sky of dense layer folds. It turned out that a dense layer on a regularly deformed neutral surface on a scale of 60° generates coronal shapes typical of solar activity minimum epochs. Threby, a weighty argument for the Molodenskii hypothesis that a dense layer is formed on the neutral surface has been obtained and it has been determined that one can find the 3D geometry of the coronal neutral surface based on modeling the visible shape of coronal helmets. The study of this geometry based on the observed coronal structures in the epoch of minimum and low solar activity indicated that the neutral surface longitudinal deformation scale remains stable and the surface latitudinal amplitude at the corona base reaches 50°–70° latitudes and tends to increase with increasing solar activity. This amplitude decreases as a power function with a variable index close to ?1 with increasing distance from the Sun. In addition, a 10° small-scale deformation of the studied surface with a predominant latitudinal flexure direction has been revealed.     

VTI介质P波非双曲时差分析

本文简要介绍了抚顺市的场地环境和建筑破坏特点，并做了相关分析.若干场地进行的大量地质勘察和试验结果表明，断层活动引起的地基不均匀沉陷是造成该市建筑破坏的主要原因，且断层引起的地基不均匀沉陷不同于一般软基不均匀沉陷.同时，本文亦分析了断层活动与地下采煤造成地壳应力失衡的必然联系.